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Polycyclic Aromatic Hydrocarbons in Agricultural Waterways in Gyeonggi and Gangwon Provinces, Korea (경기 및 강원지역 농업용수 중 PAHs의 모니터링 연구)

  • Kim, Leesun;Park, Byung-Jun;Lee, Sung-Eun
    • Korean Journal of Environmental Biology
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    • v.34 no.3
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    • pp.216-221
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    • 2016
  • Level and distribution of fourteen polycyclic aromatic hydrocarbons (PAHs) in the agricultural water samples collected in the waterways located in Gyeonggi and Gangwon, Korea were determined for monitoring and risk assessment. A simplified, fast but effective extraction and clean-up methods combined with gas chromatography tandem mass spectrometry (GC-MS/MS) was employed to measure the concentration of the target compounds. The extraction of the analytes of interest in water sample (10 mL) was performed with acetonitrile (10 mL) and the salt. To purify the target PAHs, the clean-up procedure was employed with 2 mL tubes of dispersive solid phase extraction. The optimized method was validated with recoveries, method detection limit (MDL), accuracy and precision. Good recoveries for each PAHs at 10 and $25{\mu}g\;L^{-1}$ were achieved (60 to 110%, with RSD <20%) with linearity (>0.99). MDL for all the analytes was achieved with $0.2{\mu}g\;L^{-1}$. GC-MS/MS results showed that concentration of phenanthrene in the water samples from Gyeonggi (20 sites) ranged from 0.82 to $2.56{\mu}g\;L^{-1}$ and from Gangwon (15 sites) ranged from 0.83 to $1.62{\mu}g\;L^{-1}$. Other PAHs were not found in the water samples but the continuous monitoring for these areas were required.

A Model of Four Seasons Mixed Heat Demand Prediction Neural Network for Improving Forecast Rate (예측율 제고를 위한 사계절 혼합형 열수요 예측 신경망 모델)

  • Choi, Seungho;Lee, Jaebok;Kim, Wonho;Hong, Junhee
    • Journal of Energy Engineering
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    • v.28 no.4
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    • pp.82-93
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    • 2019
  • In this study, a new model is proposed to improve the problem of the decline of predict rate of heat demand on a particular date, such as a public holiday for the conventional heat demand forecasting system. The proposed model was the Four Season Mixed Heat Demand Prediction Neural Network Model, which showed an increase in the forecast rate of heat demand, especially for each type of forecast date (weekday/weekend/holiday). The proposed model was selected through the following process. A model with an even error for each type of forecast date in a particular season is selected to form the entire forecast model. To avoid shortening learning time and excessive learning, after each of the four different models that were structurally simplified were learning and a model that showed optimal prediction error was selected through various combinations. The output of the model is the hourly 24-hour heat demand at the forecast date and the total is the daily total heat demand. These forecasts enable efficient heat supply planning and allow the selection and utilization of output values according to their purpose. For daily heat demand forecasts for the proposed model, the overall MAPE improved from 5.3~6.1% for individual models to 5.2% and the forecast for holiday heat demand greatly improved from 4.9~7.9% to 2.9%. The data in this study utilized 34 months of heat demand data from a specific apartment complex provided by the Korea District Heating Corp. (January 2015 to October 2017).

Numerical Study on the Evaporation Characteristics of Biocrude-oil Produced by Fast Pyrolysis (급속열분해를 통하여 생산된 바이오오일 액적의 증발 특성에 관한 수치해석적 연구)

  • Choi, Sang Kyu;Choi, Yeon Seok;Kim, Seock Joon;Han, So Young
    • Applied Chemistry for Engineering
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    • v.27 no.6
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    • pp.646-652
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    • 2016
  • Biomass is regarded as one of the promising energy sources to deal with the depletion of fossil fuels and the global warming issue. Biocrude-oil can be produced through the fast pyrolysis of biomass feedstocks such as wood, crops, agricultural and forestry residues. It has significantly higher viscosity than that of conventional petroleum fuel and contains solid residues, which can lower the spray and atomization characteristics when applied to the burner. In addition, biocrude-oil consists of hundreds of chemical species derived from cellulose, hemicellulose and lignin, and evaporation characteristics of the biocrude-oil droplet are distinct from the conventional fuels. In the present study, a numerical study was performed to investigate the evaporation characteristics of biocrude-oil droplet using a simplified composition of the model biocrude-oil which consists of acetic acid, levoglucosan, phenol, and water. The evaporation characteristics of droplets were compared at various surrounding air temperatures, initial droplet diameters, and ethanol mixing ratios. The evaporation time becomes shorter with increasing air temperature, and it is much sensitive to the air temperature particularly in low temperature ranges. It was also found that the biocrude-oil droplet evaporates faster in cases of the smaller initial droplet diameter and larger ethanol mixing ratio.

Waterquality Characteristics and Ecosystem Health Assessments Using a LEHA Fish Model in Shingu Reservoir (신구저수지의 수질특성 및 LEHA 어류모델을 이용한 생태건강도 평가)

  • Lee, Jae-Yon;Lee, Sang-Jae;Han, Jung-Ho;Lee, Eui-Hang;Choi, Ji-Woong;Hwang, Soon-Jin;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.41 no.spc
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    • pp.42-49
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    • 2008
  • For this study, we collected fishes of four times at the four site during June 2006 ${\sim}$ September 2007. In the result, the tolerance and omnivore species like a Carassius auratus and Pseudorasbora parva were largely dominated over all, and the sensitive species was not appeared at all except S4 in Shingu reservoir. This reservoir was appeared the simplified of trophic guild was shown in Shingu reservoir. Demonstrating that the omnivore species was occupied 78% of whole. According to the water chemistry data set obtained from the Korea Rural community & Agriculture corporation during $2002{\sim}2005$, the Shingu reservoir showed severe eutrophication and water pollution, therefore the increase of primary production and frequent algal blooms had been occurred. On the other hand, ecosystem health of reservoir was appeared "Fair${\sim}$Poor", and we judged that eutrophication and water pollution were due to this. Consequently, we thought that interception of nutrients and organic matters from the farmland and village and management of reservoir would be need, after this.

A Study on the Manure Management and Effectively Utilization (가축배설물 처리.이용 평가 및 효율적 활용방안)

  • Hong, Ji-Hyung
    • Journal of Animal Environmental Science
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    • v.15 no.1
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    • pp.69-74
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    • 2009
  • A survey questionnaire that addressed the issues to manure compost producers and users was prepared. The questionnaire addressed three main topics as follows: 1) types of manure treatment and composting facilities are being operated, 2) quantity of manure compost produced and used, 3) problems experienced in producing and using manure compost. A total of 30 manure compost producers and 10 manure compost users were interviewed. Solid manure are applied to composting. Slurry and wastewater are simplified aeration method to produce liquid fertilizer. The open elongated type manure composting are generally used on manure compost centers jointly used by several farms. The amount of annually manure compost production was most common in the range of $5{\sim}10$ thousand tons per manure compost center. The manure compost utilization and cucumber yield were mostly $6{\sim}15$ tons and $20{\sim}27$ tons per 10a of cucumber farmland, respectively. Environmentally friendly use both of manure compost and chemical fertilizer are recommended for natural recycling agriculture.

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A FEA Study on the Bond Property according to the Rib-Shape of Reinforcement (철근 마디형상에 따른 부착특성에 관한 해석적 연구)

  • Mihn, Joon-Soo;Hong, Geon-Ho
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.2
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    • pp.38-46
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    • 2014
  • Effects of various parameters on bond property between reinforcing bar and concrete are investigated in many researchers, and various study is on going to improve the bond strength. Properties of interface between reinforcement and concrete is important role in bond property. This study analyzed the interfacial bond mechanism between deformed bar and concrete by finite element analysis (FEA) to evaluate the effect of rib shape. The FEA model in this study is simplified 2D plane stress model. The variables of analysis are selected by rib angle, rib height, rib spacing and relative rib area. From the results of analysis, reinforcing bars with rib angle $30{\sim}60^{\circ}$ showed better bond strength than the others. Bond strength ratio following to the rib height is proportionally increased up to the $0.12d_b$, but rib spacing has little effect on bond strength. The results also indicated that relative rib area can be efficiently represented the properties of deformed shape in reinforcing bars, and zigzagged rib height shape showed excellent bond strength increase.

A System Dynamics Model for Negotiation strategy Analysis with North Korea (남북관계와 대북협상전략)

  • 곽상만
    • Korean System Dynamics Review
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    • v.1 no.2
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    • pp.5-31
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    • 2000
  • The summit meeting of the South North Korean leaders was a turning point in the relationships between the two countries. It was followed by the Red-Cross Meeting, Minister-Level Meeting, economic agreements, which have increased the relationship more colorful in both quantities and qualities. However, the half-century period for separation was too long to overcome all the problems by only one event. The two countries have quite different social systems; one politically strong person is governing the North, while many interest groups are involved in political decision making processes in the South. In short, it would take a long time to settle down all the problems residing between the two countries. A system dynamics model is developed to describe the long term dynamics of the relations between the South and North Koreas. As a first attempt, the model focuses only on the diplomatic meeting issues between the South and North. The model aggregates diplomatic issues into 5 categories; economic issues, security issues, infrastructure, cultural issues, and past problems. It assumes that there would not be any dramatic changes between the two countries. It is a conceptual model composed of around 200 variables, and should not be used as a forecast tool. However, it captures most of the logics discussed in the papers and conferences concerning the South and North Korea relations. Many sensitivity studies and Monte Carlo simulations have shown that the simulation results matches with mental models of experts; that is the model can be used as a learning tool or as a secondary opinion until the data required by the model is collected. In order to analyze the current situation, five scenarios are simulated and analyzed; the functional approach, the conditional approach, the balanced approach, the circumstantial approach, and the strategic approach. The functional approach represents that the South makes efforts in the area where the possibility of agreement is high for the next 10 years. The conditional approach is a scenario where the South impose all difficult issues as conditions for resolving other diplomatic issues. The balanced approach is resolving the five issues with the same priorities, while the circumstantial approach is resolving issues which seem to be resolved easily. Finally, another optimum approach has been seek using the system dynamics model developed. The optimum strategy (it is named as the strategic approach) was strikingly different from other four approaches. The optimum strategy is so complicated that no one could find it with mental model(or by just insights). Considering that the system dynamic model used to find the optimum is a simplifind (maybe over simplified) version of the reality, it is concluded that a well designed system dynamics model would be of great help to resolving the complicated diplomatic problems in any kind.

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The Profitability Analysis of BESS Installation with PV Generation under RPS (RPS 제도 하에서의 태양광발전 연계형 배터리시스템 수익분석 방법에 관한 연구)

  • Kim, Chang-Soo;Yoo, Tae-Hyun;Rhee, Chang-Ho
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.107-117
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    • 2017
  • Since South Korea started to apply Renewable Portfolio Standard (RPS) in 2012, there have been huge investment for deploying renewable technologies. Recently, the government determined to incentivize battery energy storage system(BESS) with renewable generations in order to induce the improvement of dispatching capability. In this paper, the annual pattern of PV generation based on actual generation data in South Korea is analyzed and the duration curve of capacity factor is proposed in order to provide the simplified analyzing methodology of present support policy for additional BESS installation for decision maker who is responsible for supply and demand planning. With suggested methodology, the range of appropriate BESS size with respect to the variation of system marginal price(SMP) and renewable energy certificate(REC) price can be derived briefly, and decision makers easily evaluate the effect of support scheme. Current policy for BESS installation support present additional BESS-related installation policy may give incentives to developers partially, however, the dependence between BESS size and benefit components (SMP and REC) can limit the deployment of the various portfolios of the BESS. Therefore, when improving the current policy in future, addressing the dependence between the technical aspects of battery size and the benefit components separately by the technical and economical parts is needed to set the suitable compensation rules for the renewable generation and BESS.

Program Development to Evaluate Permeability Tensor of Fractured Media Using Borehole Televiewer and BIPS Images and an Assessment of Feasibility of the Program on Field Sites (시추공 텔리뷰어 및 BIPS의 영상자료 해석을 통한 파쇄매질의 투수율텐서 계산 프로그램 개발 및 현장 적용성 평가)

  • 구민호;이동우;원경식
    • The Journal of Engineering Geology
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    • v.9 no.3
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    • pp.187-206
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    • 1999
  • A computer program to numerically predict the permeability tensor of fractured rocks is developed using information on discontinuities which Borehole Televiewer and Borehole Image Processing System (BIPS) provide. It uses orientation and thickness of a large number of discontinuities as input data, and calculates relative values of the 9 elements consisting of the permeability tensor by the formulation based on the EPM model, which regards a fractured rock as a homogeneous, anisotropic porous medium. In order to assess feasibility of the program on field sites, the numerically calculated tensor was obtained using BIPS logs and compared to the results of pumping test conducted in the boreholes of the study area. The degree of horizontal anisotropy and the direction of maximum horizontal permeability are 2.8 and $N77^{\circ}CE$, respectively, determined from the pumping test data, while 3.0 and $N63^{\circ}CE$ from the numerical analysis by the developed program. Disagreement between two analyses, especially for the principal direction of anisotropy, seems to be caused by problems in analyzing the pumping test data, in applicability of the EPM model and the cubic law, and in simplified relationship between the crack size and aperture. Aside from these problems, consideration of hydraulic parameters characterizing roughness of cracks and infilling materials seems to be required to improve feasibility of the proposed program. Three-dimensional assessment of its feasibility on field sites can be accomplished by conducting a series of cross-hole packer tests consisting of an injecting well and a monitoring well at close distance.

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A New Organic Modifiers for Anti-Stiction (부착방지를 위한 새로운 표면 개질 물질)

  • Kim, Bong-Hwan;Chun, Kuk-Jin;Lee, Yoon-Sik
    • Journal of Sensor Science and Technology
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    • v.11 no.2
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    • pp.102-110
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    • 2002
  • The chemical and mechanical characteristics of a new surface modifier, dichlorodimethysilane (DDMS, $(CH_3)_3SiCl_2$), for stiction-free polysilicon surfaces are reported. The main strategy is to replace the conventional monoalkyltrichlorosilane(MTS, $RSiCl_3$) such as octadecyltrichlorosilane (ODTS) or 1H,1H,2H,2H-perfluorodecyltrichlorosilane (FDTS) with dialkyldichlorosilane (DDS, $R_2SiCl_2$) with twit short chains, especially DDMS. DDMS, with shorter chains in aprotic media, rapidly deposits on the chemically oxidized polysilicon surface at room temperature and successfully prevents long cantilevers of 3 mm in length from in-use as well as release stiction. DDMS-modified polysilicon surfaces exhibit satisfactory hydrophobicity, long term stability and thermal stability, which are comparable to those of FDTS. DDMS as an alternative to FDTS and ODTS provides a few valuable advantages; ease in handling and long-term storage in solution, low temperature-dependence and low cost. In addition to the new modifier molecule, the simplified process of direct release right after washing the modified surface with isooctane was proposed to cut the processing time.