• Journal of the Korean Ceramic Society
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• v.42 no.7 s.278
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• pp.503-508
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• 2005

A simple and effective method for the synthesis of LiMn$_{2}$O$_{4}$ powder as a cathode material for lithium secondary battery is reported. Micrometer size LiMn$_{2}$O$_{4}$ was prepared by combustion synthesis technique employing initial mixture of l.l LiNO$_{3}$ -1.3Mn-0.7MnO$_{2}$-1NaCl composition. Parametric study of the combustion process including molar ratio of Mn/MnO$_{2}$ and NaCl concentration were carried out under air atmosphere. The combustion products obtained were additionally heat treated at the temperature 900$^{\circ}C$ and the washed by distilled water. The results of charging-discharging characteristics revealed that LiMn$_{2}$O$_{4}$ cell synthesized in the presence of NaCl had a high capacity and much better reversibility than one formed without NaCl An approximate chemical mechanism for LiMn$_{2}$O$_{4}$ formation is proposed.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.7
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• pp.679-688
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• 2010

The major objective of the present study is to extend the applications of inverse analysis to more realistic engineering fields with a complex combustion process rather than the traditional simple heat-transfer problems. In order to do this, the unknown initial mass fractions of $CH_4/O_2$ are estimated from the temperature measurement data by inverse analysis in the practical diffusion-controlled turbulent combustion problem. In order to ensure efficient inverse analysis, the repulsive particle swarm optimization (RPSO) method, which belongs to the class of stochastic evolutionary global optimization methods, is implemented as an inverse solver. Based on this study, it is expected that useful information can be obtained when inverse analysis is used in the diagnosis, design, or optimization of real combustion systems involving unknown parameters.

• Journal of Mechanical Science and Technology
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• v.18 no.8
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• pp.1338-1348
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• 2004

A simplified method that models the deflagration process occurring in closed or vented vessels is described. When combustion occurs within the spherical or cylindrical vessels, the flame moves spherically or segmentally to the vessel periphery. The volume and area of each element along the propagating flame front are calculated by using simple geometrical rules. For instabilities and turbulence resulting in enhanced burning rates, a simple analysis results in reasonable agreement with the experimental pressure transients when two burning rates (a laminar burning rate prior to the onset of instability and an enhanced burning rate) were used. Pressure reduction caused by a vent opening at predetermined pressure was modeled. Parameters examined in the modeling include ignition location, mixture concentration, vented area, and vent opening pressure. It was found that venting was effective in reducing the peak pressure experienced in vessels. The model can be expected to estimate reasonable peak pressures and flame front distances by modeling the enhanced burning rates, that is, turbulent enhancement factor.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.2
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• pp.455-462
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• 1991

This paper present an analysis method of crankshaft of four cylinder internal combustion engine for studying dynamic characteristics of the shaft. For simple analysis, uniform sections of journal, pin and arm parts were assumed. Transfer Matrix Method was used, considering branched part and coordinate transformation part. Natural frequencies, natural modes and transfer functions of crank shaft were investigated based upon the Timosenko beam theory: It was shown that the calculated natural frequencies, modeshapes agree well with the experimental results.

• Magazine of the Korean Society of Agricultural Engineers
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• v.17 no.4
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• pp.3970-3979
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• 1975

On account of the development of the high speed internal combustion engines, several methods for increasing burning velocity has been investigated lately. Installation of a squash area on a cylinder head is one of the simple and practical method to induce the strong tubulant flow of air-fuel mixtureinto a combustion chamber. In this study, a four-stroke engine used for agricultural purpose was tested as an experimental model. A mathematical model of the squash velocity was derived, and also, several characteristics of the squash phenomena during the motoring of the engine used as a modelwere investigated. The results obtained were as follows: (1) Mathematical model of squash velocity was established and cheked (2) Squaash velocity and engine speed were found to be proportional to the squash area while they were inversely proportional to the squash width. (3) Squash velocity and crank angle at which the squash velocity become its peak were influenced by the magnitude of squash clearance: increase of squash clearance made squash velocity reduced acd made the peak of the squash velocity for from the top dead center and (4) When the squash area is divided in small areas baving unit width along the squash section, squash velocity at each unit width was proportional to the magnitude of the squash distance covered by the unit width.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.4
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• pp.80-87
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• 2004

To understand the each performance parameter correlation of flight type liquid-propellant rocket engine for KSR-III(Korea Sounding Rocket-III), the analysis of engine stand-alone combustion test results was carried out. Considering the variation of ablative material combustion chamber caused by erosion, linear regression analysis that ignores oxidizer/fuel ratio effect and two-variable 2nd-order polynomial regression analysis that considers oxidizer/fuel ratio change were performed. It can be described that linear regression analysis is simple and very practical method, and can predict the performance within 1% error inside analyzed region. And two-variable 2nd-order polynomial regression analysis can predict with very high accuracy inside region and shows that KSR-III engine's optimum oxidizer/fuel ratio for thrust(or specific impulse) is 2.22 and that for combustion chamber pressure(or characteristic velocity) is 2.17.

• Fire Science and Engineering
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• v.11 no.1
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• pp.21-35
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• 1997

The natural convection and combined heat transfer induced by fire in a rectangular enclosure is numerically studied. The model for this numerical analysis is partially opened right wall. The solution procedure includes the standard k-$\varepsilon$ model for turbulent flow and the discrete ordinates method (DOM) is used for the calculation of radiative heat transfer equation. In numerical study, SIMPLE algorithm is applied for fluid flow analysis, and the investigations of combustion gas induced by fire is performed by FAST model of HAZARD I program. In this study, numerical simulation on the combined naturnal convection and radiation is carried out in a partial enclosure filled with absorbed-emitted gray media, but is not considered scattering problem. The streamlines, isothermal lines, average radiation intensity and kinetic energy are compared the results of pure convection with those of the combined convection-radiation, the combined heat transfer. Comparing the results of pure convection with those of the combined convection-radiation, the combined heat transfer analysis shows the stronger circulation than those of the pure convection. Three different locations of heat source are considered to observe the effect of heat source location on the heat transfer phenomena. As the results, the circulation and the heat transfer in the left region from heating block are much more influenced than those in the right region. It is also founded that the radiation effect cannot be neglected in analyzing the building in fire. And as the results of combustion gas analysis from FAST model, it is found that O2 concentration is decreased according to time. While CO and CO2 concentration are rapidly increased in the beginning(about 100sec), but slowly decreased from that time on.

• Journal of the Korean Society of Safety
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• v.36 no.2
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• pp.87-93
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• 2021

Modern society shows rapid growth that is different from that of the development of existing technologies. The development of these technologies has led to the tendency of buildings to become dense, large and advancing. Regarding fire hazards, the possibility of large-scale fires causing fatal damage, due to the rapid spread of fire, increases. Therefore, for this reason, fire defense, i.e. detection and fire extinguishing facilities, in buildings are essential and well applied. But there are always limitations to that. Based on this reason, we would like to suggest the introduction of a new concept of a fire safety system. The method presented here is not only to use a single system for fire detection and fire extinguishing systems but to jointly use it in the environment and energy management fields within the building. However, an important step is required before introducing a system of these technologies. The fire extinguishing method proposed by this system is a method of extinguishing by blocking oxygen flowing into the space where the fire occurred. However, a sufficient basis is needed for this system to be applied in practice. Therefore, in this study, we intend to conduct a preliminary experiment to introduce the new concept of fire detection and extinguishing. The experiment used ethanol with a relatively simple combustion reaction and a high possibility of complete combustion. As a result, it was confirmed how the internal values changed during a fire using ethanol. Resultingly, we obtained the internal oxygen concentration and internal environmental changes according to the initial flame size. Lastly, the data accumulated in this study can be used as data for application in an automatic fire extinguishing system.

• Advances in aircraft and spacecraft science
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• v.1 no.3
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• pp.273-289
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• 2014

Accuracy of a reconstruction technique assuming a constant characteristic exhaust velocity ($c^*$) efficiency for reducing hybrid rocket firing test data was examined experimentally. To avoid the difficulty arising from a number of complex chemical equilibrium calculations, a simple approximate expression of theoretical $c^*$ as a function of the oxidizer to fuel ratio (${\xi}$) and the chamber pressure was developed. A series of static firing tests with the same test conditions except burning duration revealed that the error in the calculated fuel consumption decreases with increasing firing duration, showing that the error mainly comes from the ignition and shutdown transients. The present reconstruction technique obtains ${\xi}$ by solving an equation between theoretical and experimental $c^*$ values. A difficulty arises when multiple solutions of ${\xi}$ exists. In the PMMA-LOX combination, a ${\xi}$ range of 0.6 to 1.0 corresponds to this case. The definition of $c^*$ efficiency necessary to be used in this reconstruction technique is different from a $c^*$ efficiency obtained by a general method. Because the $c^*$ efficiency obtained by average chamber pressure and ${\xi}$ includes the $c^*$ loss due to the ${\xi}$ shift, it can be below unity even when the combustion gas keeps complete mixing and chemical equilibrium during the entire period of a firing. Therefore, the $c^*$ efficiency obtained in the present reconstruction technique is superior to the $c^*$ efficiency obtained by the general method to evaluate the degree of completion of the mixing and chemical reaction in the combustion chamber.

• Journal of the korean Society of Automotive Engineers
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• v.7 no.2
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• pp.55-63
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• 1985

This study is focused on deposition process leading to inefficiency and hot corrosion in fossil fuel-fired furnaces and engines. An improved understanding of the coupled thermodynamics, kinetics, and transport processes governing the deposition rate of inorganic oxides and salts from hot gases containing these compounds can suggest more efficient test strategies and control measures. Accordingly, an optical re-evaporation method for accurately measuring the growth rate of deposits under laboratory burner conditions has been developed. To demonstrate the technique and provide data suitable for theoretical model development, a deliberately simple chemical system and target geometry are used. Potassium sulfate(K$_{2}$SO$_{4}$)is introduced into a premixed propane-air flat flame at atmospheric pressure. The growth rate of $K_{2}$SO$_{4}$ on an electrically heated Pt ribbon is measured by re-evaporation technique.