• 제목/요약/키워드: Silver nitrate

검색결과 208건 처리시간 0.032초

문화재 보존·보관용 천연염색지 개발 (제1보) - 천연염색지의 제조 및 열화특성 - (Development of Natural Dyed Korean Traditional Paper for Cultural Properties Conservation and Storage (Part 1) - Manufacture and Aging Properties of Natural Dyed Hanji -)

  • 이상현;유승일;최태호
    • 펄프종이기술
    • /
    • 제47권6호
    • /
    • pp.139-146
    • /
    • 2015
  • We manufactured natural dyed Korean traditional paper (Hanji) for cultural properties conservation and storage with goldthread (Coptis chinensis) and silver nitrate ($AgNO_3$). Goldthread and silver nitrate are known to be an excellent antimicrobial activity. The effect of content of goldthread and silver nitrate on properties of dyed Hanji was investigated. Color strength of dyed Hanji decreased with increasing content of silver nitrate. After-mordanting with 3% silver nitrate improved lightfastness of dyed Hanji. Tannic acid treatment increased K/S value of dyed Hanji. As the amount of the increase in goldthread content was reduced silver nitrate content. Sim-mordanting method was used for simplifying manufacture process. Silver nitrate sim-mordanting method increased K/S value of goldthread than after-mordanting method.

질산은 처리된 실크의 환원 발색 (Cathodic Coloration of Silk Fabric Treated with Silver Nitrate)

  • 정문화;이문철
    • 한국염색가공학회지
    • /
    • 제21권2호
    • /
    • pp.14-21
    • /
    • 2009
  • In this article, silk fabric was treated with silver nitrate ($AgNO_3$) as oxidizing agent, with conditions such as concentration, and treating time, and subsequently treated with reducing agents such as sodium boron hydride ($NaBH_4$) and sodium sulfide ($Na_2S$) to obtain cathodic coloration. After coloration of silk fabric, dyeing properties (K/S value), colorfastnesses such as wash, rubbing and light, and antibacterial activity property were examined. $AgNO_3$ treating time and reducing time did not influence K/S value, whereas the pH value at alkaline region showed a high K/S value of silk fabric. The cathodic colorations of silk fabric with both of reducing agents at $30^{\circ}C$ have excellent color fastnesses. Also the high antibacterial activities were obtained by the treatment with silver nitrate even at 1% of lower concentration.

질산은을 산소 캐리어로 하는 CA막의 제조 (Preparation of Cellulose Acetate Containing Silver Nitrate as Oxygen Carrier)

  • 안필성;이우태
    • 한국산업융합학회 논문집
    • /
    • 제2권2호
    • /
    • pp.83-90
    • /
    • 1999
  • A cellulose acetate membrane containing silver nitrate was prepared by gelatinizing in water at $2^{\circ}C$ after evaporating solvent from the casting solution on a glass plate. Permeation experiments for oxygen and nitrogen were conducted in the ranges of temperature, $5-40^{\circ}C$ and pressure difference, $1-5kg/cm^2$ in order to investigate the effects of temperature and pressure difference on permeation characteristics of the membrane. When the evaporation time was increased, the permeability of oxygen decreased but the separation factor of oxygen against nitrogen increased since a more dense layer was formed on the membrane surface. When the silver nitrate was added, the permeation flux was doubled and the separation factor was improved from 3.0 to 3.3. This implies that silver nitrate acts as an oxygen carrier in the membrane.

  • PDF

들깨유로부터 $\alpha$-Linolenic Acid의 순수분리 (Isolation of Pure $\alpha$-Linolenic Acid from Perilla Seed Oil)

  • 정보영;류수노;허한순
    • 한국식품영양과학회지
    • /
    • 제26권6호
    • /
    • pp.1028-1032
    • /
    • 1997
  • Low-temperature crystallization method silver nitrate-impregnated silicic acid column chromatography were applied for the isolation of pure $\alpha$-linolenic acid(ALA) from perilla seed oil. ALA or 78% in purity(HALA; yield, 83%) was obtained from the fatty acid mixture(ALA, 65.7%) derived from perilla oil by the low-temperature crystallization method, when the mixture was frozen at -8$0^{\circ}C$ for 210min. ALA over 90% in purity(yield, 71%) was also obtained from HALA ethyl esters(ALA, 78%) by the silver nitrate-impregnated silicic acid column(100cm$\times$10cm, i.d.) chromatography. In addition, the silver nitrate-impregnated silicic acid could be semipermanently used for isolation of ALA, because $Ag^{+}$ ion was not dissociated from the stationary phase.

  • PDF

균일 침전법에 의한 은 나노 입자 합성 (Synthesis of Silver Nano-particles by Homogeneous Precipitation)

  • 강원모;김호건
    • 한국분말재료학회지
    • /
    • 제15권5호
    • /
    • pp.386-392
    • /
    • 2008
  • Silver particles were synthesized from silver nitrate by homogeneous precipitation and chemical reduction methods involving the intermediate silver cyanate. The obtained silver particles were characterized by XRD, SEM, TEM, and BET. Urea which could prevent the agglomeration of the reduced silver particles was used as a homogeneous precipitator. The spherical silver particles with average particle diameter of 100 nm were obtained under the optimum reaction conditions. The optimum synthetic conditions were found as follows: reaction temperature $100^{\circ}C$, reaction time 60 min, concentration of silver nitrate $1{\times}10^{-2}$ mol, urea $5{\times}10^{-3}$ mol, and sodium citrate $8.5{\times}10^{-4}$ mol. The phase of obtained silver particles was crystalline state and the silver particles were relatively dense, which had the surface area of $0.7571\;m^{2}/g$.

Dye-silver double staining method for proteins in SDS-polyacrylamide gels using a dye as a silver sensitizer

  • Jin, Li-Tai;Hwang, Sun-Young;Yoo, Gyurng-Soo;Choi, Jung-Kap
    • 대한약학회:학술대회논문집
    • /
    • 대한약학회 2003년도 Proceedings of the Convention of the Pharmaceutical Society of Korea Vol.2-2
    • /
    • pp.145.2-145.2
    • /
    • 2003
  • We have developed a silver staining method using a dye as a silver sensitizer. Dye staining is performed in combination with silver nitrate staining. Dye-silver staining shortens the time of silver staining (~1 hr) and improves the sensitivity better than that of silver diamine stain (1-10 ng) or comparable to that of silver nitrate stain with glutaraldehyde as a silver sensitizer. In dye staining (silver sensitizing step), it has been proven that the sensitivity is at least 4 times comparing with that of CBBR stain and staining time is about 45 min. (omitted)

  • PDF

Polyethersulfone (PES) ultrafiltration (UF) membranes loaded with silver nitrate for bacteria removal

  • Basri, H.;Ismail, A.F.;Aziz, M.
    • Membrane and Water Treatment
    • /
    • 제2권1호
    • /
    • pp.25-37
    • /
    • 2011
  • PES UF membranes containing silver were prepared to impart antibacterial properties for waste water treatment. Asymmetric membranes for antibacterial application were prepared from polyethersulfone (PES) and silver nitrate ($AgNO_3$) (PES/$AgNO_3$=15/2 by weight) solution in N-Methyl-2-pyrrolidone (NMP) via simple wet phase inversion technique. These membranes were characterized by polyvinylpyrrolidone (PVP) and polyethylene glycol (PEG) of different molecular weights (1000 ppm in water) at room temperature and on operating pressure of 5 bars. It was observed that the water flux of PES-$AgNO_3$ membrane is slightly lower than virgin PES but still increased linearly with the increment of pressure applied. The morphology of the resulting membranes was examined using Field-Emission Scanning Electron Microscope (FESEM) coupled with Energy Dispersive Spectroscopy (EDS). Elemental analysis using EDS proved that silver is successfully loaded on the membrane surfaces. Due to the success of loading silver on membrane surfaces, antibacterial activities were evaluated via agar diffusion method against Escherichia coli (E.coli) and Staphylococcus aureus (S.aureus) culture. By incorporating 2 wt% of silver nitrate, PES-$AgNO_3$ showed significant inhibition ring on both E.coli and S.aureus. Filtration of E.coli solution (OD 0.31) showed satisfactory rejection data with ~100% inhibition growth after 24 hours incubation at $37^{\circ}C$. Resultant membranes also exhibit better tensile strength (compared to virgin PES) up to 71% may be due to the suggested interactions. The residual silver during fabrication was measured using ICP-MS and result showed that the residual silver content of PES-$AgNO_3$ membrane was only ~1% of the original silver added in the polymer solution. These studies have shown that PES-$AgNO_3$ UF membranes are potential in improving the filtration in water treatment.

콜로이드 Ag 나노입자 합성시 계면활성제의 영향 (Effect of Surfactant on Synthesis of Colloidal Ag Nanoparticles)

  • 이종국;최남규;서동석
    • 한국재료학회지
    • /
    • 제15권5호
    • /
    • pp.340-347
    • /
    • 2005
  • Silver nanoparticles were synthesized by chemical reduction method from aqueous silver nitrate solution ana hydrazine as a reduction agent. The morphology, particle size and shape were dependent on the mixing method, reaction temperature and time, molar ratio of hydrazine and silver nitrate, the kind of surfactant, and the addition of surfactant. The stability of the colloidal silver was achieved by the adsorption of surfactant molecules onto the particle. Silver nanoparticles have a characteristic absorption maximum at 430 nm under UV irradiation. It was found that the colloid was nanometer m size and formed very stable dispersion of silver. The Ag nanoparticles obtained showed the spherical shape with the size range of 10-30 nm.

질산염이 Saccharomyces cerevisiae의 발효작용에 미치는 영향

  • 김상준
    • 한국미생물생명공학회:학술대회논문집
    • /
    • 한국미생물생명공학회 1979년도 춘계학술대회
    • /
    • pp.115.3-115
    • /
    • 1979
  • 중금속을 함유한 13종의 질산염을 명 농도별로 첨가하여 주정효모 Saccharomyces cerevisine의 주정생산과 발효작용에 미치는 영향을 조사하였다. 1. 일반적으로 중금속을 함유한 질산염은 그 첨가량이 0.0001mo1. 보다 고농도일수록 Saccharo-myces cerevisiae의 발효작용을 점차 억제하였다. 2. Nickel nitrate, chromium nitrate들의 0.0001 moi.의 첨가는 Saccharomyces cerevisiae의 alcohol 발효작용을 약간촉진시켰다. 3. Cadmium nitrate 0.001mo1. 이상, cupric nit-rate, nickel nitrate, cobalt nitrate 0.01mo1. 이상, 그리고 silver nitrate, mercurous nitrate, manganese nitrate, zinc nitrate, lead nitrate, chromiun nitrate, ferric nitrate, bismuth nitrate 0.1mol. 의 농도에서 Saccharomyces cerevisiae 의 발효작용은 완전히 조지되었다.

  • PDF

열에 노출된 종이에 유류된 잠재지문 현출에 관한 연구 (Development of Fingerprints Deposited on Papers Found at a Fire Scene)

  • 김채원;김연지;서윤희;유제설
    • 한국화재소방학회논문지
    • /
    • 제32권3호
    • /
    • pp.88-94
    • /
    • 2018
  • 화재현장에서 발견되는 종이 증거의 지문은 용의자 신원에 대한 단서를 찾을 수 있는 중요한 증거이다. 하지만 화재현장의 온도는 매우 높기 때문에 종이의 잠재지문이 손상될 가능성이 높아 지문 현출에 어려움이 따른다. 이에 따라 본 연구는 고온에 노출된 종이에 남겨진 잠재지문을 현출하기 위해 다공성 표면에 적용하는 시약인 닌히드린, 1,8 - Diazafluoren - 9 - One (DFO), 질산은을 사용하여 그 효과성을 비교하였다. 건열프레스기를 사용하여 종이가 탄화되지 않을 정도의 온도조건인 $200^{\circ}C$에서 노출시간을 달리하여 종이에 열을 가하였다. 닌히드린은 모든 조건에서 현출력이 떨어졌으며 DFO는 노출시간이 길어질수록 감도가 좋지 않았다. 질산은은 모든 조건에서 융선 및 특징점을 확인할 수 있는 상태의 지문이 현출되었다. 따라서 화재 현장에서 수집한 종이에서 지문을 현출하고자 할 때는 아미노산 반응 시약보다 염화물 반응 시약인 질산은을 사용해볼 것을 권장한다.