• Transactions on Electrical and Electronic Materials
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• v.10 no.1
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• pp.9-15
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• 2009

There is a growing demand for a high voltage silicone rubber composite with high mechanical property and high electrical property. The effect of modified cross-linking agent on the mechanical, electrical properties, and short-circuit test performance of silicone rubber insulators have been investigated. To use base polymer, the various silicone polymers were prepared by the equilibrium polymerization. Aluminum trihydrate surface was treated by vinyl silane. Liquid silicone rubber nanocomposite was prepared from the compounding of VPMPS, HPDMS, catalyst, and alumina trihydrate modified with 1,3,5-trivinyl-l,3,5-trimethylcyclotrisiloxane. The mechanical property and electrical property for insulation materials were measured, indicating the high tensile strength and the good short-circuit property.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.623-624
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• 2007

This work examines the effects of swelling MI type HVDC cable oil on the semiconductive silicone rubber and silicone rubber as used in accessories for application on outdoor termination (EBA) slip on sleeve. The behavior of volume resistivity is monitored as a function of the amount of cable oil diffused into the material. Resistivities of semiconductive silicone samples up to the typical insulator range (${\sim}10^{10}{\Omega}-cm$) are observed as a consequence of swelling due to the presence of the diffused oil. The measured volume resistivities of the oil-impregnated semiconductive silicone rubber are compared to desired value as function of stress relief cone.

• Transactions on Electrical and Electronic Materials
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• v.7 no.3
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• pp.134-140
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• 2006

The effect of surface treatment of fillers on the mechanical, electrical properties, and tracking performance of silicone rubber insulators have been investigated. For base polymer, $\alpha,\;\omega$) vinyl poly(dimethyl-methylphenyl) siloxane(VPMPS) containing dimethyl siloxane and methylphenyl siloxane was prepared by the equilibrium polymerization. High voltage silicone rubber composites(HVSRC) were prepared from VPMPS, nano-silica, and alumina trihydrate (ATH) modified by various coupling agents. Bound rubber of uncured silicone rubber, cross-linking density of the vulcanizate as well as the mechanical, electrical properties, and tracking performance were measured.

• Elastomers and Composites
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• v.33 no.1
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• pp.37-43
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• 1998

The permeation of gas through polymer membrane at temperatures above its glass transition, generally occurs by a solution-diffusion mechanism. This mechanism is performed by the affinity difference between polymeric materials and gas molecules, and various technologies, such as copolymerization, impregnation and so on, have been researched to improve the affinity of polymeric material for the gases. In this study, permeability and selectivity for some gases were obtained from steady-state rates of gas permeation through silicone rubber membrane which is prepared by supercritical fluid extraction method. The permeability was measured by the volumetric method proposed by Barrer. Permeability was increased generally with temperature and permeation pressure. Silicone rubber membrane shows a higher permeability to $CO_2$ than to $O_2$, $N_2$. This results probably reflect the relatively high solubility of CO_2 in silicone rubber membrane, which is due to the affinity of $CO_2$ molecules. Since separation powers of $CO_2/N_2$, $CO_2/O_2$ were more than 200, and 100, respectively, it is able to separate $CO_2$ from the air, and the optimum temperature and pres-sure was 328.15 K, 60 cmHg respectively. In future, it is possible that the silicone rubber membrane can be used for separation or concentration of $CO_2$ through experiment for mixed gas separation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.11
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• pp.1001-1007
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• 2003

The silicone fluids have been generally used as processing agent in silicone rubber(SIR) compounding. The addition of hydroxy silicone (HS) fluids to SIR for insulator housing material is required to meet the good electrical performance and the good processability. In this study, SIR with HS fluids was evaluated to investigate how the kinds of them affect insulation properties. The contact angle of the virgin sample of 40-HS SIR was low and its recovery rate was also slow. The recovery rate of 50-HS SIR was the highest being decreased with the viscosity increase of HS fluids. The tracking resistances and the corona aging resistance of 70-HS SIR and 1,040-HS SIR were excellent Tracking resistance depended largely on heat resistance of silicone fluids. But arc resistance didn't depend merely on the kind of silicone fluids.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.18 no.8
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• pp.696-701
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• 2005

This paper was investigated the changes of surface properties of high-temperature-vulcanized (HTV) semiconductive silicone rubber due to oxygen plasma discharge. The modifications produced on the silicone rubber surface by oxygen plasma were accessed using Fourier transform infrared spectroscopy(FTIR), X-ray photoelectron spectroscopy(XPS), contact angle and Surface Roughness Tester. The results of the chemical analysis Showed that C-H bonds were broken due to plasma discharge and Silica-like bonds (SiOx, x=$3\~4$) increased. It is thought that the above changes lead to the increase of surface energy of high-temperature-vulcanized (HTV) semiconductive silicone rubber also, Surface roughness was increased with cleavage of side-chains and oxidation process, it confirmed change as the SEM. The micromorphology of surface and hydrophobicity due to plasma discharge based on our results were discussed.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.46-49
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• 2003

Microsystem technology (MST) which originated from semiconductor processes has been widely spreaded into tile other industry such as sensors, micro fluidics and displays. The MST, however. has been troubled in spreading with its high cost and material limitations. So, in this paper, new process for micromolding technology using silicone rubber mold was introduced. Silicone rubber mold, which was fabricated by vacuum casting. can be transferred a master pattern to a final product with the same shape but different materials. In order to verify the possibility of application of silicone rubber mold to the MST, its transferability was evaluated. and then it applied to the fabrications of polishing pad and PDP barrier ribs.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.8
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• pp.1380-1387
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• 2003

Microsystem technology (MST) which originated from semiconductor processes has been widely spreaded into the other industry such as sensors, micro fluidics and displays. The MST, however, has been troubled in spreading with its high cost and material limitations. So, in this paper, new process for micromolding technology using silicone rubber mold was introduced. Silicone rubber mold, which was fabricated by vacuum casting, can be transferred a master pattern to a final product with the same shape but different materials. In order to verify the possibility of application of silicone rubber mold to the MST, its transferability was evaluated, and then it applied to the fabrications of polishing pad and PDP barrier ribs.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.258-261
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• 2001

In this paper, aging characteristics of silicone rubber used for outdoor insulation have been investigated with regards to salt fog condition and heat aging effect. We look over the change of properties of silicone rubber in salt fog chamber with average leakage current monitoring for observing the transformation of surface degradation properties of silicone rubber with different ATH(alumina trihydrate, $Al_2O_3{\cdot}3H_2O$) filler contents. Surface resistivity, SEM(Scanning Electro Microscope) were measured.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.560-564
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• 1999

In general, the main dielectric materials for EHV electric appliances were epoxy, EPDM and Silicone rubber. The Silicone rubber has been rosed so many among them in EHV appliances in the worldwide, especially in Europe and North America. The reason why it is very stable in the thermal, mechanical and electrical environment. Therefore it is still becoming increasingly widespread in the application of the EHV appliances as a main dielectric material. On this study, investigated about real appliances and tested on basic properties of the Silicone rubber compared to organic dielectric material that is EPDM. At the result, the Silicone rubber is more dominant as main dielectric material for EHV appliances than any other organic polymers.