• Title/Summary/Keyword: Silicone resin

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A Study on Resin Flow to Make a Replica Using a Silicone Mold

  • Bae, Kum-Soo;Rhee, Sang-Yong;Kim, Young-Baek
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.8 no.2
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    • pp.94-99
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    • 2008
  • The replica of silicone mold which can produce the test samples and the market-displayable products without making expensive metallic patterns is advantageous because it incurs less cost than the ordinary method that manufactures the products from the metallic patterns. However, the production of the products using silicone mold should require a technician with professional knowledge about the metallic patterns every time. Thus we tried to judge whether a forming analysis software for iron molding can be applied to silicon molding in this paper. In other words, this paper suggests a method to use a computer simulator from the designing step of the silicone mold, which is the most important part in making replica using simple silicone molds to the step of pouring the cast. The paper shows that if the know-how of a professional worker is provided in advance, an amateur worker can easily produce silicone molds of the best quality, the defective rate of the products will be decreased, and the replica will have a more complete status. By doing so, we suggested a possibility for reducing the delivery time at the production sites and for improving the product quality.

BOND STRENGTH OF VARIOUS RESINS TO DENTURE TEETH BY SURFACE TREATMENT (의치상 레진치아의 표면처리에 따른 수복레진과의 결합강도에 대하여)

  • Vang, Mong-Sook
    • The Journal of Korean Academy of Prosthodontics
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    • v.37 no.1
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    • pp.42-50
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    • 1999
  • This study investigated the effects of surface treatment for filling resins on the surface texture of denture resin teeth by the use of scanning electron microscope. This study also evaluated the bond strength of filling resins to denture resin teeth. The denture resin teeth in this study was Endura Posterio(Shofu Co., Japan). The ailing resins used were Coe-cure(Coe Co., USA), Vertex RS (Dentimax Ziest, Holland), and light cured resin Z-100(3M Co., USA). The test sample were divided into 3 parts. Group 1 : Sandblasted with $50{\mu}m$ Aluminum oxide. Group 2 : Treated with #60 silicone carbide paper Group 3 : Treated with monomer brush application. Control Group : No Treatment. The results were as follows ; 1. The bond strength of filling resins to denture resin teeth is increased by surface treatment. 2. Regardless of the filling resins, there was a significant difference with # 60 silicone carbide paper treated group. 3. Regardless of each group, the bond strength according to the filling resins were decreased in the following order: Vertex RS, Coe-cure and Z-100.

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EFFECT OF DENTURE BASE SURFACE PRETREATMENTS ON THE TENSILE BOND STRENGTH BETWEEN A RESILIENT LINER AND A PROCESSED DENTURE BASE RESIN (의치상 레진의 표면 전처리가 연성 이장재와의 인장결합강도에 미치는 영향)

  • Yoon, Min-Chul;Jeong, Chang-Mo;Jeon, Young-Chan
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.5
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    • pp.621-632
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    • 2007
  • Statement of problem: The failure of adhesion between the resilient denture liner and the denture base is a serious problem in clinic. Purpose: The purpose of this study was to evaluate the effect of denture base resin surface pretreatments (mechanical and/or chemical) on the tensile bond strength between a resilient liner and processed denture resin. Material and method. Acrylic-based resilient liners (Soft liner; GC co., Japan & Coe-Soft; GC America Inc. USA) and silicone-based resilient liners (Mucosoft, Parkell Inc., USA & Dentusil; Bosworth co., USA) were used. Specimens in each soft lining material were divided two groups with or without mechanical pretreatment. Each denture base specimen received 1 of 4 chemical pretreatments including: (1) no treatment, (2) 30-s acetone treatment, (3) 15-s methylene chloride treatment, (4) 180-s methyl methacrylate treatment. All specimens were thermocycled and placed under tension until failure in a universal testing machine. Results: 1. Silicone-based resilient liners exhibited significantly higher tensile bond strengths than acrylic-based resilient liners (P<.05). 2. Grinding the denture base resin improved tensile bond strengths of silicone-based resilient liners, but reduced tensile bond strengths of acrylic-based resilient liners (P<.05). 3. In acrylic-based resilient liners, treating with acetone significantly increased the bond strength of Soft liner and treating with methyl methacrylate significantly increased the bond strength of Coe-Soft (P<.05). However they were not effective compared to silicone-based resilient liner. 4. In silicone-based resilient liners, treating with all chemical etchants significantly increased the bond strength of Mucosoft to denture base, and treating with methylene chloride and methyl methacrylate increased the bond strength of Dentusil to denture base (P<.05). Conclusion: Although chemical and mechanical pretreatments were not effective on tensile bond strength of acrylic-based resilent liner to denture base, treating the denture base resin surface with appropriate chemical etchants after mechanical pretreatment significantly increased the tensile bond strength of silicone-based resilient liner to denture base.

Synthesis of Silicone Softner for Permanent Press Finish and Its Characterization (Permanent Press 가공용 실리콘 유연제의 합성과 그의 특성화)

  • Park, Chang-Hwan;Kim, Seung-Jin;Kim, Young-Geun;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.1
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    • pp.29-34
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    • 1995
  • Silicone softner(SSN-3) for permanent press(PP) finish was prepared by blending beef tallow hardened oil for Improving softness, water, the emulsion, which was synthesized from pentaerythritol monostearate as a softening component and silicone oil KF-96 as a lubricating component. The prepared SSN-3 and the PP finishing resin were applied to PP finishing cotton broad cloth and P/C gingham samples using one bath method. The properties such as crease recovery, tear strength, bending resistance test were tested. The samples treated with SSN-3 and PP finishing resin have improved properties, compared with nontreated samples, those treated only with PP finishing resin, those treated with commercial PP finishing softners and PP finishing resin. Also from the bending resistance test, the two kinds of fabric samples treated with SSN-3 of 3% showed grade 5 and these were good enough in feeling.

Effect of Capsaicin and Silicone Resin Treatment on Inhibition of Thermal Oxidation in Frying Oil (Capsaicin과 규소수지 처리가 튀김유의 가열산화 억제에 미치는 영향)

  • 이미숙;이근보
    • The Korean Journal of Food And Nutrition
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    • v.13 no.6
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    • pp.534-538
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    • 2000
  • Sample frying oil was manufactured from simple mixing treatment of capsicum. butter flavor and silicone resin. the amount were 0.20, 0.15% ($\omega$/$\omega$) and 10 rpm in soybean oil, respectively. This frying oil was confirmed to improving of heat stability as well as removal effect of meat flavor. Frying oil obtained from treatment of capsicum and silicone resin was appeared, acid value and smoke point were 0.301, 232$\^{C}$, than its value in the non-treated soybean oil were 0.385. 220$\^{C}$, respectively, in the case of continuous frying at 185$\pm$2$\^{C}$. These effects were likely to according both anti-oxidation effect of capsicum and inhibition of free fatty acids and smoke production from anti-expansion of surface area in frying oil. Meat flavor and burnt flavor of oil in the frying oil and fried foods were weakened by treating of butter flavor(0.15%, $\omega$/$\omega$), this effect will be produced to new type\`s frying oil product.

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Buckling Formation on Steel-Based Solar Cell Induced by Silicone Resin Coat and Its Improvement on Performance Efficiency (실리콘 고분자 수지의 버클링을 통한 스틸기반 태양전지의 효율 향상)

  • Park, Young Jun;Oh, Kyeongseok
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.519-524
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    • 2019
  • Even though stainless steel foil is not a highly efficient material for film-type solar cell, it has strong passivation capability without additional process. In this study, silicone resin was employed during a-Si:H thin film solar cell fabrication for the purpose of planarization and electrical insulation. In the first stage of process, silicone resin was coat onto the stainless steel (STS) using spin coater with thickness of $2{\sim}3{\mu}m$ and followed by aluminum deposition using ion beam application. Unexpectedly buckling was formed during aluminum deposition process. After subsequent fabrication processes, solar cell performance was evaluated. In voltage-current data, slight increase of cell performance was obtained and interpreted by the increase of light scattering.

Preparation and Properties of Flame Retardant Epoxy Resins Containing Phosphorous/Silicone Components (인/실리콘 함유 난연성 에폭시 수지의 제조 및 물성)

  • Kim, Chang-Heon;Ha, Do-Young;Lee, Young Hee;Lee, Dong-Jin;Kim, Han-Do
    • Clean Technology
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    • v.23 no.4
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    • pp.378-387
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    • 2017
  • To obtain epoxy resin with permanently attached flame-retardant groups, phosphorus compound containing di-hydroxyl group [10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ] and silicone compound containing di-hydroxyl group (polydimethylsiloxane, hydroxyl terminated, PDMS) were reacted with uncured epoxy prepolymer (diglycidyl ether of bisphenol A, DGEBA) and then cured using 4,4-diaminodiphenylmethane (DDM) as a crosslinking agent. The properties of the resulting epoxy materials were characterized using Fourier transform infrared (FTIR) spectrometer, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), limiting oxygen index (LOI) test/vertical burning test (UL 94-V test), tensile properties test and impact test. This study examined the effect of phosphorus/silicone compound contents on the thermal/mechanical properties and flame retardancy of cured epoxy resins containing phosphorus and silicone compounds. It was found that the thermal/mechanical properties of epoxy resins containing phosphorus and silicone components were higher than those of simple epoxy resin. The flame-retardancy (LOI: 29.9 ~ 31.8% and UL 94-V: V-0) of all samples containing phosphorus compound and phosphrous compound/silicone compound was found to be passed the flame-retardant requirements (LOI: > 30%, UL 94-V: V-0) of LOI and vertical burning tests. However, the flame-retardancy (LOI: 21.4% and UL 94-V: no rating) of simple epoxy resin was found to be failed the flame-retardant requirements.

Synthesis of Modified Silane Acrylic Resins and Their Physical Properties as Weather-Resistant Coatings (실란 변성아크릴수지의 합성과 고내후성 실리콘/아크릴수지 도료의 도막물성)

  • Park, Hong-Soo;Hong, Seok-Young;Kim, Song-Hyoung;Yoo, Gyu-Yeol;Ahn, Sung-Hwan;Hahm, Hyun-Sik;Kim, Seong-Kil
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.1
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    • pp.10-22
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    • 2007
  • To prepare weather-resistant silicone/acrylic resin coatings for an architectural purpose, tetrapolymers were synthesized by a radical polymerization. 3-Methacryloxypropyltrimethoxysilane (MPTS) as a silicone monomer and n-butyl acrylate, methyl methacrylate, and n-butyl methacrylate as acrylic monomers were used. The compositions of monomers were adjusted to fix the glass transition temperature of acrylic polymer for $20^{\circ}C$. The composition of MPTS in the synthesized polymer were varied from 10 wt% to 30 wt%. On the basis of synthesized resin amber paints were prepared and their physical properties and effects for weatherability were examined. The presence of MPTS in silicone/acrylic resins generally resulted in low molecular weight and broad molecular weight distribution, and also lowered the viscosity of the copolymers. The coated films prepared from these resins showed good and balanced properties in general. Adhesion to the substrate was outstanding in particular. Weatherability tests were carried out in three different types such as outdoor exposure, QUV, and SWO. The test results showed that the silicone/acrylic resins containing 30 wt% of MPTS had weather-resistant properties.

Wettability of denture relining materials under water storage over time

  • Jin, Na-Young;Lee, Ho-Rim;Lee, Hee-Su;Pae, Ahran
    • The Journal of Advanced Prosthodontics
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    • v.1 no.1
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    • pp.1-5
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    • 2009
  • STATEMENT OF PROBLEM. Poor wettability of denture relining materials may lead to retention problems and patient discomfort. PURPOSE. Purpose of this study is to compare and evaluate wettability of nine denture relining materials using contact angle measurements under air and water storage over time. MATERIAL AND METHODS. Nine denture relining materials were investigated in this study. Two heat-curing polymethyl-methacrylate(PMMA) denture base materials: Vertex RS, Lang, one self-curing polyethyl-methacrylate(PEMA) chairside reline resin: Rebase II, six silicone relining materials: Mucopren soft, Mucosoft, $Mollosil^{{R}}$ plus, Sofreliner Touch, GC $Reline^{TM}$ Ultrasoft, Silagum automix comfort were used in this experiment. Contact angles were measured using high-resolution drop shape analysis system(DSA 10-MK2, KRUESS, Germany) under three conditions(in air after setting, 1 hour water storage, and 24 hours water storage). Nine materials were classified into three groups according to material composition(Group 1: PMMA, Group 2: PEMA, Group 3: Silicone). Mean values of contact angles were compared using independent samples t-test and one-way ANOVA, followed by a Scheffe's post hoc analysis($\alpha$=0.01). RESULTS. Contact angles of materials tested after air and water storage increased in the following order: Group 1(PMMA), Group 2(PEMA), Group 3(Silicone). Heat-cured acrylic denture base resins had more wettability than silicone relining materials. Lang had the highest wettability after 24 hours of water storage. Silicone relining materials had lower wettability due to their hydrophobicity. Wettability of all denture relining materials, except Rebase II and $Mollosil^{{R}}$ plus, increased after 24 hours of water storage. CONCLUSIONS. Conventional heat-cured resin showed the highest wettability, therefore, it can be suggested that heat-cured acrylic resin is material of choice for denture relining materials.