• 제목/요약/키워드: Silica particle

검색결과 502건 처리시간 0.028초

고순도 압축공기 제조시스템의 흡착식 Dryer에서 에너지절감을 위한 운전방법에 관한 연구 (A Study on Operating Method to Save Energy from the Adsorption Dryer in the Process of Purifying Compressed Air)

  • 강석완;장성호;김현준;김성수;이영욱
    • 산업경영시스템학회지
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    • 제39권3호
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    • pp.180-191
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    • 2016
  • Optimizing energy usage for maximum efficiency is an essential goal for manufacturing plants in every industrial manufacturing sector. The generation and distribution of purifying compressed air is a large expense incurred in practically all manufacturing processes. Not only is the generation and treatment expensive equipment of compressed air, but frequent maintenance and effective operation is also required. As a plant's compressed air system is often an integral part of the production process, it needs to be reliable, efficient, and easy to be maintain. In this paper, we study to find operating method to save energy from the adsorption dryer in the process of purifying compressed air, which is required for a clean room production site in "A" company. The compressed air passes through a pressure vessel with two "towers" filled with a material such as activated alumina, silica gel, molecular sieve or other desiccant material. This desiccant material attracts the water from the compressed air via adsorption. As the water clings to the desiccant, the desiccant particle becomes saturated. Therefore, Adsorption dryer is an extremely significant facility which removes the moisture in the air $70^{\circ}C$ below the dew point temperature while using a lot of energy. Also, the energy consumption of the adsorption dryer can be varied by various operating conditions (time, pressure, temperature, etc). Therefore, based on existing operating experiments, we have searched operating condition to maximize energy saving by changing operating conditions of the facility. However, due to a short experiment period (from September to October), further research will be focused on considering seasonality.

정전기분광분석방법에 의한 알파입자비적밀도의 이론적 계산연구 (Theoretical Calculation on Alpha Track Density by Using an Electrostatic Ion Spectrometer)

  • 윤석철;하정우
    • Journal of Radiation Protection and Research
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    • 제18권1호
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    • pp.25-35
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    • 1993
  • 알파비적밀도의 이론계산방법을 개발하기 위하여 정전기방법을 이용한 분광계를 특별히 설계 제작하였다. 이 정전기분광계를 사용하여 라돈의 첫째딸핵종인 Po-218의 이온에 대해 $0.07{\sim}5.0cm^2/V\;sec$ 범위의 이동도스펙트럼을 측정하였다. 이 측정은 실리카겔, 활성탄, 분자구조의 시브필터를 통과한 탈입자가스를 사용하는 라돈쳄버내에서 수행되었다. 제작된 정전기분광계를 사용하여 쳄버내에서 새로 생성된 Po-218이온의 이동도는 $1.92cm^2/V\;s$인 것으로 측정되었다. 알파비적밀도의 이론적계산방법에 의해 얻어진 결과를 측정에 의해 얻어진 결과와 비교하였으며 측정된 스펙트럼에 관계된 불확실도를 분석하였다. 이론계산방법에 의해 얻어진 알파비적밀도와 측정된 값과의 차이에 대한 이유는 이론계산방법에서 이온의 라돈 쳄버에서의 벽제거효과를 고려하지 않았기 때문인 것으로 밝혀졌다.

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LPS - SiC 세라믹스의 굽힘강도 특성에 미치는 미시조직 영향 (Microstructure Effects on Bending Strength Characteristics of LPS - SiC Ceramic)

  • 윤한기;정헌채
    • 한국해양공학회지
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    • 제20권5호
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    • pp.77-81
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    • 2006
  • In this study, monolithic liquid phase sintered SiC (LPS-SiC) was made by the hot pressing method with nano-SiC powder, whose particle size is 30 nm and less on the average. Alumina ($Al_{2}O_{3}$), yttria ($Y_{2}O_{3}$), and silica ($S_{i}O_{2}$) were used for sintering additives. To investigate the effects of $S_{i}O_{2}$, the $Al_{2}O_{3}/Y_{2}O_{3}$ composition was fixed and the ratio of $S_{i}O_{2}$ was changed, with seven different ratios tested. And to investigate the effects of the sintering temperature, the sintering temperature was changed, with $1760^{\circ}C,\;1780_{\circ}C$, and $1800_{\circ}C$ being used with a $S_{i}O_{2}$ ratio of 3 wt%. The materials were sintered for 1 hour at $1760^{\circ}C,\;1780^{\circ}C$ and $1800^{\circ}C$ under a pressure of 20 MPa. The effects on sintering from the sintering system used, as well as from the composition of the sintering additives, were investigated by density measurements. Mechanical properties, such as flexural strength, were investigated to ensure the optimum conditions for a matrix of SiCf/SiC composites. Sintered densityand the flexural strength of fabricated LPS-SiC increased with an increase in sintering temperature. Particularly, the relative density of a sintered body at $1800^{\circ}C$ with a non-content of $S_{i}O_{2}$, a specimen of AYSO-1800, was 95%. Also, flexural strength was about 750MPa.

산업 재해의 안전관리를 위한 열경화에 의한 304 스테인레스 스틸에 대한 폴리우레탄 도료의 영향 (Effects of Polyurethane Coatings on 304 Stainless Steel Formed by Thermoset for Safety Management of Industrial Disaster)

  • 김기준;이주엽
    • 한국응용과학기술학회지
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    • 제29권2호
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    • pp.317-322
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    • 2012
  • 미세 조직은 SEM, FT-IR 스펙트라, 인장특성, 그리고 [NCO]/[OH]의 mole %, 입도분석에 의해 측정하였다. 친환경적인 NATM에 관한 관심이 고조됨에 따라 스테인레스같은 금속코팅에 더욱더 중요한 열경화 무용제 수지를 합성 하였다. 이 수지는 일반적 도료와 비교하여 매우 강도가 강하고 내구성이 매우 좋다. 폴리우레탄 수지는 폴리올, IPDI, 실리콘 계면활성제, 촉매, 충전제로 구성된다. 폴리우레탄 화합물은 가교제가 첨가된 수지가 가교제가 첨가되지 않은 수지보다 물성이 우수함을 나타냈다. 견고한 폴리우레탄 도료의 기계적 특성은 [NCO]/[OH]와 가교제가 증가함에 따라 강도가 증가하였다. 합성한 도료의 물성 향상은 스테인레스 산업뿐만 아니라 다양한 산업에서 폴리우레탄 고분자 수지가 강구조물의 보수보강에 많은 응용이 기대된다.

유동층 화학기상증착(FB-CVD)으로 제조한 광촉매 박막증착 비드의 조업변수에 따른 반응성 (Photocatalytic Activities of Titania Deposited Beads by FB-CVD as Operation Variables)

  • 임남윤;이승용;박재현;곽지니;박해웅
    • Korean Chemical Engineering Research
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    • 제44권3호
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    • pp.300-306
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    • 2006
  • 유동층 화학기상 증착법으로 모재의 종류, 유동층 반응기 내부의 온도, 압력 그리고 산소유량 등의 여러 가지 조업변수들을 변화시키며 광촉매가 박막증착된 비드를 제조하였고 제조된 광촉매코팅비드의 광반응성 측정을 통해 최적조업조건을 결정하였다. 제조한 광촉매에 대하여 FE-SEM, XRD 그리고 XPS 분석을 수행하였고, 광반응성은 아세트알데히드의 분해능력을 측정하여 분석하였다. 광촉매가 박막증착된 비드의 FE-SEM 분석 결과 글라스 비드 위의 티타니아는 비교적 매끄럽게 증착되었고, 실리카 위의 티타니아는 입자의 형태로 증착되었으며 알루미나 위의 티타니아는 결정상을 이루며 증착됨을 확인할 수 있었다. 그리고 광반응성 측정 결과 알루미나를 모재로 사용하여 온도는 $600^{\circ}C$, 압력은 5 torr에서 제조하였을 때 아세트알데히드 광분해 반응에서 가장 높은 광반응성을 보였고, 산소 유량은 큰 영향을 미치지 않는 것으로 나타났다.

반경질 폴리우레탄 발포체의 물성에 대한 사슬 연장제와 무기 충전제의 영향 (Effects of Chain Extender and Inorganic Filler on the Properties of Semi-Rigid Polyurethane Foams)

  • 차국찬;송점식;이석민;문무성
    • 폴리머
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    • 제34권1호
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    • pp.8-13
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    • 2010
  • 발포체의 물성은 발포체의 밀도, 사용된 폴리머의 기계적 물성과 열린 셀의 함량, 셀 크기, 셀 크기 분포, 셀 형태, 스킨층의 두께 등을 포함하는 셀 구조에 의존하며, 이러한 발포체의 밀도는 사용된 폴리머의 종류와 가교제의 농도 그리고 가공 기술 및 가공 조건과 같은 다양한 원료 물질과 가교 조건에 영향을 받는다. 본 연구에서는 폴리에스터 폴리올, MDI, 아민계 촉매, 틴계 촉매, 실리콘 유화제, 물을 기본 폴리우레탄 발포체의 조성으로 설정하였으며, 발포체에 있어서 stiff-chain 요소인 사슬 연장제의 첨가에 의하여 가교 밀도를 증가시켰다. 또한, 폴리우레탄 발포체의 기계적 물성을 높이기 위해 무기 충전제로 입자 크기와 $SiO_2$ 함량이 다른 실리카와 탈크 각각 2종류를 사용하였다. 발포체의 제조시 사슬 연장제와 무기 충전제의 종류와 함량비를 달리하면서 모듈러스, 인장 강도, 압축 강도, 경도의 물성 변화를 알아보았고, 전자현미경을 통해 셀의 크기 변화와 무기 충전제의 분포도를 관찰하였다.

국내산 규조토의 수열반응에 의한 Kaolinite질 인공점토의 합성에 관한 연구 (The Synthesis of Kaolinitic Clay Minerals from Domestic Diatomite by Hydrothermal Process)

  • 김남일;박계혁;정창주
    • 한국세라믹학회지
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    • 제31권11호
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    • pp.1401-1413
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    • 1994
  • The synthesis of kaolinite mineral from domestic diatomite for silica resource, commercial vailable gibbsite or alumina for alumina resource were made under various hydrothermal treatment, and the sythetic effect of acidic mineralizers, temperature treatment with time duration, particle size of alumina on formation of kaolinite mineral and the plastic properties of synthesized kaolinite were investigated. The various acidic mineralizers which are HCl, HNO3, H2SO4 and Oxalic acid were employed for hydrothermal reaction in the range of 0.01 mol/ι to 2 mol/ι concentration of each mineralizers. It was found that HCl in the level of 1 mol/ι solution produced highly yields of well-crystallized and platy form kaolinite mineral and gave the most effective extraction of iron oxide, compared to that of others, that HNO3 produced highly yield of kaolinite but lower extraction of iron oxide, that H2SO4 produced low yield of kaolinite and formed alunite mineral, and that oxialic acid formed spherical crystalline kaolinite and gave low extraction of iron oxide. Moreover, it showed that kaolinite minerals were well synthesized in a wide range of less than 2 mol/ι acids, but were poorly synthesized at more than 2 mol/ι acids. However, boehmite and kaolinite were coexistently formed in the temperature range of 18$0^{\circ}C$ and 20$0^{\circ}C$ when the calcined diatomite and gibbsite were involved. The well-ordered kaolinite mineral as a platy form was highly synthesized in the temperature range of 220 and 24$0^{\circ}C$, when the same marterials as above were used with treatment of 1 mol/ι HCl solution. The results also revealed that the size of crystalline platy form kaolinite, synthesized from alumina and calcined diatomite with treatment in 1 mol/ιHCl solution at 24$0^{\circ}C$, was much larger than that of gibbsite and calcined diatomite shown previously, and that kaolinite and corundum minerals were coexistently formed under any hydrothermal treatment conditions. The plasticity of synthesized kaolinite from under 2 ${\mu}{\textrm}{m}$ alumina and calcined diatomite was very poor, and that of the synthesized kaolinite from raw diatomite and gibbsite gave higher than that of calcined diatomite and gibbsite.

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Microcystis aeruginosa에 대한 Lactobacillus graminis의 성장 억제능, microcystin 분해 및 살조 물질의 특성 (Inhibition of Growth and Microcystin Toxicity, and Characterization of Algicidal Substances from Lactobacillus graminis against Microcystis aeruginosa)

  • 주재형;박범수;이은선;강윤호;한명수
    • 생태와환경
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    • 제49권3호
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    • pp.176-186
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    • 2016
  • For several decades, lactic acid bacterium (Lactobacillus graminis: LAB) has been generally recognized as safe. To develop the pan-environmental bio-control agent, algicidal activity of the live LAB cell and its culture filtrate (CF) was examined against Microcystis aeruginosa. LAB cells perfectly lysed M. aeruginosa within 3 days, while the CF had a less effect than the live cells, approximately 78% inhibition of algal growth during a same culture period. The concentration of microcystin in alone culture of M. aeruginosa was $7.1{\mu}gL^{-1}$, but gradually increased and leach $158.5{\mu}gL^{-1}$ on 10 days. However, LAB cells clearly decreased the microcystin by $10.3{\mu}gL^{-1}$ in the same period, approximately 93.5%. CF of LAB showed a strong algicidal activity over 75% between pH 2-7, 91.3% by the treatment of proteinase K, 87.8% by below 3 kDa in particle size, and 75.3% by heat treatment, respectively. Of five solvents, fractions of CF passed through solvents diethyl ether and ethyl acetate showed an obvious algicidal activity in the algal-lawn test. Among 5 fractions purified by silica-gel TLC plate, two spots showed a most strong removal activity on M. aeruginosa. Another analysis of GC indicate that CF contained six representative fatty acids. Even though most of these substance have been known as an anti-algal substance against M. aeruginosa, oleic acid is the most effective. These results suggested that the culture filtrate or specific substances, like a fatty acids, in comparison with live L. graminis can be a successful and eco-friendly agent to control Microcystis bloom.

포졸란계 미분말과 ∥ 형 무수석고 치환 시멘트 페이스트 유동성과 시멘트 모르타르의 유동성 및 압축강도 (Fluidity of Cement Paste and Fluidity and Compressive Strength of Cement Mortar Substituted by Pozzolanic fine Powders and II-Anhydrite)

  • 노재성;이범재;김도수;이병기
    • 콘크리트학회지
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    • 제9권3호
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    • pp.149-156
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    • 1997
  • 시멘트 모르타르의 압축강도 향상을 휘하여 분말혼화제를 제조하였으며,분말혼화재 사용에 따르는 유동성 감소를 억제하고자 고유동화제를 사용하였다. 분말혼화재(FAS)는 불산부생 II형 무수석고와 플라이애쉬 및 실리카흄을 혼합제조하여 시멘트 대신 각각10,20 wt% 씩 치환하였다. 물/고형분비(W/S)=0.40에서 FAS 로 치환된 시멘트 페이스트의 유동성은 저하되었고, 유동성 저하의 억제를 위한 고유동화제는 NSF와 NT-2가 효과적이었다. 시멘트 모르타르의 유동성은 II형 무수석고의 분말도가 미세할수록 증가하였고, 유동성저하는 FAS를 10 wt% 치환하였을 때 작게 나타났다. 압축강도는 10 wt%치환한 공시체가 20 wt%치환한 것보다 높게 나타났고 특히 $\gamma$ 를 10 wt%치환한 공시체( CI )에서 가장 높은 압축강도값을 나타내었다.

Effect of surface treatments and universal adhesive application on the microshear bond strength of CAD/CAM materials

  • Sismanoglu, Soner;Gurcan, Aliye Tugce;Yildirim-Bilmez, Zuhal;Turunc-Oguzman, Rana;Gumustas, Burak
    • The Journal of Advanced Prosthodontics
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    • 제12권1호
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    • pp.22-32
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    • 2020
  • PURPOSE. The aim of this study was to evaluate the microshear bond strength (µSBS) of four computer-aided design/computer-aided manufacturing (CAD/CAM) blocks repaired with composite resin using three different surface treatment protocols. MATERIALS AND METHODS. Four different CAD/CAM blocks were used in this study: (1) flexible hybrid ceramic (FHC), (2) resin nanoceramic (RNC), (c) polymer infiltrated ceramic network (PICN) and (4) feldspar ceramic (FC). All groups were further divided into four subgroups according to surface treatment: control, hydrofluoric acid etching (HF), air-borne particle abrasion with aluminum oxide (AlO), and tribochemical silica coating (TSC). After surface treatments, silane was applied to half of the specimens. Then, a silane-containing universal adhesive was applied, and specimens were repaired with a composite, Next, µSBS test was performed. Additional specimens were examined with a contact profilometer and scanning electron microscopy. The data were analyzed with ANOVA and Tukey tests. RESULTS. The findings revealed that silane application yielded higher µSBS values (P<.05). All surface treatments were showed a significant increase in µSBS values compared to the control (P<.05). For FHC and RNC, the most influential treatments were AlO and TSC (P<.05). CONCLUSION. Surface treatment is mandatory when the silane is not preferred, but the best bond strength values were obtained with the combination of surface treatment and silane application. HF provides improved bond strength when the ceramic content of material increases, whereas AlO and TSC gives improved bond strength when the composite content of material increases.