• Journal of Ceramic Processing Research
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• 제13권spc1호
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• pp.145-148
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• 2012

Spherical silica aerogel powders were fabricated via an emulsion polymerization method from a water glass. A water-in-oil emulsion, in which droplets of a silicic acid solution are emulsified with span 80 (surfactant) in n-hexane, was produced by a high power homogenizer. After gelation, the surface of the spherical silica hydrogels was modified using a TMCS (trimethylchlorosilane)/n-hexane solution followed by solvent exchange from water to n-hexane. Hydrophobic silica wet gel droplets were dried at 80 ℃ under ambient pressure. A perfect spherical silica aerogel powder between1 to 12 ㎛ in diameter was obtained and its size can be controlled by mixing speed. The tapping density, pore volume, and BET surface area of the silica aerogel powder were approximately 0.08 g·cm-3, 3.5 ㎤·g-1 and 742 ㎡·g-1, respectively.

• Korean Chemical Engineering Research
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• 제50권6호
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• pp.945-951
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• 2012

광촉매반응기의 충전제로서 glass bead-광촉매담체를 control로 하고 다공성의 silica-based 광촉매담체를 사용하였을 때의 악취 및 VOC를 함유한 폐가스의 광촉매 처리효율에 대한 광촉매담체 다공성의 영향평가를 수행하였다. 다공성의 silica-based-광촉매담체의 광촉매 코팅량은 $1,716.3{\mu}g/cm^2$로서 nonporous glass bead(control)에 담지된 광촉매코팅량인 $670{\mu}g/cm^2$ 값의 약 250%이었다. Porous silica-based 담체가 충전된 광촉매반응기의 황화수소 및 톨루엔 제거효율은 각각 22% 및 82%로서, glass-bead 담체가 충전된 UV/광촉매반응기의 경우의 황화수소 및 톨루엔 제거효율인 각각 19% 및 53%와 비교하였을 때에 황화수소의 경우는 약 16% 증가하였고 톨루엔의 경우는 약 55% 증가하였다. 따라서 다공성의 silica-based 광촉매담체를 사용함으로써 황화수소와 톨루엔의 동시처리효율을 각각 제고하였고, 처리효율의 제고율은 황화수소보다 톨루엔의 경우가 3.4배 높았다.

• 한국분말재료학회지
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• 제20권2호
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• pp.134-137
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• 2013

The quartz glasses were prepared by fumed silica powders sintering method at $1210^{\circ}C$, $1230^{\circ}C$, $1250^{\circ}C$ in air and the effect of sintering temperature on their properties were investigated. The X-ray diffraction pattern, the OH concentration, the light transmittance, the apparent porosity and the density were analyzed. The transparent quartz glass were obtained above $1230^{\circ}C$. The OH-group and macroscopic pores were removed above $1230^{\circ}C$ and highest density and light transmittance were obtained at $1250^{\circ}C$.

• Transactions on Electrical and Electronic Materials
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• 제16권1호
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• pp.5-9
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• 2015

Optical and electrical properties were studied for Antimony doped tin oxide thin films from precursors containing 10, 30, 50, and 70 atom% of Sb deposited on bare sodalime silica, barrier layer coated sodalime silica, and pure silica glass substrates by sol-gel spinning technique. The direct band gaps were found to vary from 3.13~4.12 eV when measured in the hv range of 2.5~5.0 eV, and varied from 4.22~5.08 eV when measured in the range of 4.0~7.0 eV. Indirect band gap values were in the range of 2.35~3.11 eV. Blue shift of band gap with respect to bulk band gap and Moss-Burstein shift were observed. Physical thickness of the films decreased with the increase in % Sb. Resistivity of the films deposited on SLS substrate was in the order of $10^{-2}$ ohm cm. Sheet resistance of the films deposited on barrier layer coated soda lime silica glass substrate was found to be relatively less.

• Elastomers and Composites
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• 제55권4호
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• pp.277-280
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• 2020

In this study, mesoporous hollow silica spheres were synthesized using a polystyrene core and cetyltriammonium chloride (CTACl) as a pore template, and a low-cost water glass instead of expensive tetraethyl orthosilicate (TEOS) as a precursor. In addition, the material was synthesized by varying the concentration of polystyrene. Later, the polystyrene core and CTACl were removed by firing in a high-temperature heat-treatment process. The synthesized product was analyzed by various methods, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), and N2-sorption analysis. It was confirmed that the hollow silica sphere had a hexagonal structure with a Brunauer-Emmett-Teller (BET) specific area of 1623 ㎡/g.

• 한국분말재료학회지
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• 제19권6호
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• pp.412-415
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• 2012

The quartz glasses were prepared by sintering of fumed silica powders and the effect of OH concentration on their surface on sintering was studied. Through the firing process, the fumed silica was crystallized from 1180 to $1260^{\circ}C$ region. The amount of hydroxyl group decreased with increase in calcination temperature and consequently the crystallization was prevented. A transparent quartz glass was obtained from fumed silica, previously calcined at $1000^{\circ}C$, by the sintering at $1250^{\circ}C$ for 1 h.

• 한국세라믹학회지
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• 제34권9호
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• pp.941-948
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• 1997

CuCl nanocrystallites dispersed nonlinear optical silica and borosilicate glasses were fabricated by sol-gel process. CuCl powder was dissolved in TEOS(Si(OC2H5)4) and TMB((CH3O)3B), precursors of silica and borosilicate glasses, with ethanol, water and HCl, and precipitated through the heat treatment in the matrix glass. The optical properties of CuCl doped glasses were measured using the spectrophotometer at room temperature and low temperature(77K); Z1, 2 and Z3 exciton peaks from the absorption spectra, were observed at about 370 nm and 380 nm, respectively. The average radius of nanocrystallites, calculated from the blue shift of Z3 excitons, was measured according to annealing temperature and time. The precipitation temperature of CuCl nanocrystallites was decreased when boron was added to silica glass. Increase of annealing temperature and time made average radius of nanocrystallites saturated about 2 nm.

• 마이크로전자및패키징학회지
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• 제28권4호
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• pp.79-83
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• 2021

본 연구에서는 기존의 silicon alkoxide(tetraethyl orthosilicate, TEOS)에 비해 단가가 저렴하여 상업화에 유리한 물유리를 전구체로 사용하여 계면활성제의 농도에 따라 형성되는 다양한 크기의 실리카 중공 미세구(hollow silica microsphere, HSM)를 합성하였다. 계면활성제의 농도에 따른 실리카 중공 미세구의 형성에 대한 물성을 퓨리에 분광기(Fourier transform infrared spectrometer), 접촉각 측정기(contact angle measurement), Brunauer-Emmett-Teller 및 Barrett-Joyner-Halenda 분석기와 전계방사형 주사전자현미경(field emission scanning electron microscopy)를 이용하여 분석하였다. 계면활성제를 적정량의 농도로 투입하여 porou s한 물유리 기반 실리카 중공 미세구를 제조할 경우 비표면적은 169 m²/g, 평균 입자 크기 25.3 ㎛ 및 표준편차는 6.25로 우수한 실리카 중공 미세구가 형성됨을 확인하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.49-54
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• 2001

Using waste glass in concrete can cause crack and strength loss by the expansion of alkali-silica reaction(ASR). In this study, ASR expansion and properties of strength were analyzed in terms of brown waste glass content, and fibers(steel fiber, polypropylene fiber) and fiber content for reduction ASR expansion due to waste glass. In this accelerated ASTM C 1260 test of waste glass, pessimum content can not be found. Also, when used the fibers with waste g1ass, there is an effect on reduction of expansion and strength loss due to ASR between the alkali in the cement paste and the silica in the waste glass. Specially, adding 1.5 vol.% of steel fiber to 20% of waste glass the expansion ratio was reduced by 40% and flexural strength was developed by up to 110% comparing with only Waste glass ( $80^{\circ}C$ $H_{2}$ O curing).

• 콘크리트학회논문집
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• 제14권3호
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• pp.440-448
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• 2002

산업의 발달과 더불어 폐유리의 발생량은 점차 증가되고 있다. 콘크리트에 폐유리를 사용할 경우 알칼리 실리카 반응(ASR)에 의한 팽창으로 콘크리트에 균열이 발생하여 성능저하를 일으킬 수 있다. 본 연구에서는 폐유리의 색깔(갈색, 녹색), 입도 및 폐유리로 인해 발생되는 ASR팽창을 저감시키기 위해 산업부산물의 종류(플라이애시, 고로슬래그 미분말)와 혼입율에 따른 ASR팽창과 강도특성을 분석하였다. 또한, 포졸란 재료로서 폐유리 분말의 사용가능성을 분석하였다. 연구결과, 폐유리의 색깔에 관계없이 폐유리의 퍼시멈 입도는 2.5~l.2mm로 나타났으며, 폐유리의 입도가 2.5~l.2 mm보다 작을수록 팽창은 점차 감소하는 것으로 나타났다. 또한, 폐유리에 산업부산물의 혼입은 ASR로 인한 팽창과 강도저하를 억제시키는데 효과적이며, 0.075 mm미만의 폐유리 분말이 포졸란 재료로서 적용이 가능한 것으로 나타났다.