• Proceedings of the Korea Concrete Institute Conference
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• 1993.10a
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• pp.144-149
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• 1993

The results of an experimental study on the manufacture and the mechanical properties of carbon fiber reinforced silica fume.cement composites and light weight fly ash.cement composites are presented in this paper. The CF reinforced silica fume.cement composites using silica fume early strength cement were prepared with Pan-derived or Pitch-derived CF, and Lt. Wt, fly ash.cement composites using fly ash, early strength cement, perlite and a small amount of foaming agent. As the test results show, the flexural strength, toughness and ductility of CF reinforced silica fume .cement composites were remarkably increased by fiber contents. Also, the manufacturing process technology of Lt. Wt. fly ash.cement composites was developed and its optimum mix proportions were proposed. And the compressive and flexural strength of the fly ash.cement composites by hot water cured were improved even more than by moist cured, but are decreased by increasing fly ash replaced ratio for cement.

• Computers and Concrete
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• v.9 no.6
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• pp.457-467
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• 2012

This study evaluates the permeability of cement-based composites, which are a mix of polyolefin fibers and silica fume. Test results indicate that permeability increases as the water/cementitious ratio increases. Silica fume in cement-based composites produced hydrated calcium silicate and filled the pores. However, permeability decreased as the addition of silica fume increased. Specimens containing polyolefin fibers also provided higher permeability resistance. The polyolefin fiber length did not have a significant effect on permeability. The decrease in the permeability is mainly due to the addition of silica fume and lower water/cementitious ratio. Addition of fibers marginally decreases the permeability. Incorporating polyolefin fiber and silica fume in composites achieved more significant decreases in permeability. The correlated test results reveal the interrelationship between them.

• Elastomers and Composites
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• v.53 no.4
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• pp.202-206
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• 2018

Five solution styrene butadiene rubber/neodymium butadiene rubber (SSBR/NdBR) composites were manufactured using different ratios of SSBR and NdBR. In this study, the composites were reinforced with NdBR and silica to confirm the physical properties of SSBR used for treads of automobile tires and the dispersibility with silica. The morphologies of the rubber composites were observed using field-emission scanning electron microscopy (FE-SEM). The crosslinking behaviors of the composites were tested using a rubber process analyzer (RPA), and the abrasion resistances were tested using a National Bureau of Standards (NBS) abrasion tester. The hardness values, tensile strengths, and cold resistances of the composites were also tested according to ASTM standards. Increased NdBR content yielded composites with excellent crosslinking properties, abrasion resistances, hardnesses, tensile strengths, and cold resistances. The crosslinking point increased due to the double bond in NdBR, thereby increasing the degree of crosslinking in the composites. The NdBR-reinforced composites exhibited excellent abrasion resistances, which is explained as follows. In SSBR, a breakage is permanent because a resonance structure between styrene and SSBR forms when the molecular backbone is broken during the abrasion process. However, NdBR forms an additional crosslink due to the breakdown of the molecular backbone and high reactivity of the radicals produced. In addition, the low glass transition temperature (Tg) of NdBR provided the rubber composites with excellent cold resistances.

• Journal of Powder Materials
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• v.30 no.4
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• pp.346-355
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• 2023

Epoxy-based composites find extensive application in electronic packaging due to their excellent processability and insulation properties. However, conventional epoxy-based polymers exhibit limitations in terms of thermal properties and insulation performance. In this study, we develop epoxy-based siloxane/silica composites that enhance the thermal, mechanical, and insulating properties of epoxy resins. This is achieved by employing a sol-gel-synthesized siloxane hybrid and spherical fused silica particles. Herein, we fabricate two types of epoxy-based siloxane/silica composites with different siloxane molecular structures (branched and linear siloxane networks) and investigate the changes in their properties for different compositions (with or without silica particles) and siloxane structures. The presence of a branched siloxane structure results in hardness and low insulating properties, while a linear siloxane structure yields softness and highly insulating properties. Both types of epoxy-based siloxane/silica composites exhibit high thermal stability and low thermal expansion. These properties are considerably improved by incorporating silica particles. We expect that our developed epoxy-based composites to hold significant potential as advanced electronic packaging materials, offering high-performance and robustness.

• Elastomers and Composites
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• v.51 no.2
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• pp.106-112
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• 2016

Maleimidopropyltriethoxysilane grafted natural rubber (MISNR) was prepared by reaction of maleic anhydride grafted natural rubber and 3-aminopropyl triethoxysilane. MISNR was used as the compatibilizer of natural rubber/silica composites. The composites were prepared by two-step mixing procedures. The final mixtures were cured with optimum cure condition, which was established by a rheometer. Effects of the amounts of compatibilizer in the composites on the cure characteristics, morphology, thermal stability, and physical and mechanical behaviors were investigated. The composites having MISNR had shown cure characteristics and physical and mechanical properties superior to those without MISNR. Silica particles in the former appeared to be more uniform and reduced in size compared with the latter. The effects of the types of silica were also evaluated.

• Elastomers and Composites
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• v.53 no.3
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• pp.175-180
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• 2018

Solution-styrene-butadiene rubber (SSBR) composites were manufactured using four kinds of fillers: silica-silane coated carbon black (SC-CB) hybrid, starch-SC-CB hybrid, pure silica, and pure starch. The influence of filler type on the mechanical properties of the rubber matrix was studied in this work. SC-CB was prepared by silane-graft-coating using vinyl triethoxy silane and carbon black, which enhanced the dispersion effect between the rubber matrix and the filler, and improved the mechanical properties of the compounds. The morphology of the composites was observed by field-emission scanning electron microscopy (FE-SEM). The thermal decomposition behavior of the composites was determined by thermogravimetric analysis (TGA), and the crosslinking behavior of the composites was tested using a rubber process analyzer (RPA). The hardness, tensile strength, swelling ratio, and gas transmittance rate of the composites were evaluated according to ASTM. The test results revealed that with the addition of SC-CB, the hybrid fillers, especially those blended with silica, showed a better reinforcement effect, the highest hardness and tensile strength, and stable thermal decomposition behavior. This implies that the silica-SC-CB hybrid filler has a notable mechanical reinforcement effect on the SSBR matrix. Because of self-crosslinking during its synthesis, the starch-SC-CB hybrid filler produced the most dense matrix, which improved the anti-gas transmittance property. The composites with the hybrid fillers had better anti-swelling properties as compared to the neat SSBR composite, which was due to the hydrophilicity of silica and starch.

• Structural Monitoring and Maintenance
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• v.11 no.2
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• pp.71-86
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• 2024

In this study, to reduce the amount of cement consumed in the production of cementitious composites, the effects of partial replacement of cement weight with nano-silica, silica fume, and copper slag on the mechanical properties of polypropylene fiber-reinforced cementitious composites are investigated. For this purpose, the effect of replacing cement weight by each of the aforementioned materials individually and in combination is studied. A total of 34 mix designs were prepared, and their compressive, tensile, and flexural strengths were obtained for each mix. Among the mix designs with one cement replacement material, the highest strength is related to the sample containing 2.5% nano-silica. In this mix design, the compressive, tensile, and flexural strengths improve by about 33%, 13%, and 15%, respectively, compared to the control sample. In the ones with two cement replacement materials, the highest strengths are related to the mix made with 10% silica fume along with 2% nano-silica. In this mix design, compressive, tensile, and flexural strengths increase by about 42%, 18%, and 20% compared to the control sample, respectively. Furthermore, in the mixtures containing three cement substitutes, the final optimal mix design for all three strengths has 15% silica fume, 10% copper slag, and 2% nano-silica. This mix design improves the compressive, tensile, and flexural strengths by about 57%, 23%, and 26%, respectively, compared to the control sample. Finally, two relationships have been presented that can be used to predict the values of tensile and flexural strengths of cementitious composites with very good accuracy only by determining the compressive strength of the composites.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2006.11a
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• pp.141-144
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• 2006

In this study, the friction and wear characteristics of pure epoxy and silica-filled epoxy resin composites with average silica particle diameter of $6-33{\mu}m$ were investigated at ambient temperature by pin-on-disc friction test. The cumulative wear volume, friction coefficient and wear rate of these materials against SiC abrasive paper were determined experimentally. The cumulative wear volume tended to increase nonlinearly with increase of sliding distance and depended on diameter of the silica particle for all these composites. The sliding wear tests of the materials demonstrated that the friction coefficient and the wear rate of silica filled epoxy composites were lower than those of the pure epoxy. silica filled epoxy.

• Journal of Environmental Science International
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• v.12 no.4
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• pp.481-485
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• 2003

Two types of polyimide/silica composite films were prepared using sol-gel method through hydrolysis and polycondensation of tetraethoxysilane (TEOS) with the polyamic acid (PAA) and end-capped PAA solution. Samples were characterized by the means of differential thermogravimetry, X-ray diffractometry, scanning electron microscopy, universal test, impedance analyzer, chemical resistance test, etc. All of the PAA/silanol solutions heat-treated at 300$^{\circ}C$ for 6h were transformed to polyimide/silica composites. It has been demonstrated that the properties of polyimide/silica composites were affected by the amount of silica addition and the bend type existed between polyimide and silica.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.65 no.11
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• pp.1840-1847
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• 2016

The surface of nanosilica and microsilica was modified in order to develop a high voltage insulation material for outdoor application. The modified silicas were well dispersed in an aliphatic cyclic epoxy resin. Dielectric properties were studied for 8 kinds of specimens: 1 kind of neat epoxy, 3 kinds of epoxy/microsilica composites, and 4 kinds of epoxy/microsilica/nanosilica composites. Complex dielectric constants were measured in the range of 10-2~1.2 Hz at room temperature.