• Archives of Pharmacal Research
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• v.14 no.2
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• pp.137-142
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• 1991

The structure of a $\beta$-allyl type phenylpropanoid was determined by single crystal X-ray diffraction analysis. The compound was recrystallized from a mixture of n-hexane and benzene in monoclinic crystal system with a = 24.782 (2), b = 10.537 (1), c = 7.871 (1) ${\AA}, \beta=95.74$ (1)$^\circ, $D_x$=1.216, $D_m$=1.22g/$cm^3$, space group $P2_1/a$, and Z=4. The structure was solved by direct method and refined by least-squares procedure to the final R value of 0.054 for 2824 observed reflections {$F{\geq}3\sigma(F)$}. The molecular geometry shows a most stable trans-form with respect to the bulky phenyls, and this conformation is settled by an intramolecular hydrogen bond. In the crystal, the molecules are arranged along with the screw axis, and stabilized by the $O{\cdot}H{\cdots}O$ type intermolecular hydrogen bonds. The other intermolecular contacts appear to be the normal van der Waals' interactions. The compound is a dimeric phenylpropanoid, and belongs to the neolignan analogues.

• Journal of the Mineralogical Society of Korea
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• v.9 no.1
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• pp.43-53
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• 1996

The detailed crystal chemistry of ilmenite from the Hadong massif was studied by the EPMA, M ssbauer spectroscopy, and Rietveld structural refinement using X-ray powder diffraction data. The ilmenite-bearing anorthosite shows complicated mineral assemblage which consists of plagioclase, clinopyroxene, hornblende, biotite, chlorite, apatite, allanite, and zircon. Anorthite is andesine in composition (Ab 28-57), and clinopyroxene drops in ferro-hypersthene (Fs 62-70). Ilmenite is trigonal symmetry with R space group, whose structure shows the alternation of Fe2+ (M1 site) octahedral layer and Ti (M2 site) layer along c axis. M ssbauer spectroscopy indicates that there are three doubles which assigned to couple of Fe2+($\delta$=0.812, 0.890mm/sec) and one Fe3+($\delta$=0.303mm/sec) in octahedral sites. Their Fe3+/$\Sigma$Fe is 0.065 and chemical formula is established as Fe2+0.94Fe3+0.07Ti0.97O3 using both EPMA and M ssbauer analysis. Rietveld structural refinement reveals that site occupancies of Fe in M1 and Ti in M2 are 91.2% and 89.4%, respectively. This implies that Ti and Fe2+ are alternatively occupy M1 and M2 sites. In addition, smaller M2 site is more preferable to Fe3+ occupancy over M1.

• The Bulletin of The Korean Astronomical Society
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• v.41 no.2
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• pp.61.1-61.1
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• 2016

Black hole (BH) mass is a fundamental quantity to understand BH growth, galaxy evolution, and connection between them. Thus, obtaining accurate and precise BH mass estimates over cosmic time is of paramount importance. The rest-frame UV CIV ${\lambda}1549$ broad emission line is commonly used for BH mass estimates in high-redshift AGNs (i.e., $2{\leq}z{\leq}5$) when single-epoch (SE) optical spectra are available. Achieving correct and accurate calibration for CIV-based SE BH mass estimators against the most reliable reverberation-mapping based BH mass estimates is thus practically important and still useful. By performing multi-component spectral decomposition analysis to obtained high-quality HST UV spectra for the updated sample of local reverberation-mapped AGNs including new HST STIS observations, CIV emission line widths and continuum luminosities are consistently measured. Using a Bayesian hierarchical model with MCMC sampling based on Hamiltonian Monte Carlo algorithm (Stan NUTS), we provide the most consistent and accurate calibration of CIV-based BH mass estimators for the three line width characterizations, i.e., full width at half maximum (FWHM), line dispersion (${\sigma}_{line}$), and mean absolute deviation (MAD), in the extended BH mass dynamic range of log $M_{BH}/M_{\odot}=6.5-9.1$.

• Archives of Pharmacal Research
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• v.15 no.1
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• pp.52-57
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• 1992

The molecular structure of a natural compound was determined by single crystal X-ray diffraction analysis. The compound was isolated by methanol extraction and repeated chromatography from the stem of Paulownia tomentosa. Yellow prismatic crystals of the compound, which were recrystallized from tetrahydrofuran, are triclinic, with a = 7.310 (6), b = 10.753(6), c = 11.586(5) ${\AA}.\;\alpha= 93.30(6),\;\beta=105.62(10),\;\gamma=109.49(7)^\circ,\;D_x=1.514,\;D_m=1.51 g/cm^3$, space group P1 and Z = 2. The structure was solved by direct method, and refined by least-squares procedure to the final R-value of 0.032 for 1271 independent reflections $(F\le3\sigma{(F))}$. The compound is one of new furanquinone analogue. The molecule has a nearly planar conformation with an intramolecular hydrogen bond. In the crystal, the planar molecules are arranged as a prallel sheet-like pattern, and these stackings are stabilized by the O-H...O type intermolecular hydrogen bonds. The other intermolecular contacts appear to be the normal van der Waals interactions.

• Proceedings of the KSRS Conference
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• 2003.11a
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• pp.37-37
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• 2003

Rice is one of the most important crop in the world and is a major export of Thailand. Optical sensors are not useful for rice monitoring, because most cultivated areas are often obscured by cloud during the growing period, especially in South East Asia. Spaceborne Synthetic Aperture Radar (SAR) such as RADARSAT, can see through regardless of weather condition which make it possible to monitor rice growth and to retrieve rice acreage, using the unique temporal signature of rice fields. This paper presents the result of a study of examining the backscatter behavior of rice using multi-temporal RADARSAT dataset. Ground measurements of paddy parameters and water and soil condition were collected. The ground truth information was also used to identify mature rice crops, orchard, road, residence, and aquaculture ponds. Land use class distributions from the RADARSAT image were analyzed. Comparison of the mean DB of each land use class indicated significant differences. Schematic representation of temporal backscatter of rice crop were plotted. Based on the study carried out in Pathum Thani Province test site, the results showed variation of sigma naught from first tillering vegatative phase until ripenning phase. It is suggested that at least, three radar data acquisitions taken at 3 stages of rice growth circle namely; those are at the beginning of rice growth when the field is still covered with water, in the ear differentiation period, and at the beginning of the harvest season, are required for rice monitoring. This pilot project was an experimental one aiming at future operational rice monitoring and potential yield predicttion.

• Bulletin of the Korean Chemical Society
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• v.21 no.1
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• pp.65-68
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• 2000

A $\mu-oxo$ diiron(III) complex and two bis( $\mu-alkoxo)$ diiron(III) complexes with biomimetic tripodal ligand containing mixed N/O donor atoms were synthesized using a mononuclear iron(III) complex as starting material. Depending on the amounts and kinds of bases used, we obtained various kinds of diiron (III) complexes. The reaction of $[$Fe^{III}$(Hbbea)Cl_2]Cl$, 1, with an equivalent amount of $KO_2$ or NaOAc produced $[$Fe^{III}$_2O(Hb-bea)_2Cl_2]Cl_2$, 2. An additional equivalent amount of NaOBz or NaOAc converts complex 2 to complex 3 or complex 4 depending on the base used. The addition of two equivalent amounts of NaOBz orNaOAc directly converts complex 1 to $[$Fe^{III}$_2(bbea)_2(OBz)_2]Cl_2$, 3, or $[$Fe^{III}$_2(bbea)_2(OAc)_2]Cl_2$, 4, depending on the base used. Crystal data are as follows: [$Fe^{III}_2O(Hbbea)_2Cl_2]Cl_2$, 2: monoclinic space group $$P2_1/n$$, a = 8.421 (1) $\AA$, b = 18.416 (2) $\AA$, c = 13.736 (1) $\AA$, $\beta$ = 104.870 $(7)^{\circ}$, V = 2058.9 (4) $\AA^3$, Z = 2, R1 = 0.0469 and wR2 = 0.1201 for reflections with I > 2 ${\sigma}$(I).

• Bulletin of the Korean Chemical Society
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• v.11 no.1
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• pp.15-19
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• 1990

The crystal structure of $(C_{12}H_{24}O_6{\cdot}K)_2K[Co(OH)_6Mo_6O_{18}]{\cdot}12H_2O$ has been determined by X-ray diffraction. Crystal data as follows ; monoclinic, space group $C_2/m,\;a\;=\;22.512(4)\;{\AA},\;b\;=\;18.304(4)\;{\AA},\;c\;=\;7.641(1)\;{\AA},\;{\beta}\;=\;90.52(2)\;{\AA}$, and Z = 2. A final conventional R value of 0.044 was obtained by least-squares refinement of 4173 independent observed $[{\mid}Fo{\mid}{\geq}3{\sigma}({\mid}Fo{\mid})]$ reflections. The $[Co(OH)_6Mo_6O_}{18}]^{-3}$ polyanion shows the well-known Anderson-structure and has approximate 3m symmetry. A $[Co(OH)_6Mo_6O_{18}]^{-3}$ polyanion is located between two crown ether complexed cations forming a sandwich structure. One potassium ion interacts with the crown ether via electrostatic interactions. The other potassium ion only interacts with the water molecules and terminal oxygen atoms of the polyanion.

• Bulletin of the Korean Chemical Society
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• v.13 no.5
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• pp.498-503
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• 1992

The protonation of RuH(NO)(Cyttp) resulted in the formation of $[RuH_2(NO)(Cyttp)]^+$ which is characterized as a classical cis-dihydried complex. This complex is fluxional and the intramolecular process involving a molecular hydrogen complex is proposed. This mechanism was further supported by the reactivity of this complex toward neutral 2-electron ligands. On the other hand, it failed to detect the existence of $[RuH_2(NO)(etp)]^+$ probably due to instability of the complex but the crystal structure of $[Ru(PMe_3)(NO)(etp)]^+$ formed by the protonation of RuH(NO)(etp) followed by the addition of $PMe_3$ was determined to have a trigonal bipyramidal structure with a linear NO in the equatorial plane and a facial etp ligand. The crystals are monoclinic, space group P21/n, with unit cell dimensions a = 14.130(2), b = 21.026 (3), c = 14.760 (1) ${\AA}$, ${\beta}$ = 97.88 $(l)^{\circ}$ V = 4344 ${\AA}^3$, Z = 4, R = 0.046 and $R_w$ = 0.056 for the 4779 intensities with $F_o^2 > 3{\sigma}(F_0^2)$ and the 440 variables.

• Journal of the Chungcheong Mathematical Society
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• v.24 no.1
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• pp.19-34
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• 2011

A bounded linear operator T on a complex Banach space X is said to have property (I) provided that T has Bishop's property (${\beta}$) and there exists an integer p > 0 such that for a closed subset F of ${\mathbb{C}}$ ${X_T}(F)={E_T}(F)=\bigcap_{{\lambda}{\in}{\mathbb{C}}{\backslash}F}(T-{\lambda})^PX$ for all closed sets $F{\subseteq}{\mathbb{C}}$, where $X_T$(F) denote the analytic spectral subspace and $E_T$(F) denote the algebraic spectral subspace of T. Easy examples are provided by normal operators and hyponormal operators in Hilbert spaces, and more generally, generalized scalar operators and subscalar operators in Banach spaces. In this paper, we prove that if T has property (I), then the quasi-nilpotent part $H_0$(T) of T is given by $$KerT^P=\{x{\in}X:r_T(x)=0\}={\bigcap_{{\lambda}{\neq}0}(T-{\lambda})^PX$$ for all sufficiently large integers p, where ${r_T(x)}=lim\;sup_{n{\rightarrow}{\infty}}{\parallel}T^nx{\parallel}^{\frac{1}{n}}$. We also prove that if T has property (I) and the spectrum ${\sigma}$(T) is finite, then T is algebraic. Finally, we prove that if $T{\in}L$(X) has property (I) and has decomposition property (${\delta}$) then T has a non-trivial invariant closed linear subspace.

• The Bulletin of The Korean Astronomical Society
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• v.44 no.1
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• pp.56.2-56.2
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• 2019

Measurement of the location of the baryon acoustic oscillation (BAO) feature in the clustering of galaxies has proven to be a robust and precise method to measure the expansion of the Universe. The best constraints so far have been provided from spectroscopic surveys because the errors on the redshift obtained from spectroscopy are minimal. This in turn means that the errors along the line-of-sight are reduced and so one can expect constraints on both angular diameter distance $D_A$ and expansion rate $H^{-1}$. But, future surveys will probe a larger part of the sky and go to deeper redshifts, which correspond to more number of galaxies. Analysing each galaxy using spectroscopy, which is a time consuming task, will not be practically possible. So, photometry will be the most convenient way to measure redshifts for future surveys such as LSST, Euclid, etc. The advantage of photometry is measuring the redshift of vast number of galaxies in a single exposure, but the disadvantage are the errors associated with the measured redshifts. Using a wedge approach, wherein the clustering is split into different wedges along the line-of-sight ${\pi}$ and across the line-of-sight ${\sigma}$, we show that the BAO information can be recovered even for photometric catalogues with errors along the line-of-sight. This means that we can get cosmological distance constraints even if we don't have spectroscopic information.