• Title/Summary/Keyword: SiO$_2$suspensions

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Fabrication of Textured $Al_2O_3-Mullite-SiC$ Nano-composite by Slip Casting in a High Magnetic Field and Reaction Sintering

  • Sakka, Yoshio;Saito, Sho;Honda, Atsushi;Suzuki, Tohru S.;Moriyoshi, Yusuke
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.327-328
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    • 2006
  • We have demonstrated that textured $Al_2O_3-mullite-SiC$ nanocomposites can be fabricated by slip casting followed by partial oxidation - reaction sintering of mixed suspensions of $Al_2O_3$ and SiC powders in a high magnetic field. The sintered density was changed by the degree of oxidation at 1200C and 1300C. The degree of orientation of alumina in the nanocomposite was examined on the basis of the X-ray diffraction patterns and scanning electron micrographs. It is confirmed that alumina-oriented nanocomposites were fabricated. The three-point bending strength at room temperature was observed for the nanocomposites.

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Fabrication of Textured $Al_2O_3-Mullite-SiC$ Nano-composite by Slip Casting in a High Magnetic Field and Reaction Sintering

  • Sakka, Yoshio;Saito, Sho;Honda, Atsushi;Suzuki, Tohru S.;Moriyoshi, Yusuke
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.455-456
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    • 2006
  • We have demonstrated that textured $Al_2O_3-mullite-SiC$ nanocomposites can be fabricated by slip casting followed by partial oxidation. reaction sintering of mixed suspensions of $Al_2O_3$ and SiC powders in a high magnetic field. The sintered density was changed by the degree of oxidation at 1200C and 1300C. The degree of orientation of alumina in the nanocomposite was examined on the basis of the X-ray diffraction patterns and scanning electron micrographs. It is confirmed that aluminaoriented nanocomposites were fabricated. The three-point bending strength at room temperature was observed for the nanocomposites.

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Material Dependence of Laser-induced Breakdown of Colloidal Particles in Water

  • Yun, Jong-Il
    • Journal of the Optical Society of Korea
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    • v.11 no.1
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    • pp.34-39
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    • 2007
  • Laser-induced breakdown of colloidal suspensions, such as polystyrene, $ZrO_2$, and $SiO_2$ particles in diameters of 100-400 nm in water is investigated by nanosecond flash-pumped Nd:YAG laser pulses operating at a wavelength ${\lambda}$= 532 nm. The breakdown threshold intensity is examined in terms of breakdown probability as a function of laser pulse energy. The threshold intensity for $SiO_2$ particles ($1.27{\times}10^{11}\;W/cm^2$) with a size of 100 nm is higher than those for polystyrene and $ZrO_2$ particles with the same size, namely $5.7{\times}10^{10}$ and $5.5{\times}10^{10}\;W/cm^2$, respectively. Results indicate that the absorption of five photons is required to induce ionization of $SiO_2$ particles, whereas the other particles necessitate four-photon absorption. These breakdown thresholds are compared with those measured by nanosecond pulses from a diode-pumped Nd:YAG laser having a different focusing geometry.

Effect of Colloidal Silica and Pre-Coating of Cathode on Copper Electrodeposited Film (구리 전착층에 미치는 콜로이달실리카 및 음극 Pre-Coating의 영향)

  • Lee, Sang-Baek;Yun, Jeong-Mo;Park, Hyeong-Ho;Bae, In-Seong;Kim, Byeong-Il
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.569-574
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    • 2001
  • The crystal structure, surface morphology and preferred orientation of the copper electrodeposit were investigated by the using sulfate bath with $SiO_2$suspensions and the cathode substrate Au sputtered. As by the addition of colloidal silica in copper electrolytic bath and Au pre-coating on substrate, the crystal particles of deposits was fined-down, made uniform and the account of particles were increased. Hardness of copper electrodeposits with colloidal silica increased about 15% in comparison with that of pure copper deposit film and (111), (200) and (311) plane of X-ray diffraction patterns were almost swept away, so preferred orientation of the copper deposits changed from (111) to (110) plane by codeposit $SiO_2$ and precoating the substrate.

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Dispersion of Silicon Nitride Particles and Sintering Additives of AlN and Nd$_2$O$_3$ in Nonaqueous Suspending Media (비수계분산매체에서 질화규소와 소결첨가제 AlN 및 Nd$_2$O$_3$의 분산)

  • 김재원;백운규;윤경진
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.210-219
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    • 1999
  • The fundamental dispersion property of Si2N4 and a combination of AlN and Nd2O3 as sintering additives in a variety of organic solvents such as alcohols, hydrocarbons, ketones, and ethers was investigated. The stabilization mechanism and interaction between organic functional groups of the various organic additives were studied to clarify the dispersibility of the ceramic particles in the nonaqueous suspending medium. characterization of the suspensions was based mainly on electrokinetic sonic amplitude(ESA) measurements and the flow curves obtained from the rheological studies as well as estimated Hamaker constants. It was found that the contribution of electrostatic repulsive forces to the Si3N4, AlN and Nd2O3 stabilization in organic media is appreciably greater than anticipated and is dependent on the physicochemical properties of organic solvents.

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Investigation of Convective Heat Transfer Characteristics of Aqueous SiO2 Nanofluids under Laminar Flow Conditions (층류유동 조건에서 SiO2 나노유체의 대류 열전달 특성에 대한 연구)

  • Park, Hyun-Ah;Park, Ji-Hyun;Jeong, Rag-Gyo;Kang, Seok-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.1-11
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    • 2016
  • The effect of the migration of nanoparticles near the wall of a channel on the convective heat transfer in a laminar flow of $SiO_2$ nanoparticle suspensions (nanofluids) under constant wall heat flux boundary conditions was numerically and experimentally investigated in this study. The dynamic thermal conductivity of the aqueous $SiO_2$ nanofluids was measured using T-type thermocouples attached to the outer surface of a stainless steel circular tube (with a length of 1 m and diameter of 1.75 mm). The nanofluids used in this study were synthesized by dispersing $SiO_2$ spherical nanoparticles with a diameter of 24 nm in de-ionized water (DIW). The enhancement of the thermal conductivity of the nanofluids (e.g., an increase of up to 7.9 %) was demonstrated by comparing the temperature profiles in the flow of the nanofluids with that in the flow of the basefluids (i.e., DIW). However, this trend was not demonstrated in the computational analysis, because the numerical models were based on continuum assumptions and flow features involving nanoparticles in a stable colloidal solution. Thus, to explore the non-continuum effects, such as the modification of the morphology caused by nanoparticle-wall interactions on the heat exchanging surfaces (e.g., the isolated and dispersed precipitation of the nanoparticles), additional experiments were performed using DIW right after the measurements using the nanofluids.

Effect of Colloidal Silica on Electredeposited Film from Copper sulfate Bath (황산구리 전해욕의 전착피막에 미치는 콜로이달실리카의 영향)

  • Lee, Sang-Baek;Kim, Byeong-Il;Yun, Jeong-Mo;Park, Jeong-Hyeon
    • Korean Journal of Materials Research
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    • v.11 no.5
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    • pp.413-418
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    • 2001
  • We investigated change of crystal structure, surface morphology and crystal orientation of the electrodeposited film from dispersed $SiO_2$ suspensions (colloidal silica) copper sulfate bath and arse corrosion potentials and physical specific properties. As addition of colloidal silica in copper electrolytic hath, the crystal Particles on filial was fined-down, made uniform and account of particles were increased. Hardness of copper electrodeposited film ascended about 15% and (111), (200) and (311) plane of X-ray diffraction patterns were almost swept away, so preferred orientation chanced from (111) to (110) plane. Also, corrosion potential of electrodeposited copper film was noble with colloidal silica addition.

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Changes of Silica Solubility in the Suspension of Sandy Loam Soil Treated with Silicate Fertilizers (사양토(砂壤土)에 규산성분비료(珪酸成分肥料) 처리시(處理時) 규산용출량(珪酸溶出量) 변화(變化))

  • Lee, Ki-Sang;Ahn, Yoon-Soo;Rhee, Gyeong-Soo;Ha, Ho-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.4
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    • pp.321-325
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    • 1986
  • A laboratory experiment was conducted to investigate silica solubility in soil with specific reference to the characteristics of iron refinery slag and wollastonite. The results are as follows; 1. The slilia concentrations successively extracted by distilled water and N-NaOAc (pH 4.0) in soil treated with the two silicate fertilizers, is higher in iron refinery slag than in wollastonite, while the pH values of soil-fertilizer suspensions successively extracted by distilled water were the opposite. 2. Silica concentrations due to increasing of fertilizer application were decreased in iron refinery slag-soil suspensions but the concentrations were increased in wollastonite-soil suspensions. 3. The amounts of silica adsorbed in different pH of soil suspension were maximized under the condition maintained pH of near to 9.4.

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