• 제목/요약/키워드: Si precipitation

검색결과 298건 처리시간 0.034초

석출경화된 Al-Pb-Gu계 베어링합금의 마모거동 (The wear properties of the precipitation hardened Al-Pb-Gu bearing alloys)

  • 홍택기;허무영;임대순;안성욱
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 1993년도 춘계학술대회 및 공장견학
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    • pp.54-58
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    • 1993
  • Cu, Si, Mg, Ca, Cd, Sn, Pb등이 첨가되는 Al계 bearing 합금은 베어링 특성이 우수하여 최근 자동차드의 엔진 부품용 베어링소재로 많이 사용되어지고 있다. 합금원소 Si는 합금의 경도를 향상시키며 Si-rich한 경한 입자를 생성시켜 소착저항력(antiseizure)을 향상시키며 또한 합금의 주조성도 향상시켜 내마모성이 요구되는 Al계 베어링 합금에 주합금원소로 첨가된다. 본 연구에서는 강제죠반법과 급냉응고법을 이용하여 Al-Pb-Gu계와 Al-Si-Gu-Pb계 베어링합금을 제조하였다. 베어링합금이 급냉응고법으로 제조되었기 때문에 합금의 기지에는 Cu가 과포된 상태로 존재하여 석출경화에 앞서 행하여지는 용체화처리와 같은 효과가 얻어졌다. 본 실험에서는 Cu가 과포화된 기지를 갖는 주조상태의 시료를 시효열처리하여 석출경화된 베어링합금을 얻어서 석출경화에 의한 기지강화가 베어링합금의 내마모성질에 어떠한 효과를 가져오는지 규명하였다.

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PREPARATION OF THE PLANARIZED $SIO_2$ PARTICLES TO MAKE IDEAL $SIO_2/TIO_2$ COMPOSITE PARTICLES FOR COSMETIC PRODUCTS

  • Shin, Dal-Sik;Kim, Kwang-Soo;Lee, Ok-Sob;Lee, Sung-Ho
    • 대한화장품학회지
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    • 제25권4호
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    • pp.43-50
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    • 1999
  • The planarized $SiO_2$ particles were prepared by two-step reduction method of making much smaller particles, micron-sized ones, to improve spreadability, adherence, and smoothness. Various pigments known as flaky extender usually have terrace layers on their surfaces, but $SiO_2$ particles in this study exhibit a smooth surface structure. These single $SiO_2$ particles were used as core particles to prepare the composite particles coated with ultra fine $TiO_2$ particles by a homogeneous precipitation method. The thickness and the morphology of the deposited $TiO_2$ layers could be modified by adjusting the reactant concentrations, the reaction time and the temperature. The characteristics of $SiO_2/TiO_2$ composite in the field of color cosmetics are to give an UV-cut effect and to enhance the chroma of human skin color, one of optical properties.

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Effect of Silicon on the Fracture Characteristics of Austempered Ductile Iron

  • Kang, In-Chan
    • 한국주조공학회지
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    • 제12권1호
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    • pp.25-31
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    • 1992
  • The effects of Si and austempering temperature on the fracture characteristics and the microstructures of austempered ductile irons were investigated. As Si content increased from 2.28% to 3.0%, the precipitation of carbides during bainitic transformation and was suppressed the amount of retained austenite increased resulting in the increase in the fracture toughness. It is believed that the high Si limited the formation of martensite in the microstructure and minimized the segregation of the other elements at cell boundaries. But in samples with too high Si content as 3.3%, the formation of islands of free ferrite in the bainitic structures was observed and the fracture toughness was measured to have degraded.

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PREPARATION OF THE PLANARIZID $SIO_2$ PARTICLES TO MAKE IDEAL $SIO_2/TIO_2$ COMPOSITE PARTICLES FOR COSMETIC PRODUCTS

  • Shin, Dal-Sik;Kim, Kwang-Soo;Lee, Ok-Sob;Lee, Sung-Ho
    • 대한화장품학회:학술대회논문집
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    • 대한화장품학회 1999년도 IFSCC . ASCS 학술대회 발표 논문
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    • pp.43-50
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    • 1999
  • The planarized SiO$_2$ particles were prepared by two-step reduction method of making much smaller particles, micron-sized ones, to improve spreadability, adherence, and smoothness. Various pigments known as flaky extender usually have terrace layers on their surfaces, but SiO$_2$ particles in this study exhibit a smooth surface structure. These single SiO$_2$ particles were used as core particles to prepare the composite particles coated with ultra fine TiO$_2$ particles by a homogeneous precipitation method. The thickness and the morphology of the deposited TiO$_2$ layers could be modified by adjusting the reactant concentrations, the reaction time and the temperature. The characteristics of SiO$_2$/TiO$_2$ composite in the field of color cosmetics are to give an UV-cut effect and to enhance the chroma of human skin color, one of optical properties.

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급냉응고된 Mg-Al-Si-xCa 합금의 시효경화 및 미세조직 (Age Hardening and Microstructure in Rapidly Solidified Mg-Al-Si-xCa Alloys)

  • 김완철;박지하;류봉선;박원욱
    • 한국주조공학회지
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    • 제19권5호
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    • pp.433-439
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    • 1999
  • Rapidly solidified Mg-Al-Si base alloys containing Ca were obtained by melt spinning. The melt-spun ribbons were aged isochronally or isothermally to investigate age hardening phenomena and microstructural change according to the alloy composition. Age hardening occurred after aging at $200^{\circ}C$ for 1h mainly due to the precipitation of $Al_2Ca$ and $Mg_2Ca$, which have coherent interfaces with the matrix. With the increase of Ca content, the hardness values of the alloy ribbons were increased. Among the alloys, Mg-10Al-2 Si-3Ca alloy showed a good thermal stability at elevated temperature.

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강소성 가공 및 열처리에 의한 Al-Mg-Si합금의 저주기 피로특성변화 (Changes of Low Cycle Fatigue Behavior of AI-Mg-Si Alloy with Severe Plastic Deformation and Heat Treatment)

  • 김원회;권숙인
    • 열처리공학회지
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    • 제22권4호
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    • pp.217-222
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    • 2009
  • The effects of severe plastic deformation by equal channel angular pressing (ECAP) and subsequent heat treatment on the low cycle fatigue behaviors of Al-Mg-Si alloy were investigated. The specimens which were peak aged at $175^{\circ}C$ after solution treatment showed cyclic hardening at all strain amplitudes, while the specimens ECAPed after solution treatment showed cyclic softening at all strain amplitudes during fatigue. The specimens aged at $100^{\circ}C$ after ECAP showed slight cyclic hardening. Various changes of cyclic fatigue behavior after severe plastic deformation and/or heat treatment were discussed in terms of the microstructural changes and precipitation conditions.

New Hypothesis "Exhaustion of Diffusion-Contributable Vacancies in Core/Rim Structure"

  • Hayshi, Koji;Yanaba, Yutaka
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2002년도 추계학술강연 및 발표대회
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    • pp.8-8
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    • 2002
  • TiC core/(Ti,Mo)C rim structure in TiC-$Mo_2C$-Ni base cermet which is generally prepared by sintering below 145$0^{\circ}C$ had been believed to be generated by the solid diffusion of Mo atoms 1 into TiC grains (D. Moskowitz and M.Humenik, 1r.:1966). Afterward, it was clarified that the c core/rim structure is generated by solution/re-precipitation mechanism : (1) $Mo_2C$ grains and s small TiC grains dissolve into the Ni liquid, (2) the dissolved Mo, Ti and C atoms migrate to the s surface of TiC coarse grains, (3) the Mo, Ti and C precipitate on the surface of TiC coarse g grains and form (Ti,Mo)C solid solution rim, and (4) the Ostwald ripening (grain growth by s solution/re-precipitation mechanism) of TiC-core/(Ti,Mo)-rim grains continues, and thus the w width of (Ti,Mo)C rim (at the same time, the grain size) increases with sintering time, etc. ( (H.Suzuki, K.Hayashi and O.Terada: 1973). The TiC-core was found not to disappear even by s sintering at 190$0^{\circ}C$ (ibid.: 1974) Recently, FeSi core/$Fe_2Si_5$-rim structure in Fe-66.7at%Si thermoelectric aIloy was found to also h hardly shrink and disappear by long heating at an appropriate temperature (1999: M.Tajima and K K.hayashD. Then, the authors considered its cause, and clarified experimentaIly that the disappearance of FeSi-core/$Fe_2Ski_5$-rim structure could be attributed to the exhaustion of diffusion-contributable vacancies in core/rim structure (N.Taniguchi and K.Hayashi:2001). At p present, the authors and my coworker are investigating whether the non-disappearance of TiC c core can be explained also from the new hypothesis "Exhaustion of diffusion-contributable v vacancies in corelrim structure".ure".uot;.

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Si 및 Mg 이온이 교환된 biphasic calcium phosphate 분말의 생체활성 거동 (Bioactivity behavior of Si and Mg ion-substituted biphasic calcium phosphate powders)

  • 김태완;김동현;진형호;이헌수;박홍채;윤석영
    • 한국결정성장학회지
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    • 제22권2호
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    • pp.92-98
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    • 2012
  • 이온이 첨가된 BCP(biphasic calcium phosphate) 분말을 제조하기 위하여 $Ca(NO_3)_2{\cdot}4H_2O$, $(NH_4)_2HPO_4$를 출발 물질로 공침법(co-precipitation process)을 이용하여 합성하였다. Si-BCP 합성을 위하여 TEOS를 Mg-BCP 합성을 위해서는 $Mg(NO_3)_2{\cdot}6H_2O$를 사용하였다. 합성된 분말의 열처리 후 결정상을 분석한 결과 HAp와 ${\beta}$-TCP가 혼재된 상을 관찰할 수 있었다. 분광학적 분석에서도 인산칼슘의 $PO^{3-}_4$$OH^-$ 그룹에 해당하는 밴드도 관찰되었다. 이온이 첨가된 BCP 분말의 생체활성 거동을 평가하기 위하여 Hanks' Balanced Salt Solution(HBSS)에 침적시켜 시간에 따라 형상의 변화 및 결정상을 분석한 결과, 두 샘플 모두에서 빠른 표면 활성을 나타내었다. 세포 성장률 평가에서도 대조군에 비하여 세포성장률이 우수함을 관찰하였다.

분위사상법을 적용한 RCP 시나리오 기반 시군별 홍수 위험도 평가 (Flood Risk Assessment Based on Bias-Corrected RCP Scenarios with Quantile Mapping at a Si-Gun Level)

  • 박지훈;강문성;송인홍
    • 한국농공학회논문집
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    • 제55권4호
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    • pp.73-82
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    • 2013
  • The main objective of this study was to evaluate Representative Concentration Pathways (RCP) scenarios-based flood risk at a Si-Gun level. A bias correction using a quantile mapping method with the Generalized Extreme Value (GEV) distribution was performed to correct future precipitation data provided by the Korea Meteorological Administration (KMA). A series of proxy variables including CN80 (Number of days over 80 mm) and CX3h (Maximum precipitation during 3-hr) etc. were used to carry out flood risk assessment. Indicators were normalized by a Z-score method and weighted by factors estimated by principal component analysis (PCA). Flood risk evaluation was conducted for the four different time periods, i.e. 1990s, 2025s, 2055s, and 2085s, which correspond to 1976~2005, 2011~2040, 2041~2070, and 2071~2100. The average flood risk indices based on RCP4.5 scenario were 0.08, 0.16, 0.22, and 0.13 for the corresponding periods in the order of time, which increased steadily up to 2055s period and decreased. The average indices based on RCP8.5 scenario were 0.08, 0.23, 0.11, and 0.21, which decreased in the 2055s period and then increased again. Considering the average index during entire period of the future, RCP8.5 scenario resulted in greater risk than RCP4.5 scenario.