• Title/Summary/Keyword: Si 분포

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Petrology and Amphibolites(Meta-Dolerite sill) in the Mungyong Areal Korea (문경지역에 분포하는 각섬암(변성조립현무암)에 대한 암석학적연구)

  • Ahn, Kun-Sang;Shin, In-Hyun;Kim, Hee-Nam
    • Journal of the Korean earth science society
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    • v.18 no.6
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    • pp.500-514
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    • 1997
  • With respect to the amphibolites in the Mungyong area of the central part of the Ogcheon Fold Belt, detail field occurrence, texture and geochemical properties within each sills and petrogenetic environment are presented. We confirmed that the amphibolites in the Sangnaeri Formation (Ogcheon Supergroup) and limestone(Cambro-Ordovician Chosun Supergroup) sequences are metamorphosed dolerite sills which are roughly concordant to bedding of country rocks. Geologic distribution of the rocks is distinctly improved compared with those of previous investigations. There are four main sills so far observed in the study area. One is emplaced in limestone(Ls Sill, about 3 m thick) and the others are emplaced in Sangnaeri Formation, which are named First Sill(about 40 m thick), Second Sill(about 100 m thick) and Third Sill(about 40 m thick) from lower to upper horizons of the meta-pelitic sequences. The thick sills are intruded by minor sills and the Third Sill is a composite sill consisting of two main and two minor sills. Each sill has fine grained chilled marginal zones and grain size increases inwards from both contacts. The Second Sill has various vein and white patch in central part and the rock compositions vary systematically from margin to central part. $SiO_2,\;Na_2O,\;K_2O\;and\;P_2O_5$ increase, whereas $TiO_2,\;FeO,\;Al_2O_3\;and\;CaO$ decrease toward the contort. We investigate the major and trace element variations of ten selected rock compositions as intruding initial magma take occurrence and chemical properties into consideration. The compositional variations of them can not be explained by fractionation crystallization of single magma. Geologic distribution, geochemical properties and previous data suggest that amphibolite precursors(basaltic magma) of the study area were intrusive as sill-like in an intracontinental rift environment.

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Environmental factors Affecting Distribution of Heterotrophic Bacteria and Chlorophyll a Content in The (마산만과 행암만 수층의 종속양양세균과 엽록소 a 함량 분포에 미치는 환경요인)

  • Sohn Jae-Hak;Ahn Tae-Young;Kim Sang -Jin
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.3 no.4
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    • pp.65-75
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    • 2000
  • The roles of environmental factors affecting on heterotrophic bacterial distribution at Hangam Bay and Masan Bay in which occurred frequently red tide, during June to November 1996 were investigated. The aquatic environment of Masan Bay and Haengam Bay showed difference in the contents of inorganic nutrients. Haengam Bay may be defined as nitrogen limited aquatic environment. On the other hand, Masan Bay appeared to the appropriate N/P molar ratio of mean 15.9 during the periods of study. By the results of simple regression, chlorophyll a showed significant correlation with precipitation (r=0.813, P<0.05) and phosphorus (r=0.846, P<0.05) at Haengam Bay, but not showed significant correlation with parameters at Masan Bay. The heterotrophic bacteria showed significant correlation with many environmental parameters at Masan Bay (Precipitation, r=0.990, P<0.01 : NO₃-N, r=0.901, P<0.05 : Dissolved inorganic nitrogen, r=0.899, P<0.05 ; N/P molar ratio, r=0.952, P<0.05 : Salinity, r: -0.934, P<0.05) than Haengam Bay (SiO₃-Si, r=0.960, P<0.01). By the results of multiple regression, the chlorophyll a was varied with only 2 factors in Masan Bay (R²=0.100) and 3 factor in Haengam Bay (R²=0.903). The major factor which affected to chlorophyll a was SiO₃-Si (R²%=67.8) in Masan Bay, and -N/P (R²%=37.6) in Haengam Bay. The heterotrophic bacteria were varied with 4 factors in Masan Bay (R²=100) and 2 factor in Haengam Bay (R²%=0.878). The major factor, which affected to heterotrophic bacteria, was SiO₃-Si (R²%=42.3) and salinity (R²%=32.1) in Masan Bay, and SiO₃-Si (R²%=76.3) in Haengam Bay. Resultingly, the influx of freshwater in Masan and Haengam Bay was enriched in inorganic nutrients, and plays an important role in the change of heteroterophic bacteria and chlorophyll a during early summer to autumn.

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Cadmium Concentrations in Environmental Tobacco Smoke of Indoor Environments (실내환경의 환경성담배연기(ETS) 중 카드뮴에 관한 연구)

  • Ha, Kwon Chul;Park, Dong-Uk;Yoon, Chung Sik
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.299-308
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    • 2003
  • The purpose of this study is to investigate cadmium concentrations among metals in ETS (Environmental Tobacco Smoke) of indoor environments and to evaluate the cadmium as a marker of ETS. The correlations of cadmium concentrations and nicotine, 3-EP, RSP, SD (Smoking Density), and SI (Smoking Index). Air samples of metals, nicotine, 3-EP, and RSP were taken in smoking room, smoking allowed office, corridor outside smoking room, and non-smoking office respectively. The SD, ACH, and SI were investigated during sampling. Airborne concentration of cadmium known as human carcinogen were qualified and quantified. The SD was 0.2 to $2.6cig/m^2{\cdot}hr$, and the mean value of SD in smoking rooms was $1.2cig/m^2{\cdot}hr$ that is higher than other researches. The mean of ACH in smoking rooms was 11.1. The concentrations of cadmium showed log-normal distributions and the geometric mean concentrations of cadmium in smoking rooms, corridor outside smoking rooms, smoking allowed offices, and non-smoking offices were $0.045{\mu}g/m^3$, $0.018{\mu}g/m^3$, $0.021{\mu}g/m^3$, and $0.017{\mu}g/m^3$ respectively. The concentrations of cadmium in smoking room showed significant difference according to category of indoor office environments (p<0.05) and showed compliance with occupational exposure limits. The correlation coefficients between cadmium and nicotine, 3-EP, and RSP were 0.53, 0.41, 0.43 respectively. The cadmium among metals showed the highest correlations (r=0.63) with SI. It was recommended cadmium among metals is a good indicator for ETS.

Petrological Study of Cretaceous Granitic Recks in the Waryongsan Area, Southwestern Gyeongsang Basin: Compositional Change of Granitic Rocks by Magma Mingling (경상분지 남서부 와룡산 일대에 분포하는 백악기 화강암류에 관한 암석학적 연구: 마그마 불균질 혼합에 의한 화강암류의 조성변화)

  • Kim Kun-Ki;Kim Jong-Sun;Jwa Yong-Joo
    • The Journal of the Petrological Society of Korea
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    • v.14 no.1
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    • pp.12-23
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    • 2005
  • Cretaceous granitic rocks in the Waryongsan area occur as a stock and show compositional changes with altitude. They include mafic microgranular enclaves (MME) with various sizes and types. The MMEs present clear evidence of magma mingling such as supercooling zone, mantling texture and back veining. The granitic rocks are divided into porphyritic granite, porphyritic granodiorite and fined-grained granite by their petrographic characteristics and modal compositions. The MMEs are discriminated to quartzdioritie, quartzmonzodiorite and tonalite. They have varying areal proportions in each granitic rock-type: 10∼l5% in the porphyritic granite, about 50% in the porphyritic granodiorite, and about 20% in the fined-grained granite. SiO₂ contents shows compositional change of 61.2∼72.0wt.%. Mean SiO₂ contents have 61.7wt.% in the porphyritic granodiorite, 68.6wt.% in the porphyritic granite. and 71.9wt.% in the fined-grained granite, respectively. Major oxide contents of the granitic rocks linearly vary with SiO₂ contents from the porphyiritic granodiorite to the fine-grained granite on Harker diagrams. Linear compositional variations seem to have been caused by differential degrees of mingling between mafic magma and host granite. Where larger amount of mafic magma was injected into the host granitic magma, the two magmas reached to thermal equilibrium more quickly and eventually chemical mixing occurred to produce the composition of the porphyritic granodiorite. On the other hand. less amount of injected mafic magma would have been responsible for mechanical mixing to produce the compositions of the porphyritic granite and the fined-grained granite. Therefore, it is considered that the granitic rocks in the Waryongsan area experienced magmas mingling resulting from the injection of more mafic magma into differentiating granitic magma, and that the compositional changes of the granitic rocks were ascribed to the degree of mingling between the two magmas.

Development of 80 kW RF Thermal Plasma Torch System for Mass Production and Research of Si Nano-Powder Manufacturing Process (양산용 80 kW급 RF Plasma Torch System 개발 및 Si 나노분말 제조 공정 연구)

  • Song, Seok-Kyun;Son, Byungkoo;Kim, Byunghoon;Lee, Moonwon;Sin, Myungsun;Choi, Sunyong;Lee, Kyu-Hang;Kim, Seong-In
    • Journal of the Korean Vacuum Society
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    • v.22 no.2
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    • pp.66-78
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    • 2013
  • In order to develop of 80 kW RF plasma torch system, we achieved three-dimensional simulations for the extraction of more information as temperature in torch and fluid behavior analysis, etc. The position of powder injection tube, the plasma discharge characteristics with various input current and various length of ceramic tube, and the plasma temperature characteristics with process gas flow rate such those was simulated. RF thermal plasma torch designed by simulation was manufactured that was measured to the maximum of 89.3 kW power. The mass production using developed 80 kW RF thermal plasma torch system were investigated by characteristics manufactured of Si nano powder. The mass-production level of Si nano-powder was average of 539 g/hr and high yield rate of 71.6%, respectively. The particle size distribution $D_{99}/D_{50}$ of manufacturing nano-powder was investigated to 1.98 as a good uniform.

Monitoring on Biological Distribution Around Historical Wooden Buildings Adjacent to River - With the Case Study of Silleuksa Temple, Yeoju City?- (수계에 인접한 목조건축물의 생물분포 모니터링 연구 - 여주 신륵사를 중심으로 -)

  • Kim, Si Hyun;Lee, Hyun Ju;Lee, Min Young;Jeong, Seon Hye;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.33 no.4
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    • pp.267-274
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    • 2017
  • The Silleuksa temple in Yeoju city is adjacent to the South Han River and often has high humidity and fog days. In addition, its proximity to forests renders it prone to damage by insects and microorganisms. In order to obtain the basic data necessary for the establishment of a cultural property preservation management plan, the biological distribution of the wooden buildings and the termite distribution in the surrounding forests were monitored for three years. The wood-boring bee, an insect known to inflict damage to heritage structures, was confirmed, and the distribution of insects varied annually and seasonally, presumably due to the location characteristics of the site and the climate change during the year. In the forest behind, termite colonies were identified as a whole and their distribution pattern was different every year. As per the results of the microorganism survey, the species distribution and pollution degree were different at the entrance of the building. Therefore, it needs continuous biological distribution and conservation environment monitoring to mitigate the effects of wood-damaging organisms.were different according to the entrance of the building.

A Study on Uncertainty of Risk of Failure Based on Gumbel Distribution (Gumbel 분포형을 이용한 위험도에 관한 불확실성 해석)

  • Heo Jun-Haeng;Lee Dong-Jin;Shin Hong-Joon;Nam Woo-Sung
    • Journal of Korea Water Resources Association
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    • v.39 no.8 s.169
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    • pp.659-668
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    • 2006
  • The uncertainty of the risk of failure of hydraulic structures can be determined by estimating the variance of the risk of failure based on the methods of moments, probability weighted moments, and maximum likelihood assuming that the underlying model is the Gumbel distribution. In this paper, the variance of the risk of failure was derived. Monte Carlo simulation was peformed to verify the characteristics of the derived formulas for various sample size, design life, nonexceedance probability, and variation coefficient. As the results, PWM showed the smallest relative bias and root mean square error than the others while ML showed the smallest ones for relatively large sample siBes regardless of design life and nonexceedance probability. Also, it was found that variation coefficient does not effect on the relative bias and relative root mean square error.

Distribution of trace metals in the deep ocean waters of the East Sea (동해심층수 개발해역의 미량금속 분포)

  • Kim, Kyung-Tae;Jang, Si-Hun;Kim, Eun-Soo;Cho, Sung-Rok;Park, Jun-Kun;Moon, Deok-Soo;Kim, Hyeon-Ju
    • Proceedings of KOSOMES biannual meeting
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    • 2006.11a
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    • pp.163-168
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    • 2006
  • In order to develop the deep ocean water, we performed to study the characteristics of vertical distribution of dissolved trace metals(Cd, Co, Cu, Ni, Pb, Zn) from Apr. to Oct., 2005 in the East Sea. Total six sampling sites were selected in Gangwon-Do and Gyeongsanbuk-Do. Accuracy of the analytical procedures was assessed by the SRM(CASS-4) for dissolved metals in seawater. The mean recoveries of CASS-4 ranged from 89.4% for Co to 99.8% for Cd. In this study, the dissolved metal concentrations varied with space, time and element. The metal concentrations showed wide range in the surface. Cd, Ni and Zn showed a nutrient-type profile with surface depletion and enrichment at depth. However, Co, Cu and Pb were irregular in the vertical distribution. All metal concentrations studied in this study are lower than the criteria of Korean drinking water.

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Correlation between Charged Silicon Nanoparticles in the Gas Phase and the Low Temperature Deposition of Crystalline Silicon Films during Hot Wire Chemical Vapor Deposition

  • Yu, Seung-Wan;Hong, Ju-Seop;Kim, Jeong-Hyeong;Yu, Sin-Jae;Hwang, Nong-Mun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.283.2-283.2
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    • 2014
  • 열필라멘트 화학증착공정(Hot Wire Chemical Vapor Deposition)에서 기상 에서 생성되는 하전된 실리콘 나노입자와 저온결정성 실리콘박막 증착의 연관성을 압력의 변화에 따른 상호비교를 통해 조사하였다. 필라멘트 온도는 $1800^{\circ}C$로 고정시키고 0.3~2 torr의 범위에서 공정 압력을 변화시키면서 증착하였다. 압력이 증가함에 따라 증착된 실리콘 박막의 결정화도는 증가하였으며, 증착속도는 감소하였다. 반응기 압력에 따른 기상에서 생성되는 나노입자의 크기분포의 변화를 조사하기 위하여 탄소막이 코팅된 투과전자현미경(Transmission Electron Microscopy) 그리드 위에 실리콘 나노입자를 포획하고 관찰하였다. 포획된 실리콘 나노입자의 크기분포와 개수농도는 압력이 증가함에 따라 감소하였다. 투과전자현미경을 이용하여 분석한 결과, 나노입자는 결정성 구조를 보였다. 압력이 증가함에 따라 나노입자의 크기가 감소하고 개수농도가 감소하는 것은 증착속도의 감소와 관련됨을 알 수 있다. 한편, 공정압력 증가에 따른 나노입자의 크기분포 및 개수농도 감소와 증착속도의 감소는 일반적으로 알려진 기상에서 석출하는 고상의 평형석출량(equilibrium amount of precipitation)이 압력의 증가함에 따라 증가한다는 사실과 일치하지 않는다. 이러한 압력경향성은 Si-H 시스템이 0.3~2 torr의 압력 영역에서 retrograde solubility를 갖는 것을 의미한다. 나노입자의 하전여부, 크기분포 및 개수농도를 측정하기 위하여 입자빔질량분석장비(Particle Beam Mass Spectroscopy)를 이용하였다. 그 결과, 실리콘 나노입자는 양 또는 음의 극성을 가진 하전된 상태임을 확인하였고, 투과전자현미경(TEM) grid에 포획한 실리콘 나노입자의 크기와 경향성이 일치하였다. 이는 나노입자가 저온의 기판에서 핵생성되어 성장하여 생성된 것이 아니라 열필라멘트 주위의 고온영역에서 생성된 것을 의미한다.

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A Study on Estimation of Rainfall Erosivity Using Frequency Analysis for Hapcheon Gauging Station (빈도해석에 의한 합천관측소의 강우침식인자 산정 연구)

  • Ahn, Jung Min;Lee, Geun Suk;Lyu, Si Wan
    • Journal of Korean Society for Geospatial Information Science
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    • v.20 no.4
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    • pp.19-27
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    • 2012
  • RUSLE(Revised Universal Soil Loss Equation) has been widely used to estimate the soil loss amount of watersheds from rainfall erosivity, soil erodibility, topographic features and cropping management condition. Rainfall erosivity is the most dominant and sensitive factor among these so that the determination of reliable rainfall erosivity is essential to estimate the soil loss of watershed. Since there has been no criterion to determine the rainfall erosivity in Korea, the empirical values, determined from the relation between the annual average rainfall and erosivity or suggested by TBR(Transport Research Board), have been used for designing the erosion control structure and controlling the soil erosion for watersheds. In this study, the procedure for estimating the rainfall erosivity using frequency analysis is proposed. The most fitted distribution function, with calculated rainfall erosivities with various frequencies and durations, has been also selected. The suggested procedure can be used to estimate the optimal value of rainfall erosivity for RUSLE in order to design soil erosion structures and control the soil erosion in watersheds effectively.