• Title/Summary/Keyword: Si(III)-H

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Effect of Silicate Mineral Filtered Water and Silicate Mineral Additive on Growth Performance and Pork Quality (규산염 광물질로 정수된 급이수 및 사료내 규산엽광물질 첨가제의 급여가 돼지의 성장능력 및 돈육의 품질에 미치는 영향)

  • Kong, C.S.;Ju, W.S.;Kil, D.Y.;Lim, J.S.;Yun, M.S.;Kim, Y.Y.
    • Journal of Animal Science and Technology
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    • v.46 no.5
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    • pp.743-752
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    • 2004
  • This experiment was conducted to investigate the effect of filtered water with silicate minerals on growth performance and pork quality. A total of 64 pigs were allotted at 37.95 kg body weight to 4 treatments in a randomized complete block(RCB) design. Each treatment had 4 replicates and treatments were I) Con(basaI diet). 2) Si-I(consumed silicate mineral filtered water and silicate mineral additive during 4 weeks before market weight), 3) Si-Il( consumed silicate mineral filtered water and silicate mineral additive during 8 weeks before market weight) and 4) Si-I1I(consumed silicate mineral filtered water and silicate mineral additive during 12 weeks before market weight). Silicate complex was added at 0.8% to basal diet. All pigs were allowed to feed and water ad libitum for 12 weeks. During last 4 weeks, average daily gain(ADG) in Si-Il and Si-III group was higher than that in Si-I group(P < 0.05). However overall experimental period, there were no significant differences in growth performance among all treatments. Acceptability of cooked pork at 7th day after slaughter in Si-lII group was higher than that in Con group(P < 0.05). The value of pH of fresh pork at 6 hours after slaughter was lower in Si-I1I group than that in Con group(P < 0.05). TBA values of fresh pork at 14th day after slaughter were lower in Si-II and Si-III groups than Con group(P < 0.05). These results demonstrated that pork quality could be improved when pigs consumed both silicate mineral and silicate mineral filtered water. However, growth performance was not improved by the consumption of silicate mineral filtered water and silicate mineral.

The Environmental Control of $Er^{3+}$ ions in $R-SiO_2/ZrO_2$ Sol-Gel Matrix ($R-SiO_2/ZrO_2$ 졸-겔 재료내 $Er^{3+}$이온의 결합 환경 제어)

  • 김주현;권정오;석상일;안복엽
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.224-224
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    • 2003
  • 광통신을 위한 구성 요소는 빛을 발생시키는 발광소자, 빛을 검출하는 수광소자 그리고 광신호를 처리하는 광신호처리 소자로 구성된다. 이때 각 소자간 광전송과 광소자에 의한 광 신호 처리 과정에서 광전송 손실이 심각하게 일어나 광정보를 상실하게 되므로 각 요소별로 광신호 증폭이 반드시 필요하다. 뿐만 아니라 완전 광화에 의한 초고속/대용량 광통신망의 구축에는 저가이며, 광집적화가 가능한 광도파로형 광증폭기가 요구되고 있다. 짧은 거리에 높은 증폭 효율을 얻기 위한 광도파로형 광증폭기를 구현하기 위해서는 광통신 파장대인 1.55$\mu\textrm{m}$ 대역의 증폭이 가능한 Er 이온을 고농도로 도핑 할 필요가 있다. 그러나 Er 이온을 단순히 고농도로 첨가하면 Er-Er 간 뭉침 현상에 의해 더 이상의 증폭이 어렵게 된다. 본 연구에서는 이러한 문제를 해결하면서 스핀 코팅이 가능하여 저가 공정이 가능한 유/무기 졸-겔 재료 내에 Er 이온을 제어된 방법으로 첨가하고 그 결합 환경을 FT-IR 및 $^{17}$ O-NMR로 분석하였다. 유/무기 졸겔 재료 제조를 위하여 먼저 MPTS(MethAcryoxyPropylTrimethoxySilane)를 부분 가수분해한 후 ZrOCl$_2$.8$_2$O (Zirconyl Chloride Octahydrate) 와 ErCl$_3$. 6$H_2O$ (Erbium(III) Chloride Hexahydrate)를 순차적으로 결합시키고, Zr/MPTS 및 Zr/Er의 첨가비에 따른 발광 특성을 PL(photoluminescence) 스팩트럼으로 분석하여 Er 이온의 주위 결합 환경이 PL에 미치는 영향을 조사하였다. 또한 Si 기판에 코팅한 Er이 도핑된 유/무기 하이브리드 졸-겔 코팅막의 굴절율 등 광도파로 재료로서의 특성도 프리즘 커플러 등을 이용하여 조사하였다.

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Synthesis and Characterization of the Large Single Crystal of Fully K+-exchanged Zeolite X (FAU), |K80|[Si112Al80O384]-FAU (Si/Al=1.41)

  • Lim, Woo-Taik;Jeong, Gyo-Cheol;Park, Chang-Kun;Park, Jong-Sam;Kim, Young-Hun
    • Bulletin of the Korean Chemical Society
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    • v.28 no.1
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    • pp.41-48
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    • 2007
  • Large colorless single crystals of sodium zeolite X, stoichiometry |Na80 |[Si112Al80O384]-FAU, with diameters up to 200 μm and Si/Al = 1.41 have been synthesized from gels with the composition of 2.40SiO2 : 2.00NaAlO2 : 7.52NaOH : 454H2O : 5.00TEA. One of these, a colorless octahedron about 200 μm in cross-section has been treated with aqueous 0.1 M KNO3 for the preparation of K+-exchanged zeolite X. The crystal structure of |K80|[Si112Al80O384]-FAU per unit cell, a = 24.838(4) A, dehydrated at 673 K and 1 × 10-6 Torr, has been determined by single-crystal X-ray diffraction techniques in the cubic space group Fd at 294 K. The structure was refined using all intensities to the final error indices (using only the 707 reflections for which Fo > 4σ (Fo)) R1 = 0.075 (based on F) and R2 = 0.236 (based on F2). About 80 K+ ions per unit cell are found at an unusually large number of crystallographically distinct positions, eight. Eleven K+ ions are at the centers of double 6-rings (D6Rs, site I; K-O = 2.492(6) A and O-K-O (octahedral) = 88.45(22)o and 91.55(22)o). Site-I' position (in the sodalite cavities opposite D6Rs) is occupied by five K+ ions per unit cell; these K+ ions are recessed 1.92 A into the sodalite cavities from their 3-oxygen planes (K-O = 2.820(19) A, and O-K-O = 78.6(6)o). Twety-three K+ ions are found at three nonequivalent site II (in the supercage) with occupancies of 5, 9, and 9 ions; these K+ ions are recessed 0.43 A, 0.75 A, and 1.55 A, respectively, into the supercage from the three oxygens to which it is bound (K-O = 2.36(13) A, 2.45(13) A, and 2.710(13) A, O-K-O = 116.5(20)o, 110.1(17)o, and 90.4(6)o, respectively). The remaining sixteen, thirteen, and twelve K+ ions occupy three sites III' near triple 4-rings in the supercage (K-O = 2.64(3) A, 2.94(3) A, 2.73(5) A, 2.96(6) A, 3.06(4) A, and 3.08(3) A).

Reactivity of aluminosilicate materials and synthesis of geopolymer mortar under ambient and hot curing condition

  • Zafar, Idrees;Tahir, Muhammad Akram;Hameed, Rizwan;Rashid, Khuram;Ju, Minkwan
    • Advances in concrete construction
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    • v.13 no.1
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    • pp.71-81
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    • 2022
  • Aluminosilicate materials as precursors are heterogenous in nature, consisting of inert and partially reactive portion, and have varying proportions depending upon source materials. It is essential to assess the reactivity of precursor prior to synthesize geopolymers. Moreover, reactivity may act as decisive factor for setting molar concentration of NaOH, curing temperature and setting proportion of different precursors. In this experimental work, the reactivities of two precursors, low calcium (fly ash (FA)) and high calcium (ground granulated blast furnace slag (GGBS)), were assessed through the dissolution of aluminosilicate at (i) three molar concentrations (8, 12, and 16 M) of NaOH solution, (ii) 6 to 24 h dissolution time, and (iii) 20-100℃. Based on paratermeters influencing the reactivity, different proportions of ternary binders (two precursors and ordinary cement) were activated by the combined NaOH and Na2SiO3 solutions with two alkaline activators to precursor ratios, to synthesize the geopolymer. Reactivity results revealed that GGBS was 20-30% more reactive than FA at 20℃, at all three molar concentrations, but its reactivity decreased by 32-46% with increasing temperature due to the high calcium content. Setting time of geopolymer paste was reduced by adding GGBS due to its fast reactivity. Both GGBS and cement promoted the formation of all types of gels (i.e., C-S-H, C-A-S-H, and N-A-S-H). As a result, it was found that a specified mixing proportion could be used to improve the compressive strength over 30 MPa at both the ambient and hot curing conditions.

Benzyl Isothiocyanate-Induced Cytotoxicity via the Inhibition of Autophagy and Lysosomal Function in AGS Cells

  • Po, Wah Wah;Choi, Won Seok;Khing, Tin Myo;Lee, Ji-Yun;Lee, Jong Hyuk;Bang, Joon Seok;Min, Young Sil;Jeong, Ji Hoon;Sohn, Uy Dong
    • Biomolecules & Therapeutics
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    • v.30 no.4
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    • pp.348-359
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    • 2022
  • Gastric adenocarcinoma is among the top causes of cancer-related death and is one of the most commonly diagnosed carcinomas worldwide. Benzyl isothiocyanate (BITC) has been reported to inhibit the gastric cancer metastasis. In our previous study, BITC induced apoptosis in AGS cells. The purpose of the present study was to investigate the effect of BITC on autophagy mechanism in AGS cells. First, the AGS cells were treated with 5, 10, or 15 μM BITC for 24 h, followed by an analysis of the autophagy mechanism. The expression level of autophagy proteins involved in different steps of autophagy, such as LC3B, p62/SQSTM1, Atg5-Atg12, Beclin1, p-mTOR/mTOR ratio, and class III PI3K was measured in the BITC-treated cells. Lysosomal function was investigated using cathepsin activity and Bafilomycin A1, an autophagy degradation stage inhibitor. Methods including qPCR, western blotting, and immunocytochemistry were employed to detect the protein expression levels. Acridine orange staining and omnicathepsin assay were conducted to analyze the lysosomal function. siRNA transfection was performed to knock down the LC3B gene. BITC reduced the level of autophagy protein such as Beclin 1, class III PI3K, and Atg5-Atg12. BITC also induced lysosomal dysfunction which was shown as reducing cathepsin activity, protein level of cathepsin, and enlargement of acidic vesicle. Overall, the results showed that the BITC-induced AGS cell death mechanism also comprises the inhibition of the cytoprotective autophagy at both initiation and degradation steps.

The Flora of Vascular Plants of Mt. Ja-Ung (Gyeong-gi-do, Pa-ju-si) Adjacent to the DMZ (DMZ 일원 자웅산(경기도 파주시) 일대의 관속식물상)

  • Young-Min Choi;Jong-Won Lee;Jin-Heon Song;Kyung-Ryul Byun;Jaesang Chung;Hee-Young Gil
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2021.04a
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    • pp.33-33
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    • 2021
  • 자웅산(264.3m)은 DMZ 접경지역인 경기도 파주시 법원읍에 위치하며, 백두대간 줄기 중 한북정맥을 따라 동쪽으로는 노고산(401m), 서쪽으로는 명학산(220m) 사이에 위치하고 있다. 2020년 4월부터 10월까지 계절별로 1회씩 총 3회 식물상 조사를 진행하였고 화상자료와 증거표본을 확보하였다. 본 조사로부터 자웅산 일대에 자생하는 관속식물은 82과 208속 267종 9아종 22변종 4품종으로 총 303분류군이 확인되었다. 양치식물은 10과 18분류군, 나자식물은 2과 6분류군, 쌍자엽식물이 62과 226분류군, 단자엽식물이 8과 53분류군으로 확인되었다. 개나리(Forsythia koreana (Rehder) Nakai), 백운산원추리(Hemerocallis hakuunensis Nakai), 키버들(Salix koriyanagi Kimura ex Goerz) 등 3과 3분류군의 특산식물이 확인되었다. 침입외래식물로는 가시도꼬마리(Xanthium italicum Moretti), 단풍잎돼지풀(Ambrosia trifida L.), 미국개기장(Panicum dichotomiflorum Michx.), 서양민들레(Taraxacum officinale F.H.Wigg.), 애기망초(Conyza parva Cronquist) 등 7과 23분류군으로 조사되어 조사식물 303분류군의 7.6%를 차지하였다. 환경부 지정 식물구계학적 특정종은 V등급이 미나리냉이(Cardamine leucantha (Tausch) O.E.Schulz), IV등급이 당단풍나무(Acer pseudosieboldianum (Pax) Kom.), 산복사나무(Prunus davidiana (Carrière) Franch.) 등 2분류군, III등급이 금낭화(Dicentra spectabilis (L.) Lem.), 꽃쥐손이(Geranium platyanthum Duthie), 분비나무(Abies nephrolepis (Trautv. ex Maxim.) Maxim.) 등 7분류군이 확인되어 III등급 이상의 특정종은 10분류군으로 파악된다.

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반극성 (11-22)n형 GaN의 실리콘 도핑농도 증가에 따른 결함감소와 이에 따른 반극성(11-22) GaN계 LED소자의 특성향상에 대한 연구

  • Lee, Jae-Hwan;Han, Sang-Hyeon;Song, Gi-Ryong;Lee, Seong-Nam
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.308.2-308.2
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    • 2014
  • 최근 III-N계 물질 기반의 광 반도체 중 m-면 사파이어 기판을 사용하여 반극성 (11-22) GaN박막을 성장하는 광반도체의 발광효율을 높이려는 연구가 많이 진행되고 있다. 하지만, 반극성 (11-22) GaN와 m-면 사파이어 기판과의 큰 격자상수 차이와 결정학적 이방성의 차이에 의해 많은 결정 결함이 발생하게 된다. 이러한 결정결함들은 반극성 LED소자내에서 누설전류 및 비발광 재결합, 순방향전압 등의 소자특성을 저하시키는 큰 요인이 되기 때문에 고효율 발광소자를 제작함에 있어 어려움을 야기시킨다. 이러한, 반극성 LED 소자의 효율 향상을 위해 결함 분석에 대한 연구를 주를 이루고 있는 상황으로, n-GaN층에 Si도핑에 관한 연구가 진행되고 있다. 이미 극성과 비극성에서는 n-GaN층에 Si이 도핑이 증가될수록 결정질이 향상되고, 양자우물의 계면의 질도 향상 되었다는 보고가 있다. 본 연구에서는 반극성 (11-22) GaN 기반의 발광소자를 제작함에 있어 n-GaN 층의 도핑 농도 변화를 통한 반극성 GaN 박막의 결정성 및 전기적 특성 변화에 따른 LED소자의 전계 발광 특성에 대한 연구를 진행하였다. 금속유기화학증착법을 이용하여 m-면 사파이어 기판에 $2.0{\mu}m$두께의 반극성 (11-22) GaN 박막을 저온 GaN완충층이 존재하지 않는 고온 1단계 성장법을 기반으로 성장하였다.[3] 이후, $2.0{\mu}m$ 반극성 (11-22) GaN 박막 위에 $3.5{\mu}m$ 두께의 n-GaN 층을 성장시켰다. 이때, n-형 도펀트로 SiH4 가스를 4.9, 9.8, 19.6, 39.2 sccm으로 변화하여 성장하였다. 이 4가지 반극성 (11-22) n-GaN 템플릿을 이용하여 동일 구조의 InGaN/GaN 다중양자우물구조와 p-GaN을 성장하여 LED 구조를 제작하였다. X-선 ${\omega}$-rocking curve를 분석한 결과, 이러한 특성은 반극성 (11-22) n-GaN층의 Si 도핑농도 증가에 따라서 각 (0002), (11-20), (10-10) 면에서 결정 결함이 감소하고, 반극성 (11-22) n형 GaN템플릿을 이용하여 성장된 반극성 GaN계 LED소자는 20mA인가 시 도핑 농도 증가에 따라 9.2 V에서 5.8 V로 전압이 감소하였으며 역방향 전류에서도 누설전류가 감소함이 확인되었다. 또한, 전계 발광세기도 증가하였는데, 이는 반극성 n형 GaN박막의 실리콘 도핑농도 증가에 따라 하부 GaN층의 결정성이 향상과 더불어 광학적 특성이 향상되고, n형 GaN층의 전자 농도 및 이동도의 동시 증가에 따라 전기적 특성이 향상 됨에 따라 LED소자의 전계 발광 특성이 향상된 것으로 판단된다.

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Vascular Plants of Construct-Reserved Site of Ecological Stream, Sohyeoncheon in Gyeongju-si (경주시 생태하천 예정지인 소현천의 관속식물상)

  • You, Ju-Han
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.21 no.5
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    • pp.61-79
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    • 2018
  • The purpose of this study is to investigate the flora of Sohyeoncheon which is planned for ecological restoration and river maintenance from upstream to downstream, and also to collect the ecological data to cope with the change of the ecosystem of Sohyeoncheon. The numbers of vascular plants were summarized as 336 taxa including 82 families, 233 genera, 298 species, 1 subspecies, 33 varieties and 4 forms. The rare plants were 3 taxa including Aristolochia contorta Bunge, Prunus yedoensis Matsum.(planting) and Koelreuteria paniculata Laxmann. The Korean endemic plants were 4 taxa including Populus tomentiglandulosa T.B.Lee(planting), Lespedeza maritima Nakai, Forsythia koreana (Rehder) Nakai(planting) and Weigela subsessilis (Nakai) L.H.Bailey. The specific plants by floristic region were 15 taxa including 1 taxon of grade V, grade IV and grade II each, 4 taxa of grade III and 8 taxa of grade I. The naturalized plants were 60 taxa and the invasive alien plants were 3 taxa. The results of analysis by vertical structures showed that naturalized plants included 31 taxa of upstream, 53 taxa of midstream and 38 taxa of downstream. An analysis of crossing structures showed that 2 taxa of water channel, 3 taxa of low waterside, 41 taxa of high waterside and 48 taxa of bank.

OBSERV ATION OF MICRO-STRUCTURE AND OPTICAL PROPERTISE OF TITANIUM DIOXIDE THIN FILMS USING OPTICAL MMEHODS

  • Kim, S.Y.;Kim, H.J.
    • Journal of the Korean institute of surface engineering
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    • v.29 no.6
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    • pp.788-796
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    • 1996
  • $TiO_2$ films prepared by RF magnetron sputtering, electron beam evaporation, ion assisted deposition (IAD) and sol-gel method are prepared on c-Si substrate and vitreous silica substrate respectively. From the transmission spectra of $TiO_2$ films on vitreous silica substrate in the spectral region from 190 nm to 900 nm, k($\lambda$) of $TiO_2$ is obtained. Using k($\lambda$) in the interband transition region the coefficients of the quantum mechanical dispersion relation of an amorphous $TiO_2$ and hence n($\lambda$) including the optically opaque region of above fundamental transition energy are obtained. The spectroscopic ellipsometry spectra of $TiO_2$ films in the spectral region of 1.5-5.0eV are model analyzed to get the film packing density variation versus i) substrate material, ii) film thickness and iii) film growth technique. The complex refractive index change of these $TiO_2$ films versus water condensation is also studied. Film micro-structures by SE modelling results are compared with those by atomic force microscopy images and X-ray diffraction data.

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Wang-ime Oreum Flora on Jeju Island (제주도 왕이메오름의 식물상)

  • Jee-Hyun Park;Min-Hee Seo;Sung-Pil Moon;Gwanpil Song
    • Journal of Environmental Science International
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    • v.32 no.12
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    • pp.861-881
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    • 2023
  • This study investigated the flora of the Wang-ime oreum located on Seogwipo-si, Jeju-do, to basic data for the Jeju Island plant distribution. A total of 366 taxa were found with 94 families, 240 genera, 358 species, 1 subspecies, 6 varieties, and 1 forma. The floristic target species in Korea appeared as 2 taxa of grade V, 13 taxa of grade IV, 46 taxa of grade III, 5 taxa of grade II, and 49 taxa of grade I. There were 14 taxa for naturalized plants. The different plant life forms that appeared were large ground plants (M)(54 taxa), small land plants (N) (52 taxa), epiphyte (E) (6 taxa), indicator plants (Ch) (4 taxa), and semi-aquatic plants (H) (168 taxa), There were 34 and 48 taxa of plants(G) and annuals (Th) respectively. From these results, Wang-ime oreum, which is adjacent to ranches and grasslands, has little artificial interference, as more plants are distributed, and fewer naturalized plants are found than in Suwolbong and Dangsanbong. Accordingly, each oreum plays an important role in the flora of Jeju-do, thus a management plan tailored to the characteristics of the volcano is necessary.