• Bulletin of the Korean Chemical Society
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• 제6권4호
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• pp.218-221
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• 1985

Transient charging and discharging currents as well as space charge limited currents have been measured in biaxially stretched poly(vinylidene fluoride) film under various poling fields and temperatures. At low temperatures and short poling times, the I-V characteristics showed shallow trap behavior. When the current values extrapolated to the infinite time, the I-V characteristics indicate that the distribution of the trap energy levels is uniform or very broad. The abnormal suppression of current at higher poling voltages and the high discharge rate observed also in the same voltage range are attributed to the morphological changes due to dipole reorientation.

• Bulletin of the Korean Chemical Society
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• 제24권1호
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• pp.65-69
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• 2003

The kinetic and chemical mechanisms of AChE-catalyzed hydrolysis of short-chain thiocholine esters are relatively well documented. Up to propanoylthiocholine (PrTCh) the chemical mechanism is general acid-base catalysis by the active site catalytic triad. The chemical mechanism for the enzyme-catalyzed butyrylthiocholine(BuTCh) hydrolysis shifts to a parallel mechanism in which general base catalysis by E199 of direct water attack to the carbonyl carbon of the substrate. [Selwood, T., et al. J. Am. Chem. Soc. 1993, 115, 10477- 10482] The long chain thiocholine esters such as hexanoylthiocholine (HexTCh), heptanoylthiocholine (HepTCh), and octanoylthiocholine (OcTCh) are hydrolyzed by electric eel acetylcholinesterase (AChE). The kinetic parameters are determined to show that these compounds have a lower Michaelis constant than BuTCh and the pH-rate profile showed that the mechanism is similar to that of BuTCh hydrolysis. The solvent isotope effect and proton inventory of AChE-catalyzed hydrolysis of HexTCh showed that one proton transfer is involved in the transition state of the acylation stage. The relationship between the dipole moment and the Michaelis constant of the long chain thiocholine esters showed that the dipole moment is the most important factor for the binding of a substrate to the enzyme active site.

• 한국산학기술학회논문지
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• 제14권4호
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• pp.1908-1914
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• 2013

본 논문에서는 지상파 디지털 방송 수신용 광대역 평면 야기 안테나의 설계방법에 대해 연구하였다. 다이폴을 급전하는 코플래너 스트립은 스트립에 내장된 마이크로스트립과 연결되고 종단은 단락되어 있다. 급전되는 다이폴에 근접한 영역에 폭이 넓은 직사각형 스트립 도파기를 부가하여 광대역 임피던스 정합과 고주파 대역의 이득특성을 구현하였고, 접지면 반사기를 추가하여 저주파 대역의 이득 특성을 개선하였다. 안테나를 소형화하기 위해 다이폴과 반사기의 모양을 반 보우-타이(V) 형으로 변형하였으며, 여러 가지 파라미터들이 안테나 특성에 미치는 영향을 관찰하였다. 제안된 구조의 안테나를 지상파 DTV 주파수 대역인 470-806 MHz 대역에서 동작하도록 설계하였다. 최적화된 안테나를 FR4 기판 상에 제작하고 특성을 실험한 결과 VSWR < 2 인 대역 450-848 MHz, 이득 > 4.1 dBi, 전후방비 > 10.4 dB 등의 우수한 성능을 갖는 것을 확인하였다.

• Bulletin of the Korean Chemical Society
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• 제28권8호
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• pp.1249-1255
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• 2007

We have investigated the photophysical properties of dansyl-N-methylaminobenzoic acid (DABAH) as a ligand and its lanthanide (Ln3+)-cored complexes (Ln3+-(DABA)3(terpy)) in order to determine the main energy transfer pathway for sensitized near infrared emission of Ln3+ ions (Ln3+ = Nd3+ and Er3+) in Ln3+- (DABA)3(terpy). The fluorescence spectrum of DABAH shows a large Stokes shift with increasing solvent polarity. This large Stokes shift might be due to the formation of a twisted intramolecular charge transfer (TICT) state, as demonstrated by the large dipole moment in the excited state. It is in good agreement with the result that the phosphorescence even in the Gd3+-cored complex based on the DABAH ligand was not observed, maybe due to the highly forbidden character of the S1 → T1 transition in the DABAH ligand. A short decay component (ca. 1 ns) was observed in Er3+-(DABA)3(terpy) whereas the fluorescence lifetimes of DABAH and its Gd3+-(DABA)3(terpy) are observed about ~10 ns. The short component could be originated from the energy transfer process between the ligand and the Ln3+ ion. Based on the fluorescence of DABAH its Ln3+- (DABA)3(terpy), the sensitization of Ln3+ luminescence in the Ln3+-(DABA)3(terpy) takes place by the energy transfer via the TICT state of DABAH in the excited singlet state rather than via the excited triplet state.

• Journal of Astronomy and Space Sciences
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• 제32권4호
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• pp.317-325
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• 2015

Energy spectra of electron microbursts from 170 keV to 340 keV have been measured by the solid-state detectors aboard the low-altitude (680 km) polar-orbiting Korean STSAT-1 (Science and Technology SATellite). These measurements have revealed two important characteristics unique to the microbursts: (1) They are produced by a fast-loss cone-filling process in which the interaction time for pitch-angle scattering is less than 50 ms and (2) The e-folding energy of the perpendicular component is larger than that of the parallel component, and the loss cone is not completely filled by electrons. To understand how wave-particle interactions could generate microbursts, we performed a test particle simulation and investigated how the waves scattered electron pitch angles within the timescale required for microburst precipitation. The application of rising-frequency whistler-mode waves to electrons of different energies moving in a dipole magnetic field showed that chorus magnetic wave fields, rather than electric fields, were the main cause of microburst events, which implied that microbursts could be produced by a quasi-adiabatic process. In addition, the simulation results showed that high-energy electrons could resonate with chorus waves at high magnetic latitudes where the loss cone was larger, which might explain the decreased e-folding energy of precipitated microbursts compared to that of trapped electrons.

• Journal of Magnetics
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• 제15권3호
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• pp.116-122
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• 2010

An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

• 한국인터넷방송통신학회논문지
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• 제16권5호
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• pp.197-203
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• 2016

본 논문에서는 저궤도 소형위성에 탑재하여 빔 조향을 능동적으로 할 수 있는 다이폴 안테나를 설계하였다. 제안된 안테나는 야기-우다 안테나의 원리를 기반으로 하였으며, 2개의 무급전 기생소자를 T자형으로 형성시켜 수직소자의 길이를 고정시킨 후 수직소자의 끝단에서의 open, short에 따라 도파기 또는 반사기로 작동되게 하였다. 설계된 안테나는 UHF 대역의 436.5 MHz를 중심으로 위성-위성 간과 위성-지상 간의 링크버짓을 통해 안테나의 목표 이득을 정하였다. 안테나 특성을 향상시키기 위해 무급전 기생소자의 수직소자인 transformer의 길이를 변경시켰으며, transformer의 길이가 ${\lambda}/4$보다 ${\lambda}/2$일 때 최대 빔 방향 이득이 0.5 dB 향상되었다. 실제 ${\lambda}/2$ transformer 제작 시에는 무급전 기생 소자의 open, short를 다이오드와 캐패시터, 인덕터로 구성된 on/off switch를 이용하여 구현하였다. 그 결과 위성-위성 간 이득은 평균 5.92 dBi로 나타났으며 위상-지상 간 이득은 평균 0.99 dBi로 확인되어 링크버짓을 통해 정한 목표 스펙을 충분히 만족하였다.

• 한국전자파학회논문지
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• 제28권11호
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• pp.902-915
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• 2017

최근 모바일 기기는 다기능, 고성능화로 정보 처리 속도는 빠르게 증가하고, 제품의 크기는 소형화, 집적화되면서 기기 내부의 회로는 안테나 또는 인접 회로로부터 방사되는 전자기 간섭에 쉽게 노출되게 되었고, 제품의 성능 저하 및 오동작을 유발시킨다. 이를 방지하기 위해 제품의 설계 단계에서 EM 시뮬레이션을 통해 제품의 전자기적 특성을 예측하고, 이를 고려하여 설계해야 하지만, EM 시뮬레이터는 분석 시간이 오래 걸리고, 분석시간을 단축시키기 위해서 고사양의 시스템 자원이 필요하다. 본 논문에서는 PEEC 방법을 이용하여 원형 전선에 대한 전자기적 특성을 빠르게 분석하는 방법을 제시하였다. PEEC 방법은 도체 내부의 전계 적분 방정식으로부터 도체의 등가회로를 모델링하고, 회로 분석법을 통해 전자기적 특성을 분석할 수 있는 방법으로, EM 시뮬레이터 대비 빠른 시간 안에 전자기적 특성을 분석할 수 있다. 본 논문에서 제시한 방법을 통해 다이폴 안테나로부터 전송선로로의 전자기 결합을 주파수 영역에서 분석하였고, 이를 EM 시뮬레이터의 분석 결과와 비교해 PEEC 방법의 유효함을 검증하였다.

• 한국전자파학회논문지
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• 제17권12호
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• pp.1240-1248
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• 2006

본 논문에서는 유도 결합 구조를 응용하여 등방향 방사 특성에 근접하고 기 상용화된 태그 칩과의 임피던스 매칭과 제작이 용이한 UHF(911 MHz) 대역 RFID 태그 안테나를 설계 제작하였다. 제안된 안테나는 $40{\times}46mm\;(0.12{\times}0.14{\lambda})$의 크기를 가지고 수직 입사의 경우에 최대 RCS가 $-18.5dBm^2$이며, 3 dB RCS 대역폭이 9 MHz(1%)이다. 태그 칩과 안테나 임피던스가 단락 상태일 때의 RCS가 방향에 따라 최대 $-16.9dBm^2$, 최소 $-21.4dBm^2$로 4.5 dB의 차이를 보여, 기존 다이폴 형태의 안테나가 가지는 입사파의 방향에 따른 문제점을 대폭 개선하였다. 또한 설계된 안테나를 제작하여 입사파 각도에 따른 RCS를 측정하였고, 시뮬레이션 결과와 유사함을 확인하였다.

• Journal of electromagnetic engineering and science
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• 제13권2호
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• pp.113-119
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• 2013

We developed a transformed, symmetrical, mushroom-like surface without via holes in cells focused on a 2.4-GHz WLAN band. Each slot in the novel type structure plays a key role in modeling at the desired frequencies. The designed artificial magnetic conductor (AMC) has several advantages, including a small size, a wider bandwidth, a short reflecting distance to the antenna, and easy fabrication because there are no via holes. Overall dimensions of the AMC cell are 21 mm $(Width){\times}21mm$ $(Height){\times}2.6mm$ (Thickness), and the bandwidth is about three times wider (11.7%) compared to that of a conventional AMC (4.0%). For evaluating the performance of the proposed structure, a reflector, which periodically consists of the designed AMC cells, was developed. The antenna with the investigated AMC reflector not only works within a quarter of the wavelength because of the extremely high wave impedance generated by the AMC cells on the surface of the structure but also reduces the specific absorption rate (SAR). Electromagnetic field (EMF) exposure to a human phantom was analyzed by applying the designed reflector to the 2.4-GHz dipole antenna in a tablet PC. The calculated peak SAR averaged over 1 g was 0.125 W/kg when the input power was 1 W and the antenna was located at 20 cm from the human phantom. However, the SAR value was only 0.002 W/kg (i.e., 98.4% blocked) when the designed reflector was inserted in front of the antenna.