• Korea-Australia Rheology Journal
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• 제14권1호
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• pp.1-9
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• 2002

Steady and dynamic shear properties of two hydrophobically modified alkali soluble emulsions (HASE), NPJI and NPJ2, were experimentally investigated. At the same polymer concentration, NPJ1 is appreciably more viscous and elastic than NPJ2. The high hydrophobicity of NPJ1 allows hydrophobic associations and more junction sites to be created, leading to the formation of a network structure. Under shear deformation, NPJ1 exhibits shear-thinning behaviour as compared with Newtonian characteristics of NPJ2. NPJ1 and NPJ2 exhibit a very high and a low level of elasticity respectively over the frequency range tested. For NPJ1, a crossover frequency appears, which is shifted to lower frequencies and hence, longer relaxation times, as concentration increases. Three different surfactants anionic SDS, cationic CTAB, and non-ionic TX-100 were employed to examine the effects of surfactants on the rheology of HASE. Due to the different ionic behaviour of the surfactant, each type of surfactant imposed different electrostatic interactions on the two HASE polymers. In general, at low surfactant concentration, a gradual increase in viscosity is observed until a maximum is reached, beyond which a continuous reduction of viscosity ensues. Viscosity development is a combined result of HASE-surfactant interactions, accompanied by constant rearrangement of the hydrophobic associative junctions, and electrostatic interactions.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.900-907
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• 2000

The three-dimensional turbulent flow in curved pipes susceptible to flow-accelerated corrosion has been analyzed numerically to predict the pressure and shear stress distributions on the inner surface of the pipes. The analysis employs the body-fitted non-orthogonal curvilinear coordinate system and a standard $ {\kappa}-{\varepsilon}$ turbulence model with wall function method. The finite volume method is used to discretize the governing equations. The convection term is approximated by a high-resolution and bounded discretization scheme. The cell-centered, non-staggered grid arrangement is adopted and the resulting checkerboard pressure oscillation is prevented by the application of a modified version of momentum interpolation scheme. The SIMPLE algorithm is employed for the pressure and velocity coupling. The numerical calculations have been performed for two curved pipes with different bend angles and curvature radii, and discussions have been made on the distributions of the primary and secondary flow velocities, pressure and shear stress on the inner surface of the pipe to examine applicability of the present analysis method. As the result it is seen that the method is effective to predict the susceptible systems or their local areas where the fluid velocity or local turbulence is so high that the structural integrity can be threatened by wall thinning degradation due to flow-accelerated corrosion.

• Korea-Australia Rheology Journal
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• 제14권2호
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• pp.49-55
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• 2002

To understand the large amplitude oscillatory shear (LAOS) behavior of complex fluids, we have investigated the flow behavior of a network model in the LAOS environment. We applied the LAOS flow to the model proposed by Vaccaro and Marrucci (2000), which was originally developed to describe the system of associating telechelic polymers. The model was found to predict at least three different types of LAOS behavior; strain thinning (G' and G" decreasing), strong strain overshoot (G' and G" increasing followed by decreasing), and weak strain overshoot (G' decreasing, G" increasing followed by decreasing). The overshoot behavior in the strain sweep test, which il often observed in some complex fluid systems with little explanation, could be explained in terms of the model parameters, or in terms of the overall balance between the creation and loss rates of the network junctions, which are continually created and destroyed due to thermal and flow energy. This model does not predict strain hardening behavior because of the finitely extensible nonlinear elastic (FENE) type nonlinear effect of loss rate. However, the model predicts the LAOS behavior of most of the complex fluids observed in the experiments.he experiments.

• Korea-Australia Rheology Journal
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• 제20권1호
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• pp.15-26
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• 2008

It has been known that there is a viscoelastic instability in the channel flow past a cylinder at high Deborah (De) number. Some of our numerical simulations and a boundary layer analysis indicated that this instability is related to the shear flow in the gap between the cylinder and the channel walls in our previous work. The critical condition for instability initiation may be related to an inflection velocity profile generated by the normal stress near the cylinder surface. At high De, the elastic normal stress coupling with the streamline curvature is responsible for the shear instability, which has been recognized by the community. In this study, an instability criterion for the flow problem is proposed based on the analysis on the pressure gradient and some supporting numerical simulations. The critical De number for various model fluids is given. It increases with the geometrical aspect ratio h/R (half channel width/cylinder radius) and depends on a viscosity ratio ${\beta}$(polymer viscosity/total viscosity) of the model. A shear thinning first normal stress coefficient will delay the instability. An excellent agreement between the predicted critical Deborah number and reported experiments is obtained.

• Macromolecular Research
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• 제13권5호
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• pp.409-417
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• 2005

The surface of rutile titania nanoparticles was chemically modified by reacting with alkoxy silane. The surface and rheological properties in silicone oil having a wide range of viscosity were investigated. Total surface free energy($\gamma_S$) of the titania particles decreased from 53.12 to 26.94 mJ/$m^2$ as the silane used for surface treatment was increased from 0 to 5.0 wt$\%$. The surface free energy of neat silane was 25.5 mJ/$m^2$, which is quite close to that oftitania particles treated with 5.0 wt$\%$ silane. Due to the hydrophobic nature oftreated-titania, the contact angle was accordingly higher for polar solvent in the order of water>ethylene glycol> formamide>$\alpha$-bromonaphthalene. In sum of rheological behavior, as the applied shear stress or viscosity of the silicone oil increased, the titania particles tend to form layers and agglomerated clusters, showing shear-thinning and shear-thickening behaviors, sequentially. A good dispersion of discrete titania particles obeying a Newtonian flow behavior was achieved at a surface energy or low concentration of silane-treated titania particles in hydrophobic silicone oil.

• 한국인쇄학회지
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• 제23권2호
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• pp.1-14
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• 2005

Generally, printing inks are composed of pigment, vehicle and additive. Among others, the vehicle transfers the pigment to substrate and then binds it on the surface. So, rheological properties of the vehicle are an important factor which has influence on printability. Thus, in this study, rheology of the vehicle was investigated by using rotational rheometer according to molecular weight of resin. Also, emlusion rheology of water in oil type and its microstructure were examined with increasing the shear rate. Consequently, the following results were obtained: (1) By viscometric flow test, zero shear viscosity and shear thinning index of vehicle increased with increasing the molecular weight of resin. (2) By relaxation and creep test, relaxation time and retardation time of vehicle increased with increasing the molecular weight of resin. (3) By frequency sweep test, crossover point of vehicle increased with increasing the molecular weight of resin. (4) G' and G" of emlusions increased with increasing the molecular weight by amplitude sweep test. (5) The shape of water drop in emlusions was changed to the capillary tube.

• Food Science and Biotechnology
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• 제17권4호
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• pp.780-786
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• 2008

Effect of acetylated starches (acetylated rice starch and acetylated tapioca starch) on rheological properties of hot pepper-soybean paste (HPSP) at different mixing ratios of rice flour (RF) and acetylated starch (AS) (10/0, 9/1, 8/2, and 7/3) was evaluated in steady and dynamic shear. All HPSP samples at $25^{\circ}C$ exhibited shear-thinning (n=0.31-0.36) and thixotropic behavior with high yield stresses and their steady flow curves were well described by power law and Casson models. The presence of AS resulted in the decrease in consistency index (K), apparent viscosity (${\eta}_{a,100}$), and yield stress (${\sigma}_{oc}$), and their predominant decreases were noticed at higher ratio of RF to AS (7/3 ratio). Arrhenius temperature relationship represents variation with temperature in the range of $5-35^{\circ}C$ with the high determination coefficients ($R^2=0.97-0.99$). Dynamic moduli (G', G", and ${\eta}^*$) values of HPSP samples mixed with AS were lower than those of HPSP with no added AS within the experimental range of frequency (0.63-62.8 rad/sec). Steady and dynamic shear rheological properties of HPSP samples seem to be greatly influenced by the presence of acetylated starch.

• Food Science and Biotechnology
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• 제15권4호
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• pp.589-594
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• 2006

The effect of five commercial gums (carboxylmethylcellulose, CMC; guar gum, GG; hydroxypropylmethyl-cellulose, HPMC; locust bean gum, LBG; and xanthan gum) at a concentration of 0.25% on the rheological properties of rice flour (RF) dispersions was investigated in steady and dynamic shear. The steady shear rheological properties showed that RF gum mixture dispersions (5%, w/w) at $25^{\circ}C$ had high shear-thinning flow behavior (n=0.20-0.31) exhibiting a yield stress. Magnitudes of consistency index (K), apparent viscosity (${\eta}_{a,100}$), and Casson yield stress (${\sigma}_{oc}$) of RF-gum mixtures were much higher than those of RF dispersion with no added gum (control). Activation energy values (6.67-10.8 kJ/mole) of RF-gum mixtures within the temperature range of $25-70^{\circ}C$ were lower than that (11.9 kJ/mole) of the control. Dynamic rheological data of log (G', G") versus log frequency (${\omega}$) of RF-gum mixtures had positive slopes (0.15-0.37) with G' greater than G" over most of the frequency range (0.63-63 rad/sec), demonstrating a frequency dependency. Tan ${\delta}$ (G"/G') values of RF-gum mixtures, except for xanthan gum, were much higher than that of the control.

• Bulletin of the Korean Chemical Society
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• 제7권4호
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• pp.257-262
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• 1986

Thixotropy is a time-dependent shear-thinning phenomenon. We derived a new thixotropic formula which is based on the generalized viscosity formula of Ree and Eyring, $f={\Sigma}\frac{X_i}{{\alpha}_i}sinh^{-1}$ () (Refer to the text concerning the notation.) The following is postulated: (1) thixotropy occurs when small flow units attached to a large flow unit separate from the latter under stress (2) elastic energy(${\omega}$) is stored on the large flow unit during the flow process, and (3) the stored energy contributes to decrease the activation energy for flow. A new thixotropic formula was derived by using these postulations, $f={\frac}{X_0{\beta}_0}{\alpha_0}{\dot{s}}+{\frac}{X_1{\beta}_1}{{\alpha}_1}{\dot{s}}+{\frac}{X_2}{{\alpha_x}}sinh^{-1}$[$({\beta}_0)_2$ exp $(-C_2{\dot{s}}^2/RT){\cdot}{\dot{s}}$] f is the shear stress, and s is the rate of shear. In case of concentrated solutions where the Newtonian flow units have little contribution to the viscosity of the system, the above equation becomes, $f=\frac{X_2}{\alpha_2}sinh^{-1}$[$({\beta}_0)_2$ exp $(-C_2{\dot{s}}^2/RT){\cdot}{\dot{s}}$]. In order to confirm these formulas, we applied to TiO2(anatase and rutile)-water, printing ink and mayonnaise systems. Good agreements between the experiment and theory were observed.

• 한국가시화정보학회지
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• 제18권3호
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• pp.103-108
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• 2020

RBC (red blood cell) deformability is one of factors inducing blood shear thinning effect. Reduction of RBC deformability increases blood viscosity in high shear region. In this study, 3D printed chip with proper distribution of wall shear rate (WSR) was proposed to measure RBC deformability of blood samples. To fabricate 3D printed chip, the design of 3D printed chip determined through numerical simulation was modified based on the resolution of the 3D printer. For the estimation of pressure drop in the 3D printed chip, two bypass outlets with low and high WSR are exposed to atmospheric pressure through the needles. By positioning the outlet of needles in the gravity direction, the formation of droplets at bypass outlets can be captured by smartphone. Through image processing and fast Fourier transform (FFT) analysis, the frequency of droplet formation was analyzed. Since the frequency of droplet formation is related with the pressure at bypass, high pressure drop caused by reduction of RBC deformability can be estimated by monitoring the formation of blood droplets using the smartphone.