• Title/Summary/Keyword: Shear viscosity

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A Rheological Study of Topical Vehicles

  • Min, Shin-Hong;Rhee, Shanghi;Kim, Yong-Bae
    • Archives of Pharmacal Research
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    • v.2 no.2
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    • pp.89-97
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    • 1979
  • To find out the rheological characteristics of several pharamaceutical semisolid products, experiments were carriedout over the temperature range of 20 to 30 .deg.C . From continuous shear rheograms obtained with a Ferranti-Shirley cone and plate viscometer, loop area, shear rates, ryild values, limiting viscosities and activation energies were calculated. The systems were metastable and their viscosity decreased with time. As the temperature was raised, products studied showed a decrease in viscosity and yield value.

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Effect of surfactant adsorption on the rheology of suspensions flocculated by associating polymers

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
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    • v.15 no.4
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    • pp.179-185
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    • 2003
  • Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.

The Curvature and Shear Effects on the Eddy Viscosity

  • Lim, Hyo-Jae
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.293-297
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    • 1999
  • Direct comparisons are made between curvature-corrected eddy viscosity models and the present experimental data. The results show that the curvature effects can be quantified through a curvature parameter R$\sub$c/ or S$\sub$c/ and a non-equilibrium value of p/$\varepsilon$. The data reveal a significant dependence of the eddy viscosity on the curvature and strain history for a fluid in a stabilizing curvature field, S$\sub$c/>1.0. Especially, experimental result shows that the eddy viscosity coefficient ratio at S$\sub$c/=3 changes from 10 to -10 although shear rate preserved constant. It is therefore suggested that proper curvature modifications, particularly the strain history effect, must be introduced into current eddy viscosity models for their application to turbulent flows subjected to curvature straining field for a non-negligible period of time.

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Measurements of Blood Viscosity Using a Pressure-Scanning Slit Viscometer

  • Sehyun Shin;Lee, Sung-Woo;Ku, Yun-Hee
    • Journal of Mechanical Science and Technology
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    • v.18 no.6
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    • pp.1036-1041
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    • 2004
  • A newly designed pressure-scanning slit viscometer is developed to combine an optical device without refraction while measuring blood viscosity over a range of shear rates. The capillary tube in a previously designed capillary viscometer was replaced with a transparent slit, which is affordable to mount optical measurement of flowing blood cells. Using a pressure transducer, we measured the change of pressure in a collecting chamber with respect to the time, p(t), from which the viscosity and shear rate were mathematically calculated. For water, standard oil and whole blood, excellent agreement was found between the results from the pressure-scanning slit viscometer and those from a commercially available rotating viscometer. This new viscometer overcomes the drawbacks of the previously designed capillary viscometer in the measuring whole blood viscosity. First, the pressure-scanning slit viscometer can combine an optical instrument such as a microscope. Second, this design is low cost and simple (i.e., ease of operation, no moving parts, and disposable).

A Study on the Rheological Properties of glucomannan(II) (Glucomannan의 유변학적 성질에 관한연구 (II))

  • 김경이
    • The Korean Journal of Rheology
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    • v.9 no.1
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    • pp.27-32
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    • 1997
  • GM 은 Amorphopallus Konjac K. Koch의 tuber의 주성분으로알카리 응고제를 첨가 함에 따라 열적으로 안정한 gel을 형성한다. GM에 침전제로 메탄올을 사용하여 4단계로 분 별하였고 각 분별물(F.1, F.2, F.3, F.4)들은 Mark-Houwink 식을 이용하여 분자량을 산출하 였다. Ubbelohde를 이용한 농도에 따른 환산점도로부터 고유 점성도값을 구한 결과 분자량 이 높은 분별물이 분자량이 낮은 분별물에 비하여 직선으로부터 벗어남을 알수 있었다. 또 한 고유점성도는 분자량이 증가할수록 증가하였고, 분자량 분포 범위가 broad하게 나타났다. GM용액의 frequency와 shear rate에 따른 viscosity를 측정한결과 낮은 frequency에서는 loss modulus(G")가 storage modulus(G")보다 큰 값을 가졌으나 높은 frequency에서는 G '가 G"보다 크게 나타났다. 이 현상은 분자들의 얽힘에 관한 시간 의존도로써 설명할수 있다. 즉높은 frequency에서는 탄소 사슬간의 얽힘들이 진동기간내에 분자결합이 끊어지기 에 충분한 시간을 갖지 못하여 그 조직이 교차 결합을 한 gel처럼 행동하게 되고 한편 낮은 frequency에서는 탄소사슬들의 얽힘이 풀리고 흐르기에 충분한 시간을 갖게된다. Shear rate에 따른 viscosity값과 frequency에 대한 dynamic viscosity값은 거의 유사한 변화를 나 타내었다.

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The Effect of Oil Rheology on Film Thickness in Engine Journal Bearing (윤활유의 유동특성이 기관 저어널 베어링의 유막두께에 미치는 영향)

  • 이동호;장병주
    • Transactions of the Korean Society of Automotive Engineers
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    • v.2 no.4
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    • pp.9-17
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    • 1994
  • Effect of Newtonian and non-Newtonian oils on minimum ol film thickness in engine journal bearing were investigated at various oil viscosities. The influence of oil viscosity and engine operating conditions on minimum oil film thickness of main bearing and con-rod bearing was examined. Minimum oil film thickness for Newtonian oils increased uniformly with kinematic viscosity. But the correlation between kinematic viscosity and minimum oil film thickness was very poor for non-Newtonian oils. According to the straight-line regression analysis for non-Newtonian oils, high temperature high shear viscosity at 1 $1{\times}10^6Sec^{-1}$, $150^{\circ}C$ increase the coefficient of determination from 0.41 to 0.77. Con-rod bearing showed better correlation between minimum oil film thickness and engine operating conditions than main bearing.

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Rheological Characterization of Hydrogen Peroxide Gel Propellant

  • Jyoti, B.V.S.;Baek, Seung Wook
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.2
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    • pp.199-204
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    • 2014
  • An experimental investigation on the rheological behavior of gelled hydrogen peroxide at different ambient temperature (283.15, 293.15 and 303.15 K) was carried out in this study. The gel propellant was rheologically characterized using a rheometer, in the shear rate ranges of 1 to $20s^{-1}$, and 1 to $1000s^{-1}$. Hydrogen peroxide gel was found to be thixotropic in nature. The apparent viscosity value with some yield stress (in-case of shear rate 1 to $20s^{-1}$) drastically fell with the shear rate. In the case of the shear rate range of 1 to $20s^{-1}$, the apparent viscosity and yield stress of gel were significantly reduced at higher ambient temperatures. In the case of the shear rate range of 1 to $1000s^{-1}$, no significant effect of varying the ambient temperature on the gel apparent viscosity was observed. The up and down shear rate curves for hydrogen peroxide gel formed a hysteresis loop that showed no significant change with variation in temperature for both the 1 to $20s^{-1}$ and the 1 to $1000s^{-1}$ shear rate ranges. No significant change in the thixotropic index of gel was observed for different ambient temperatures, for both low and high shear rates. The gel in the 1 to $20s^{-1}$ shear rate range did not lead to a complete breakdown of gel structure, in comparison to that in the 1 to $1000s^{-1}$ shear rate range.

Comparison of Shear-Thinning Blood Flow Characteristics between Longitudinal and Transverse Vibration

  • Choi, Sung-Ho;Shin, Se-Hyun;Lee, Kyung-Tae
    • Journal of Mechanical Science and Technology
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    • v.18 no.12
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    • pp.2258-2264
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    • 2004
  • This article described the numerical investigation of shear-thinning blood flow characteristics when subjected to longitudinal and transverse vibrations and delineated the underlying mechanisms of the flow rate enhancements, respectively. In order to fully consider the mechanical vibrations of the capillary, a moving wall boundary condition was adopted. The present numerical results showed that the longitudinal vibration caused a significant increase of wall shear rates, which resulted in a decrease of viscosity and the subsequent increase of flow rates. However, the shear rate for the transverse vibration was slightly increased and the calculated flow rate was underestimated comparing with the previous experimental results.

Pressure Dependence of the Viscosity of Toluene (톨루엔의 점성도에 대한 압력 의존성)

  • Kim, Jeong Rim
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.251-256
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    • 1999
  • Viscosities of toluene were experimentally determined by the falling-ball method at several temperatures and pressures to investigate the pressure and temperature dependence of the viscosity of toluene. With the shear stress of the viscous flow of toluene, the shear free energy, the shear entropy, and the shear enthalpy were defined to discuss the variations of the shear thermodynamic properties with pressure. The effect of temperature and pressure on the shear thermodynamic properties obtained experimentally can be explained by means of the molecular thermal agitation due to temperature incleasing and the steric effect of the closed molecules of to Iuene due to pressure elevation.

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