• Title/Summary/Keyword: Separators

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Dependence of Thermal and Electrochemical Properties of ceramic Coated Separators on the Ceramic Particle Size (알루미나 크기에 따른 세라믹 코팅 분리막의 열적 특성 및 전기화학적 특성)

  • Park, Sun Min;Yu, Ho Jun;Kim, Kwang Hyun;Kang, Yun Chan;Cho, Won Il
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.27-33
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    • 2017
  • Conventional lithium ion batteries suffer from notorious safety issues caused by inevitable lithium dendrite formation and proliferation during over/fast charging processes. The lithium dendrites or mechanical damage on the separator induce internal short circuit in LiB that generates extensive amount of heat within contacted electrode surfaces through the separator. During this heat generation, conventional polyolefin separators shrinks dramatically, and increasing short circuit pathway, that causes the battery to explode. To overcome this serious issue, ceramic coated separators are developed in commercial LiB to enhance thermal and mechanical stability. In this paper, various size(IL = 488.5 nm, I = 538.7 nm, S = 810.3 nm, D = 1533.3 nm) of $Al_2O_3$ particles are coated using styrene-butadiene rubber(SBR) / carboxymethyl cellulose(CMC) binder on PE separator to investigate its thermal stability and electrochemical effect on LiB coin cell with NCM cathode and Li metal anode.

Preparation of Porous Separators for Zn Air Batteries through Phase Inversions of Polyetherimide-PVP Solutions (Polyetherimide-PVP 용액의 상전이를 통한 아연공기전지의 다공성 분리막 제조)

  • Cho, Yu Song;Kim, Young Kyoung;Koo, Ja-Kyung
    • Membrane Journal
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    • v.24 no.3
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    • pp.231-239
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    • 2014
  • Polyetherimide (PEI) membranes for separators in Zn air batteries were prepared via phase inversion process from casting solution composed of PEI, n-methylpyrolidone (NMP), and polyvinylpurrolidone (PVP). Furthermore, Zn air batteries were fabricated with the separators. The effects of PEI content and PVP addition in the casting solution on the morphology, mechanical strength, ionic conductivity were investigated through SEM, stress-strain test and ac impedance test. The elelctrochemical performances of the batteries were evaluated through galvanostatic discharge analysis. The mechanical strength of the membrane increased with increasing PEI composition in the casting solution. Little effect of PVP addition into the solution on the mechanical strength of the membrane was investigated. The ionic conductivity value decreased with increasing PEI composition in the solution. With addition of PVP, ionic conductivity of membrane increased until 10 wt% to show the maximum value of 0.1 S/cm. In the higher range of PVP addition over 10%, the ionic conductivity decreased with increasing PVP addition. Ionic conductivity of separator strongly affected the capacity of Zn air battery, and the battery assembled with the separator which showed high ionic conductivity showed high capacity.

Separator Properties of Silk-Woven Fabrics Coated with PVdF-HFP and Silica and the Charge-Discharge Characteristics of Lithium-ion Batteries Adopting Them (PVdF-HFP와 실리카가 코팅된 실크 견직물의 분리막 특성과 이를 채용한 리튬이온전지의 충방전 특성)

  • Oh, Seem Geon;Lee, Young-Gi;Kim, Kwang Man;Lee, Yong Min;Kim, Sang Hern;Kim, Yong Joo;Ko, Jang Myoun
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.330-334
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    • 2013
  • Mixtures of poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) and silica nanoparticles are coated on the surface of a silk fabrics separator. The coated separators are finally prepared by injecting an electrolyte solution and then characterized for use of lithium-ion battery separator/electrolyte. In the preparation, various contents of dibutylphthalate (DBP) as a plasticizer are used to enhance the formation of micropores within the coated membrane. The coated silk fabrics separators are characterized in terms of ionic conductivity, drenching rate, and electrochemical stability, and the charge-discharge profiles of lithium-ion batteries adopting the coated separators are also examined. As a result, the coated silk fabrics separator prepared using DBP 40~50 wt% and silica shows the superior separator properties and high-rate capability. This is due to (i) high sustainability of silk fabrics, (ii) the formation of micropores with the coated layer membrane by DBP, (iii) increase in drenching rate by silica nanoparticles to involve great enhancements in specific surface area and ionic conductivity.

Development of EPICS-IOC Measuring Magnetic Field at A/Q separator for Separating Specific Ions (가속이온 분리를 위한 A/Q Separator에서 자장측정용 EPICS-IOC 개발)

  • Lee, Su-Yeong;Yim, Hee-Joong;Kim, Jae-Hong;Mun, Jun-Yeong;Park, Mi-Jeong;Lee, Sang-Il;Lee, Dong-Hoon
    • Journal of the Institute of Convergence Signal Processing
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    • v.22 no.3
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    • pp.91-98
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    • 2021
  • The installation and performance test of the ISOL (Isotope Separation On Line) system for the generation and separation of Rare Isotopes (RI) beams is in progress at the Rare Isotope Science Project (RISP), Institute for Basic Science (IBS). The various RI beams generated by the ISOL target/ion source go through the beam lines and separators, and only the RI beam desired by the user is selected and transmitted to the superconducting linear accelerator at the downstream of the ISOL. In the ISOL system, two separators are installed to separate a specific RI beam, and control is performed by the Experimental Physics and Industrial Control System (EPICS). In this study, an EPICS IOC (Input-Output Control) was developed to measure the magnetic field of a dipole magnet for mass separation of a multivalent (n+) RI beam in the A/Q separator, which is one of the ISOL RI beam separators. The operational stability of the A/Q separator was tested through a magnetic field measurement using a Hall probe.

A Review on Ultrathin Ceramic-Coated Separators for Lithium Secondary Batteries using Deposition Processes (증착 기법을 이용한 리튬이차전지용 초박막 세라믹 코팅 분리막 기술)

  • Kim, Ucheol;Roh, Youngjoon;Choi, Seungyeop;Dzakpasu, Cyril Bubu;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.25 no.4
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    • pp.134-153
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    • 2022
  • Regardless of a trade-off relationship between energy density and safety, it is essential to improve both properties for future lithium secondary batteries. Especially, to improve the energy density of batteries further, not only thickness but also weight of separators including ceramic coating layers should be reduced continuously apart from the development of high-capacity electrode active materials. For this purpose, an attempt to replace conventional slurry coating methods with a deposition one has attracted much attention for securing comparable thermal stability while minimizing the thickness and weight of ceramic coating layer in the separator. This review introduces state-of-the-art technology on ceramic-coated separators (CCSs) manufactured by the deposition method. There are three representative processes to form a ceramic coating layer as follows: chemical vapor deposition (CVD), atomic layer deposition (ALD), and physical vapor deposition (PVD). Herein, we summarized the principle and advantages/disadvantages of each deposition method. Furthermore, each CCS was analyzed and compared in terms of its mechanical and thermal properties, air permeability, ionic conductivity, and electrochemical performance.

The Exposure Level of Respirable Dust of Underground Coal Mines in Taebaek Area (태백지역 석탄광산의 호흡성 분진 폭로 농도)

  • 윤영노;이정주
    • Journal of Korean Society for Atmospheric Environment
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    • v.4 no.1
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    • pp.23-32
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    • 1988
  • The exposure level of respirable dust and silica for the coal workers of underground coal mines in Taebaek area was evaluated. Personal air samplers were attached to the coal workers-drillers, coal cutters, their helpers, haulers, and separators. Normality and lognormality of respirable dust and silica concentrations were tested by Kolmogorov-Smirnov one-sample test, differences of means of respirable dust and silica concentration were tested by group-t-test and paired t-test, and relation between respirable dust and silica concentration were tested by regression test.

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Experimental Study on Virtual Cyclones as Aerosol Separators (입자 분리를 위한 Virtual Cyclone의 실험적 연구)

  • Kim Dae-Seong;Xiang Rongbiao;Lee Gyu-Won
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.301-302
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    • 2002
  • Virtual cyclones have been the subject of aerosol separation studies since they were first developed by Torczynski and Rader (1996). In the virtual cyclone (originally referred to as the anticyclone), the main particle-laden flow follows a wall that curves away from the original flow direction rather than curving into the original direction, as in a cyclone. Although a wall forms the inner boundary of the main flow, its outer boundary is formed by an adjacent flow, often a confined recirculating flow, into which particles are transferred by centrifugal action. (omitted)

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Optical and structural properties of broad-band circular Bragg reflectors deposited by glancing angle deposition (경사입사 증착방법을 이용한 넓은 영역 원평광 브래그 반사경의 광학적, 물리적 특성)

  • Park, Yong-Jun;Jang, Dae-Ho;Sobahan, K.M.A.;HwangBo, Chang-Gwon
    • Proceedings of the Optical Society of Korea Conference
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    • 2008.02a
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    • pp.283-284
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    • 2008
  • In this paper, we report a broadband circular polarization reflectors and color separators realized as cascades of helical films with different pitch thickness. These helical films were prepared by glancing angle deposition technique.

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