• Title/Summary/Keyword: Separation process

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SEPARATION OF STRONTIUM AND CESIUM FROM TERNARY AND QUATERNARY LITHIUM CHLORIDE-POTASSIUM CHLORIDE SALTS VIA MELT CRYSTALLIZATION

  • WILLIAMS, AMMON N.;PACK, MICHAEL;PHONGIKAROON, SUPATHORN
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.867-874
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    • 2015
  • Separation of cesium chloride (CsCl) and strontium chloride ($SrCl_2$) from the lithium chloride-potassium chloride (LiCl-KCl) salt was studied using a melt crystallization process similar to the reverse vertical Bridgeman growth technique. A ternary $SrCl_2-LiCl-KCl$ salt was explored at similar growth rates (1.8-5 mm/h) and compared with CsCl ternary results to identify similarities. Quaternary experiments were also conducted and compared with the ternary cases to identify trends and possible limitations to the separations process. In the ternary case, as much as 68% of the total salt could be recycled per batch process. In the quaternary experiments, separation of Cs and Sr was nearly identical at the slower rates; however, as the growth rate increased, $SrCl_2$ separated more easily than CsCl. The quaternary results show less separation and rate dependence than in both ternary cases. As an estimated result, only 51% of the total salt could be recycled per batch. Furthermore, two models have been explored to further understand the growth process and separation. A comparison of the experimental and modeling results reveals that the nonmixed model fits reasonably well with the ternary and quaternary data sets. A dimensional analysis was performed and a correlation was identified to semipredict the segregation coefficient.

Treatment of High Concentration Organic Wastewater with a Sequencing Batch Reactor (SBR) Process Combined with Electro-flotation as a Solids-liquid Separation Method

  • Choi, Younggyun;Park, Minjeong;Park, Mincheol;Kim, Sunghong
    • Environmental Engineering Research
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    • v.19 no.4
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    • pp.395-399
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    • 2014
  • Operation characteristics of the sequencing batch reactor (SBR) process with electro-flotation (EF) as a solid liquid separation method (EF-SBR) were investigated. EF-SBR process showed excellent solid-liquid separation performance which enabled to separate biosolids from liquid phase within 30 min and to extend cyclic reaction time. Although influent organic loading rate was increased stepwise from 5 to 15 g COD/day, food to microorganisms (F/M) ratio could be maintained about 0.3 g COD/g VSS/day in EF-SBR because biomass concentration could be easily controlled at desired level by EF. However, it was impossible to increase biomass concentration at the same level in control SBR (C-SBR) process because solid-liquid separation by gravity settling showed a limitation at higher mixed liquor suspended solids (MLSS) concentration with 60 min of settling time. Total chemical oxygen demand (TCOD) removal efficiency of EF-SBR process was not decreased although influent organic loading rate became 3 times higher than initial value. However, it was seriously deteriorated in C-SBR process after increasing the rate over 10 g COD/day, which was accounted for insufficient organic removal by relatively higher food to microorganisms (F/M) ratio as well as biosolids wash-out by a limitation of gravity sedimentation.

The Effect of Cu Reflow on the Pd-Cu Alloy Membrane Formation for Hydrogen Separation (수소분리용 Pd-Cu 합금 분리막의 Cu Reflow 영향)

  • Mun, Jin-Uk;Kim, Dong-Won
    • Journal of the Korean institute of surface engineering
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    • v.39 no.6
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    • pp.255-262
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    • 2006
  • Pd-Cu alloy membrane for hydrogen separation was fabricated by sputtering and Cu reflow process. At first, the Pd and Cu was continuously deposited by sputtering method on oxidized Si support, the Cu reflow process was followed. Microstructure of the surface and permeability of the membrane was investigated depending on various reflow temperature, time, Pd/cu composition and supports. With respect to our result, Pd-Cu thin film (90 wt.% Pd/10 wt.% Cu) deposited by sputtering process with thickness of $2{\mu}m$ was heat-treated for Cu reflow The voids of the membrane surface were completely filled and the dense crystal surface was formed by Cu reflow behavior at $700^{\circ}C$ for 1 hour. Cu reflow process, which is adopted for our work, could be applied to fabrication of dense Pd-alloy membrane for hydrogen separation regardless of supports. Ceramic or metal support could be easily used for the membrane fabricated by reflow process. The Cu reflow process must result in void-free surface and dense crystalline of Pd-alloy membrane, which is responsible for improved selectivity oi the membrane.

An Analysis of Hot-Rolling in the Twin-Roll Strip Casting Process by using the Slab Method (슬랩법을 이용한 쌍롤식 박판주조 공정의 열간 압연 해석)

  • Shim, Hyun-Bo
    • Transactions of Materials Processing
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    • v.3 no.1
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    • pp.63-83
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    • 1994
  • In this paper, the slab method have been applied to investigate the strip casting process in which hot coil is produced from molten steel directly. In the twin roll strip casting process, molten steel supplied by the nozzle cools and solidifies due to the heat extraction effect of the rolls and hot rolling of the solidified shell takes place simultaneously. The analysis of hot rolling has been carried out by using the existing results of solidification analysis for the twin roll strip casting process. The current slab method provides basic design data such as roll separation force, rolling torque, rolling power as well as end dam separation force which are required to design strip caster. The effect of friction on the basic process parameters are investigated also. It is shown that the use of appropriate friction coefficient is important and that the characteristics of hot rolling in the twin-roll strip casting process is quite different from the conventional hot rolling processes.

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A Study on the Development for a Cryogenic Air Separation Unit (심랭식 공기분리장치 개발 연구)

  • 문흥만
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2001.02a
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    • pp.132-135
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    • 2001
  • Cryogenic air separation unit(ASU) was developed about 100 year ago in Europe. However, because there is not any ability of process design or manufacturing of ASU in Korea, many ASUs come from advanced countries every year. The purpose of this study is the development of cryogenic air separation unit by our own ability, especially cold box for nitrogen production. On this study, we developed the computer program for physical properties of gases and process simulation. We also did process design and manufactured of cold box, including air separation column, liquid air heat exchanger and condenser. The result of cold box test was successful.

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A Qualitative Study on the Adjustment of Separated Families in South and North Korea : Focusing on Separated Families Living in South Korea (남북이산가족의 적응에 관한 질적 고찰 : 남한 거주 이산가족을 중심으로)

  • Choi, Youn-Shil
    • Journal of Families and Better Life
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    • v.25 no.1 s.85
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    • pp.183-207
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    • 2007
  • The purpose of this study was to improve the understanding of the essential experience of Separated Families in South and North Korea in a socio-cultural context and to explore their post-separation adjustment process from the perspective of the families. Major findings in this study are summarized as follows. First, 'han' was the central phenomenon that the participants experienced following their separation. Second, the core issue in the process of post-separation adjustment was 'accepting the separation and rearrangement of reality for reunion', and over time the participants went through four stages in their adjustment process: the stage of being overwhelmed, the stage of conflict, the stage of awareness, and the stage of acceptance. Third, the main factors affecting the participants' adjustment were supportive systems, available resources(individual variables) and interaction with other separated families. fourth, four types were observed in the typology of adjustment and reunion of the participants.

New Pervaporation Membrane for Petroleum Separation

  • Nam, Sang-Yong;John R. Dorgan
    • Proceedings of the Membrane Society of Korea Conference
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    • 2003.07a
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    • pp.77-80
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    • 2003
  • Hydrocarbon-hydrocarbon separations are one of the most important processes in petroleum refining. Distillation process has been used for separating hydrocarbons, but this conventional process is very energy consuming. Pervaporation separation through polymeric membranes is an emerging process alternative to distillation because of energy savings, compact system installation, reduced capital investment, and other performance attributes. In hydrocarbon separations, polymeric membranes are easily swollen by hydrocarbons and can lose mechanical strength. Chemically robust membranes are needed for the separation of hydrocarbons. In this study, the blend membrane was applied to separate benzene and cyclohexane. This is a model system for aliphatic and aromatic separation. Cyclohexane is also physically very similar to benzene and as a result of the very closing boiling points (0.6$^{\circ}C$), benzene and cyclohexane form an azetrope. Thus the system provides a good model for azeotrope breaking by pervaporation. The semi-quantitative thermodynamic model predicts that the calculated selectivity increases with increasing Hydrin contents in the blend membranes. Pervaporation experiments utilizing various operating temperatures and feed concentrations with different blend membranes are compared with the result from semi-quantitative thermodynamic calculations.

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Acromioclavicular Separation with the Fracture of the Coracoid Process - 2 Cases report - (견봉쇄골 탈구와 동반된 오구돌기 골절 - 2예 보고 -)

  • Yoo, Jae-Ho;Hahn, Sung-Ho;Yang, Bo-Kyu;Ahn, Young-Jun;Zoo, Min-Hong;Yi, Seung-Rim
    • Clinics in Shoulder and Elbow
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    • v.10 no.1
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    • pp.124-130
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    • 2007
  • The acromioclavicular separation (AC separation) is a common injury, which is often accompanied by the rupture of the coracoclavicular ligament (CC ligament) in severe occasions. In rare forms of AC separation, the fracture of the coracoid process would occur rather than the rupture of the CC ligament. Only 31 cases of such injury have been reported in the English literature. We present 2 additional cases with literature review. The fracture of the coracoid process is not readily seen on anteroposterior shoulder radiograms. Severe AC separation without widening of CC distance on anteroposterior shoulder radiogram heralds the fracture of the coracoid process.

Behavioral responses to cow and calf separation: separation at 1 and 100 days after birth

  • Sarah E. Mac;Sabrina Lomax;Cameron E. F. Clark
    • Animal Bioscience
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    • v.36 no.5
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    • pp.810-817
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    • 2023
  • Objective: The aim was to compare the behavioral response to full separation of cows and calves maintained together for 100 days or 24 h. Methods: Twelve Holstein-Friesian cow-calf pairs were enrolled into either treatment or industry groups (n = 6 cow-calf pairs/group). The treatment cows and calves were maintained on pasture together for 106±8.6 d and temporarily separated twice a day for milking. The Industry cows and their calves, were separated within 24 h postpartum. Triaxial accelerometer neck-mounted sensors were fitted to cows 3 weeks before separation to measure hourly rumination and activity. Before separation, cow and calf behavior was observed by scan sampling for 15 min. During the separation process, frequency of vocalizations and turn arounds were recorded. At separation, cows were moved to an observation pen where behavior was recorded for 3 d. A CCTV camera was used to record video footage of cows within the observation pens and behavior was documented from the videos in 15 min intervals across the 3 d. Results: Before separation, industry calves were more likely to be near their mother than Treatment calves. During the separation process, vocalization and turn around behavior was similar between groups. After full separation, treatment cows vocalized three times more than industry cows. However, the frequency of time spent close to barrier, standing, lying, walking, and eating were similar between industry and treatment cows. Treatment cows had greater rumination duration, and were more active, than industry cows. Conclusion: These findings suggest a similar behavioral response to full calf separation and greater occurrence of vocalizations, from cows maintained in a long-term, pasture-based, cow-calf rearing system when ompared to cows separated within 24 h. However, further work is required to assess the impact of full separation on calf behavior.

Simulation of Separation Properties of Propylene/propane in Silver Nanoparticle Containing Facilitated Transport Membrane (전산모사 프로그램을 이용한 은나노함유 촉진수송막의 프로필렌/프로판 분리특성 예측)

  • Park, Chae Young;Han, Sang Hoon;Kim, Jeong Hoon;Lee, Yongtaek
    • Membrane Journal
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    • v.24 no.5
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    • pp.409-415
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    • 2014
  • This study is aimed to separate propylene and propane using membrane process instead of NCC(Naphtha Cracking Center) $C_3$ splitter. Membrane process is a low energy consumption and eco-friendly process while $C_3$ splitter requires high energy consumption in petrochemical processes. In this study, high performance facilitated transport membrane (FTM) is used for propylene/propane separation. FTM module was prepared on top of porous polyetherimide hollow fiber using PVP/$AgBF_4$/TCNQ. We developed simulation program predicting the membrane separation properties under operation conditions. Separation properties of FTM module for propylene and propane were obtained from the simulation program based on the pure gas permeation data. Based on these results, it is predicted that an one-stage membrane process provides 99.5% of propylene at permeate side from a binary gas mixture of 95/5 vol% $C_3H_6$ / vol% $C_3H_8$ supplied as a feed gas.