• Title/Summary/Keyword: Separation condition

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Studies on the Technical Development of the Traditional Korean Golden Varnish(Hwangchil) (III) - Main Component Analysis of Korea Golden Varnishes Traditonally Refined from the Exudates of Dendropanax morbifera Lev. - (전통 황칠 도료 개발에 관한 연구(III) - 전통 황칠 도료의 주성분 분석 -)

  • Lim, Kie-Pye;Jung, Woo-Yang;Hong, Dong-Hwa
    • Journal of the Korean Wood Science and Technology
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    • v.26 no.3
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    • pp.73-80
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    • 1998
  • In order to reconstruct the traditional technology of Korean golden varnish coatings, this study was carried out to separate and determine some main coloring components of the exudates of D. morbifera and its traditionally refined golden varnishes using a process of solvent extractions, chromatographies and spectrometries. The results obtained are as follows: 1. The exudate and its traditional-refined golden varnishes appear to have a kind of natural polyacetylenes because it has some triple bond peaks in FT-IR spectrometry. 2. Some yellowing spots of the polar-solvent extrats from the exudates and refined varnishes separated on TLC appeared under natural drying condition, but those of non-polar solvent extract such as hexane did not. 3. A traditional refining method for reconstructing a Korea golden varnishes was thought to be better than solvent separation because the former had higher triple-bond peaks than the latter in FT-IR spectrometry. 4. One of main conponents in the hexane-extracts of the traditional-refined varnishes and the exudates had the same molcular weighr of 204, but the fragmentation patterns was a little different between the exudate and the refined. in LC-MS soectrometry.

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High Rate Dissolved Air Flotation (DAF) for the Removal of Algae Species (유입원수 조류제거를 위한 high rate DAF 최적화 연구)

  • Jung, Woosik;An, Ju-Suk;Song, Keun-Won;Oh, Hyun-Je
    • Journal of Korean Society of Water and Wastewater
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    • v.31 no.5
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    • pp.415-419
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    • 2017
  • In recent years there have been large increases in the hydraulic loading rates used to design dissolved air flotation (DAF) facilities for drinking water applications. High rate DAF processes are now available at loading rates of 20 to $40m^3/m^2{\cdot}h$. This research evaluated dissolved air flotation as a separation method for algae and organic compounds from water treatment plants. During the service period of 2016. 5. to 2017. 6., DAF pilot plants ($500m^3/day$) process has shown a constantly sound performance for the treatment of raw water, yielding a significantly low level of turbidity (DAF treated water, 0.21~1.56 NTU). As a result of analyzing the algae cell counts in the influent source, it was expressed at 100-120 cells/mL. In DAF treated water, the removal efficient of alge cell counts was found to be upto 90%. The stable turbidity and algae removal were confirmed by operating the high rate DAF process under the condition of the surface loading rate of $30m^3/m^2{\cdot}hr$.

Performance Analysis of IGCC Gas Turbine Considering Turbine Operation Condition Change due to Modulation of Nitrogen Dilution (질소희석량 조절에 따른 터빈 운전조건 변화를 고려한 IGCC 용 가스터빈의 성능분석)

  • Kim, Chang Min;Kang, Do Won;Kim, Tong Seop
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.11
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    • pp.1023-1029
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    • 2013
  • The integration between a gas turbine and an air separation unit (ASU) is important in IGCC plants. The portion of ASU air extracted from the gas turbine and the degree of nitrogen supply from the ASU to the gas turbine side are important operating parameters. Their effect on the gas turbine performance and operability should be considered in a wide ambient temperature range. In this study, appropriate nitrogen dilution rate and turbine inlet temperature that satisfy the two limitations of turbine blade temperature and maximum allowable power output were predicted. The air integration was set at zero. The simulation showed that the power output increases and turbine blade temperature decreases as the nitrogen dilution increases. The maximum allowable power output can be obtained under medium and low ambient temperature ranges. Under a high ambient temperature range, the achievable power is less than the maximum power.

Chiral Mesoporous Silica for Asymmetric Metal-free Catalysis: Enhancement of Chirality thorough Confinement Space by Plug Effect

  • Jeong, Eun-Yeong;Im, Cheong-Rae;Park, Sang-Eon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.199-199
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    • 2011
  • The addition of a carbanion to ${\yen}{\acute{a}}{\yen}{\hat{a}}$-unsaturated carbonyl compounds is of importance in the C-C bond formation reactions for modern pharmaceuticals and organic synthesis. Recently, heterogeneous asymmetric catalysis became more attractive area of research because of the easy recovery and separation of the catalyst from the reaction system. Most of synthetic methods for heterogeneous catalysts were grafting or immobilization of homogeneous catalyst onto the solid supports. Trans-1,2-Diaminocyclohexane(DACH) and L-proline ligands have been enormously used as chiral ligands in several catalytic transformation under homogenous conditions. Our group prepared l-proline functionalized mesoporous silica was synthesized under acidic condition using a poly(ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) triblock copolymer template (EO20PO70EO20, Pluronic P-123, BASF). Furthermore, we successfully directly synthesized trans-1,2 diaminocyclohexane functionalized mesoporous silica by using microwave method. The direct functionalization of chiral ligand into the framework of mesoporous materials is expected to be useful for the heterogeneous asymmetric catalysis. So, we adopt the direct synthesis of chiral ligand functionalized mesoporous silica by using thermal and microwave irradiation. Then, chiral ligand functionalized mesoporous silicas were applied to enantioselective asymmetric catalytic reactions.

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The Analysis of Ethanol Distribution Level in Biological Specimens (생체 시료중에서 Ethanol 농도 분포에 관한 연구)

  • Hong, Hoon-Gi;Kim, Dong-Wook
    • Analytical Science and Technology
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    • v.11 no.3
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    • pp.222-228
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    • 1998
  • Five kinds of packed column and two kinds of capillary column were used to get optimum condition for ethanol analysis by using fifteen different volatile, low molecular weight organic substances. Only two columns, Gaskuropack 54 and DB-1, showed good separation efficiency. In the adding salt-effect experiment 0.6N - perchloric acid, 1M - meta-phosphoric acid and saturated NaCl solution were used for alcohol concentration measurement of biological fluids and tissue specimens. Among adding salt experiment, adding saturated NaCl solution showed the most stable value of alcohol concentration. This fact might be due to the increased vaporization of alcohol in the saturated NaCl solution. In the time-course of blood alcohol concentration, the alcohol level was lineary decreased to the diameter of vessel containing specimens. This result was interpreted in view of ethanol level, weight, water content, and hematocrit value. The ethanol distribution levels were measured from samples of blood and tissue obtained from 25 postmortems cases investigated by NISI. This study showed that the distribution level was decreased in order of brain, blood, kidney, spleen, liver, and lung.

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Wave-Energy Extraction by a Compact Circular Array of Buoys (원형으로 배열된 다수 부이에 의한 파랑에너지 추출)

  • Cho, Il-Hyoung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.26 no.2
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    • pp.103-111
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    • 2014
  • The wave power, extracted from a circular array of small power buoys, is investigated under the potential theory. It is assumed that the buoy's radius, the draft, and the separation distance are much smaller than the water depth, the wave length, and the radius of a circular deployment area. The boundary value problem involving the macro-scale boundary condition on the mean surface covered by buoys is solved using the eigenfunction expansion method. The capture width, which is defined as the ratio of the extracted power to the wave power per unit length of the incident wave crest, is assessed for various combinations of packing ratio, radius of a circular array, and PTO damping coefficient. It is found that the circular array deployment is more effective in the viewpoint of efficiency than the single large buoy of the same total displaced volume.

Analysis on the Performance and the Emission of the Integrated Gasification Combined Cycle Using Heavy Oil (중잔사유 가스화 복합발전 사이클의 성능 및 환경배출 해석)

  • Lee, Chan;Yun, Yong-Seong
    • Journal of Energy Engineering
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    • v.10 no.3
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    • pp.188-194
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    • 2001
  • The process simulations are made on the IGCC power plant using heavy residue oil from refinery process. In order to model combined power block of IGCC, the present study employs the gas turbine of MS7001FA model integrated with ASU (Air Separation Unit), and considers the air extraction from gas turbine and the combustor dilution by returned nitrogen from ASU. The exhaust gas energy of gas turbine is recovered through the bottoming cycle with triple pressure HRSG (Heat Recovery Steam Generator). Clean syngas fuel of the gas turbine is assumed to be produced through Shell gasification of Visbreaker residue oil and Sulfinol-SCOT-Claus gas cleanup processes. The process optimization results show that the best efficiency of IGCC plant is achieved at 20% air extraction condition in the case without nitrogen dilution of gas turbine combustor find at the 40% with nitrogen dilution. Nitrogen dilution of combustor has very favorable and remarkable effect in reducing NOx emission level, while shifting the operation point of gas turbine to near surge point.

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The Development of China's Venture Capital Industry and the Characteristics of its Capital Spatial Configuration (중국 벤처캐피탈 산업의 발전 과정 및 자본 공간 배치의 특성)

  • Jin, Xiaowei
    • Journal of the Economic Geographical Society of Korea
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    • v.20 no.4
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    • pp.431-452
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    • 2017
  • This paper examines the development process of China's venture capital industry and the characteristics of its capital spatial configuration. The results reveal that the development of China's venture capital industry has its unique modality, which varies greatly from existing studies, namely, the desynchronized paces of industry development as well as the regional real capital supply and demand trend. More detailed observation shows the Chinese venture capital's spatial configuration has three main characteristics: first, the separation of the registered location and the actual location of business operation; second, the division and spatial configuration of the venture fund's capital circulation. To find the relevant factors related to the above phenomena, a correlation analysis was conducted between both market factors and non-market factors with the above capital spatial configuration. The analysis confirmed that besides the market factors, local legislative condition also presents a high correlation with the phenomena.

Characteristics of the Transverse Fuel Injection into a Supersonic Crossflow using Various Injector Geometries (분사구 형상에 따른 초음속 유동장 내 수직 연료 분사 특성)

  • Kim, Seihwan;Lee, Bok Jik;Jeung, In-Seuck;Lee, Hyoungjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.3
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    • pp.53-64
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    • 2018
  • In this study, computational simulation was performed to investigate the characteristics of air/fuel mixing according to the shape of the injector exit when the transverse jet was injected into a supersonic flow. Non-reacting flow simulation was conducted with fixed mass flow rate and the same cross-sectional area. To validate the results, free stream Mach number and jet-to-crossflow memetum ratio are set to 3.38 and 1.4, respectively, which is same as the experimental condition. Further, separation region, structure of the under-expended jet, jet penetration height, and flammable region of hydrogen for five different injectors compared.

Experimental Study on the Eddy Making Damping Effect at the Roll Motion of a Rectangular Barge (사각형 바지선의 횡동요 와류 감쇠에 대한 실험적 연구)

  • Jung, Kwang-Hyo;Suh, Sung-Bu;Chun, Ho-Hwan
    • Journal of the Society of Naval Architects of Korea
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    • v.44 no.3 s.153
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    • pp.267-278
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    • 2007
  • This experimental study investigated on the eddy making effect on the roll motion of a rectangular barge in a two-dimensional wave tank. The structure was used to simulate a simplified rectangular barge in the beam sea condition. The structure with a draft one half of its height was hinged at the center of gravity and free to roll by waves. The rectangular barge was tested with regular waves with a range of wave periods that are shorter, equal to, and longer than its roll natural period. Particle image velocimetry (PIV) was employed to obtain the velocity field in the vicinity of the structure. The coupled interactions between the incident wave and the barge were demonstrated by examining the vortical flow fields to elucidate the eddy making effect during the roll motion. For incoming wave with a wave period same as the roll natural period, the barge roll motion was reduced by the eddy making damping effect. At the wave period shorter than the roll natural period, the structure roll motion was slightly reduced by the vertical flow around the barge. However, at the wave period longer than the roll natural period, the eddy making effect due to flow separation at structure corners indeed amplifies the roll motion. This indicates that not only can the eddy making effect damp out the roll motion, it can also increase the roll motion.