• Title/Summary/Keyword: Separation condition

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Ion-Pair Chromatography of Aromatic Carboxylic Acids on the Reversed-phase System (역상계에서 방향족 카르복시산류의 이온-쌍 크로마토그래피)

  • Hae-Beom Oh;Sam-Woo Kang;Seung-Seok Lee
    • Journal of the Korean Chemical Society
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    • v.30 no.3
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    • pp.312-319
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    • 1986
  • Dodecyltrimethylammonium bromide (DTAB) was examined as a counter-ion in the investigation of capacity factor and separation of aromatic carboxylic acids on alkyl-modified silica (ODS) column as a stationary phase by ion-pair chromatography on reversed-phase system. The capacity factor of samples was influenced by the several factors such as a concentration of counter-ion as well as kinds and concentration of electrolyte, concentration of methanol in mobile phase and kinds and position of functional group in sample molecule. Some mixtures of samples were able to be separated under optimum condition.

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Preparation and Photoelectrochemical Behavior of Cu2O/TiO2 Inverse Opal Heterojunction Arrays

  • Kim, Hyun-Sik;Lee, Sang-Kwon;Kang, Soon-Hyung
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.149-153
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    • 2012
  • The $Cu_2O/TiO_2$ inverse opal heterojunction arrays were developed by electrochemical deposition of $Cu_2O$ nanoparticles on $TiO_2$ inverse opal arrays. The $Cu_2O$ nanoparticles completely filled the inner pores of $TiO_2$ inverse opal film (prepared by liquid phase deposition with an average thickness of 400 nm) and covered the entire area; exhibiting high crystalline properties of anatase and cubic phase from $TiO_2$ and $Cu_2O$, respectively. From asymmetric current-voltage profile, it was noticeable that a heterojunction was well formed for charge transport from $Cu_2O$ to $TiO_2$ film resulting from the enhanced charge separation yield. In addition, increased photocurrent of 0.19 $mA/cm^2$ (versus 0.08 $mA/cm^2$ under dark condition) was obtained at -0.35 V from the heterojunction structure in the 0.5M $Na_2SO_4$ solution.

Fatigue Effect and Particle Rearrangement of Geosynthetics Filter Layer with Cyclic Flow Conditions (교번흐름 조건에 따른 토목섬유 필터층의 재료분리 및 지오텍스타일의 피로영향 분석)

  • Oh, Young-In;Yoo, Jeon-Yong;Kim, Hyun-Tae
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.1554-1561
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    • 2005
  • Geotextiles form one of the two largest groups of geosynthetics and it is consisted two major types of synthetic material (Woven, Non-woven). The functions of geotextiles are separation, reinforcement, filtration, drainage and as a moisture barrier. Within these functions, however, there are a large number of applications or use areas. Although the many research scholar and engineer developed and established the design criteria and construction methodology of geosynthetics filter layer, because the lack of suitable design terminology and uncertainty of long term durability, sustainable research still needed for optimum design methodology to the complicate field conditions. Especially, more intensive research needed about under the cyclic flow condition and fine silty sand base material. In this paper, the filter model test performed under cyclic flow with various boundary conditions (period and frequency of cyclic flow, types of geosynthetic filter material, surcharge etc.).

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A Study on Flux Efficiency on Membrane for Water Reclamination according to Coagulations (하수처리수 재이용을 위한 막분리 공정시 응집조건에 따른 투과효율 변화에 관한 연구)

  • Jung, Jin-Hee;Jang, Sung-Ho;Choi, Young-Ik
    • Journal of Environmental Science International
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    • v.20 no.6
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    • pp.767-773
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    • 2011
  • The objectives of this research are to investigate the proper coagulation conditions which are a type and doses of coagulants, mixing conditions (velocity gradients and mixing times), pH and so on through Jar-test, to evaluate the flux variations, permeate, backwashing according to characteristics of pretreatment of the wastewater by means of MF membranes for river maintenance water reuse. The effluent water from B-city K-sewage treatment plant are used for this research. Turbidity and suspended solids(SS) are 14.2 NTU and 10.4 mg/L respectively. This condition causes fouling for membrane process. The flux decline could be reduced when coagulation pretreatment was carried out. Optimal coagulations PAC which are commonly used in the sewage treatment plant was observed in this research. The results indicate that an optimal coagulation dose and pH are 80 ppm and pH of 7 respectively, but coagulation efficiency was lower at strong acid or strong base. Results showed that continuous and steady operations in membrane separation process by means of the effective removal of organic matter and turbidity with coagulation pretreatment of sewage secondary effluent were achieved.

Response of Oxygen Consumption and Gill Tissue of Fish Exposed to Red Tide Organism Cochlodinium polykrikoides (적조생물 Cochlodinium polykrikoides에 노출된 어류의 산소 소모량 및 조직 변화)

  • Shim, Jeong-Min;Lee, Chu;Lee, Yong-Hwa;Kim, Bong-Suck
    • Journal of Environmental Science International
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    • v.18 no.11
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    • pp.1283-1289
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    • 2009
  • Eco-physiological research and the control of Cochlodinium polykrikoides was carried out to elucidate eco-physiological characteristics of red tide organism through culture experiment depending on the condition of photon irradiance. Oxygen consumption of C. polykrikoides was high with a value of 1.12 mg/L/hr in the dark compared with that of 0.13 mg/L/hr at $100{\mu}mEm^{-2}s^{-1}$. DO values in a circular chamber with the lapse of time in seawater containing C. polykrikoides were declined in the dark period. DO values of seawater containing C. polykrikoides in the dark were declined from 7.01 mg/L to 2.65 mg/L in 30 cm depth and from 7.01 mg/L to 6.63 mg/L in 5 cm depth depending on the depth of circular culture vessel. Olive flounder, Paralichthys olivaceus and file fish, Stephanolepis cirrhifer exposed to Cochlodinium showed the separation of the lamella epithelium from gill filament, which disrupted the respiratory process at the gill level.

THE COMPARISON OF PIFS AND HEAT TRANSFER WITH BASE CONFIGURATIONS (기저 형상에 따른 PIFS 및 열전달 비교 연구)

  • Kim, J.G.;Lee, J.W.;Kim, K.H.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.195-200
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    • 2010
  • Numerical investigation was conducted to study the effects of after-body configurations and nozzle lip on the PIFS(Plume Induced Flow Separation) and eat flux to the base face. Two dimensional and axi-symmetric non-equilibrium Navier-Stoke's solver with $k-{\omega}$ SST turbulence model was used to solve the launching vehicle type configuration with propulsive jet. The experimental result of Robert J. McGhee was compared with our computational results for code validation. Three types of the after-body configurations (Straight, Boat-tail, Flare type) were simulated for this study. And the nozzle lip effect was studies using the three types of base configurations same simulation conditions. As a result of numerical investigations, higher pressure ratio condition and boat-tail after-body configuration caused severe PIFS phenomenon but the flare type after-body configuration and low pressure ratio suppressed PIFS. Flare type after-body configuration and low pressure ratio case reduced heat flux to base face. The nozzle lip dispersed the heat flux widely along the base face and the nozzle lip.

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Numerical Simulation of Turbulent Heat Transfer in Locally-Forced Separated and Reattaching Flow (국소교란에 의한 박리 재부착 유동에서의 난류 열전달 수치해석)

  • Ri, Gwang-Hun;Seong, Hyeong-Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.1
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    • pp.87-95
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    • 2001
  • A numerical study was made of heat transfer in locally-forced turbulent separated and reattaching flow over a backward-facing step. The local forcing was given to the flow by means of sinusoidally oscillating jet from a separation line. A Rhee and Sung version of the unsteady $\kappa$-$\varepsilon$-f(sub)u model and the diffusivity tensor heat transfer model were employed. The Reynolds number was fixed at Re(sub)H=33,000 and the forcing frequency was varied in the range 0$\leq$fH/U(sub)$\infty$$\leq$2. The condition of constant heat flux was imposed at the bottom wall. The predicted results were compared and validated with the experimental data of Chun and Sung and Vogel and Eaton. The enhancement of heat transfer in turbulent separated and reattaching flow by local forcing was evaluated and analyzed.

Numerical Modelling Of The Coastal Upwelling Near The Poleward Edge Of The Western Boundary Current

  • An, Hui Soo
    • 한국해양학회지
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    • v.16 no.1
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    • pp.12-23
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    • 1981
  • A numerical experiment is made in order to clarify the mechanism of the upwelling phenomenon along the coast near the poleward edge of the western boundary current. The possibility of the upwelling is suggested from the analysis of the observational data in the east of Honshu, Japan, and in the south eastern coast of Korean Peninsula. This upwelling phenomenon is very deep and can be traced to the bottom layer. The upwelling phenomenon seems to be a general oceanic feature which characterizes the region along the west coast near the poleward edge of the western boundary current. This experiment is simulating the oceanic condition of the transition region between Kuroshio front and the Oyashio front in the east of Honshu, Japan. The possible explanations of the causes of the upwelling are as follows;In the interior of the modeled ocean the cold heavy water supplied from the north and the warm light water from the south make the north-south gradient of the pressure field and accelerate the eastward current to produce the h-orizontal divergence feld near the west coast. The divergence is compensated by the upwelling near the separation region. Another one is that the upwell-ed cold water strengthen constantly the pressure gradient which is balanced by the northward current and is weakened by the horizontal diffusion.

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Chromatographic Behavior of Proteins on Stationary Phase with Aminocarboxy Ligand

  • Li, Rong;Ju, Ming-Yang;Chen, Bin;Sun, Qing-Yuan;Chen, Guo-Liang;Shi, Mei;Wang, Xiao-Gang;Zheng, Jian-Bin
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.590-594
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    • 2011
  • An aminocarboxy aspartic acid-bonded silica (Asp-Silica) stationary phase was synthesized using L-aspartic acid as ligand and silica gel as matrix. The standard protein mixtures were separated with prepared chromatographic column. The effects of solution pH, salt concentration and metal ion on the retention of proteins were examined, and also compared with traditional iminodiacetic acid-bonded silica (IDA-Silica) column. The results show that Asp-Silica column exhibited an excellent separation performance for proteins. The retention of proteins on Asp-Silica stationary phase was consistent with electrostatic characteristic of cation-exchange. The stationary phase displayed typical metal chelate property after fixing copper ion (II) on Asp-Silica. Under competitive eluting condition, protein mixtures were effectively isolated. Asp ligand showed better ion-exchange and metal chelating properties as compared with IDA ligand.

Analysis of Conductive Interference nearby High Voltage Power Lines under Fault Condition (송전선로 지락시 철탑 인근의 대지전위간섭 해석모델)

  • Choi, J.K.;Lee, W.K.;Ryu, H.Y.;Shin, B.H.;Son, K.M.;Kim, T.Y.;Hwang, G.C.
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.466-467
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    • 2008
  • In case of a line-to-ground fault at transmission lines, a portion of fault current will flow into the earth through the footings of the faulted tower causing electrical potential rise nearby the faulted tower footings. In this situation, any buried pipelines or structures nearby the faulted tower can be exposed to the electrical stress by earth potential rise. Although many research works has been conducted on this phenomena, there has been no clear answer of the required separation distance between tower footings and neary buried pipeline because of its dependancy on the soil electrical charactersics of the concerned area and the faulted system.

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