• 제목/요약/키워드: Separation Coefficient

검색결과 432건 처리시간 0.029초

Fourier 변환을 이용한 ZnCdSe 전이점 연구 (Study on critical point of ZnCdSe by using Fourier analysis)

  • 윤재진;공태호;김영동
    • 한국진공학회지
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    • 제16권6호
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    • pp.458-462
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    • 2007
  • 타원편광분석법은 반도체 물질의 광 특성과 전이점 연구에 유용하게 쓰이는 기술이다. 측정된 유전율 함수로부터 전이점을 구하기 위해서 전통적으로 이차 미분스펙트럼을 이용하여 분석하는데, 이 방법은 high frequency 의 잡음을 크게 증폭시키는 단점이 있다. 본 연구에서는 역 공간 푸리에 변환 (Fourier transform)을 이용하여 low-, medium-, high-index 의 푸리에 계수로부터 baseline, 정보, high frequency 잡음을 분리하는 방법을 소개하고자 한다. 이 방법을 이용하여 광전자소자에 폭넓게 사용되는 ZnCdSe 화합물 반도체의 $E_1,\;E_1+{\Delta}_1$ 전이점에 대한 연구를 하여 전통적인 이차 미분법과 비교해 보았다.

Multiresidue Determination of Quinolones in Porcine, Chicken, and Bovine Muscle Using Liquid Chromatography with Fluorescence Detection

  • Lee, Sang-Hee;Shim, You-Sin;Kim, Hyun-Ju;Shin, Dong-Bin
    • Food Science and Biotechnology
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    • 제18권4호
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    • pp.978-984
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    • 2009
  • An analytical method for the simultaneous determination of 9 quinolones (QNs) in porcine, chicken, and bovine muscles was developed and validated using liquid chromatography-fluorescence detector (LC-FLD). The samples were extracted using a liquid-liquid extraction (LLE) process. Chromatographic separation was achieved on a reverse phase $C_8$ column with a gradient elution using a mobile phase of 200 mM ammonium acetate buffer (pH 4.5) and acetonitrile (ACN). The proposed method was validated according to the Food and Drug Administration (FDA) guideline for bioanalytical assay procedures. Recoveries of QNs were 83.1-111.9% with relative standard deviations (RSDs) below 15%. Linearity within a range of 30-500 ${\mu}g/kg$ was obtained with the correlation coefficient ($R^2$) of 0.9967-0.9999. The limits of detection (LOD) were 1-16 ${\mu}g/kg$. These values were lower than the maximum residues limits (MRLs) established by the European Union (EU). The present method was successfully applied to determine QNs in edible muscles.

음이온 계면활성제 미셀형성을 이용한 중공사 한외여과막 시스템에서의 코발트(Co)이온 제거 (Removal of Co++ Ion in the Hollow Fiber Ultrafiltration System using Anion Surfactant Micellar Enhancement)

  • 양현수;한광희;최광순
    • 공업화학
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    • 제7권1호
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    • pp.109-117
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    • 1996
  • 음이온 계면활성제의 미셀을 이용하여 한외여과막에서의 금속이온의 제거 기술은 분리공정이 간단하고 상변화가 필요없어 폐수로부터 중금속과 작은 분자량의 분자들을 제거할 수 있는 최근에 발전된 기술이다. 임계미셀농도 이상에서 계면활성제 분자들은 서로 모이고 거대분자 또는 미셀을 형성한다. 양이온의 코발트 이온과 음이온 계면활성제 미셀과의 정전기적인 결합으로 크기가 커진 거대분자가 한외여과막에서 제거되었다. 막투과압력차는 한외여과막에서의 금속의 제거율에 비교적 작은 영향을 끼치는 반면 음이온 계면활성제와 금속염간의 비(S/M)는 상당한 영향을 끼쳤다.

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입자 이동 방식에서 Laser Induced Fluorescence와 뭉침에 관한 연구 (A Study on Laser Induced Fluorescence and Coagulation in Particle Transport Mode)

  • 김기준
    • 한국응용과학기술학회지
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    • 제23권4호
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    • pp.340-346
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    • 2006
  • The influences of fluorescence, scattering, and flocculation in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by the spectroscopy of laser induced fluorescence (LIF). The effects of optical properties in scattering media have been found by the optical $parameters({\mu}_s,\;{\mu}_a,\;{\mu}_t)$. Flocculation is an important step in many solid-liquid separation processes and is widely used. When two particles approach each other, interactions of several colloid particles can come into play which may have major effect on the flocculation and LIF process, The value of scattering coefficient ${\mu}_s$ is large by means of the increasing particles of scatterer it has been found that the slope decays exponentially as a function of distance from laser source to detector. It may also aid in designing the best model for oil chemistry, biopharmaceutical products, laser medicine and application of medical engineering on LIF and coagulation in particle transport mode.

Factors Affecting Voluntary Information Disclosure on Annual Reports: Listed Companies in Ho Chi Minh City Stock Exchange

  • NGUYEN, Thi Mai Huong;NGUYEN, Ngoc Tien;NGUYEN, Hong Thu
    • The Journal of Asian Finance, Economics and Business
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    • 제7권3호
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    • pp.53-62
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    • 2020
  • The study aims to provide some plausible explanation for why Vietnamese listed companies only stop at the level of truthful presentation of information related to accounting data through the opinion of independent auditors. The information is only at the level of compliance with the requirements of Circular 155/2015/TT-BTC in form, but in essence is sketchy. What factors affect the level of voluntary disclosure of listed companies in Vietnam? In order to identify the factors affecting voluntary information disclosure on annual reports of listed companies, the study collected data on annual reports of 122 companies listed on the stock market in Ho Chi Minh City in the period 2015-2018 and uses regression analysis methods. The research presents 8 factors affecting the level of voluntary information disclosure including: Firm size, Listed time, Profitability, Solvency, Separation of board of directors and executive director, Board size, Organizational ownership and Foreign ownership. Next, the study conducted descriptive statistical analysis correlation coefficient analysis to examine the correlation and relevance of independent variables measured by the scale ratio, testing multiple linear regression model. The results of the study show that factors listed time, profitability and organizational ownership affecting voluntary information disclosure on annual reports of listed companies in Vietnam.

SENSITIVE DETERMINATION OF ELEVEN PHENOLIC ENDOCRINE-DISRUPTING CHEMICALS IN HUMAN URINE USING GAS CHROMATOGRAPHY/MASS SPECTROMETRY -SELECTED ION MONITORING

  • Kim, Hyub;Jang, Cheol-Hyeon
    • Environmental Engineering Research
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    • 제12권3호
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    • pp.93-100
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    • 2007
  • I improved an analytical method for determining trace amounts of eleven phenolic endocrine-disrupting chemicals (11 phenolic EOCs) in human urine. The 11 phenolic EOCs were subjected to hydrolysis and then to solid phase extraction with a XAD-4 column. Alkylphenols, chlorophenols, and bisphenol A in XAD-4 column were eluted with acetonitrile, and the eluate was concentrated under a nitrogen stream, and then tert-butyldimethylsilylation. Separation and determination were done by gas chromatography, using mass spectrometry operating in the selective ion monitoring mode for quantitation. For tert-butyldimethylsily (TBDMS) derivatization the recoveries were $91.2{\sim}125.9%$, the limits of quantitation (LOQ) for the 11 phenolic EOCs in the nanogram-per-milliliter range ($0.025{\sim}1.000\;ng/mL$) were thus achieved by using 1 mL of urine, and the SIM responses were linear with the correlation coefficient varying by $0.9300{\sim}0.9943$. Based on the results for urine samples from unexposed individuals, 4-tert-octylphenol and pentachlorophenol were detected in hydrolysed urine sample. Other alkylphenols, chlorophenols and bisphenol A were not detected.

피형면에 충돌하는 2차원 분류와 전달특성 및 유동구조 - 충돌 분류의 전열특성 - (Heat Transfer Enhancement and the Flow Structure of a Two-Dimensional Jet Impinging on Wavy Wall)

  • 최국광;차지영
    • 대한기계학회논문집
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    • 제10권1호
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    • pp.96-101
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    • 1986
  • 본 연구에서는 2차원 충돌분류에 있어서 전열면상에 비교적 큰 스케일을 가진 트랜스버스 리브(transverserib)형의 피형돌기를 만들고 충돌영역을 포함하여 통상열전달율이 현저하게 낮아지는 하류역까지의 넓은 영역에 걸쳐 전달회진을 목적 으로 전달특성을 실험적으로 조사하고 전보에서 다룬 거형의 트랜스버스 리브를 갖는 전열면에서의 결과와 비교 검토하였다. 한편 돌기면상의 유동형태의 상세를 smoke wire법에 의해 충돌분류 특유의 종과류와 그 신장에 대하여 조사하고 표면부유법 (surface floating method)에 의해 비교적 큰 스케일의 돌기에 따른 흐름의 박이 및 재부착에 관해서 조사하여 이들과 전열기구와의 관계를 정성적으로 검토하였다.

자율 제어봉을 이용한 실린더 후류의 유동제어에 관한 연구 (Flow Control of Turbulent Wake Behind a Circular Cylinder Using a Self-adjusting Rod)

  • 임희창;감동혁;이상준
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2002년도 학술대회지
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    • pp.467-470
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    • 2002
  • The offects of a small control rod (d=3mm) located near a main circular cylinder on the drag reduction and wake structure modification were investigated. The location of the small control rod mounted on a rod-like spring is self-adjusting according to the wake structure far optimal control of the flow around the main cylinder. The experiments were carried out at the Reynolds numbers based on the cylinder diameter (D=50mm) in the range $Re_{D}=1{\times}10^4{\~}6{\times}10^4$. Mean velocity and turbulent statistics were measured with varying the angle along the cylinder circumference ${\Theta}=15^{\circ},\;30^{\circ},\;45^{\circ}$ and the distance between the main and control rods L =0.7, 1. Compared with the bare cylinder, the main circular cylinder with the fixed and self-adjusting rods reduced drag coefficient by $10{\%}$ at the angle of ${\Theta}=45^{\circ}$. For the main cylinder with self-adjusting rot as the Reynolds numbers increase, the streamwise mean velocity is increased, however, the turbulence intensity is decreased. In addition, the control rods tested in this study are effective at higher Reynolds number than at lower Reynolds number.

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디퓨저 확대각이 임계노즐의 임계압력비에 미치는 영향 (The Influence of the Diffuser Divergence Angle on the Critical Pressure of a Critical Nozzle)

  • 김재형;김희동;박경암
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2002년도 학술대회지
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    • pp.131-134
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    • 2002
  • Compressible gas flow through a convergent-divergent nozzle is choked at the nozzle throat under a certain critical pressure ratio, and then being no longer dependent on the pressure change in the downstream flow field. In practical, the flow field at the divergent part of the critical nozzle can affect the effective critical pressure ratio. In order to investigate details of flow field through a critical nozzle, the present study solves the axisymmetric, compressible, Wavier-Stokes equations. The diameter of the nozzle throat is D=8.26mm and the half angle of the diffuser is changed between $2^{\circ}\;and\;10^{\circ}$ Computational results are compared with the previous experimental ones. The results obtained show that the divergence angle is significantly influences the critical pressure ratio and the present computations predict the experimented discharge coefficient and critical pressure ratio with a good accuracy. It is also found that a nozzle with the half angle of $4^{\circ}$ nearly predicts the theoretical critical pressure ratio.

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추출발효에 의한 알코올.제조공정 개발(III) -추출 알코올 발효에 최적인 PEG/Dx의 조성- (Process Development of Alcohol Production by Extractive Fermentation(III) -An Optimum Composition of PEG/Dx for Extractive Alcohol Fermentation-)

  • 허병기;김진한목영일
    • KSBB Journal
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    • 제8권2호
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    • pp.178-184
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    • 1993
  • Extractive fermentations with the extract of Jerusalem artichoke in an aqueous-two-phase-system of polyethyleneglycol(PEG) and dextran(Dx) were investigated to obtain the effects of composition of PEG and Dx on both fermentation ,characteristics and partition ratio of alcohol. The specific growth rate of K. Fraglis CBS 1555 increased with a decrease of concentration of PEG and Dx. It augmented along with concentration of initial sugar up to 80g/l but decreased thereafter. The specific production rate of alcohol showed a rising tendency up to 100g/lof initial sugar, whereafter represented a decreasing trend. The partition ratio of alcohol between two phases augmented according to decrease of Dx comic. and increase of PEG cone. regardless of initial sugar concentrations. The ratio, however, decreased with Increment of initial sugar concentration at constant composition of PEG and Dx. The partition coefficient of alcohol had an ascending effect to the increase of PEG cone, but it had little effect on the changes of concentrations of Dx and initial sugar. The present study suggests that the optimum composition of PEG and Dx in the aqueous-two-phase-system by extractive fermentation were around 6.5%(w/v) of PEG and 3%(w/v) of Dx in considerations of emulsion state, sedimentation and separation of two phases, alcohol partition ratio, and specific growth rate.

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