• Title/Summary/Keyword: Separation Behavior Analysis

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Fabrication and characterization of polysulfone ultrafiltration membrane using polyethylene glycol and tartaric acid: morphology and performance in protein separation

  • Sharma, N.;Purkait, M.K.
    • Membrane and Water Treatment
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    • v.8 no.6
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    • pp.591-612
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    • 2017
  • Increase in the hydrophilicity (HPCT) of polysulfone (PS) membrane and subsequently decrease in fouling can be achieved by surface modification of PS based membranes. Therefore, in this work, ultrafiltration membranes with increased HPCT were prepared using the enantiomeric tartaric acid (D-TA) and racemic tartaric acid (DL-TA). Phase inversion technique was used for the preparation of polyethylene glycol and TA blended PS membrane. Morphological analysis of the fabricated membranes was done by scanning electron microscope and atomic force microscopy. Bovine serum albumin (BSA) solution was taken for finding the permeation and rejection behavior of prepared membranes. Maximum BSA rejection was increased by 70.5% for the modified membrane.

토양-휴민의 물리화학적 특성 및 PAHs의 결합 특성 연구

  • Im Dong-Min;Sin Hyeon-Sang
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2006.04a
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    • pp.16-19
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    • 2006
  • Humin is the insoluble fraction of humic materials and play an important roles in the irreversible sorption of hydrophobic organic contaminants onto soil particles. However, there have been limited knowledge about the sorption and chemical properties of humin due to the difficulties in its separation from the inorganic matrix(mainly clays and oxides). In this study, do-ashed humin was isolated from a soil sample after removing free lipid and alkali-soluble humic fractions followed by dissolution of mineral matrix with 2% HF, and characterized by elemental analysis, C-13 NMR spectroscopic method. Sorption behavior of 1-naphthol with humin was also investigated from aqueous solution. C-13 NMR spectra indicate that humin molecules are mainly made up of aliphatic carbon including carbohydrate, methylene chain etc.. Sorption intensity for 1-naphthol was increased as organic carbon content of humin increased and log Koc values for the 1-naphthol sorption were determined to be ${\sim}3.12$

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Numerical Study on the Dynamic Response in Elastomeric Oil Seals

  • Shim, Woo Jeon;Sung, Boo-Yong;Kim, Chung Kyun
    • KSTLE International Journal
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    • v.1 no.1
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    • pp.43-47
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    • 2000
  • Oil seals will experience a small amplitude dynamic excitation due to the shaft eccentricity as well as out-of-roundness of the shaft. The direct integration method is selected to analyze the time domain response of the seal lip-shaft contact. The physical properties of rubber seal materials are experimentally analyzed. Effects of both frequency and temperature on the material stiffness behavior are investigated for the linear viscoelastic materials of the seal. Using the nonlinear transient model, a finite element analysis of the lip-shaft contact behaviors under dynamic conditions is presented as a function of the shaft eccentricity, the shaft interference and the garter spring stiffness. The FEM results based on the experimental data indicate that the increased rotating speed may produce the separation conditions. These results will be very useful in predicting the leakage of oil seals under dynamic conditions.

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Plasma Uniformity Analysis of Inductively Coupled Plasma Assisted Magnetron Sputtering by a 2D Voltage Probe Array

  • Joo, Junghoon
    • Applied Science and Convergence Technology
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    • v.23 no.4
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    • pp.161-168
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    • 2014
  • A real-time monitoring of immersed antenna type inductively coupled plasma (ICP) was done with a homemade 2 dimensional voltage probe array to check the uniformity of the plasma. Measured voltage values with a high impedance voltmeter are close to the floating potential of the plasma. As the substrate carrier was moving into a magnetron sputtering plasma diffusive from a $125mm{\times}625mm$ size cathode, measured results showed reliably separation of plasma into the upper and lower empty space over the carrier. Infra red thermal imaging camera was used to observe the cross corner effect in situ without eroding a target to the end of the usage. 3 dimensional particle trace model was used to analyze the magnetron discharge's behavior.

Comparison of Axial and Radial Flow Chromatography on Protein Separation Speed and Resolution (축방향과 반경방향흐름 크로마토그래피의 단백질 분리속도와 분리능에 대한 비교)

  • 김윤하;이은규
    • KSBB Journal
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    • v.10 no.5
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    • pp.482-490
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    • 1995
  • The relationship between pressure drop and liquid flow rate, for an axial and a radial flow chromatographic column packed with compressible porous media was theoretically analyzed using modified Kozeny-Carman equation. The results were compared with experimental observations obtained using compressible DEAE-agarose as a model medium. At 2-9 psi range studied, the theoretical derivation accounting for 'gel compression' effect predicted simple Langmuirian type response of volumetric flow rate to changes in pressure drop. On the other hand, the experimental response was more or less sigmoidal. At the same pressure drop, radial column showed 2-3 times higher flow rates than those of axial column both theoretically and experimentally. Using r-HBsAg crude extract, protein resolution effects between the two types of columns at different flow rates were compared side-by-side. It turned out that, though general chromatographic behavior was very similar, axial column was somewhat superior in terms of r-HBsAg recovery yield and specificity. However, the number of theoretical plates analysis indicated the protein resolution effects were comparable.

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A cohesive model for concrete mesostructure considering friction effect between cracks

  • Huang, Yi-qun;Hu, Shao-wei
    • Computers and Concrete
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    • v.24 no.1
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    • pp.51-61
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    • 2019
  • Compressive ability is one of the most important mechanical properties of concrete material. The compressive failure process of concrete is pretty complex with internal tension, shear damage and friction between cracks. To simulate the complex fracture process of concrete at meso level, methodology for meso-structural analysis of concrete specimens is developed; the zero thickness cohesive elements are pre-inserted to simulate the crack initiation and propagation; the constitutive applied in cohesive element is established to describe the mechanism of crack separation, closure and friction behavior between the fracture surfaces. A series of simulations were carried out based on the model proposed in this paper. The results reproduced the main fracture and mechanical feature of concrete under compression condition. The effect of key material parameters, structure size, and aggregate content on the concrete fracture pattern and loading carrying capacities was investigated. It is found that the inner friction coefficient has a significant influence on the compression character of concrete, the compression strength raises linearly with the increase of the inner friction coefficient, and the fracture pattern is sensitive to the mesostructure of concrete.

Buckling and Postbuckling Behavior of Stiffened Laminated Composite Panels (보강된 복합적층 판넬의 좌굴 및 좌굴후 거동 연구)

  • Lee, In-Cheol;Gyeong, U-Min;Gong, Cheol-Won;Hong, Chang-Seon;Kim, Cheon-Gon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.10
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    • pp.3199-3210
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    • 1996
  • The buckling and postbuckling behaviors were sutdied analytically and experimentally for stiffened laminated composite panels under compression loading. The panels with I-, blade, -and hat-shapeed stiffeners were investigated. In the analysis, the stiffened panels were anlyzed using the nonlinear finite element method combined with an improved arc-length method. The progressive failure analysis was done by adopting the maximum stress criterion and complete unloading failure model. The effects of the fiber angles were investigated on the buckling and postbuckling behaviors. In the experiment, the web and the lower cap of each stiffener were formed by the continuous lay-up of the skin for cocuring the stiffened panels. Therefore, the separation between stiffener and skin was not found in the junction part even after postbuckling ultimate load and the stiffened panels had excellent postbuckling load carrying capacity. A shadow moire thchnique was used to monitor the out-of-plane deformations of the panels. The piezoelectric films were attached to the panels to get the failure characteristics of the panel. The analytical results on the buckling load, postbuckling ultimate load, and failure pattern showed good agreement with the experimental results.

Analysis on Behavior Characteristics of Underground Facility Backfilled with Clsm According to Adjacent Excavation (CLSM으로 되메움된 지하 인프라 매설물의 근접 굴착에 따른 거동특성 분석 )

  • Seung-Kyong, You;Nam-Jae, Yu;Gigwon, Hong
    • Journal of the Korean Geosynthetics Society
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    • v.21 no.4
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    • pp.101-109
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    • 2022
  • This study describes the results of model experiment to analyze the effect of backfill material types on the behavior of underground facility. In the model experiment, backfill materials around the existing underground facility were applied with soil (Jumunjin standard sand) and CLSM. The displacement of underground facility was analyzed for each excavation stage considering the separation distance between the excavation surface and the backfill area based on the experimental results. When soil was applied as a backfill material, the soil on the back of the excavation surface collapsed by excavation and formed an angle of repose, and the process of slope stability was repeated at each excavation stage. In addition, the displacement of underground facility began to occur in the excavation stage that the failure line of soil passes the installation location of the underground facility. When CLSM was applied as a backfill material, there was almost no horizontal and vertical displacement of the ground regardless of the separation distance from the excavation surface even when excavation proceeded to the backfill depth. Therefore, this result showed that it can have a resistance effect against the lateral earth pressure generated and the collapse of the original ground by adjacent excavation, if a backfill material with high stiffness such as CLSM is applied.

Modeling Study on a Circulatory Hollow-Fiber Membrane Absorber for $CO_{2}$ Separation (이산화탄소 분리를 위한 순환식 중공사 막흡수기에 관한 모델링 연구)

  • Chun, Myung-Suk;Lee, Kew-Ho
    • Membrane Journal
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    • v.5 no.1
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    • pp.35-43
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    • 1995
  • For several years lots of attempts have been made to establish the liquid membrane-based techniques for separations of gas mixtures especially containing carbon dioxide. A more effective system to separate $CO_{2}$ from flue gases, a circulatory hollow-fiber membrane absorber(HFMA) consisting of absorption and desorption modules with vacuum mode, has been considered in this study. Gas-liquid mass transfer has been modeled on a membrane module with non-wetted hollow-fibers in the laminar flow regime. The influence of an absorbent flow rate on the separation performance of the circulatory HFMA can be predicted quantitatively by obtaining the $CO_{2}$ concentration profile in a tube side. The system of $CO_{2}/N_{2}$ binary gas mixture has been studied using pure water as an(inert) absorbent. As the absorbent flow rate is increased, the permeation flux(i.e., defined as permeation rate/membrane contact area) also increases. The enhanced selectivity compared to the previous results, on the other hand, shows the decreasing behavior. It has been found obviously that the permeation flux depends on the variations of pressure in gas phase of desorption module. From an accurate comparison with the results of conventional flat sheet membrane module, the advantageous permeability of this circulatory HFMA can be clearly ascertained as expected. Our efforts to the theoretical model will provide the basic analysis on the circulatory HFMA technique for a better design and process.

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Improvement of Toughness of Tetrafunctional Epoxy (TGDDM) Resin Using Polyamideimide (PAI) Resin (폴리아미드이미드 수지를 이용한 4관능성 에폭시 수지의 강인화 향상)

  • 박수진;허건영;이재락;홍영택;최길영
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.599-606
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    • 2002
  • In this study, 4,4'-tetraglycidyl diaminodiphenyl methane (TGDDM)/polyamideimide (PAI) blends were cured using diaminodiphenyl sulfone (DDS). And the effect of addition of different PAI contents to neat TGDDM was investigated in the thermal, mechanical, and morphological properties of the blends. The cure behavior and thermal stability of the cured specimens were monitored by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), respectively. Also, the critical stress intensity factor (K$\_$IC/) was measured in UTM, and the phase separation behavior and final morphology of TGDDM/PAI blends were examined in scanning electron microscopy(SEM). As a result, the cure temperature and cure activation energy (E$\_$a/) were decreased with increasing the PAI content. The decreasing of cure temperature and cure activation energy were probably due to the presence of secondary amine group of PAI backbone used as co-initiator. But, the decomposition activation energy (E$\_$t/) and K$\_$IC/ value were increased up to 5. 10 phr of PAI content, respectively and they were decreased above the PAI contents. These results were explained on the basis of chain scission reaction by etherification. And morphology of blends observed from SEM was confirmed in co-continuous structures.