• Title/Summary/Keyword: Sensitivity to metals

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Effect of the Various Heavy Metals on the Growth and Phosphorus (P) Removal Capacity of the Phosphorus Accumulating Microorganism (Pseudomonas sp.) (다양한 중금속이 인 축적 미생물 (Pseudomonas sp.)의 생장과 인 제거에 대한 효과)

  • Kim, Hee-Jung;Yoo, Ri-Bi;Han, Seok-Soon;Woo, Sun-Hee;Lee, Moon-Soon;Baek, Ki-Tae;Chung, Keun-Yook
    • Korean Journal of Environmental Agriculture
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    • v.29 no.2
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    • pp.189-196
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    • 2010
  • The removal of phosphorus (P) in the wastewater is essential for the prevention of eutrophication in the river and stream. This study was initiated to evaluate the effect of the various heavy metals on the growth and P removal capacity of Pseudomonas sp., which was well known as phosphorus accumulating microorganism(PAO's) in the EBPR(Enhanced Biological Phosphorus Removal) process. The five heavy metals used in the study were Cu, As, Zn, Ni, and Cd. The growth rate of Pseudomonas sp. was the greatest at $25^{\circ}C$, but the removal efficiency of P was the highest at $30^{\circ}C$. The $IC_{50}$ (median Inhibition Concentration) values of Pseudomonas sp. for the Cu, As, Zn, Ni, and Cd were 2.35, 11.04, 1.80, 4.92, and 0.24 mg/L, respectively. Therefore, it appears that the sensitivity of the heavy metals to Pseudomonas sp. was in the following order: Cd> Zn> Cu> Ni> AS. Also, the P removal efficiencies by Pseudomonas sp. were correspondingly decreased as the concentrations of heavy metals were increased.

Characteristics of a Metal-loaded SnO2/WO3 Thick Film Gas Sensor for Detecting Acetaldehyde Gas

  • Jun, Jae-Mok;Park, Young-Ho;Lee, Chang-Seop
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.1865-1872
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    • 2011
  • This study investigates the sensitivity of a gas sensor to volatile organic compounds (VOCs) at various operating temperatures and catalysts. Nano-sized powdered $WO_3$ prepared by sol-gel and chemical precipitation methods was mixed with various metal oxides. Next, transition metals (Pt, Ru, Pd, and In) were doped on the surface of the mixture. Metal-$WO_3$ thick films were prepared using the screen-printing method. The physical and chemical properties of the films were studied by SEM/EDS, XRD, and BET techniques. The measured sensitivity to VOCs is defined as the ratio ($R_a/R_g$) of resistance ($R_{air}$) of $WO_3$ film in the air to resistance ($R_{gas}$) of $WO_3$ film in a VOCs test gas. The sensitivity and selectivity of the films were tested with various VOCs such as acetaldehyde, formaldehyde, methyl alcohol, and BTEX. The thick $WO_3$ film containing 1 wt % of Ru and 5 wt % of $SnO_2$ showed the best sensitivity and selectivity to acetaldehyde gas at an operating temperature of 300 $^{\circ}C$.

Evaluation of the sub-lethal toxicity of Cu, Pb, bisphenol A and polychlorinated biphenyl to the marine dinoflagellate Cochlodinium polykrikoides

  • Ebenezer, Vinitha;Ki, Jang-Seu
    • ALGAE
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    • v.27 no.1
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    • pp.63-70
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    • 2012
  • Algae are sensitive to a wide range of pollutants, and are effective bioindicators in ecotoxicity assessments. Here, we evaluated the sub-lethal sensitivity of the marine dinoflagellate Cochlodinium polykrikoides upon exposure to copper (Cu), lead (Pb), bisphenol A (BPA), and Aroclor 1016 (polychlorinated biphenyl, PCB). Toxic effects were assessed by observations of the reduction in cell counts and chlorophyll a levels after exposure to each toxicant. C. polykrikoides displayed dose-dependent, sigmoidal responses when exposed to the tested chemicals. $EC_{50}$-72 h values for Cu, Pb, BPA, and PCB were 12.74, 46.70, 68.15, and $1.07mg\;L^{-1}$, respectively. PCB, which is an endocrine-disrupting chemical, was the most sensitive, proving its toxic effect on the dinoflagellate. This study provides baseline data on the toxic effects of commonly used heavy metals and endocrine-disrupting chemicals to a marine dinoflagellate.

Sensitivity of Daphnia magna to the Toxic Materials by the static Test (Static Test에 의한 Daphnia magna의 환경오염물질에 대한 민감성 평가)

  • 한의정;최성헌;김진일
    • Journal of environmental and Sanitary engineering
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    • v.9 no.2
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    • pp.101-109
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    • 1994
  • Acute toxicity of heavy metals( mercury, cadmium lead, chromium and copper ), organophosphours insecticides( EPN, 2, 4- D, and parathion ), and other chemicals( arsenic, cyanide, and phenol ) to Daphnia magna was analyzed. Acute toxicity of heavy metals, organophosphours insecticides and other chemicals on Daphnia magna, LC$_{50}$ was showed 0.07-0.73mg/1, 0.22-1.94mg/t and 1.73-39.92mg/1 respectively. Daphnia magna to most of toxic chemicals was sensitive and then it seems to be useful except phenol in toxic test of water. Toxic chemicals were classified as Group 1 which had a high LC$_{50}$ value and the low increase rate of toxicity according to the increase of concentration, Group 2 which had a high LC$_{50}$ value and the high increase rate of toxicity, Group 3 which had a low LC$_{50}$ value and the low increase rate of toxicity. To Daphnia magna, lead, chromium, EPN, and parathion were included in Group 1; Mercury and copper in Group 2; Arsenic and cadmium in Group 3; Cyanide 2,4- D, and phenol in Group 4.

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Acute Toxicity of Carassius auratus and Pungtungia herzi Lavra on Mercury, Lead and Copper Exposure (수은, 납 및 구리에 대한 붕어(Carassius auratus)와 돌고기(Pungtungia herzi) 자어의 급성독성)

  • Cho, Kyu-Seok;Park, Jong-Ho;Kang, Ju-Chan
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.265-268
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    • 2004
  • Larva of Carassius auratus and Pungtungia herzi were exposed to mercury ($HgCl_2$), lead ($PbCl_2$) and copper ($CuSO_4$) to determine acute toxicity. The toxicity tests were conducted triplicate and the $LC_{50}$ values (24, 48, 72 and 96 hours) were determined for two species. Data obtained from the toxicity tests were evaluated using the probit analysis. Although sensitivities of two species to mercury were relatively similar, C. auratus was more susceptible than P. herzi to the exposure of lead but P. herzi was more sensitive than C. auratus on copper. The sensitivity on three metals tested may be ranked in the following order from highest to lowest toxicity on larval stage of these fish: mercury > copper > lead. It is suggested that acute toxic test at the larval stage of C. auratus and P. herzi, indigenous species in Asia area, is an important part of the ecotoxicological assessment of some heavy metals.

Isolation of Cadmium Ion-resistant Bacteria and Resitance to Various Heavy Metals (카드봄 내성균의 분리와 각종 중금속에 대한 저항성의 연구)

  • Yeeh, Yeehn;Lee, Jong-Kun
    • Korean Journal of Microbiology
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    • v.17 no.2
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    • pp.49-57
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    • 1979
  • Cadimium ion-resistant microorganism was isolated from the sludge of wastewater. The physiological, morphological and other cultural data showed that this strain belonged to Citrobacter freudii. A clearcut distinction of growth among nutrient broth, typtic soy broth and synthetic medium was demonstrated. The resistant cells showed only slight mutagenic action. During the growth of bacterial population in resting state, the organisms reduced the initial level of resistance to cadmium ions when they were not kept in contact with cadmium ions in bacteral multiplication. And cadmium ion-resistant and cadmium ion-sensitive strain were found to show equal, lower or higher sensitivity to other heave metals.

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Fatigue Crack Propagation Characteristics of Duplex-Stainless Steel Weldments (II) -Crack Propagation on Near-Threshold Region- (2상계 스테인리스강 용접부의 피로크랙 전파특성 (II) -하한계치 근접에서의 전파특성-)

  • 권종완;김상대;이택순
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.1
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    • pp.115-124
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    • 1989
  • Near-threshold fatigue crack-growth behavior at room temperature for a duplex stainless steel weldments was investigated to evaluate the effect of load ratio, microstructural change, and residual stresses. Near-threshold fatigue crack propagation behavior is found to show a marked sensitivity to .alpha./.gamma. phase ratio, and little residual stress effects. Threshold values in the heat affected zones are higher than those of base metals and threshold values for crack growth decrease with increasing the load ratio in the base metals and weldments. The fractrographic features in base metals, weldments and heat affectred zones were discussed in terms mechanism of crack growth.

Modelling the Tensile Instability of Nanocrystalline Metallic Materials (나노금속재료의 인장불안정에 대한 모델링)

  • Kim H. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2001.10a
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    • pp.251-254
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    • 2001
  • In this paper, the effect of grain refinement on room temperature ductility of copper was addressed. Recent experimental results have shown that this material, as well as a number of other single-phase metals that are ductile when coarse-grained, loose their ductility with decreasing grain size in the sub micrometer range. A recently developed model in which such materials are considered as effectively two-phase ones (with the grain boundaries treated as a linearly viscous second phase) was applied to analyze stability of Cu against ductile necking. As a basis, Hart's stability analysis that accounts for strain rate sensitivity effects was used. The results confirm the observed trend for reduction of ductility with decreasing grain size. The model can be applied to predicting the grain size dependence of ductility of other metallic materials as well.

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Design and Fabrication of MOSFET Type Hydrogen Gas Sensor Using MEMS Process (MEMS 공정기술을 적용한 MOSFET형 수소센서의 설계, 제작에 관한 연구)

  • Kim, Bum Joon;Kim, Jung Sik
    • Korean Journal of Metals and Materials
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    • v.49 no.4
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    • pp.304-312
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    • 2011
  • In this study, MOSFET type micro hydrogen gas sensors with platinum catalytic metal gates were designed, fabricated, and their electrical characteristics were analyzed. The devised MOSFET Hydrogen Sensors, called MHS-1 and -2, were designed with a platinum gate for hydrogen gas adsorption, and an additional sensing part for higher gas sensitivity and with a micro heater for operation temperature control. In the electrical characterization of the fabricated Pt-gate MOSFET (MHS-1), the saturated drain current was 3.07 mA at 3.0 V of gate voltage, which value in calculation was most similar to measurement data. The amount of threshold voltage shift and saturated drain current increase to variation of hydrogen gas concentration were calculated and the hydrogen gas sensing properties were anticipated and analyzed.

Study for the Liquid Metals Enabled Stretchable Electronics (액체금속을 활용한 신축성 전자소재 개발 동향)

  • Joo Hyung Lee;Yoon Su Lee;Jin Yoo;Seoyeon Won;Taehwan Lim
    • Journal of Industrial Technology
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    • v.43 no.1
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    • pp.25-31
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    • 2023
  • Stretchable and flexible electronics that comply with dynamic movements and micromotion of the human tissues can enable real-time monitoring of physiologic signals onto the human skin and in the brain, respectively. Especially, gallium based liquid metal stretchable electronics can offer human-interactive biosensors to monitor various physiologic parameters. However, the liquid-like nature, surface oxidation and contamination by organic materials, and low biostability of the liquid metals have still limited the long-term use as bioelectronics. Here we introduced electrochemical deposition without oxidation pathways to overcome these practical challenges in liquid metal bioelectronics. CNT/PDDA composite with reduction way and PEDOT:BF4 with oxidation way under organic solvent are suggested as rationally designed material engineering approaches. We confirmed that the structures with the soft, flexible, and stretchable liquid metal platform can successfully detect dopamine with a high sensitivity and selectivity, record neural signals including action potentials without scar formation, and monitor physiologic signals such as EMG and ECG.