• 제목/요약/키워드: Semi-Empirical Methods

검색결과 87건 처리시간 0.023초

Study of the unsteady pressure oscillations induced by rectangular cavities in a supersonic flow field

  • Krishnan L.;Ramakrishna M.;Rajan S.C.
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2003년도 The Fifth Asian Computational Fluid Dynamics Conference
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    • pp.294-298
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    • 2003
  • The complex, unsteady, self-sustained pressure oscillations induced by supersonic flow past a rectangular cavity is investigated using numerical simulations. The present numerical study is performed using a parallel, multiblock solver for the two-dimensional, compressible Navier­Stokes equations. Open cavities with length-to-depth (L / D) ratio in the range 0.5 - 3.3 are considered. This paper sheds light on the cavity physics, cavity oscillatory mechanism, and the organisation of vortical structures inside the cavity. The vortex shedding phenomenon, the shear layer impingement event at the aft wall and the movement of the acoustic/compression wave within the cavity are well predicted. The vortical structures· and the source of the acoustic disturbances are found to be located near the aft wall of the cavity. With the increase in the cavity length, strong recompression of the flow near the aft wall leading to a sudden jump in the cavity form drag is observed. The estimated cavity tones are in good agreement with the available semi­empirical relation. Multiple peaks are noticed in deep and long cavities. For the present free­stream Mach number 1.71, it is observed that around L/D=2.0, the cavity oscillatory mechanism changes from the transverse to longitudinal oscillatory mode. The effects of this transition on various fluid dynamics and acoustic properties are also discussed.

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원형 경량 압전 복합재료 작동기를 이용한 마이크로 펌프의 개발 (Development of Micropump using Circular Lightweitht Piezo-composite Actuator)

  • 구옌탄텅;구남서
    • 한국항공우주학회지
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    • 제34권6호
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    • pp.35-41
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    • 2006
  • 본 논문에서는 무밸브 마이크로펌프에 사용되는 압전 다이아프램의 성능을 향상시키는 방법이 연구되었다. 큰 작동 변위와 작동력을 가지는 원형 형태의 경량 압전 복합재료 작동기(LIPCA)를 마이크로 펌프용으로 제작하였다. 유한요소 해석과 실험을 통하여 원형 LIPCA의 성능을 예측하여 최적의 적층 형태를 설계하였다. 최적의 원형 LIPCA를 기반으로 포토리소그라피법과 PDMS 몰딩법을 사용하여 무밸브 마이크로 펌프를 제작하였다. 압전 다이아프램의 작동 변위 및 마이크로 펌프의 유량과 배압을 실험적으로 계측하였고, 반경험식을 사용하여 예측한 유량과 비교하였다. 이상의 연구에서 원형 LIPCA가 마이크로 펌프용으로 사용되는 보통의 압전 작동 다이아프램을 대체할 수 있는 우수한 작동기임을 확인할 수 있었다.

Silver Sol과 Silver Mirror Substrate를 이용한 Fluorescein의 SERS 연구 (SERS Study of Fluorescein Using the Silver Sol and Silver Mirror Substrates)

  • 이철재;최현국;정맹준
    • 한국산업융합학회 논문집
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    • 제10권1호
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    • pp.27-32
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    • 2007
  • It has been recently reported that the SERS (Surface Enhanced Raman Scattering) effect of the silver mirror substrate made by Tollen's method is much superior to that of other substrates. In this study, the experiments for comparison of surface enhancement of silver sol and silver mirror substrates were done, where we checked the characteristics of silver mirror substrate made by Tollen's method. The surface enhancement of fluorescein was analyzed by silver sol and silver mirror substrates. We observed the SERS spectra of fluorescein. The assignments of the vibrational bands shown in SERS spectra are given based on both literature and the semi-empirical calculations at the PM3 methods. The surface enhancement properties for fluorescein showed that the silver mirror was more superior to sliver sol substrates. Spectra of fluorescein revealed that fluorescein was adsorbed on silver surfaces by a common oxygen atom. According to the 'surface selection rule', the vibrations in the band intensities reflect the adsorption orientation of the molecule on to the surface of SERS substrates. Therefore, we deduced that the adsorption orientation of fluorescein was little tilted perpendicular to the silver surfaces by using of the surface selection rules.

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TV 사극 <이산>의 현대적 감각의 의상디자인 개발 - 주요 여자 등장인물들의 의상을 중심으로 - (Development of Costume Design with Contemporary Taste in TV Historical Drama - Focused on the Costume of Main Female Characters -)

  • 이금희;이혜란
    • 복식문화연구
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    • 제18권1호
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    • pp.44-63
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    • 2010
  • The purpose of this study was to examine the process to manufacture costume design of main female characters of TV historical drama and suggest the costume, which is developed with contemporary taste. As study methods, the literature study using books and theses concerning costume, fine art, culture and history were used for theoretical background and the empirical study method manufacturing actual costume on the basis of literature and relic were used for dress manufacture. The study results were as follows. The costume was decided by researching historical investigation material on the basis of synopsis, grasping director's basic intention, setting design direction, preparing design map of each character, selecting style, detail, fabric and color, manufacturing sample and performing camera test. The design concept of was Modern & Chic & Clean, short & fitted chogori, chima with wide & abundant cocoon silhouette, clean & bright colors and 100% silk fabric. For the design discrimination of royal semi-formal costume, color was used to symbolize character and pattern was used to symbolize social status. In addition, detail change was adopted depending on the body shape of actor and there was almost no design discrimination in silhouette and fabric. Petticoat of the west, modernization of transitional pattern and change of detail were adopted as design elements to add contemporary taste.

Evaluation of shear capacity of FRP reinforced concrete beams using artificial neural networks

  • Nehdi, M.;El Chabib, H.;Said, A.
    • Smart Structures and Systems
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    • 제2권1호
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    • pp.81-100
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    • 2006
  • To calculate the shear capacity of concrete beams reinforced with fibre-reinforced polymer (FRP), current shear design provisions use slightly modified versions of existing semi-empirical shear design equations that were primarily derived from experimental data generated on concrete beams having steel reinforcement. However, FRP materials have different mechanical properties and mode of failure than steel, and extending existing shear design equations for steel reinforced beams to cover concrete beams reinforced with FRP is questionable. This paper investigates the feasibility of using artificial neural networks (ANNs) to estimate the nominal shear capacity, Vn of concrete beams reinforced with FRP bars. Experimental data on 150 FRP-reinforced beams were retrieved from published literature. The resulting database was used to evaluate the validity of several existing shear design methods for FRP reinforced beams, namely the ACI 440-03, CSA S806-02, JSCE-97, and ISIS Canada-01. The database was also used to develop an ANN model to predict the shear capacity of FRP reinforced concrete beams. Results show that current guidelines are either inadequate or very conservative in estimating the shear strength of FRP reinforced concrete beams. Based on ANN predictions, modified equations are proposed for the shear design of FRP reinforced concrete beams and proved to be more accurate than existing equations.

Experimental and ab initio Computational Studies on Dimethyl-(4-{4-{3-methyl-3-phenyl-cyclobutyl)-thiazol-2-yl]-hydrazonomethyl}-phenyl)-amine

  • Yuksektepe, Cigdem;Saracoglu, Hanife;Caliskan, Nezihe;Yilmaz, Ibrahim;Cukurovali, Alaaddin
    • Bulletin of the Korean Chemical Society
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    • 제31권12호
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    • pp.3553-3560
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    • 2010
  • A new hydrazone derivative compound has been synthesized and characterized by IR, $^1H$-NMR, $^{13}C$-NMR and UV-vis. spectroscopy techniques, elemental analysis and single-crystal X-ray diffraction (XRD). The new compound crystallizes in monoclinic space group C2/c. In addition to the crystal structure from X-ray experiment, the molecular geometry, vibrational frequencies and frontier molecular orbitals analysis of the title compound in the ground state have been calculated by using the HF/6-31G(d, p), B3LYP/6-311G(d, p) and B3LYP/6-31G(d, p) methods. The computed vibrational frequencies are used to determine the types of molecular motions associated with each of the observed experimental bands. To determine conformational flexibility, molecular energy profile of (1) was obtained by semi-empirical (AM1) calculation with respect to a selected degree of torsional freedom, which was varied from $-180^{\circ}$ to $+180^{\circ}$ in steps of $10^{\circ}$. Molecular electrostatic potential of the compound was also performed by the theoretical method.

계면 전단응력이 있을 때와 없을 때 하강하는 난류액막에 대한 개선된 열전달 예측 모델 (An Improved Heat Transfer Prediction Model for Turbulent Falling Liquid Films with or Without Interfacial Shear)

  • Park, Seok-Jeong;Chun, Moon-Hyun
    • Nuclear Engineering and Technology
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    • 제27권2호
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    • pp.189-202
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    • 1995
  • 계면 전단응력이 있을 때와 없을 때 가열 또는 응축되면서 하강하는 난류액막의 열전달 계수를 예측하기 위한 개선된 방법을 제시하였다. 특히 큰 계면 전단응력이 있을 때 하강하는 난류액막에 적용할 수 있도록 Mudawwar와 El-Masri의 준 실험적 난류모델을 수정하여 Yih와 Liu가 제안한 통합적 접근방법에 사용한 와류점성모델대신에 사용하였다. 광범위한 크기의 계면전단응력에 대해 액막 레이놀즈 수 대액체막 두께 및 접근적 열전달 계수를 개선된 방법과 다른 여러 기존 방법으로 예측하여 실험값들과 비교하였다. 그 결과 일반적으로 수정한 모델과 예측한 값이 다른 기존 모델로 예측한 값보다 실험 치와 더밀접하게 일치하는 것을 보여주었다.

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Synthesis, spectral, thermal, structural study and theoretical treatment of new complexes of mannich base with Ni(II) and study of cytotoxicity effect on (Hepa-2) cell line and antimicrobial activity

  • Omar H. Al-Obaidi
    • 분석과학
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    • 제36권2호
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    • pp.70-79
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    • 2023
  • The synthesis of the Mannich base as a ligand (L) N-(morpholino (phenyl) methyl) acetamide is the subject of this study. Elemental analyses, FT-IR spectra, UV-vis, 1H-NMR, and magnetic measurements were used to confirm the synthesis of the [Ni(L)2]Cl2 complex, thermal analysis (TG/DTG), atomic absorption, and scanning, and structurally explained as electron microscopy (SEM), and X-ray powder diffraction (XRD) methods. The melting point of the complex and its molar conductivity were also measured. The suggested geometries of the complexes formed have a tetrahedral structure, according to the data acquired using various techniques. Theoretical approaches to the complex formation have been investigated. For molecular mechanics and semi-empirical calculations, the HYPERCHEM6 program had been used. The effect of the novel Ni(II) complex on the cancer cell Hepa-2 (human hepatocellular ademocarcinoma), that is the human laryngeal cancer, was studied. It has been found that these ligand and complex have potent effects on the cancer cell. The antibacterial activity of the free ligand and its complex was evaluated against two kinds of human pathogenic bacteria. The first category is Gram-positive (Staphylococcus aureas, epiderimids), whereas the second group is Gram-negative (Psedamonas aeruginosa, Escherichia coli) (from the diffusion method). Finally, it was discovered that various chemicals had varied growth-inhibiting effects on bacteria.

Non-Suicidal Self-Injury and Emotional Dysregulation in Male and Female Young Adults: A Qualitative Study

  • Daphnee Thomas;Celine Bonnaire
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • 제34권3호
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    • pp.159-168
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    • 2023
  • Objectives: Non-suicidal self-injury (NSSI) has been theoretically, clinically, and empirically associated with emotional dysregulation. NSSI is a means of regulating emotional states, particularly negative emotions. However, empirical studies on this topic are scarce and the literature lacks qualitative research on individuals' perceptions and comprehension of the function of self-injury. Thus, this qualitative study aimed to provide novel insights into the relationship between NSSI and emotional dysregulation in young adults. Methods: Twelve participants (mean age=22.7 years, 9 females and 3 males) from different support groups and a healthcare center participated in semi-structured interviews on NSSI-related emotional processes. Three aspects were investigated: reasons for NSSI, function of NSSI, and emotions. Each interview was voice recorded and typically lasted between 20 and 40 minutes. All responses were analyzed using thematic analysis. Results: Four major themes were identified. The results showed that NSSI had both intrapersonal and interpersonal functions, within which emotional regulation played a significant role. NSSI was also used to regulate positive emotions. The results also showed a sequence of emotions among the participants, going from feeling overwhelmed to feeling relatively calm but guilty. Conclusion: NSSI has several functions for the same individual. Thus, it would be interesting to provide integrative therapy, such as emotion-focused therapy, which focus on improving intrapersonal and interpersonal emotion regulation skills and strategies.

A hybrid approach to predict the bearing capacity of a square footing on a sand layer overlying clay

  • Erdal Uncuoglu;Levent Latifoglu;Zulkuf Kaya
    • Geomechanics and Engineering
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    • 제34권5호
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    • pp.561-575
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    • 2023
  • This study investigates to provide a fast solution to the problem of bearing capacity in layered soils with easily obtainable parameters that does not require the use of any charts or calculations of different parameters. Therefore, a hybrid approach including both the finite element (FE) method and machine learning technique have been applied. Firstly, a FE model has been generated which is validated by the results of in-situ loading tests. Then, a total of 192 three-dimensional FE analyses have been performed. A data set has been created utilizing the soil properties, footing sizes, layered conditions used in the FE analyses and the ultimate bearing capacity values obtained from the FE analyses to be used in multigene genetic programming (MGGP). Problem has been modeled with five input and one output parameter to propose a bearing capacity formula. Ultimate bearing capacity values estimated from the proposed formula using data set consisting of 20 data independent of total data set used in MGGP modelling have been compared to the bearing capacities calculated with semi-empirical methods. It was observed that the MGGP method yielded successful results for the problem considered. The proposed formula provides reasonable predictions and efficient enough to be used in practice.