• Bulletin of the Korean Chemical Society
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• 제21권5호
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• pp.465-470
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• 2000

The conformations and energies of p-tert-butylcalix[4] crown-6-ether (1) and its alkyl ammonium complexes have been simulated by AM1 semi-empirical quantum mechanics and molecular mechanics calculations using a variety of forcefields (MM2, MM+, CVFF). We performed molecular dynamics calculations to simulate the behavior of these coplexes primartily focusing on the three representative conformations (cone, partial cone, 1,3-alternate) of host molecule 1. When we performed AM1 semi-empirical and molecular mechanics calculations, the one conformation was generally found to be most stable for all the employed calculation methods. The primary binding site of host 1 for the recognition of alkyl ammonium guests was confirmed to be the central part of the crown moiety. The complexation enthalpy calculations revealed that the alkyl amonium cations having smaller and linear alkyl group showed the better complexation efficiencies when combined with p-tert-butylcalix[4]crown-6-ether, that is in satisfactory agreement with the experimental results.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 1998년도 춘계학술대회논문집
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• pp.179-184
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• 1998

Semi-solid forging can be applied in industry only with enough knowledge of the effects of the forming parameters related with the process and their exact control which can be obtained by empirical or numerical methods. In the current study, the effects of process variables on semi-solid forging are discussed based on mainly numerical results. Die preheating temperature, initial solid fraction of the workpiece, and die velocity were selected as process variables, and numerical analyses using a rigid-thermoviscoplastic finite element approach that considered the release of latent heat due to phase change were carried out. In the analyses, a proposed flow stress material characterization and a solid fraction updating algorithm were employed. The obtained results from numerical analysis are discussed and are compared with some experimental observations.

• Wind and Structures
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• 제22권4호
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• pp.503-524
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• 2016

The suitability of Computational Fluid Dynamics (CFD) simulations on the built environment for the purpose of estimating average roughness characteristics and for studying wind flow patterns within the environment is assessed. Urban models of various levels of complexity are considered including an empty domain, array of obstacles arranged in regular and staggered manners, in-homogeneous roughness with multiple patches, a semi-idealized built environment, and finally a real built environment. For each of the test cases, we conducted CFD simulations using RANS turbulence closure and validated the results against appropriate methods: existing empirical formulas for the homogeneous roughness case, empirical wind speed models for the in-homogeneous roughness case, and wind tunnel tests for the semi-idealized built environment case. In general, results obtained from the CFD simulations show good agreement with the corresponding validation methods, thereby, giving further evidence to the suitability of CFD simulations for built environment studies consisting of wide-ranging roughness. This work also provides a comprehensive overview of roughness modeling in CFD-from the simplest approach of modeling roughness implicitly through wall functions to the most elaborate approach of modeling roughness explicitly for the sake of accurate wind flow simulations within the built environment.

• Steel and Composite Structures
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• 제45권1호
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• pp.1-21
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• 2022

In the structural analysis of steel frames, joints are generally considered as rigid or hinged considering their moment transfer ability. However, the first studies conducted with the beginning of the 20th century showed that the joints do not actually fit these two definitions. In reality, a joint behaves between these two extreme points and is called semi-rigid. Including the actual state of the joint in the structural analysis provides significant economic advantages, so the subject is an intense field of study today. However, it does not find enough application area in practice. For this reason, a large-scale literature published from the first studies on the subject to the present has been examined within the scope of the study. Three important points have been identified in order to examine a joint realistically; modelling the load-displacement relationship, performing the structural analysis and how to design. Joint modelling methods were grouped under 7 main headings as analytical, empirical, mechanical, numerical, informational, hybrid and experimental. In addition to the moment-rotation, other important external load effects like axial force, shear and torsion were considered. Various evaluations were made to expand the practical application area of semi-rigid connections by examining analysis methods and design approaches. Dynamic behaviour was also included in the study, and besides column-beam connections, other important connection types such as beam-beam, column-beam-cross, base connection were also examined in this paper.

• Communications for Statistical Applications and Methods
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• 제30권4호
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• pp.355-368
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• 2023

This article introduces the R package ELCIC (https://cran.r-project.org/web/packages/ELCIC/index.html), which provides an empirical likelihood-based information criterion (ELCIC) for model selection that includes, but is not limited to, variable selection. The empirical likelihood is a semi-parametric approach to draw statistical inference that does not require distribution assumptions for data generation. Therefore, ELCIC is more robust and versatile in the context of model selection compared to the currently existing information criteria. This paper illustrates several applications of ELCIC, including its use in generalized linear models, generalized estimating equations (GEE) for longitudinal data, and weighted GEE (WGEE) for missing longitudinal data under the mechanisms of missing at random and dropout.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2003년도 봄 학술발표회 논문집
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• pp.365-368
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• 2003

Despite of the simple equipment and operation, DMT has been widely used to obtain various soil parameters and those parameters have been successfully applied to geotechnical design practice. Among them, the estimation of horizontal coefficient of consolidation is so useful that many researchs recently have been carried out. However, simulation of the penetration of the DMT blade is complex due to the inherent difficulty on analyzing a plane strain deformation of the soil around blade. Therefore, empirical and semi-empirical methods that use the theoretical solution developed fur piezocone with some assumptions have been used to estimate the coefficient of consolidation from Dilatometer dissipation test. In this paper, coefficients of consolidation c$\_$h/ which were obtained using equivalent radius that is same area with the DMT blade and optimization technique are compared with those obtained from Oedometer test and other interpretation methods. It was found that a new method used in this study can give more precise horizontal coefficient of consolidation than other methods do.

• International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
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• 제4권1호
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• pp.38-43
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• 2001

This paper provides review of research results undertaken on reinforced concrete wall panels in one way and two way. The review also highlights two well accepted code design methods from the American (ACI) and Australia Concrete structures standards. The emphasis is on walls under axial compression only with changes in various parameters. These include the variation of panel dimensions panels (ie. Slenderness, thinness and aspect ratios), steel reinforcement, eccentricities, concrete strength and support conditions. The main purpose of this review is to compile research previous by undertaken to highlight the inadequate in certain research literature. It is envisage that this review will expose areas in wall research required so that inadequate in current methods can be rectified.

• Nuclear Engineering and Technology
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• 제47권7호
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• pp.939-944
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• 2015

The calibration methods of neutron-measuring devices such as the neutron survey meter have advantages and disadvantages. To compare the calibration factors obtained by the shadow cone method and semi-empirical method, 10 neutron survey meters of five different types were used in this study. This experiment was performed at the Korea Atomic Energy Research Institute (KAERI; Daejeon, South Korea), and the calibration neutron fields were constructed using a $^{252}Californium$ ($^{252}Cf$) neutron source, which was positioned in the center of the neutron irradiation room. The neutron spectra of the calibration neutron fields were measured by a europium-activated lithium iodide scintillator in combination with KAERI's Bonner sphere system. When the shadow cone method was used, 10 single moderator-based survey meters exhibited a smaller calibration factor by as much as 3.1-9.3% than that of the semi-empirical method. This finding indicates that neutron survey meters underestimated the scattered neutrons and attenuated neutrons (i.e., the total scatter corrections). This underestimation of the calibration factor was attributed to the fact that single moderator-based survey meters have an under-ambient dose equivalent response in the thermal or thermal-dominant neutron field. As a result, when the shadow cone method is used for a single moderator-based survey meter, an additional correction and the International Organization for Standardization standard 8529-2 for room-scattered neutrons should be considered.

• 천문학회보
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• 제39권1호
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• pp.33.2-33.2
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• 2014

Halo merger trees are essential backbones of semi-analytic models for galaxy formation and evolution. Recent studies have pointed out that extracting merger trees from numerical simulations of structure formation is non-trivial; different algorithm can give differing merger histories. Thus they should be carefully understood before being used as input for models of galaxy formation. As one of the projects proposed in the SUSSING MERGER TREES Workshop, we investigate the impact of different halo merger trees on a semi-analytic model. We find that the z = 0 global galaxy properties in our model show differences between trees when using a common parameter set, but that these differences are not very significant. However, the star formation history of the Universe and the properties of satellite galaxies can show marked differences between trees with different methods for constructing a tree. Calibrating the SAM for each tree individually to the empirical data can reduce the discrepancies between the z = 0 global galaxy properties, however this is at cost of increasing the differences in evolutionary histories of galaxies. Furthermore, the underlying physics implied can vary, resulting in key quantities such as the supernova feedback efficiency differing by factors of 2. Such a change alters the regimes where star formation is primarily suppressed by supernovae. Therefore, halo merger trees extracted from a common halo catalogue using different, but reliable, algorithms can result in a difference in the semi-analytic model, however, given the enormous uncertainties in galaxy formation physics, these are not necessarily significant.

• 터널과지하공간
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• 제13권4호
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• pp.245-259
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• 2003

Refering to the articles "Squeezing rocks in tunnels(Barla, 1995)" and "Tunnelling under squeezing rock conditions(Barla 2002)" this article deals with technologies for design, stability analysis and construction of the tunnel being driven in the squeezing rock mass. The definition of this type of behavior was proposed by ISRM(1994). The identification and quantification of squeezing is given according to both the empirical and semi-empirical methods available to anticipate the potential of squeezing problems in tunnelling. Based on the experiences and lessons learned in recent years, the state of the art in modem construction methods was reported, when dealing with squeezing rock masses by either conventional or mechanical excavation methods. The closed-form solutions available for the analysis of the rock mass response during tunnel excavation are described in terms of the ground characteristic line and with reference to some elasto-plastic models for the given rock mass. Finally numerical methods were used for the simulation of different models and for design analysis of complex excavation and support systems, including three-dimensional conditions in order to quantify the influence of the advancing tunnel face to the deformation behavior of the tunnel.