• 한국세라믹학회지
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• 제32권8호
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• pp.931-937
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• 1995

AlN powder and whiskers were synthesized by direct nitridation of aluminum powder in pure nitrogen atmosphere. The nitridation reaction of aluminum powder was initiated by heating the sample to the ignition temperature and the reaction was finished in less than 3 minutes. AlN whisker-shaped morphology was observed predominantly when the sample was heated above 90$0^{\circ}C$.

• 한국산업융합학회 논문집
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• 제26권5호
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• pp.757-763
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• 2023

Major industrial accidents in which workers die due to fires or explosions while working at chemical substance handling workplaces continue to occur. Among the major industrial accidents that occurred between 2005 and 2021, the accident status by work situation and equipment was analyzed. Through analysis, it was confirmed that storage, reaction, and piping facilities were the main causes of the accident, and a self-checklist for each facility was developed. Verification was conducted through the supply and use groups to evaluate the suitability of the use, duties, and items of the self-checklist. The user group showed higher satisfaction than the supplier group for all three suitability of use, job, and item. In particular, since the inspection items of the self-checklist were organized around the cause of the accident derived through the analysis of actual accident cases, the satisfaction level was high in all groups. It is expected that the self-checklist developed through this study will be useful not only for large companies but also for small and medium-sized chemical industries that lack professional manpower.

• 한국세라믹학회지
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• 제36권2호
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• pp.203-209
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• 1999

Si 기판위에 Ba2YCu3O7-$\delta$ 고온초전도체를 응용하기 위해 요구되는 buffer층으로 유망한 재료인 LaAlO3 단일상 분말을 고상반응법과 자발착한 연소반응법으로 제조하였다. 제조된 LaAlO3 분말의 입자형태와 결정상태는 scanning electron microscope (SEM)과 X-ray diffractometer (XRD)를 이용하여 분석하였다. 분말의 비표면적과 소결특성은 각각 Brunauer-Emmett-Teller(BET) 방법과 dilatometer를 측정하였다. 고상반응법으로 LaAlO3 분말을 제조할 때에는 하소온도를 150$0^{\circ}C$까지 높게 하여도 단일상을 얻는 것이 어려웠으나 자발착한 연소반응법에 의한 분말제조는 $650^{\circ}C$의 저온에서 하소하여도 쉽게 얻을 수 있었다. Dilatometer 측정을 통하여 분석해 보면, 고상반응법에 의한 분말보다 자발착한 연소반응법에 의한 분말로 제조된 소결체가 고상반응법에 의한 소결체에 비해 1.4배나 큰 소멸밀도(98.87%)를 가졌다. 이렇게 소결밀도에서 큰 차이가 나는 것은 자발착한 연소방법에 의한 분말의 평균 입자크기가 nano crystal size이고 비표면적 값(56.54 $m^2$/g)이 매우 크기 때문이다. 두가지 방법으로 제조된 분말을 이용, LaAlO3 layer를 스크린 프린팅과 소결법으로 Si 기판상에 제조하였으며 자발착한 연소합성법으로 제조된 분말은 110$0^{\circ}C$에서 우수한 소결특성을 나타내었다.

• 한국결정성장학회지
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• 제8권4호
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• pp.573-580
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• 1998

MgO와 Al 분말을 자전고온연소합성법으로 $MgAl_2O_4$ 스피넬 상을 합성하였다. MgO 와 Al을 테르밋 반응으로 생성하였으며, 가열반응생성으로 $800^{\circ}C$ 예열온도에서 반응시켰다. DTA/TG, 합성생성물, 최고온도 공정조건에 대해 연구하였고, MgO와 Al은 MgO+2Al+ 3/$2O_3$ $\rightarrow$ $MgAl_2O_4$ 로 합성되었다. 미반응된 재료로부터 MgAl2O4 스피넬의 활성화 에너지는 -264.8kcal/mol의 발생열량과 5634K의 최고 반응온도로 계산되었다. 테르밋 반응후의 시험편의 체적느 6% 증가하였다.

• 한국운동역학회지
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• 제16권4호
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• pp.83-94
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• 2006

The purpose of this study is to elucidate how walking speed influences on change of angles of lower extremity and ground reaction force in normal and obese people. One group with normal body weight who were experimented at a standard speed of 1.5m/s and the other obese group were experimented at two different walking speeds (standard speed of 1.5m/s and self-selected speed of 1.3m/s). We calculated angles of lower extremity and ground reaction force during stance phase through video recording and platform force measuring. When the obese group walked at the standard speed, dorsi-flexion angle of ankle got bigger and plantar-flexion angle of ankle got smaller, which were not statistically significant. There was no significant difference of knee joint angles between normal and obese group at the same speed walking but significant post hoc only for the first flexion of knee joint in obese group. $F_z1$ was bigger than $F_z3$ in vertical axis for ground reaction force in both groups at the standard speed walking and the same force value at self-selected speed in obese group. $F_y3$ was always bigger than $F_y1$ in anterior-posterior axis in both groups.

• 한국구조물진단유지관리공학회 논문집
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• 제24권1호
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• pp.67-73
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• 2020

본 연구에서는 실험을 통하여 자기치유 재료 혼입 모르타르 보의 자기치유 성능을 평가하였다. 실험에는 일반 모르타르 보 실험체와 자기치유 모르타르 보 실험체가 사용되었으며, 모르타르의 압축강도, 내력 및 균열의 자기치유 효과를 비교하여 자기치유 성능을 평가하였다. 실험결과 자기치유 재료를 혼입한 모르타르의 압축강도가 일반 모르타르의 압축강도보다 작았지만 28일 압축강도에 대한 118일 압축강도 비율은 동일하게 나타났다. 실험체의 내력은 재령일이 길어질수록 증가하는 경향을 나타냈다. 일반 모르타르 실험체는 균열이 발생할 경우 재령일이 증가하여도 하중은 회복되지 않았으나 자기치유 모르타르 실험체의 경우 반응 생성물의 영향으로 내력이 다소 회복되는 경향을 나타냈다. 균열폭은 두 종류의 실험체 모두 치유기간이 지난 후 감소하는 경향을 보였으나 자기치유 모르타르 실험체에서만 반응생성물이 관찰되었다.

• 한국재료학회지
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• 제18권3호
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• pp.153-158
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• 2008

Fe-aluminides have the potential to replace many types of stainless steels that are currently used in structural applications. Once commercialized, it is expected that they will be twice as strong as stainless steels with higher corrosion resistance at high temperatures, while their average production cost will be approximately 10% of that of stainless steels. Self-propagating, high-temperature Synthesis (SHS) has been used to produce intermetallic and ceramic compounds from reactions between elemental constituents. The driving force for the SHS is the high thermodynamic stability during the formation of the intermetallic compound. Therefore, the advantages of the SHS method include a higher purity of the products, low energy requirements and the relative simplicity of the process. In this work, a Fe-aluminide intermetallic compound was formed from high-purity elemental Fe and Al foils via a SHS reaction in a hot press. The formation of iron aluminides at the interface between the Fe and Al foil was observed to be controlled by the temperature, pressure and heating rate. Particularly, the heating rate plays the most important role in the formation of the intermetallic compound during the SHS reaction. According to a DSC analysis, a SHS reaction appeared at two different temperatures below and above the metaling point of Al. It was also observed that the SHS reaction temperatures increased as the heating rate increased. A fully dense, well-bonded intermetallic composite sheet with a thickness of $700\;{\mu}m$ was formed by a heat treatment at $665^{\circ}C$ for 15 hours after a SHS reaction of alternatively layered 10 Fe and 9 Al foils. The phases and microstructures of the intermetallic composite sheets were confirmed by EPMA and XRD analyses.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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• pp.155-158
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• 2002

Fabrication process of metal/intermetallic laminated composites by using self-propagating high temperature synthesis(SHS) reactions between Ni and Al elemental metal foils have been investigated. Al foils were sandwiched between Ni foils and heated in a vacuum hot press to the melting point of aluminium. SHS reaction kinetics was thermodynamically analyzed through the final volume fraction of the unreacted Al related with the initial thickness ratio of Ni:Al and diffusion bonding stage before SHS reaction. Thermal aging of laminated composites resulted in the formation of functionally gradient series of intermetallic phases. Microstructure showed that the main phases of intermetallics were NiAl and $Ni_3Al$ having higher strength at room and high temperatures. The volume fractions of intermetallic phases were measured as 82.4, 58.6, 38.4% in 1:1, 2:1, 4:1 initial thickness ratio of Ni:Al.

• 한국세라믹학회지
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• 제37권4호
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• pp.332-337
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• 2000

Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

• 한국염색가공학회지
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• 제19권5호
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• pp.37-40
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• 2007

The electrostatic layer-by-layer technique provides a convenient way to control the construction of ultrathin films at nano-scale ranges and can be easily obtained. It can be also applicable to fiber substrate with dye compounds. We have fabricated multilayer dye films using diazonium resin and three couplers, which are prepared by self-assembly approach. This method is based on layer-by-layer deposition using electrostatic attraction between oppositely charged ions. Beside, the diazo coupling reaction proceeded to form azo dye layer on the PET fibers the same time. The corresponding results of the multilayer films have been discussed on the level of color strength (K/S).