• Title/Summary/Keyword: Self-healing technology

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Anti-Corrosion Characteristics of Steel Structures with Polyaniline Anti-Corrosive Coatings (강 구조물에 대한 폴리아닐린 함유도료의 방청특성)

  • Song, Min-Kyung;Kong, Seung-Dae;Oh, Eun-Ha;Yoon, Hun-Cheol;Kim, Yoon-Shin;Im, Ho-Sub
    • Journal of Environmental Health Sciences
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    • v.36 no.3
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    • pp.236-246
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    • 2010
  • In preparative anti-corrosive coating experiments, polyaniline was obtained by reacting an oxidizing agent with the monomer aniline. Further, the primer coating was prepared using a variety of widely-used materials such as urethane resin. For the top coating, epoxy resin and acrylic urethane resin were used. Characteristics of the coatings were assessed according to KS and ASTM specifications, and the structure of the polyaniline was characterized using FT-IR and TGA. For analysis of anti-corrosive properties in salt-spray experiments, measurements of the oxidation state of iron and surface atomic analysis were conducted using XPS and SEM-EDX. Unlike general anti-corrosive coatings which exhibit anti-corrosive effects only as a primer coating, the anti-corrosive coatings using polyaniline as the anti-corrosive pigment showed a marked synergistic effect with the top coatings. In other words, the top coatings not only produce a fine view effect, but also increase, through interaction with the primer coatings, the resistance to diffusion of corrosive factors from the external environment. It was also found that, unlike the heavy metal oxide-forming layer of the passive barrier alone, the polyaniline anti-corrosive pigment oxidized iron at the interface with the iron substrate to form a passive barrier in the oxidic layer, and itself formed a potential barrier layer with anti-corrosive factors from the external environment. Although the passive layer was damaged, the damaged area did not become completely oxidized iron; on the contrary, it showed a tendency to reduction. This can be interpreted such that a passive layer is formed again on the damaged area, and that at the same time there is a tendency to self-healing.

Bone Formation Effect of the RGD-bioconjugated Mussel Adhesive Proteins Composite Hydroxypropyl Methylcellulose Hydrogel Based Nano Hydroxyapatite and Collagen Membrane in Rabbits

  • Kim, Dong-Myong;Kim, Hyun-Cho;Yeun, Chang-Ho;Lee, Che-Hyun;Lee, Un-Yun;Lim, Hun-Yu;Chang, Young-An;Kim, Young-Dae;Choi, Sung-Ju;Lee, Chong-Suk;Cha, Hyung Joon
    • Journal of Marine Bioscience and Biotechnology
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    • v.7 no.2
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    • pp.58-70
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    • 2015
  • Injectable RGD-bioconjugated Mussel Adhesive Proteins (RGD-MAPs) composite hydroxypropyl methylcellulose (HPMC) hydrogels provide local periodontal tissue for bone filling in periodontal surgery. Previously we developed a novel type of injectable self-supported hydrogel (2 mg/ml of RGD-MAPs/HPMC) based porcine nano hydroxyapatite (MPH) for dental graft, which could good handling property, biodegradation or biocompatibility with the hydrogel disassembly and provided efficient cell adhesion activity and no inflammatory responses. Herein, the aim of this work was to evaluate bone formation following implantation of MPH and collagen membrane in rabbit calvarial defects. Eight male New Zealand rabbits were used and four circular calvarial defects were created on each animal. Defects were filled with different graft materials: 1) collagen membrane, 2) collagen membrane with MPH, 3) collagen membrane with bovine bone hydroxyapatite (BBH), and 4) control. The animals were sacrificed after 2 and 8 weeks of healing periods for histologic analysis. Both sites receiving MPH and BBH showed statistically increased augmented volume and new bone formation (p < 0.05). However, there was no statistical difference in new bone formation between the MPH, BBH and collagen membrane group at all healing periods. Within the limits of this study, collagen membrane with MPH was an effective material for bone formation and space maintaining in rabbit calvarial defects.

The Effects of Human Relationship Class Using Simsang-Poetry Therapy on the Mental Health of Nursing Students (심상 시치료를 활용한 인간관계 수업이 간호대생의 정신건강에 미치는 효과)

  • Jeong Hye Bak;Hyun Mi Jo
    • The Journal of the Convergence on Culture Technology
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    • v.10 no.3
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    • pp.137-144
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    • 2024
  • This study shows the effectiveness of mental health by applying the Light of the Mind program to 45 nursing students who applied for the Human Relations class at JS University and showed 90% attendance once a week for a total of 10 sessions and 60 minutes per session. The 'Light of the Heart' program was carried out in the Simsang-Poetry therapy stage and technique, an integrated art and cultural therapy that recognizes the 'light' representing 'inner positivity'. As a result of phenomenological and qualitative analysis of the participants' descriptions, the categories of source, healing power, positive perception, self-realization, positive emotion, potential, and self-awareness were shown, and there was a statistically significant difference in the experimental group compared to the control group when analyzing before and after the resilience scale. This study is significant in that it improved the mental health of nursing students through human relations classes. It is necessary to develop and carry out various programs for the promotion of human relations and mental health of college students, and it will be helpful to the mental health of modern people by expanding this program to the general public.

Ginsenosides Rk1 and Rg5 inhibit transforming growth factor-β1-induced epithelial-mesenchymal transition and suppress migration, invasion, anoikis resistance, and development of stem-like features in lung cancer

  • Kim, Hyunhee;Choi, Pilju;Kim, Taejung;Kim, Youngseok;Song, Bong Geun;Park, Young-Tae;Choi, Seon-Jun;Yoon, Cheol Hee;Lim, Won-Chul;Ko, Hyeonseok;Ham, Jungyeob
    • Journal of Ginseng Research
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    • v.45 no.1
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    • pp.134-148
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    • 2021
  • Background: Lung cancer has a high incidence worldwide, and most lung cancer-associated deaths are attributable to cancer metastasis. Although several medicinal properties of Panax ginseng Meyer have been reported, the effect of ginsenosides Rk1 and Rg5 on epithelial-mesenchymal transition (EMT) stimulated by transforming growth factor beta 1 (TGF-β1) and self-renewal in A549 cells is relatively unknown. Methods: We treated TGF-β1 or alternatively Rk1 and Rg5 in A549 cells. We used western blot analysis, real-time polymerase chain reaction (qPCR), wound healing assay, Matrigel invasion assay, and anoikis assays to determine the effect of Rk1 and Rg5 on TGF-mediated EMT in lung cancer cell. In addition, we performed tumorsphere formation assays and real-time PCR to evaluate the stem-like properties. Results: EMT is induced by TGF-β1 in A549 cells causing the development of cancer stem-like features. Expression of E-cadherin, an epithelial marker, decreased and an increase in vimentin expression was noted. Cell mobility, invasiveness, and anoikis resistance were enhanced with TGF-β1 treatment. In addition, the expression of stem cell markers, CD44, and CD133, was also increased. Treatment with Rk1 and Rg5 suppressed EMT by TGF-β1 and the development of stemness in a dose-dependent manner. Additionally, Rk1 and Rg5 markedly suppressed TGF-β1-induced metalloproteinase-2/9 (MMP2/9) activity, and activation of Smad2/3 and nuclear factor kappa B/extra-cellular signal regulated kinases (NF-kB/ERK) pathways in lung cancer cells. Conclusions: Rk1 and Rg5 regulate the EMT inducing TGF-β1 by suppressing the Smad and NF-κB/ERK pathways (non-Smad pathway).

A Study on the Upland Use Plans Using Farm Manager Registration Information and Spatial Data (농업경영체 등록정보와 공간데이터를 활용한 밭 이용 방안 연구: 전라남도 무안군·해남군을 중심으로)

  • Oh, Yun-Gyeong;Yoo, Seung-Hwan;Choi, Soo-Myung;Lee, Jimin
    • Journal of The Korean Society of Agricultural Engineers
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    • v.60 no.4
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    • pp.27-35
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    • 2018
  • Food consumption pattern changes, including a decrease in rice consumption and increasing demand for fresh vegetables, along with declining food self-sufficiency rate, more importance is being placed on agricultural industry within Korea. Taking these changes into consideration, there is an increasing necessity for managing upland fields on agricultural sector to revitalize agricultural land use. Therefore, in this study, upland use type was classified into agricultural economic, environmental conservation, and rural social frames. The purpose of this study was to suggest upland use plan with farm manager registration information and spatial data. As results of this analysis, the mean area of agricultural economic frame in Haenam (16.47 ha) was found to be wider than Muan (3.17 ha), and scale improvement zones (54 zones) were located in only Haenam. In case of environmental conservation frame, there's no zone of scenic agriculture land in both study areas, but landuse transition zones were located in Muan (278 zones) and Haenam (604 zones). Agro-healing zones of rural social frame were 1,018 zones in Muan and 1,588 zones in Haenam and kitchen garden sites were 342 zones in Muan and 370 zones in Haenam. These results could be used when we establish the plan of an agricultural infrastructure project or select places for a collaborative agricultural land use project.

Improved Corrosion and Abrasion Resistance of Organic-Inorganic Composite Coated Electro-galvanized Steels for Digital TV Panels

  • Jo, Du-Hwan;Noh, Sang-Geol;Park, Jong-Tae;Kang, Choon-Ho
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.213-217
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    • 2015
  • Recently, household electronic industries require environmentally-friendly and highly functional steels in order to enhance the quality of human life. Customers especially require both excellent corrosion and abrasion resistant anti-fingerprint steels for digital TV panels. Thus POSCO has developed new functional electro-galvanized steels, which have double coated layers with organic-inorganic composites on the zinc surface of the steel for usage as the bottom chassis panel of TVs. The inorganic solution for the bottom layer consists of inorganic phosphate, magnesium, and zirconium compounds with a small amount of epoxy binder, and affords both improved adhesion properties by chemical conversion reactions and corrosion resistance due to a self-healing effect. The composite solution for the top layer was prepared by fine dispersion of organic-inorganic ingredients that consist of a urethane modified polyacrylate polymer, hardener, silica sol and a titanium complex inhibitor in aqueous media. Both composite solutions were coated on the steel surface by using a roll coater and then cured through an induction furnace in the electro-galvanizing line. New anti-fingerprint steel was evaluated for quality performance through such procedures as the salt spray test for corrosion resistance, tribological test for abrasion resistance, and conductivity test for surface electric conductance regarding to both types of polymer resin and coating weight of composite solution. New composite coated anti-fingerprint steels afford both better corrosion resistance and abrasion properties compared to conventional anti-fingerprint steel that mainly consists of acrylate polymers. Detailed discussions of both composite solutions and experimental results suggest that urethane modifications of acrylate polymers of composite solutions play a key role in enhanced quality performances.

Synthesis of UV Curable Polyurethane Adhesives Based on Various Compositions of Mixed Polyol with Improved Adhesion and Flexural Properties (다양한 조성의 혼용 폴리올에 기초한 접착력 및 굴곡성이 향상된 자외선 경화형 폴리우레탄 접착제의 합성)

  • Won-Young Lee;Soo-Yong Park;Guni Kim;Ildoo Chung
    • Journal of Adhesion and Interface
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    • v.23 no.4
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    • pp.137-143
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    • 2022
  • In this study, the polyurethane acrylates (PUA) resin with good adhesive and flexibility for adhesive for shoes and clothing were synthesized using that poly(tetramethylene adiphate glycol) (PTAd), poly(tetramethylene ether glycol) (PTMG) as polyester polyol and polyether polyol respectively, including 4,4'-methylene diphenyl diisocyanate (MDI), isophorone diisocyanate (IPDI), 1,4-butandiol (1,4-BD), 2-hydroxyethyl methacrylate (2-HEMA) and dibutyl amine (DBA). The effect of polyol blend in the polyurethane acrylate on thermal and mechanical properties, adhesion strength and flexural strength were studied. The glass transition temperature (Tg) of PUA was confirmed in range of -70~-40 ℃. In addition, the glass transition temperature (Tg), decomposition temperature (Td), tensile strength adhesion strength and heat resistance were increased as increasing of PTAd amount while the elongation, water resistance and flexural properties were decreased. The synthesized polyurethane acrylate with 5:5 ratio of PTAd and PTMG indicated the highest adhesion strength and flexural properties.