• Title/Summary/Keyword: Self-discharge

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SiO2/styrene butadiene rubber-coated poly(ethylene terephthalate) nonwoven composite separators for safer lithium-ion batteries

  • Lee, Jung-Ran;Won, Ji-Hye;Lee, Sang-Young
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.51-56
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    • 2011
  • We develop a new nonwoven composite separator for a safer lithium-ion battery, which is based on coating of silica ($SiO_2$) colloidal particles/styrene-butadiene rubber (SBR) binder to a poly(ethylene terephthalate) (PET) nonwoven support. The $SiO_2$ particles are interconnected by the SBR binder and closely packed in the nonwoven composite separator, which thus allows for the development of unusual porous structure, i.e. highly-connected interstitial voids formed between the $SiO_2$ particles. The PET nonwoven serves as a mechanical support that contributes to suppressing thermal shrinkage of the nonwoven composite separator. The $SiO_2$/SBR content in the nonwoven composite separators plays an important role in determining their separator properties. Porous structure, air permeability, and electrolyte wettability of the nonwoven composite separators, in comparison to a commercialized polyethylene (PE) separator, are elucidated as a function of the $SiO_2$/SBR content. Based on this understanding of the nonwoven composite separators, the effect of $SiO_2$/SBR content on the electrochemical performances such as self-discharge, discharge capacity, and discharge C-rate capability of cells assembled with the nonwoven composite separators is investigated.

Reentrainment of Carbon Soot Particles in a Corona Discharge Reactor (코로나 방전 반응기에서 Carbon Soot 입자의 재비산)

  • Lee, Jae-Bok;Hwang, Jung-Ho;Bae, Gwi-Nam
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.7
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    • pp.1002-1009
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    • 2000
  • Among the various types of diesel after-treatment device, the corona discharge reactor may be considered as a powerful process for trapping submicron particles. But after precipitation on the electrodes occurs, the reentrainment of particles is severe and often causes low or negative precipitation efficiency. Experiments were performed to investigate the effect of an applied voltage on the reentrainment of soot particles from the electrodes. A co-annular laminar diffusion flame burner was used as the soot generator. When a highly negative voltage was applied, exfoliation of the deposited soot particles and an increase in concentration of particles smaller than approximately 150 nm were observed. Turbulence induced from the negative tuft corona and sputtering caused particle reentrainment from the corona wire and from plates as well. Under soot laden combustion gas, a streamer corona often occurred in the wire-cylinder reactor. Because of its transient nature, streamer corona violently increased the concentration of reentrained particles and CO gas.

Spent fuel simulation during dry storage via enhancement of FRAPCON-4.0: Comparison between PWR and SMR and discharge burnup effect

  • Dahyeon Woo;Youho Lee
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4499-4513
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    • 2022
  • Spent fuel behavior of dry storage was simulated in a continuous state from steady-state operation by modifying FRAPCON-4.0 to incorporate spent fuel-specific fuel behavior models. Spent fuel behavior of a typical PWR was compared with that of NuScale Power Module (NPMTM). Current PWR discharge burnup (60 MWd/kgU) gives a sufficient margin to the hoop stress limit of 90 MPa. Most hydrogen precipitation occurs in the first 50 years of dry storage, thereby no extra phenomenological safety factor is identified for extended dry storage up to 100 years. Regulation for spent fuel management can be significantly alleviated for LWR-based SMRs. Hydride embrittlement safety criterion is irrelevant to NuScale spent fuels; they have sufficiently lower plenum pressure and hydrogen contents compared to those of PWRs. Cladding creep out during dry storage reduces the subchannel area with burnup. The most deformed cladding outer diameter after 100 years of dry storage is found to be 9.64 mm for discharge burnup of 70 MWd/kgU. It may deteriorate heat transfer of dry storage by increasing flow resistance and decreasing the view factor of radiative heat transfer. Self-regulated by decreasing rod internal pressure with opening gap, cladding creep out closely reaches the saturated point after ~50 years of dry storage.

Determination of electron energy distribution functions in radio-frequency (RF) and microwave discharges (RF/마이크로웨이브 방전에서의 전자에너지 분포함수의 결정)

  • 고욱희;박인호;김남춘
    • Journal of the Korean Vacuum Society
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    • v.10 no.4
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    • pp.424-430
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    • 2001
  • An electron Boltzmann equation is solved numerically to calculate the electron energy distribution functions in plasma discharge which is generated by radio-frequency (RF) and microwave frequency electric field. The maintenance field strengths are determined self-consistently by solving the homogeneous electron Boltzmann equation in the Lorentz approximation expressed by 2nd order differential equation and an additional particle balance equation expressed by integro-differential equation. By using this numerical code, the electron energy distribution functions in argon discharge are calculated in the range from RF to microwave frequency. The influence of frequency of the HF electric field on the electron energy distribution functions and ionization rate are investigated.

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Numerical studied on consequenses of the ion pumping effect in helicon plasmas (헬리콘 플라즈마에서 이온 펌핑 효과의 영향에 대한 수치적 해석 연구)

  • 조수원;박인호;최성을;권명회
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.353-360
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    • 1999
  • The global balance model is applied to investigate the transient behavior of the electron density and temperature in helicon plasmas. The power absorption calculated from the solutions of the Maxwell equations is used in solving the power balance equation. A balance model for the neutral gas is also considered to fins its density self-consistently. It is turned out that the numerical results reasonably explain consequences of the ion pumping effect including the occurrence of two distinct modes of pulsed helicon discharge which have been observed experimentally. The behavior of the discharge parameters are fond to be primarily dependent on the power absorption and the gas flow rate, but the pressure controls the electron density and temperature of the final steady state as well as the transient state even with the same flow rate. Finally, it is shown that the electron density virtually the linear relationship between the density and the magnetic field is retained for a higher pressure when the effect of the ion pumping is negligible.

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Plasma-immersion ion Deposition of Hydrogenated Diamond-like Carbon Films on Dielectric Substrates

  • Kon;Chun, Hui-Gon;Cho, Tong-Yul;Nikolay S. Sochugov;You, Yong-Zoo
    • Journal of Korean Vacuum Science & Technology
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    • v.6 no.4
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    • pp.143-148
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    • 2002
  • Method of plasma-immersion ion deposition of hydrogenated DLC films on relatively thick flat dielectric substrates from plasma of not-self-sustained low-pressure gas arc discharge is suggested. Coating properties have been investigated experimentally, average energy Per a deposited carbon atom depending on discharge current has been calculated. Optimum deposition parameters lot obtaining sufficiently hard and transparent high-adhesive a-C:H films on a 4-mm thick glass substrates have been determined. Possibility to use these coatings for photo-tools protection from abrasion wear at low operating loads is shown in general.

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리튬 2차 전지의 1차원 열적 특성을 고려한 지능형 용량예측

  • Lee, Jeong-Su;Ho, Bin;Kim, Gwang-Seon;Im, Geun-Uk;Jo, Jang-Gun;Jo, Hyeon-Chan
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2007.06a
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    • pp.244-249
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    • 2007
  • In this paper, in order to get the characteristics of the lithium secondary cell, such as cycle life, charge and discharge characteristic, temperature characteristic, self-discharge characteristic and the capacity recovery rate etc, we build a mathematical model of battery. In this one-dimensional model, Seven governing equations are made to solve seven variables $c,\;c_s,\;{\Phi}_1,\;{\Phi}_2,\;i_2,\;j\;and\;T$. The mathematical model parameters used in this model have been adjusted according to the experimental data measured in our lab. The connecting research of this study is to get an accurate estimate of the capacity of battery through comparison of results from simulation and fuzzy logic system. So the result data from this study is reorganized to fit the fuzzy logic algorithm.

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Sustain Discharge Mode Assisted by Various Auxiliary Pulses in AC PDP

  • Cho, Byung-Gwon;Tae, Heung-Sik;Chien, Sung-Ii
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.113-116
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    • 2003
  • The sustain discharge mode using various auxiliary pulses was proposed to improve both the luminance and luminous efficiency of ac-plasma display panel (ac-PDP). It was found that the various auxiliary pulses, which were applied at the rising and falling time of the sustain pulse, played a role in strengthening both the main and self-erasing discharges. As a result, the sustain waveforms with auxiliary pulse improved both the luminance of 23 % and the luminous efficiency of 36 %, when compared with the conventional sustain waveform without auxiliary pulse.

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TWO-WAY F냐 simulation OF THE DIAPHRAGM COMPRESSOR AND NON-RETURN CHECK VALVE (고압용 다이아프램 압축기 및 체크 밸브의 2-way FSI 수치해석)

  • Choi, B.S.;Yoon, H.G.;Yoo, I.S.;Park, M.R.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.86-92
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    • 2010
  • A metal diaphragm compressor has been widely used for supplying a high pressures gas. This compressor mainly consists of gas oil space and metal diaphragm. Gas sucked in the gas space is compressed by an oscillating metal diaphragm existed between the gas and oil space. A non-return discharge and suction check-valve are components of the compressor that draw off the compressed oil and gas. Those components are self-actuated by differential pressures. Therefore, the rapid response and stable operating conditions are required. In the present study, to find out the dynamic behavior of the suction, discharge valve and diaphragm compressor, the unsteady flow field has been investigated numerically by using the unsteady two-way FSI (Fluid Structure Interaction) simulation method, $k-{\omega}$ turbulent model and mesh deformation.

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A Study for the Fault Location of Insulation Defects considering Waveguide Characteristics in GIS (GIS의 도파관 특성을 고려한 절연결함 위치판정에 관한 연구)

  • Lee, Seung-Chul;Jung, Seung-Yong;Lee, Jae-Ho;Koo, Ja-Yoon
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.2
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    • pp.252-255
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    • 2008
  • A study for discharge pattern analysis partial and fault location by use of UHF sensors in GIS. However, in the latter case, the results considered the velocity of EM waves modified by the waveguide characteristics of GIS bus bar were not reported yet. In this paper, UHF wide band sensor to detect partial discharge signals have been designed and manufactured to get the widest band characteristic by an application of Fat-Dipole UHF antenna and the result that the transmission velocity of EM waves is 2/3 of the light have been got through the consideration of waveguide characteristics. Also, to verify applicability on site of the developed method, self-designed external type UHF sensor have been installed on operating GIS in Korea Midland Power co. and detected location of the fault. Through the fault have been found at the location, the reliability of the developed method have been proved.