• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2359-2362
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• 2007

MALDI-TOF-MS technique was applied to obtain structural and compositional information of synthetic polyamides, Nylon6 and Nylon66. Mass spectra of both the original and the hydrolyzed polyamide samples were analyzed using the self calibration method as well as the internal calibration method with the standard materials of known masses. The MALDI-TOF mass spectra of Nylon6 samples showed the presence of protonated, sodiated, and potassiated ions that were assigned to cyclic and NH2/COOH terminated linear oligomers. From the MALDI-TOF mass spectra of Nylon66 samples, the potassiated linear oligomers with three different end groups are identified as well as the cyclic oligomers, i.e., NH2/COOH terminated oligomers, NH2/NH2 terminated oligomers, and COOH/COOH terminated oligomers. Full characterization of the molecular species and end groups present in the polyamide samples has been achieved, and also the changes in mass spectral patterns after the hydrolysis of the samples are presented.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.477-482
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• 2011

The structural analysis of polytrimethylene terephthalate (PTT) and characterization of the hydrolytic degradation products after acid hydrolysis were performed using MALDI-TOF mass spectrometry. Mass spectra of the PTT samples were analyzed using a self-calibration method as well as an internal calibration method with standard materials of known masses. PTT structures constituting the samples were determined from the analyses of the spectra, and their relative compositions were estimated. The MALDI-TOF mass spectra of the acid-hydrolyzed PTT sample showed three main series of oligomer products with different end groups in accordance with the hydrolysis schemes. From the spectra of both $Na^+$ and $K^+$ adducts, it was concluded that the PTT samples have higher affinity for $Na^+$ compared with $K^+$ and therefore show higher ionization efficiency with sodium ions when dithranol is used as a matrix. Two different wavelength laser beams ($\lambda$ = 337 nm and 355 nm) were tested and it was observed that the 355 nm beam was more efficient in obtaining the MALDI spectra of PTT using dithranol as a matrix under our experimental conditions.

• Journal of the Korean Data and Information Science Society
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• v.21 no.3
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• pp.407-417
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• 2010

In Basel II compliance, internal rating systems are allowed for banks to enhance the self control and the validation of the system are getting more important. The validation methods are composed of qualitative test and quantitative test, three basic standards of which are discriminatory power, stability and calibration. The aim of this article is to review the quantitative tests for calibration and find a new method for it. These methods for discrimination between forecasted PD and observed PD include binomial test, chi square test, Brier score, traffic lights approach, normal test and extended traffic lights approach. We introduce a modified extended traffic lights approach considering asset correlations.

• Nuclear Engineering and Technology
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• v.51 no.2
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• pp.526-532
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• 2019

In this study, an in-house $^{152}Eu$ calibration source was produced from a custom epoxy matrix with a density of ${\rho}=1.14g\;cm^{-3}$, which is chemically stable and durable form after its solidification. The homogeneity of $^{152}Eu$ in matrix was obtained better than 98%. For a Marinelli beaker geometry, an efficiency calibration procedure was applied to a n-type, coaxial, 78.5% relative efficient HPGe detector in the energy range of 121.7-1408.0 keV by using in-house $^{152}Eu$ calibration source. Then the measured efficiencies for Marinelli geometry were compared with the results calculated by MEFFTRAN and ANGLE softwares for the validation. Although MEFFTRAN and ANGLE have two different efficiency transfer algorithms to calculate the efficiencies, they usually need to use a reliable and accurate reference efficiency values as input data. Hence, reference efficiency values were obtained experimentally from a multinuclide standard source for the same detector-Marinelli geometry. In the present source characterization, the corrections required for self-absorption and true coincidence summing effects for $^{152}Eu$ gamma-rays were also obtained for a such close counting geometry condition. The experimental results confirmed the validity of efficiency calculations obtained by MEFFTRAN and ANGLE softwares that are calculation tools.

• Structural Engineering and Mechanics
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• v.42 no.1
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• pp.1-12
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• 2012

In this study, Pasternak foundation model, which is a two parameter foundation model, is used to analyze the behavior of laterally loaded beams embedded in semi-infinite media. Total potential energy variation of the system is written to formulate the problem that yielded the required field equations and the boundary conditions. Shear force discontinuities are exposed within the boundary conditions by variational method and are validated by photo elastic experiments. Exact solution of the deflection of the beam is obtained. Both foundation parameters are obtained by self calibration for this particular problem and loading type in this study. It is shown that, like the first parameter k, the second foundation parameter G also depends not only on the material type but also on the geometry and the loading type of the system. On the other hand, surface deflection of the semi infinite media under singular loading is obtained and another method is proposed to determine the foundation parameters using the solution of this problem.

• Journal of the Korean Institute of Intelligent Systems
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• v.21 no.4
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• pp.442-448
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• 2011

There are many research results about a self-localization technique of mobile robot. In this paper we present a self-localization technique based on the features of ceiling vision using a fisheye lens. The features obtained by SIFT(Scale Invariant Feature Transform) can be used to be matched between the previous image and the current image and then its optimal function is derived. The fisheye lens causes some distortion on its images naturally. So it must be calibrated by some algorithm. We here propose some methods for calibration of distorted images and design of a geometric fitness model. The proposed method is applied to laboratory and aile environment. We show its feasibility at some indoor environment.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• v.9 no.1
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• pp.1141-1144
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• 2005

In this paper, we propose an automatic displacement system for testing stability of structure. Photogrammetry is a method which can measure accurate 3D data from 2D images taken from different locations and which is suitable for analyzing and measuring the displacement of structure. This paper consists of camera calibration, feature extraction using coded target & retro-reflective circle, 3D reconstruction and analyzing accuracy. Multi-view camera which is used for measuring displacement of structure is placed with different location respectively. Camera calibration calculates trifocal tensor from corresponding points in images, from which Euclidean camera is calculated. Especially, in a step of feature extraction, we utilize sub-pixel method and pattern recognition in order to measure the accurate 3D locations. Scale bar is used as reference to measure. the accurate value of world coordinate..

• Advances in robotics research
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• v.2 no.1
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• pp.45-57
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• 2018

Even though the popularity of projection mapping continues to increase and it is being implemented in more and more settings, most current projection mapping systems are limited to special purposes, such as outdoor events, live theater and musical performances. This lack of versatility arises from the large number of projectors needed and their proper calibration. Furthermore, we cannot change the positions and poses of projectors, or their projection targets, after the projectors have been calibrated. To overcome these problems, we propose a projection mapping method using a projector robot that can perform projection mapping in more general or ubiquitous situations, such as shopping malls. We can estimate a projector's position and pose with the robot's self-localization sensors, but the accuracy of this approach remains inadequate for projection mapping. Consequently, the proposed method solves this problem by combining self-localization by robot sensors with position and pose estimation of projection targets based on a 3D model. We first obtain the projection target's 3D model and then use it to accurately estimate the target's position and pose and thus achieve accurate projection mapping with a projector robot. In addition, our proposed method performs accurate projection mapping even after a projection target has been moved, which often occur in shopping malls. In this paper, we employ Ubiquitous Display (UD), which we are researching as a projector robot, to experimentally evaluate the effectiveness of the proposed method.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.9
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• pp.893-897
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• 2008

To achieve the challenges of low-cost MEMS gyros for the precise self-localization of mobile robots, this paper examines an effective method of minimizing the drift on the heading angle that relies solely on integration of rate signals from a gyro. The main idea of the proposed approach is to use wavelet de-noising filter in order to reduce random noise which affects short-term performances. The proposed method was applied to Epson XV3500 gyro and the performances are verified by the comparisons with an existing commercial gyro module of vacuum cleaning robots.

• Korean Journal of Remote Sensing
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• v.19 no.6
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• pp.431-445
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• 2003

In this paper, we experimentally investigated the precision of 3D positioning using 4S-Van images in photograrmmetric perspective. The 3D calibration target was built over building facade outside and was captured separately by two CCD cameras installed in 4S-Van. After then, we determined the interior orientation parameter for each CCD camera through self-calibration technique. With the interior orientation parameter computed, the bundle adjustment was performed to obtain the exterior orientation parameters simultaneously for two CCD cameras using calibration target image and object coordinates. The reverse lens distortion coefficients were computed and acquired by least squares method so as to introduce lens distortion into epipolar line. It was shown that the reverse lens distortion coefficients could transform image coordinates into lens distorted image coordinates within about 0.5 pixel. The proposed semi-automatic matching scheme incorporated with lens distorted epipolar line was implemented with scene images captured by 4S-Van in moving. The experimental results showed that the precision of 3D positioning from 4S-Van images in photograrmmetric perspective is within 2cm in the range of 20m from the camera.