• Title/Summary/Keyword: Self-assembled Monolayer

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Surface modification for block copolymer nanolithographyon gold surface

  • Hwang, In-Chan;Bang, Seong-Hwan;Lee, Byeong-Ju;LeeHan, Bo-Ram;Kim, Hyeong-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.33.2-33.2
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    • 2009

  • Block copolymer lithography has attracted great attention for emerging nanolithography since nanoscaleperiodic patterns can be easily obtained through self-assembly process without conventional top-down patterning process. Since the morphologies of self-assembled block copolymer patterns are strongly dependent on surface energy of a substrate, suitable surface modification is required. Until now, the surface modification has been studied by using random copolymer or self-assembled mono layers (SAMs). However, the research on surface modifications has been limited within several substrates such as Si-based materials. In present study, we investigated the formation of block copolymer on Au substrate by $O_2$ plasma treatment with the SAM of 3-(p-methoxy-phenyl)propyltrichloro-silane [MPTS, $CH_3OPh(CH_2)_3SiCl_3$]. After $O_2$ plasma treatment, the chemical bonding states of the surface were analyzed by X-ray photoelectron spectroscopy (XPS). The static contact angle measurement was performed to study the effects of $O_2$ plasma treatment on the formation of MPTS monolayer. The block copolymer nanotemplates formed on Au surface were analyzed by scanning electron microscopy. The results showed that the ordering of self-assembled block copolymer pattern and the formation of cylindrical nano hole arrays were enhanced dramatically by oxygen plasma treatment. Thus, the oxidation of gold surface by $O_2$ plasma treatment enables the MPTS to form the monolayer assembly leading to surface neutralization of gold substrates.

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Nano-scale Probe Fabrication Using Self-assembly Technique and Application to Detection of Escherichia coli O157:H7

  • Oh, Byung-Keun;Lee, Woochang;Lee, Won-Hong;Park, Jeong-Woo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.4
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    • pp.227-232
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    • 2003

  • A self-assembled monolayer of protein G was fabricated to develop an immunosensor based on surface plasmon resonance (SPR), thereby improving the performance of the antibodybased biosensor through immobilizing the antibody molecules (lgG). As such, 11-mercaptoundecanoic acid (11-MUA) was adsorbed on a gold (Au) support, while the non-reactive hydrophilic surface was changed through substituting the carboxylic acid group (-COOH) in the 11-MUA molecule using 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrocholide (EDAC). The formation of the self-assembled protein G layer on the Au substrate and binding of the antibody and antigen were investigated using SPR spectroscopy, while the surface topographies of the fabricated thin films were analyzed using atomic force microscopy (AFM). A fabricated monoclonal antibody (Mab) layer was applied for detecting E. coli O157:H7. As a result, a linear relationship was achieved between the pathogen concentration and the SPR angle shift, plus the detection limit was enhanced up to 10$^2$ CFU/mL.

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Electrochemical Properties of Self-Assembled Viologen Monolayers Using Quartz Crystal Analyzer (QCA를 이용한 자기조립된 Viologen 단분자막의 전기화학적 특성)

  • Lee, Dong-Yun;Park, Sang-Hyun;Shin, Hoon-Kyu;Park, Jae-Chul;Chang, Jeong-Soo;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.141-144
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    • 2004

  • Molecular self-assembled of surfactant viologens are recently interesting because they can be from functional electrodes as well as micelle assemblies which can be profitably utilized for display devices, electrochemical studies and electrocatalysis as electron acceptor or electron mediator. The electrochemical behavior of self-assembled viologen monolayer on Au electrode surface has been investigated with QCM which has been known as nano-gram order mass detector. A monolayer of viologen is immobilized on the gold electrode surface and the normal potentials corresponding to the to the successive one-electron transfer processes of the viologen actives are two peaks in 0.1mol/l phosphate buffer solution respectively. These result suggest that the viologen SAMs are stable and well-behaved monolayers.

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