• 한국건설순환자원학회논문집
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• 제7권3호
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• pp.235-242
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• 2019

이 연구의 목적은 단면확대 보강을 위해 개발된 폴리머와 초속경 시멘트를 혼입한 콘크리트의 자기 충전성 확보를 위한 배합상세 수정이다. 보강용 콘크리트의 자기충전성은 일본토목학회(JSCE 1999)와 유럽통합기준(EFNARC 2002)에서 제시된 자기충전 콘크리트의 굳기 전 물성시험 및 성능기준을 통해 평가하였다. 실험결과, 동일한 물-결합재 비에서 단위 결합재양을 증가(페이스트 부피비 증가)시키면, 점성이 증가 하지만, 단위수량도 증가하여 점성에 의한 유동성 저하는 없었다. 단면확대 보강용 콘크리트를 위해 개발된 결합재를 이용한 일반강도 콘크리트 배합 시 자기다짐 성능을 확보하기 위한 배합조건은 물-결합재비 38%에서 단위결합재양은 $430kg/m^3{\sim}470kg/m^3$, 잔골재율은 40%~46% 수준이 추천될 수 있었다.

• 콘크리트학회논문집
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• 제19권3호
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• pp.377-383
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• 2007

최근 콘크리트의 품질과 구조물의 신뢰성을 향상시키기 위해서 고성능콘크리트의 현장 적용이 늘고 있다. 이러한 고성능콘크리트의 배합 설계 방법으로는 모르타르-굵은골재 2상계 배합 이론과 페이스트-골재 2상계 배합 이론이 있다. 이 중 모르타르-굵은골재 2상계 배합이론은 모르타르의 레올로지 특성을 부여함에 있어 반복적인 실험을 통해서 그 값을 결정해야 하는 문제점을 가지고 있다. 페이스트-골재 2상계 배합 이론은 최적 잔골재율과 단위결합재량과의 관계 및 콘크리트의 충전성을 확보할 수 있는 한계 골재 용적비 등이 고려되어 있지 않아 고성능콘크리트에의 적용 예가 없는 실정이다. 또한 이들 고성능콘크리트의 배합 설계 이론은 일반콘크리트와는 달리 유동성 및 충전성에 중점을 두고 있어 배합 설계에서 강도 특성을 고려하지 않고 있으며, 사용 재료의 단위량은 일반콘크리트와 같이 시행착오법으로 결정하고 있다. 이에 본 연구에서는 고성능콘크리트의 배합 설계에 최대 밀도 이론을 도입하여 사용 골재의 공극이 최소가 되는 최적 잔골재율 산정으로 배합 설계 시 시행착오를 줄이고, 강도를 고려한 최소 단위 결합재량의 결정으로 강도와 유동성을 동시에 만족할 수 있는 합리적이며 간편한 고성능콘크리트의 배합 설계법을 제안하고자 하였다. 연구 결과 본 연구에서 제안된 배합 설계법은 최소 공극을 갖는 최적 잔골재율 사용과 최소 단위 결합재량 이상의 결합재를 사용함으로써 시행착오를 줄일 수 있어 자기충전성을 갖는 고성능콘크리트를 간편하게 제조할 수 있다.

• Advances in materials Research
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• 제11권2호
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• pp.147-164
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• 2022

This study aims to investigate the influence of scoria aggregate (SA) and silica fume (SF) as a replacement of conventional aggregate and ordinary Portland cement (OPC), respectively. Three types of concrete were prepared namely normal weight concrete (NWC) using limestone aggregate (LSA) and OPC (control specimen), lightweight concrete (LWC) using SA and OPC, and LWC using SA and partial SF (SLWC). The representative workability and compressive strength properties of the developed concrete were evaluated, and the results were correlated with non-destructive ultrasonic pulse velocity and Schmidt hammer tests. The LWC and SLWC yielded compressive strength of around 30 MPa and 33 MPa (i.e., 78-86% of control specimens), respectively. The findings indicate that scoria can be beneficially utilized in the development of structural lightweight concrete. Present renewable sources of aggregate will preserve the natural resources for next generation. The newly produced eco-friendly construction material is intended to break price barriers in all markets and draw attraction of incorporating scoria based light weight construction in Saudi Arabia and GCC countries. Findings of the SWOT analysis indicate that high logistics costs for distributing the aggregates across different regions in Saudi Arabia and clients' resistant to change are among the major obstacles to the commercialized production and utilization of lightweight concrete as green construction material. The findings further revealed that huge scoria deposits in Saudi Arabia, and the potential decrease in density self-weight of structural elements are the major drivers and enablers for promoting the adoption of lightweight concrete as alternative green construction material in the construction sector.

• 콘크리트학회논문집
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• 제12권2호
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• pp.99-107
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• 2000

This research investigates experimentally an effect on the properties of the high flowing concrete to be poured in the under-ground slurry wall of Inchon LNG receiving terminal(#213,214-TK) according to variations of concrete materials. Variables for sensitivity test were selected items as followings. 1) Concrete temperature (3cases), 2) Unit water (5cases), 3) Fineness modulus of fine aggregate (5cases), 4) Particle size of lime stone powder (3cases), 5) Replacement ratio of blast-furnace slag (4cases) and 6) Addition ratio of high range water reducing agent (5cases). And fresh conditions of the super flowing concrete should be satisfied with required range including slump flow(65$\pm$5cm), 50cm reaching time of flow(4~10sec), V-lot flowing time(10~ 20sec), U-box height(min. 300mm) and air content(4$\pm$1%). As results for sensitivity test, considered flow-ability, self-compaction and segregation resistance of the high flowing concrete, material variations and conditions of fresh concrete should be satisfied with the range as follwings. 1) Concrete temperature are 10~2$0^{\circ}C$(below 3$0^{\circ}C$), 2) Surface moisture of fine aggregate is within $\pm$ 0.6%, 3) Fineness modulus of fine aggregate is 2.6$\pm$0.2, 4)Replacement ratio of blast-furnace slag is 45~50% and 5) Addition ratio of high range water reducing agent is within 1%. Based on the specification for quality control, we successfully finished concrete pouring on the under-ground slurry wall having 75,000㎥(#213,214-TK) and accumulated real date in site.

• BMB Reports
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• 제42권1호
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• pp.53-58
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• 2009

The methyl-directed mismatch repair (MMR) mechanism has been extensively studied in vitro and in vivo, but one of the difficulties in determining the biological relationships between the MMR-related proteins is the tendency of MutL to self-aggregate. The properties of a stable MutL homologue were investigated using a thermostable MutL (TmL) from Thermotoga maritima MSB8 and whose size exclusion chromatographic and crosslinking analyses were compatible with a dimeric form of TmL. TmL underwent conformational changes in the presence of nucleotides and single-stranded DNA (ssDNA) with ATP binding not requiring ssDNA binding activity of TmL, while ADPnP-stimulated TmL showed a high ssDNA binding affinity. Finally, TmL interacted with the T. maritima MutS (TmS), increasing the affinity of TmS to mismatched DNA base pairs and suggesting that the role of TmL in the formation of a mismatched DNA-TmS complex may be a pivotal observation for the study of the initial MMR system.

• 한국환경과학회지
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• 제29권2호
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• pp.201-207
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• 2020

A new chemosensor based on a self-assembled system has been devised to detect Hg²⁺ions efficiently. We demonstrated that the amphiphilic building blocks consisting of pyrene and boronic acid (1) aggregate in aqueous solutions and provide an outstanding sensing platform for sensitive detection. The self-assembled 1 exhibited high selectivity and sensitivity for Hg²⁺ion detection via fluorescence quenching, where the Hg²⁺ion detection ensued from a fast transmetallation of 1. The Stern-Volmer (SV) quenching constant for its fluorescence quenching by Hg²⁺ions was approximately 1.58 × 10⁸ M^-1. In addition, self-assembled 1 exhibited excellent sensing abilities at nano-molar concentration levels when tap water and freshwater samples were contaminated with of Hg²⁺ ions.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.77-80
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• 2005

Lightweight concrete is known for its advantage of reducing the self-weight of the structures, reducing the areas of sectional members as well as making the construction convenient. Thus the construction cost can be saved when applied to structures such as long-span bridge and high rise buildings. However, the lightweight concrete requires specific mix design method that is quite different from the typical concrete, since using the typical mix method would give rise the material segregation as well as lower the strength by the reduced weight of the aggregate. In order to avoid such problems, it is recommended to apply the mix design method of self-compacting concrete for the lightweight concrete. Experimental tests were performed as such compressive strength, dry shrinkage and carbonation of high strength lightweight self-compacting concrete.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.585-588
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• 2006

The environment-friendly building material, photocatalyst/scoria/loess concrete, was prepared using scoria and loess (which have merits as building materials) and photocatalyst (which has the functions to compose the environmental contaminants and of self cleaning). In order to apply this material as a building material, the compressive and flexible strengths, and water absorptivity (which have been set by Korea Industrial Standard) were measured. The optimum mixing ratio of photocatalyst/scoria/loess concrete was obtained at the condition of $393kg/m^3$ of coarse aggregate, $802kg/m^3$ of fine aggregate in case of scoria, $80kg/m^3$ of loess, $12kg/m^3$ of photocatalyst, $400kg/m^3$ of cement, and $2kg/m^3$ of AE water reducing agent. The photocatalyst/scoria/loess concrete prepared by above mixing ratio of raw materials showed 25 MPa of compressive strength, $3.8{\sim}4.6$ MPa of flexible strength and $11.4{\sim}12.0%$ of water absorptivity, indicating that the quality of this material was suitable for Korea Industrial Standard (more than 21 MPa for compressive strength, more than 2.0 MPa for flexible strength in case of lightweight aggregate, and less than 15 % for water absorptivity in case of clay brick) for using as a building material.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.549-554
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• 2002

In Powder System, SCC demands high dosage of superplasticizer and a lage amout of powder for suitable fluidity and viscosity. Okamura's method of most representative mixing design method in SCC of Powder-System is unfavorable economically because of using a large amount of powder. In addition, many ready-mixed concrete plants do not use his mix design method and procedure due to complexity for practical application. Therefore, Nan Su proposed more simple mix design method than Okamura's. It had an advantage in simplicity in practical application and required a smaller amount of powders compared with Okamura's method. This paper proposed an optimal mixture proportion of SCC with consideration of Nan Su's method. The new and modified mix design method required a smaller amount of powder than that of Nan Su's. To check the properties of SCC, considered with the requirements specified by the Japanese Society of Civil Engineering.(JSCE)

• Bulletin of the Korean Chemical Society
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• 제35권6호
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• pp.1590-1600
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• 2014

Cinchona-based bifunctional catalysts have been extensively employed in the field of organocatalysis due to the incorporation of both hydrogen-bonding acceptors (quinuclidine) and hydrogen-bonding donors (e.g., alcohol, amide, (thio)urea and squaramide) in the molecule, which can simultaneously activate nucleophiles and electrophiles, respectively. Among them, cinchona-derived (thio)urea and squaramide catalysts have shown remarkable application potential by using their bifurcated hydrogen bonding donors in activating electrophilic carbonyls and imines. However, due to their bifunctional nature, they tend to aggregate via inter- and intramolecular acid-base interactions under certain conditions, which can lead to a decrease in the enantioselectivity of the reaction. To overcome this self-aggregation problem of bifunctional organocatalysts, we have successfully developed a series of sulfonamide-based organocatalysts, which do not aggregate under conventional reaction conditions. Herein, we summarize the recent applications of our cinchona-derived sulfonamide organocatalysts in highly enantioselective methanolytic desymmetrization and decarboxylative aldol reactions. Immobilization of sulfonamide-based catalysts onto solid supports allowed for unprecedented practical applications in the synthesis of valuable bioactive synthons with excellent enantioselectivities.