• 제목/요약/키워드: Self diffusion

검색결과 386건 처리시간 0.031초

고출력용 산업안전 보조전원의 Supercapacitor (Supercapacitor of Auxiliary Electric Power Source in Industrial Safety for High Output)

  • 허진우;강안수
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2003년도 추계학술대회
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    • pp.335-343
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    • 2003
  • In the electrode fabrication of unit cell, it was ascertained that electrochemical characteristics were greatly increased with 90 wt.% of BP-20, 5 wt.% of Super P and 5 wt.% of mixed binder [P(VdF-co-HFP) : PVP =7 : 3] The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. The electrochemical characteristics of 2.3 V/3,000 F grade EDLC were as follows: 0.35 m of DC-ESR (100 A discharge), 0.14 mof AC-ESR (AC amplitude 100 mV), 2.80 Wh/kg (3.73 Wh/L) of energy density and 4.64 kW /kg (6.19 kW/L) of power density. Power output was compatible with electric vehicle applications, uninterrupted power supply and engine starter, in due consideration of Ragone relations.

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Sulphamethomidine의 젖소에 있어서의 유선과 신장을 통한 배출 (Mammary and renal excretion of sulphamethomidine in cows)

  • 이장낙
    • 대한수의학회지
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    • 제7권2호
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    • pp.51-55
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    • 1967
  • The mammary excretion of suphamethomidine after intravenous and/or oral administration was investigated in cow. The results show that sulphamethomidine is bound to plasma proteins to a great extent (80~90%). Ay a dosage of 60 mg./kg. maximal concenration in plasma of this sulphonamide was reached 7-10 hours after oral dosing. The sulphonamide concentration in plasma slowly declined after both oral and intravenous administration (fig. 1, 2, and 3) The concentration of sulphonamide in milk was very low and the excretion was completed in 7 days after a single oral dose and 5 days after intravenous injection while in the case of blood plasma it was 11 and 7 days, respectively. In addition, the renal excretion of sulphamethomidine was investigated while under continuous intravenous intravenous infusion. The excretion ratios varies according to self depression (table. 1). Blockade of the tubular secretion with diodone lowered the excretion of sulphamethomidine. It is concluded that the renal excretion of sulphamethomidine in cows occurs by filtration by slight tubular secretion and also by a high rate of back diffusion.

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AISI D2 Steel의 이온질화시 Multilayer의 생성에 의한 표면강화

  • 조균택;손석원;이영국;이원범
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.302-302
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    • 2013
  • 본 연구는 이온질화시 self-sputtering에 의한 AISI D2 소재의 표면경화에 대한 연구를 진행하였다. 이를 위해 이온질화시 질소가스와 아르곤 가스를 이용해 이온질화를 수행하였다. 이에 대한 결과는 optical micrograph (OM), scanning electron microscopy (SEM), X-ray diffraction(XRD), transmission electron microscopy (TEM)를 이용해 분석하였다. 실험결과, 소재의 경도는 570 HV에서 약 1470 HV까지 상승하였다. 극표면에 CrN-enriched layer의 형성 및 극표면 아래층에서 질소의 과포된 화합물층을 관찰할 수 있었다. 표면경화는, 극표면에 CrN-enriched layer의 형성과, 아래 N의 과포화에 의한 ${\gamma}$?autenite) phase, 그리고 diffusion layer의 형성에 의한 multi-layer의 형성으로 표면에 강화에 기여한것으로 사료된다.

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[ $Ni_3Al-Fe-Cr$ ] Alloy Processed by Combined Mechanical Alloying - Reactive Synthesis

  • Orban, Radu L.;Lucaci, Mariana
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1316-1317
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    • 2006
  • The paper investigates the possibility to avoid extrinsic embrittlement of $Ni_3Al$, also increasing the high temperature strength, by alloying with both Fe - of a high strengthening effect and Cr - able to remove a part of diffused oxygen along the grain boundaries. As Cr homogenization in $Ni_3Al$ is difficult because of its low diffusion coefficient, for its improving a mechanical alloying (MA) step before the compound synthesis by Self-propagating High-temperature Synthesis (SHS) was adopted. The obtained better homogenization resulted in higher mechanical resistance and deformability than of the unalloyed $Ni_3A/Ni_3Al$ alloys of the same composition obtained without MA step.

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Influence of High-energy Milling and Sintering Cycle on Obtaining of TiAl from Elemental Ti and Al Powders

  • Esteban, P.G.;Gordo, E.;Ruiz-Navas, E.M.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.727-728
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    • 2006
  • The present work studies the influence of high-energy milling (HEM) and sintering cycle of Ti and Al powders on the obtainment of TiAl. This study shows that HEM modifies the diffusion processes during the sintering stage. The samples were obtained by cold uniaxial and isostatic pressing, pre-sintered at different temperatures, and heated up to the sintering temperature. This study also shows the effect of powder additions processed by HEM on the sintering behavior of elemental Ti and Al powders.

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자체건조를 고려한 초기재령 콘크리트의 부등건조수축 (Differential Drying Shrinkage of concrete an Early Ages Considering Self-desiccation)

  • 김진근;이칠성
    • 콘크리트학회지
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    • 제10권5호
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    • pp.197-204
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    • 1998
  • 초기재령에서 외기에 노출된 콘크리트는 수분확산으로 인하여 부등건조수축이 발생하고, 또한 자체건조로 인하여 자기수축도 발생한다. 따라서 콘크리트 재부의 수축변형도는 이러한 자기수축을 포함하고 있으므로 이를 고려해야 한다. 본 연구에서는 초기재령에서 콘크리트 강도에 따라 자기수축의 영향을 고려하여 부둥건조수축에 대한 실험과 해석을 수행하였다. 또한 콘크리트 내부의 부등수분분포로 인한 수축변형도에 대하여 실험결과와 해석결과를 비교하여, 해석방법의 타당성을 검증하였다. 실험 및 분석결과에 의하면 저강도콘크리트는 수분확산으로 인하여 주로 수축현상이 일어나고 자기수축의 영향은 거의없었다. 그렇지만 고강도 콘크리트는 자기수축에 의해서도 영향을 받았다. 그리고 콘크리트의 부등건조수축은 강도에 따라 큰 차이를 나타냈다. 또한 제시한 해석방법에 의한 해석결과는 실험결과를 잘 예측하였다.

제주 스코리아로부터 합성된 제올라이트에 의한 납이온 흡착 (Adsorption of Lead Ion by Zeolites Synthesized from Jeju Scoria)

  • 감상규;현성수;이민규
    • 한국환경과학회지
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    • 제20권11호
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    • pp.1437-1445
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    • 2011
  • The adsorption performance of lead ion was studied using five zeolites (Na-P1, sodalite (SOD), analcime (ANA), nepheline hydrate (JBW), cancrinite (CAN)) synthesized from Jeju scoria. The adsorption performances of lead ion decreased in the order of Na-P1 > SOD > ANA > JBW > CAN. These results showed that the synthetic zeolite with a higher cationic exchange capacity showed a higher adsorption performance. The uptake of lead ion by synthetic zeolites were described by Freundlich model better than Langmuir model. The adsorption kinetics of lead ion by synthetic zeolites fitted the pseudo 2nd order kinetics better than pseudo 1st order kinetics. The effective diffusion coefficients of lead ion by synthetic zeolites were ten times higher than the zeolite A synthesized from coal fly ash.

혁신관리에 있어서 장애와 저항의 극복방안 (A Study on Conquest Plans of the Barrier and Resistance in Innovation Management)

  • 이승희;노규성
    • 디지털융복합연구
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    • 제3권1호
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    • pp.9-25
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    • 2005
  • The purpose of this study is to explore conquest plans of the barrier and resistance in innovation management. In addition, this study is to describe the model of innovation resistance that reflects adoption process stages and identify the factors that drive the resistance of consumers and the barriers. Whenever organizations try to plan and implement some kind of innovation in organizations, they confront the resistance and barriers in many ways. By understanding innovation resistance and barrier, organizations can not only design better innovations but can develop strategies to reduce resistance and conquer the barriers. Thus they accelerate innovation. Also, these results indicate that people resist innovation strongly when it betrays their value, needs and beliefs or when they felt the pressure on self-conviction and mental risk, loss, and lack of knowledge. Understanding the factors that drive the innovation resistance and barrier has important implications for both theoretical development and managerial action.

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Navier-Stokes 방정식을 사용한 수평원관상의 $LiBr-H_{2}O$ 흡수특성에 대한 연구 (Parametric Study on the $LiBr-H_{2}O$ Absorption Process on Horizontal Tubes Using Wavier-Stokes Equations)

  • 민준기;최도형
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 1999년도 춘계 학술대회논문집
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    • pp.213-218
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    • 1999
  • The $LiBr-H_{2}O$ absorption process on a horizontal tube has been analyzed using the numerical method which incorporates the fully elliptic Navier-Stokes equations for the momentum equations, the energy and mass-diffusion equations. On a staggered grid, the SIMPLER algorithm with the QUICK scheme is used to solve these equations along with the MAC method for the free surface tracking. With the assumption that the absorbent is linear, calculations have been made for various inlet temperature and flow-rate conditions. The detailed results of the parametric study, such as the temperature, concentration, absorption mass flux and wall heat flux distributions are presented. The self-sustained feature of the absorption process is clearly elaborated. The analyses have also been carried out for multiple tube arrangement and the results show that the absorption rate converges after a few tube rows.

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AA 2014 알루미늄 합금의 고상율에 따른 미세조직 및 반응고 변형 거동 (Microstructures and Deformation Behavior of AA 2014 Aluminum Alloys in the Semi-Solid State)

  • 한도석
    • 한국주조공학회지
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    • 제37권5호
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    • pp.157-163
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    • 2017
  • In the present study, the microstructural evolution and deformation behavior of AA 2014 aluminum alloys with different microstructures in a semi-solid state were investigated. For a given alloy, applied load and deformation time, the measured strain was higher at a higher temperature, indicative of a lower solid fraction. When a large proportion of the liquid was present as intragranular droplets, the alloy would not as easily deform because the effective liquid fraction between the solid grains had decreased. Greater deformation was achieved with higher grain boundary misorientations due to the enhanced wetting of the grain boundaries with liquid. A semi-empirical constitutive model is proposed for semi-solid deformation under the conditions in the present study. The mechanism of semi-solid deformation incorporates the initial flow of the liquid in the early stages of deformation, followed by a more gradual increase in the strain due to deformation by grain sliding accompanied by self-diffusion in the solid grains.