• Title/Summary/Keyword: Self corrosion

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A study on the activation characteristics of multi-phase Zr-based hydrogen storage alloy for Ni-MH rechargeable battery (Ni-MH 2차전지용 다상의 Zr계 수소저장합금 전극의 활성화 특성에 관한 연구)

  • Lee, Ho;Jang, Kuk-Jin;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.4
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    • pp.161-171
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    • 1997
  • $AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

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A study on the residual stresses in circumferential welds of the pipes (파이프 원주방향 용접부의 잔류응력 연구)

  • 남궁재관;홍재학
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.2
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    • pp.693-702
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    • 1991
  • The existence of residual stress in the circumferential butt welded pipes is one of the most important problems concerning stress corrosion cracking in service. In this paper, the residual stress distributions in three kinds of circumferential butt welded pipes were measured by the hole drilling strain gage method and calculation using finite element method is performed and its results are compared with the experiments. At the inner surface of the pipe region near the center line of welding is under high tensile residual stress. However, as the distance from the center line of welding increases, the tensile component decreases and finally becomes compressive residual stress at region far away from the center line of welding. The longitudinal residual stress at the outer surface is compressive regardless of the diameter of pipe and the circumferential stress is changed rom compressive to tensile as pipe diameter increases. The results also demonstrate that the residual stress is mainly caused by self restraint bending force in the pipe welding.

The assessment of self cleaning velocity and optimal flushing velocity in water distribution system (상수관망의 자가세척 유속과 적정 플러싱 유속 평가)

  • Bae, Cheol-Ho;Choi, Doo Yong;Kim, Ju-Hwan;Kim, Do-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.4
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    • pp.441-451
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    • 2014
  • The flushing is important to maintain good water quality in water main. It is a technique of using water velocity to remove sediments in water distribution system. The variety of water quality problems can occur in a distribution system, so too can a variety of benefits be gained by system flushing. In order to effectively perform the flushing, the contaminants to be removed to set up and it can be solved, it is necessary to ensure the proper flow rate. In this study, the removal of contaminants present in the inner water pipe attached loose deposits such as fine particles of granular activated carbon, sand and iron corrosion product sought to derive flow rates. Thus, the constant observation of using pilot plant scale water distribution plant for the movement of floating characteristics of particles were assessed.

A Study on the Behavior Characteristics of a New-Type FRP-Concrete Composite Deck (신개념 FRP-콘크리트 합성 바닥판의 거동 특성 고찰)

  • Cho Keunhee;Chin Won Jong;Kim Sung Tae;Cho Jeong-Rae;Kim Byung-Suk
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.746-749
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    • 2004
  • A new-type of FRP-concrete composite bridge deck system is proposed and its behaviors are experimentally studied. The new-typedeck consists of FRP as a permanent form and main tension resisting member and concrete as a compression resisting member. A suitable bonding method such as silica coating is applied to the interface between FRP and concrete to ensure composite behavior. The proposed deck system uses the box-shape FRP member, while a typical FRP-concrete composite deck uses the I-shape FRP member. Theproposed deck system has inherent advantages of a FRP-concrete composite deck like corrosion free and easy construction. The new-type deck shows the equal performances compared to a previous one, and has the advantage of reducing self-weight. In this study, the static tests on 3-span FRP-concrete decks in full scale are carried out, so that load-displacement relation, stress distribution, failure mode and design criteria are analyzed. The test results show that the deflection design criterion (L/800, L: span length) is satisfied at the service load state. No concrete tensile crack occurs in the negative moment region above the main girder, regardless of no tensile reinforcement at upper concrete portion.

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Experimental study on durability of strengthened corroded RC columns with FRP sheets in tidal zone of marine environment

  • Kashi, Amin;Ramezanianpour, Ali Akbar;Moodi, Faramarz
    • Computers and Concrete
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    • v.19 no.4
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    • pp.339-346
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    • 2017
  • The main objective of this paper was to illuminate the effect of marine environmental condition on durability of reinforced concrete (RC)-corroded columns strengthened with carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) layers. Small-scale columns were prepared and corroded by an accelerated corrosion process. After strengthening, compressive strength tests were carried out on control and weathered specimens. In this research, a marine simulator was designed and constructed similar to the tidal zone of marine environment in south of Iran which was selected as a case study in this research. Mechanical properties of wrapped specimens were studied after placing them inside the simulator for 3000 hours. Marine environment decreased ultimate strength by 4.5% and 26.3% in CFRP and GFRP-wrapped columns, respectively. In some corroded-columns, strengthening was carried out after replacing damaged cover by self-compacted mortar. In this method, by confining with one layer of CFRP and GFRP, 4.2% and 22.4% reduction in ultimate strength was observed, respectively, after exposure. Furthermore, the elastic-brittle behavior has been verified in this retrofit method. Also results of tension tests revealed, the ultimate tensile strength was degraded by 2% and 28.8% in CFRP and GFRP sheets, respectively, after applying marine exposure.

Early-Age and Restrained Shrinkage of Very-Early Strength Latex Modified Concrete (초속경 라텍스개질 콘크리트의 초기수축 및 구속건조수축)

  • Choi, Pan-Gil;Kim, Young-Gon;Sim, Do-Sic;Lee, Bong-Hak
    • Journal of Industrial Technology
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    • v.25 no.A
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    • pp.49-56
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    • 2005
  • Recently, very-early strength latex-modified concrete(below ; VES-LMC) has been developed for repairing and overlaying the old concrete bridge deck. VES-LMC provides the advantage of very-early-strength, as well as high flexural strength, bond strength, durability, resistance to corrosion, reduced water permeability and resistance to damage from freeze-thaw cycles. The compressive and flexural strength of VES-LMC are 21 MPa and 4.5 MPa at 3 hours after concrete placing, respectively. However, VES-LMC would have a relatively large shrinkage at early-age because of reduced water-cement ratio, big water self-dissipation, and rapid hydration reaction. Therefore, the purpose of this study was to evaluate the early-age and restrained shrinkage of VES-LMC, having an experimental variables such as latex contents and cement types. The latex contents included 0%, 5%, 10%, 15% and 20%, and the cement types included ordinary portland cement and very-early strength cement.

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Determination of electrical and geometric properties of brown eggs

  • Sung Yong Joe;Jun Hwi So;Seon Ho Hwang;Soon Jung Hong;Seung Hyun Lee
    • Korean Journal of Agricultural Science
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    • v.49 no.4
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    • pp.857-869
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    • 2022
  • Eggs are considered an excellent complete food because they contain many major energy sources, including protein. Eggs are one of the most widely consumed foods worldwide, and egg consumption is steadily increasing. Eggs are generally classified according to their quality and weight. Various characteristics of eggs must be considered for the design and effective utilization of equipment used for the transport, processing, packaging, and storage of eggs. In this study, egg surface area, volume, density, etc. were measured according to the grade of the egg. The values of several geometrical properties that were measured tended to increase with increasing egg grade. The smallest grade eggs had the lowest shell thickness and density. The electrical conductivity of the eggshell and its contents was measured with a self-made electrode and equipment. The egg shell showed properties similar to insulators, and as the thickness increased, the electrical conductivity tended to increase. The electrical conductivity of the egg yolk showed almost constant values under all conditions. The electrical conductivity of the egg white and mixture was particularly low at 0.1 kHz. Fouling and electrode corrosion occurred in a low frequency region due to the egg white. In this study, various geometric and electrical characteristics of eggs were measured, and based on this, factors that could serve as new indicators for egg processed production were analyzed and investigated.

The structure Optimization Research of the Automation Welding Equipment of the Large L-type Using the Response Surface Method (반응표면법을 이용한 대형 L-type 자동화용접장치의 구조최적화 연구)

  • Jang, Junho;Jung, Wonjee;Lee, Dongsun;Jung, Jangsik;Jung, Sung Ho
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.1
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    • pp.138-144
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    • 2013
  • The automation technology for overlay welding is needed due to the occurrence of severe corrosion and abrasion on the surface of internal contact in different shape of fittings. In Korea, different shapes of fittings have been manufactured by using the imported equipment of overlay welding automation at some companies. Thus the research on the development of overlay welding automation system (in short, OWAS) for a large L-type tube is urgently needed. In this paper, the investigation is focused on the optimal design of a supporting base for the (currently developing) OWAS of large L-type tube. Specifically we assume that the base which supports the equipment during the process of overlay welding is loaded as self-weight in the direction of gravity through static analysis especially when it is rotated 180 degree on the OWAS. For optimal design of a supporting base for OWAS of large L-type tube, Solidworks(R) (for 3-dimensional modelling) and ANASYS Workbench(R) (for structural analysis) are incorporated so as to proceed an optimization routines based on Response Surface Method (RSM) and Design of Experiment (DOE). In more specific, DOE finds out major factors (or dimensions) of the supporting base by using MINITAB(R). Then the regression equations between design variables (the major factors of supporting base) and response variables (deformation, stress and safety factor for the supporting base), which will be resulted in by RSM, verify the major factors of DOE. In the next step, Central Composite Design (CCD) plans 20 simulations of ANASYS Workbench(R) and then figures out the optimal values of design variables which will be reflected on the manufacturing of supporting base. Finally welding experiment is conducted to figure out the influence of overlay welding quality in applying the optimized design values of supporting base to the actual OWAS.

Heat Pump System Using Heated Effluent of Thermal Power Generation Plant as a Heat Source (해수를 이용한 화력발전소 폐열회수 히트펌프 시스템)

  • Ryou, Y.S.;Kang, Y.K.;Kim, Y.H.;Jang, J.K.;Kim, J.G.;Lee, H.M.;Kang, G.C.;Nah, K.D.;Huh, T.H.
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.190-190
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    • 2011
  • In South Korea the gross generation and heated effluent of power generation plant was 259 TWh and 4.73 billion tons in 2008. And then the waste heat from power generation was 388 TWh. It shows that the efficiency of thermal power generation plant is about 40%. Therefore to reduce $CO_2$ emission from thermal power generation plant, the energy of this heated effluent must be reused to heat buildings or farm facilities. In South Korea horticultural facilities of about 25% are heated in winter season. Total area of greenhouses which are heated is about 13,000 ha. Total heat amount needed to warm greenhouse of 13,000 ha in winter season is only 3.4% of total waste heat from power generation plant. In this study a heat pump system was designed to reuse the waste heat from power generation. Especially new heat exchanger was developed to recover the thermal energy from waste water and this model considered anti-corrosion against sea water and low cost for economic feasibility. This heat recovery system was installed in mango growing greenhouse around thermal power generation plant in Seogwipo-city, Jeju Special Self-Governing Province. The result of preliminary test shows that the heating cost of about 90% is saved as compared to boiler using tax free light oil as a fuel.

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A wireless impedance analyzer for automated tomographic mapping of a nanoengineered sensing skin

  • Pyo, Sukhoon;Loh, Kenneth J.;Hou, Tsung-Chin;Jarva, Erik;Lynch, Jerome P.
    • Smart Structures and Systems
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    • v.8 no.1
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    • pp.139-155
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    • 2011
  • Polymeric thin-film assemblies whose bulk electrical conductivity and mechanical performance have been enhanced by single-walled carbon nanotubes are proposed for measuring strain and corrosion activity in metallic structural systems. Similar to the dermatological system found in animals, the proposed self-sensing thin-film assembly supports spatial strain and pH sensing via localized changes in electrical conductivity. Specifically, electrical impedance tomography (EIT) is used to create detailed mappings of film conductivity over its complete surface area using electrical measurements taken at the film boundary. While EIT is a powerful means of mapping the sensing skin's spatial response, it requires a data acquisition system capable of taking electrical impedance measurements on a large number of electrodes. A low-cost wireless impedance analyzer is proposed to fully automate EIT data acquisition. The key attribute of the device is a flexible sinusoidal waveform generator capable of generating regulated current signals with frequencies from near-DC to 20 MHz. Furthermore, a multiplexed sensing interface offers 32 addressable channels from which voltage measurements can be made. A wireless interface is included to eliminate the cumbersome wiring often required for data acquisition in a structure. The functionality of the wireless impedance analyzer is illustrated on an experimental setup with the system used for automated acquisition of electrical impedance measurements taken on the boundary of a bio-inspired sensing skin recently proposed for structural health monitoring.