• Title/Summary/Keyword: Selective catalytic reduction on diesel particulate filter

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Overview of the Effect of Catalyst Formulation and Exhaust Gas Compositions on Soot Oxidation In DPF

  • Choi Byung Chul;FOSTER D.E.
    • Journal of Mechanical Science and Technology
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    • v.20 no.1
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    • pp.1-12
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    • 2006
  • This work reviews the effects of catalyst formulation and exhaust gas composition on soot oxidation in CDPF (Catalytic Diesel Particulate Filter). DOC's (Diesel Oxidation Catalysts) have been loaded with Pt catalyst (Pt/$Al_{2}O_3$) for reduction of HC and CO. Recent CDPF's are coated with the Pt catalyst as well as additives like Mo, V, Ce, Co, Fe, La, Au, or Zr for the promotion of soot oxidation. Alkali (K, Na, Cs, Li) doping of metal catalyst tends to increase the activity of the catalysts in soot combustion. Effects of coexistence components are very important in the catalytic reaction of the soot. The soot oxidation rate of a few catalysts are improved by water vapor and NOx in the ambient. There are only a few reports available on the mechanism of the PM (particulate matter) oxidation on the catalysts. The mechanism of PM oxidation in the catalytic systems that meet new emission regulations of diesel engines has yet to be investigated. Future research will focus on catalysts that can not only oxidize PM at low temperature, but also reduce NOx, continuously self-cleaning diesel particulate filters, and selective catalysts for NOx reduction.

A Study on Selective Catalytic Reduction on Diesel Particulate Filter Catalyst and Coating Technology the Removal of Particulate Matters and NOx for Old Special Cargo Vehicles (노후 특수·화물 차량 PM/NOx 저감을 위한 SDPF 촉매 및 코팅 기술 연구)

  • Jeong, Kwanhyoung;Seo, Philwon;Oh, Hungsuk;Kim, Jongkook;Kang, Soyeon;Kang, Jeongho;Kim, Hyunjun;Shin, Byeongseon
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.695-699
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    • 2021
  • In this study, Selective Catalytic Reduction on Diesel Particulate Filter (SDPF) after-treatment system was introduced to simultaneously remove NOx and Particulate Matters (PM) emitted from trucks and special cargo vehicles using old engine. First, in order to select an Selective Catalytic Reduction (SCR) catalyst for SDPF, the de-NOx performance of V/TiO2 and Cu-Zeolite catalysts were compared, and the SCR catalyst characteristics were analyzed through Brunauer Emmett Teller (BET), X-ray Diffraction (XRD) and NH3-TPD (Temperature Programmed Desorption). From the activity test results, the Cu-zeolite catalyst showed the best thermal stability. For optimal coating of SDPF, slurry was prepared according to the target particle size. From the coating stability and back pressure test results of SDPF according to the amount of SCR coating, As a result of comparing coating stability, back pressure, and de-NOx performance by producing A, B, and C samples for each loading amount of the SDPF catalyst, the best results were found in the B sample. The engine dynamometer test was conducted for the optimal SDPF after-treatment system, and the test results satisfied Eu-5 regulations.

The Application of Dump Combustor for Evaluation of After-Treatment System (후처리장치 성능 평가를 위한 Dump Combustor의 활용)

  • Nam, Youn-Woo;Lee, Won-Nam;Oh, Kwang-Chul;Lee, Chun-Beom
    • Journal of the Korean Society of Combustion
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    • v.12 no.3
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    • pp.16-23
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    • 2007
  • Employing an after-treatment system has almost become a mandatory requirement for Diesel vehicles, which results from a reinforced exhaust regulations as the number of vehicles powered by a Diesel engine increases. The Diesel Particulate Filter (DPF) system is considered as one of the most efficient method to reduce particulate matter (PM); however, the improvement of a regeneration performance at any engine operation point presents a considerable challenge by itself. Temperature, gas composition and flow rate of exhaust gas are important parameters in DPF evaluation processes, especially during a regeneration process. Engine dynamometer and segment tester are generally used in DPF evaluation so far. These test methods, however, could not completely evaluate the effect of various parameters on real DPF, such as oxygen concentration, amount of soot and exhaust gas temperatures. The evaluation of DPF systems using a dump combustor has been verified experimentally and this dump combustor system is likely to be appropriate for the DOC (Diesel Oxidation Catalyst) and SCR (Selective Catalytic Reduction) assessments test, too.

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The Application of Dump Combustor for Evaluation of DPF(Diesel Particulate Filter) System (DPF 성능 평가를 위한 Dump Combustor의 활용)

  • Nam, Youn-Woo;Lee, Won-Nam;Oh, Kwang-Chul;Lee, Chun-Beom
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.98-103
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    • 2007
  • The number of vehicles employing diesel engines is rapidly rising. Accompanying this trend, application of an after-treatment system is strictly required as a result of reinforced exhaust regulations. The Diesel Particulate Filter (DPF) system is considered as the most efficient method to reduce particulate matter (PM), but the improvement of a regeneration performance at any engine operation point presents a considerable challenge by itself. Temperature, gas compostion and flow rate of exhaust gas are important parameters in DPF evaluation, especially regeneration process. Engine dynamometer and degment tester are generally used in DPF evaluation so far. But these test method couldn't reveal the effect of various parameters on real DPF, such as O2 concentration, amount of soot and exhaust gas temperature. This research has studied the possibility using dump combustor that used to take an approach lean premixed combustion in gas turbine for a DPF power and optimized. It is possible that utilize the system as DOC (Diesel Oxidation Catalyst) and SCR(Selective Catalytic Reduction) assessments test as well as DPF evaluation

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Study on the On-Board Test of After-Treatment Systems to Reduce PM-NOx in Low-Speed Marine Diesel Engine (선박용 저속디젤엔진 적용을 위한 PM-NOx 동시저감 배출저감설비 해상실증 연구)

  • Dong-Kyun Ko;Suk-Young Jeong;In-Seob Kim;Gye-Won An;Youn-Woo Nam
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.5
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    • pp.497-504
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    • 2023
  • In this study, Selective catalytic reduction (SCR) + Diesel particulate filter (DPF) system was installed on a ship with a low-speed engine to conduct the on-board test. The target ship (2,881 gross tons, rated power 1,470 kW@240 rpm ×1) is a general cargo ship sailing in the coastal area. Drawing development, approvals and temporary survey of the ship were performed for the installation of the after-treatment system. For performance evaluation, the gaseous emission analyzer was used according to the NOx technical code and ISO-8178 method of measurement. The particulate matter analyzer used a smoke meter to measure black carbon, as discussed by the International Maritime Organization (IMO). Tests were conducted using MGO (0.043%) and LSFO (0.42%) fuels according to the sulfur content. The test conditions were selected by considering the engine rpm (130, 160 and 180). Gaseous emission and particulate matter (smoke) were measured according to the test conditions to confirm the reduction efficiency of the after treatment system. The results of NOx emission and particulate matter (smoke) revealed that reduction efficiency was more than 90%. The exhaust pressure met the allowable back pressure (less than 50 mbar). This study confirms the importance of the on-board test and the potential of SCR + DPF systems as a response technology for reducing nitrogen oxides and particulate matter.

Characteristics of Simultaneous Removal of NOx and PM over a Hybrid System of LNT/DPF + SCR/DPF in a Single Cylinder Diesel Engine (단기통 디젤엔진에서 LNT/DPF + SCR/DPF 하이브리드 시스템의 NOx 및 PM 동시저감 특성)

  • Kang, Wooseok;Park, Su Han;Choi, Byungchul
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.2
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    • pp.152-160
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    • 2016
  • The market demand for diesel engine tends to increase in general passenger cars as well as commercial vehicles because of its advantages. However, to meet the vehicle emissions regulation which will be more stringent in the future, it is necessary to plurally apply all after-treatment technologies such as diesel oxidation catalyst (DOC), catalyzed diesel particulate filter (CDPF), lean NOx trap (LNT) and selective catalytic reduction (SCR), and so on. Accordingly, the exhaust after-treatment system for diesel vehicle requires the technology of minimizing the numbers of catalysts by integrating every individual catalysts. The purposes of this study is to develop hybrid exhaust after-treatment device system which simultaneously uses LNT/DPF and SCR/DPF catalyst concurrently reducing NOx and particulate matter (PM). As the results, the hybrid system with $NH_3$ generated at LNT/DPF working as a reducing agent of SCR/DPF catalyst, improving NOx conversion rate, was found to be more excellent in de-NOx performance than that in LNT/DPF alone system.

Impact of Ash Deposit on Conversion Efficiency of Wall Flow Type Monolithic SCR Reactor (벽유동 방식 담체를 사용하는 SCR 촉매 반응기에서 재 퇴적이 변환 효율에 미치는 영향에 대한 연구)

  • Park, Soo-Youl
    • Journal of Power System Engineering
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    • v.17 no.1
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    • pp.27-35
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    • 2013
  • SCR (Selective Catalytic Reduction) on DPF (Diesel Particulate Filter) is a multi-functional after-treatment device which integrates soot filtration and DeNOx function into a single can. Because of its advantage in package and cost, the SCR on DPF is considered as a potential candidate for future application. It inherently employes wall flow type monolithic reactor so ash included in exhaust gas may deposit inside the inlet channel of this device. This study is intended to identify the impact of ash deposit on SCR reaction under wall flow type monolithic reactor. Simulation approach is used so relevant species transport equations for wall flow type monolith is derived. These equations can be solved together with momentum conservation equations and give solution for conversion performance. Both ash deposit and clean catalyst case are simulated and comparison of these two cases gives an insight for the impact of ash deposit on conversion performance. Ash deposit can be classified as ash layer and ash plug. and impact of ash deposit is described along with different morphology of ash deposit.

A Basis Study on the Optimal Design of the Integrated PM/NOx Reduction Device (일체형 PM/NOx 동시저감장치의 최적 설계에 대한 기초 연구)

  • Choe, Su-Jeong;Pham, Van Chien;Lee, Won-Ju;Kim, Jun-Soo;Kim, Jeong-Kuk;Park, Hoyong;Lim, In Gweon;Choi, Jae-Hyuk
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.6
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    • pp.1092-1099
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    • 2022
  • Research on exhaust aftertreatment devices to reduce air pollutants and greenhouse gas emissions is being actively conducted. However, in the case of the particulate matters/nitrogen oxides (PM/NOx) simultaneous reduction device for ships, the problem of back pressure on the diesel engine and replacement of the filter carrier is occurring. In this study, for the optimal design of the integrated device that can simultaneously reduce PM/NOx, an appropriate standard was presented by studying the flow inside the device and change in back pressure through the inlet/outlet pressure. Ansys Fluent was used to apply porous media conditions to a diesel particulate filter (DPF) and selective catalytic reduction (SCR) by setting porosity to 30%, 40%, 50%, 60%, and 70%. In addition, the ef ect on back pressure was analyzed by applying the inlet velocity according to the engine load to 7.4 m/s, 10.3 m/s, 13.1 m/s, and 26.2 m/s as boundary conditions. As a result of a computational fluid dynamics analysis, the rate of change for back pressure by changing the inlet velocity was greater than when inlet temperature was changed, and the maximum rate of change was 27.4 mbar. This was evaluated as a suitable device for ships of 1800kW because the back pressure in all boundary conditions did not exceed the classification standard of 68mbar.