• Title/Summary/Keyword: Segregation-Free

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Melt-solid interface and segregation in horizontal bridgman growth using 2 - and 3 - dimensional pseudo - steady - state model (2차원 및 3차원 정상상태 모델에 의한 수평브릿지만 결정성장에서의 고 - 액 계면과 편석)

  • 민병수;김도현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.4
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    • pp.306-317
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    • 1995
  • Abstract Gallium arsenide crystal is usually grown from the melt by the horizontal Bridgman method. We constructed pseudo - steady - state model for crystal growth of GaAs which inclue melt, crystal and the free interface. Mathematical equations of the model were solved for flow, temperature, and concentration field in the melt and temperature field in the crystal. The location and shape of the interface were also solved simultaneously. In 2 - dimensional model, the shape of the interface is flat with adiabatic thermal boundary condition, but it becomes curved with completely conducting thermal boundary condition. In 3 - dimensional model, the interface is less curved than 2 - dimensional case and the flow intensity is similar to that of 2 - dimensional case. With the increase of flow intensity vertical segregation shows maximum value in both 2 - and 3 - D model. However, the maximum value occurs in lower flow intensity in 2 - D model because the interface is more curved for the same flow intensity.

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Selective Surface Oxidation of 590MPa TRIP Steel and Its Effect on Hot-Dip Galvanizability (590 MPa TRIP강의 선택적 표면산화 거동과 표면 산화막이 도금특성에 미치는 영향)

  • Kim, Seong-Hwan;Im, Jun-Mo;Huh, Joo-Youl;Lee, Suk-Kyu;Park, Rho-Bum;Kim, Jong-Sang
    • Korean Journal of Metals and Materials
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    • v.49 no.4
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    • pp.281-290
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    • 2011
  • In order to gain better understanding of the selective surface oxidation and its influence on the galvanizability of a transformation-induced plasticity (TRIP) assisted steel containing 1.5 wt.% Si and 1.6 wt.% Mn, a model experiment has been carried out by depositing Si and Mn (each with a nominal thickness of 10 nm) in either monolayers or bilayers on a low-alloy interstitial-free (IF) steel sheet. After intercritical annealing at $800^{\circ}C$ in a $N_2$ ambient with a dew point of $-40^{\circ}C$, the surface scale formed on 590 MPa TRIP steel exhibited a microstructure similar to that of the scale formed on the Mn/Si bilayer-coated IF steel, consisting of $Mn_{2}SiO_{4}$ particles embedded in an amorphous $SiO_{2}$ film. The present study results indicated that, during the intercritical annealing process of 590 MPa TRIP steel, surface segregation of Si occurs first to form an amorphous $SiO_{2}$ film, which in turn accelerates the out-diffusion of Mn to form more stable Mn-Si oxide particles on the steel surface. During hot-dip galvanizing, particulate $Fe_{3}O_{4}$, MnO, and Si-Mn oxides were reduced more readily by Al in a Zn bath than the amorphous $SiO_{2}$ film. Therefore, in order to improve the galvanizability of 590 TRIP steel, it is most desirable to minimize the surface segregation of Si during the intercritical annealing process.

Numerical simulation of dynamic segregation of self-consolidating concrete (SCC) in T-box set-up

  • Hosseinpoor, Masoud;Khayat, Kamal H.;Yahia, Ammar
    • Computers and Concrete
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    • v.20 no.3
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    • pp.297-310
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    • 2017
  • A CFD software was used to simulate free surface flow of SCC in the T-Box test. In total, seven simulations were developed to study the effect of rheological parameters on the non-restricted flow performance of SCC in both horizontal and vertical directions. Different suspending fluids having five plastic viscosity values between 10 and 50 Pa.s, three yield stress values between 14 and 75 Pa, one density of $2500kg/m^3$, and one shear elasticity modulus of 100 Pa were considered for suspension of 178 spherical particles of 20-mm diameter and $2500kg/m^3$ density. The results of the simulations are found to correlate well to changes in rheological parameters of the suspending fluid. Plastic viscosity was shown to be the most dominant parameter affecting flowability and dynamic stability compared to the yield stress. A new approach was proposed to evaluate performability of SCC based on a trade-off between flowability and dynamic stability.

A Study on the Gravity Segregation in Monotectic Al Alloys.(II);The Effect of Master Alloy Addition on the Distribution of Pb, Bi Particles (Al계 편정합금의 중력 편석에 관한 연구(II);Pb, Bi 입자의 분산에 미치는 모하금 첨가의 영향)

  • Hwang, Ho-Eul;Lee, Jai-Ha;Kim, Hee-Myung;Choe, Jeong-Cheol;Yoon, Eui-Park
    • Journal of Korea Foundry Society
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    • v.10 no.5
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    • pp.392-398
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    • 1990
  • To improve free-cutting property, fine Pb, Bi particles is necessary to be distributed evenly in Al-Cu alloy. The control of added element size and distribution are very difficult because of the physical properties of Pb, Bi. The effect of master alloy compositions on microstructure and particle distribution was investigated. The ribbon shape of Pb-50wt% Bi master alloy showed the best results. And Ti addition improved even distribution of Pb, Bi particles. Particles grown from $L_2$ phase were considered to be the Pb, Bi compound.

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Activated Physical Properties at Air-Polymer Interface

  • Kajiyama, Tisato
    • Macromolecular Research
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    • v.15 no.2
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    • pp.109-113
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    • 2007
  • The surface molecular motion of monodisperse polystyrene (PS) films was examined using scanning vis-coelasticity microscopy (SVM) in conjunction with lateral force microscopy (LFM). The dynamic storage modulus, E', and loss tangent, $tan\delta$, at a PS film surface with number-average molecular weights, $M_n$, smaller than 30 k were found to be smaller and larger than those for the bulk sample, even at room temperature, meaning that the PS surface is in a glass-rubber transition or fully rubbery sate at this temperature when the $M_n$ is small. In order to quantitatively elucidate the dynamics of the molecular motion at the PS surface, SVM and LFM measurements were performed at various temperatures. The glass transition temperature, $T_g$, at the surface was found to be markedly lower than the bulk $T_g$, and this discrepancy between the surface and bulk became larger with decreasing $M_n$. Such an intensive activation of the thermal molecular motion at the PS surfaces can be explained in terms of an excess free volume in the vicinity of the film surface induced by the preferential segregation of the chain end groups.

Stable In-reactor Performance of Centrifugally Atomized U-l0wt.%Mo Dispersion Fuel at Low Temperature

  • Kim, Ki-Hwan;Kwon, Hee-Jun;Park, Jong-Man;Lee, Yoon-Sang;Kim, Chang-Kyu
    • Nuclear Engineering and Technology
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    • v.33 no.4
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    • pp.365-374
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    • 2001
  • In order to examine the in-reactor performance of very-high-density dispersion fuels for high flux performance research reactors, U-l0wt.%Mo microplates containing centrifugally atomized powder were irradiated at low temperature. The U-l0wt.%Mo dispersion fuels show stable in- reactor irradiation behaviors even at high burn-up, similar to U$_3$Si$_2$ dispersion fuels. The atomized U-l0wt.%Mo fuel particles have a fine and a relatively uniform fission gas bubble size distribution. Moreover, only one of third of the area of the atomized fuel cross-sections at 70a1.% burn-up shows fission gas bubble-free zones, This appears to be the result of segregation into high Mo and low Mo.

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Effect of Silicon on the Fracture Characteristics of Austempered Ductile Iron

  • Kang, In-Chan
    • Journal of Korea Foundry Society
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    • v.12 no.1
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    • pp.25-31
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    • 1992
  • The effects of Si and austempering temperature on the fracture characteristics and the microstructures of austempered ductile irons were investigated. As Si content increased from 2.28% to 3.0%, the precipitation of carbides during bainitic transformation and was suppressed the amount of retained austenite increased resulting in the increase in the fracture toughness. It is believed that the high Si limited the formation of martensite in the microstructure and minimized the segregation of the other elements at cell boundaries. But in samples with too high Si content as 3.3%, the formation of islands of free ferrite in the bainitic structures was observed and the fracture toughness was measured to have degraded.

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Design Program of Deck Plate Slab System with Non-welding Truss Type Reinforced Bar (철근트러스 압접 데크플레이트 바닥 구조의 설계 프로그램)

  • Yoon, Myung-Ho;Oh, Sang-Hoon
    • Journal of The Korean Digital Architecture Interior Association
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    • v.8 no.1
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    • pp.57-64
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    • 2008
  • There are many problems in present truss-deck slab system for example welding defect, segregation, water leakage, rust and tarnish etc. These problems may be caused by spot welding thin galvanized steel plate and lattice bar. The TOX Joining Systems is to join metal sheets of different material and thickness with and without coating or painting without adding heat or a joining part. Newly developed TOX-deck slab system using non-welding joint is free from above mentioned problems. The objects of this study are suggestion of design strength of TOX joint by experimental and statistical analyses and development of window based program to design the TOX-deck slab system.

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The development of new soybean strain with ti and cgy1 recessive allele

  • Choi, Sang Woo;Park, Jun Hyun;Chung, Jong Il
    • Journal of Plant Biotechnology
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    • v.45 no.4
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    • pp.328-332
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    • 2018
  • Soybean [Glycine max (L.) Merr.] seed is an important dietary source of protein, oil, carbohydrate, isoflavone and other various nutrients for humans and animals. However, there are anti-nutritional factors in the raw mature soybeans. Kunitz trypsin inhibitor (KTI) protein and stachyose are the main anti-nutritional factors in soybean seed. The ${\alpha}^{\prime}$-subunit of ${\beta}$-conglycinin protein exhibit poor nutritional and food processing properties. The genetic removal of the KTI and ${\alpha}^{\prime}$-subunit proteins will improve the nutritional value of the soybean seed. The objective of this research was to develop a new soybean strain with KTI and ${\alpha}^{\prime}$-subunit protein free ($titicgy_1cgy_1$ genotype) and proper agronomic traits. A breeding population was developed from the cross of the Bl-1 and 15G1 parents. A total of 168 $F_2$ seeds from the cross of the BL-1 and 15G1 parents were obtained. The segregation ratios of 9: 3: 3: 1 ($104Ti\_Cgy_{1\_}:\;30Ti\_cgy_1cgy_1:\;21cgy_1cgy_1Ti\_:\;13titicgy_1cgy_1$) between the Ti and $Cgy_1$ genes in the $F_2$ seeds were observed (${\chi}^2=5.12$, P=0.5-0.10). Two $F_4$ plant strains with proper agronomical traits and $titicgy_1cgy_1$ genotype (free of both KTI and ${\alpha}^{\prime}$-subunit protein) were selected and harvested. 2 strains (S1 and S2) had yellow seed coats and hilum. The plant height of the S1 strain was 65 centimeters. The 100-seed weight was 29.2 g. The plant height of the S2 strain was 66 centimeters and 100-seed weight was 26.2 g. The two strains selected in this research will be used to improve the new cultivar that will be free of the KTI and ${\alpha}^{\prime}$-subunit proteins.

Synthesis of Few-layer Graphene Film on a Ni Substrate by Using Filtered Vacuum Arc Source Method

  • Kim, Chang-Su;Seo, Ji-Hun;Gang, Jae-Uk;Kim, Do-Geun;Kim, Jong-Guk;Lee, Hyeong-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.157-157
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    • 2011
  • Graphene has generated significant interest in the recent years as a functional material for electronics, sensing, and energy applications due to its unique electrical, optical, and mechanical properties. Much of the considerable interest in graphene stems from results obtained for samples mechanically exfoliated from graphite. Practical applications, however, require reliable and well-controlled methods for fabrication of large area graphene films. Recently high quality graphene layers were fabricated using chemical vapor deposition (CVD) on nickel and copper with methane as the source of the carbon atoms. Here, we report a simple and efficient method to synthesize graphene layers using solid carbon source. Few-layer graphene films are grown using filtered vacuum arc source (FVAS) technique by evaporation of carbon atom on Ni catalytic metal and subsequent annealing of the samples at 800$^{\circ}$C. In our system, carbon atoms diffuse into the Ni metal layer at elevated temperatures followed by their segregation as graphene on the free surface during the cooling down step as the solubility of carbon in the metal decrease. For a given annealing condition and cooling rate, the number of graphene layers is easily controlled by changing the thickness of the initially evaporated amorphous carbon film. Based on the Raman analysis, the quality of graphene is comparable to other synthesis methods found in the literature, such as CVD and chemical methods.

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