• Title/Summary/Keyword: Seed structure

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Photoelectrochemical Properties of a Vertically Aligned Zinc Oxide Nanorod Photoelectrode (수직으로 정렬된 산화아연 나노막대 광전극의 광전기화학적 특성)

  • Park, Jong-Hyun;Kim, Hyojin
    • Journal of the Korean institute of surface engineering
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    • v.51 no.4
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    • pp.237-242
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    • 2018
  • We report on the fabrication and photoelectrochemical (PEC) properties of a ZnO nanorod array structure as an efficient photoelectrode for hydrogen production from sunlight-driven water splitting. Vertically aligned ZnO nanorods were grown on an indium-tin-oxide-coated glass substrate via seed-mediated hydrothermal synthesis method with the use of a ZnO nanoparticle seed layer, which was formed by thermally oxidizing a sputtered Zn metal thin film. The structural and morphological properties of the synthesized ZnO nanorods were examined using X-ray diffraction and scanning electron microscopy, as well as Raman scattering. The PEC properties of the fabricated ZnO nanorod photoelectrode were evaluated by photocurrent conversion efficiency measurements under white light illumination. From the observed PEC current density versus voltage (J-V) behavior, the vertically aligned ZnO nanorod photoelectrode was found to exhibit a negligible dark current and high photocurrent density, e.g., $0.65mA/cm^2$ at 0.8 V vs Ag/AgCl in a 1 mM $Na_2SO_4$ electrolyte. In particular, a significant PEC performance was observed even at an applied bias of 0 V vs Ag/AgCl, which made the device self-powered.

수평 구조 Zinc Oxide Nanorods 기반 센서의 전극 금속별 특성 비교

  • Lee, Jae-Hyeok;Kim, Seon-Min;Lee, Su-Min;Kim, Seong-Hyeon;Kim, Tae-Geun;Jo, Jin-U
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.377-377
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    • 2012
  • 반도체 물질로서 Zinc oxide (ZnO) nanorod (NR)는 Hydrothermal growth method로 제작 시 고가의 장비가 필요치 않기에 저비용 대면적 박막을 제작하는데 적합하지만 NR들의 array 조절과 각각의 rod와 전극 간의 연결에서 어려움을 가지고 있다. 최근 연구에서는 이러한 NR array 형상 조절과 소자의 성능 향상을 위하여 tilted sputtering method를 이용해 seed layer를 lateral 하게 형성하여 성장시켜 표면적을 극대화함으로서 응용되는 센서의 성능을 향상시키는 연구가 진행되고 있다. 본 연구에서는 이렇게 향상된 수평구조의 ZnO NR과 다양한 전극 금속 간의 schottky barrier의 높이 차이에 따라 sensitivity와 response time의 차이를 측정하였다. NR들을 전계방출형 전자현미경과 XRD로 분석 NR의 lateral structure 및 결정성을 확인하였다. 그리고 이렇게 형성한 NR을 소자화하여 Au, Ag, Al을 전극 금속물질로 사용한 경우에 대하여 sensing performance와 전극 금속의 schottky barrier의 상관관계를 확인하였다.

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Directionality of ο-Phthalaldehyde adsorbed onto H-passivated Si(100) Surface Characterized by NEXAFS and HRPES

  • Kim, Ki-Jeong;Yang, Sena;Kang, Tai-Hee;Kim, Bong-Soo;Lee, Hang-Gil
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1973-1975
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    • 2010
  • The electronic and adsorption structure of o-phthalaldehyde (OPA) on the H-Si(100) surface was investigated by using Near Edge X-ray Fine Structure (NEXAFS) and high resolution photoemission spectroscopy (HRPES). We confirmed that the OPA grown on the H-Si(100) surface showed good dependency with about 60 degree tilting angle using NEXAFS and a single O 1s peak by using HRPES. Hydrogen atom passivated on the Si(100) surface was found to be a seed for making one dimensional organic line that uses a chain reaction as the H-Si(100) surface was compared with the hydrogen free Si(100) surface.

Tracheid Structure in Aerial System of Several Ophioglossaceous Plants (수 종 고사리삼과 식물 지상부의 가도관 구조)

  • 김경식
    • Journal of Plant Biology
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    • v.36 no.4
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    • pp.337-343
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    • 1993
  • Tracheid structure of aerial system in five species of Ophioglossaceae and one species of Osmundaceae was examined with light and scanning electron microscopy. The species were Botrichium multifidum var. robustrum, B. ternatum, strictum, B. virginianum, Ophioglossum vulgatum, and Osmunda japonica. Three types of tracheids could be recognized by the pattern of secondary wall thickening; helical, irregular reticulate and circular bordered pitted tracheids. Among them, the appearance of circular bordered pitted tracheids supported that ophioglossaceous plants might have phylogenetic relationship with progymnosperm-seed plant line. Circular and elliptical bordered pits in shape were observed in five ophioglossaceous species; the former was subdivided into large and small types in size. In conclusion, three types of bordered pits were found: (1) large circular type- O. vulgatum, (2) small circular type- B. multifidum var. robustrum, B. ternatum and (3) elliptical type-B. strictum, B. virginianum. B. strictum and B. virginianum belong to subgenus Osmundopteris had the elliptical bordered pits. Therefore, this group might be interpreted as the most primitive in this family; however, such suggestion did subgenus Osmundopteris was classified into the most advanced group.

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Three-dimensional Flow Structure inside a Plastic Microfluidic Element (미소유체요소 내부유동의 3차원 측정 및 수치해석)

  • Lee Inwon;An Kwang Hyup;Nam Young Sok;Lee In-seop
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.419-422
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    • 2002
  • A three-dimensional inlet flow structure inside a microfluidic element has been investigated using a micro-PIV(particle image velocimetry) measurement as well as a numerical analysis. The present study employs a state-of-art micro-PIV system which consists of epi-fluorescence microscope, 620nm diameter fluorescent seed particles and an 8-bit megapixel CCD camera. For the numerical analysis, a commercial software CFD-ACE+(V6.6) was employed for comparison with experimental data. Fixed pressure boundary condition and a 39900 structured grid system was used for numerical analysis. Velocity vector fields with a resolution of $6.7{\times}6.7{\mu}m$ has been obtained, and the attention has been paid on the effect of varying measurement conditions of particle diameter and particle concentration on the resulting PIV results. In this study, the microfluidic elements were fabricated on plastic chips by means of MEMS processes and a subsequent melding process.

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Dimensions of Structural Elements in Fusiform Ray of Sitka Spruce (Picea sitchensis (Bong.) Carr.) Affecting Radial Permeability

  • Usta, Ilker
    • Journal of the Korean Wood Science and Technology
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    • v.33 no.5 s.133
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    • pp.1-6
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    • 2005
  • The anatomical structure of fusiform ray was examined by scanning electron microscopy (and microscopic images were analysed by image analyser) to explain the differences in radial fluid uptake between the extremes in the radial treatment data, i.e. between the selected trees of QCI (Queen Charlotte Islands in Rhondda, South Wales) and SO (South Oregon in Dalby, North-East England) planted in the UK. The ray structure of these two seed origins was examined microscopically and different patterns of ray composition were observed. The most important anatomical features influencing radial permeability were the nature of fusiform ray, and the condition of the resin canals, epithelial cells and intercellular spaces in particular.

Directionality of O-Phthaladehyde adsorbed on H-Si(100) Surface Using NEXAFS and HRPES

  • Kim, Gi-Jeong;Park, Seon-Min;Im, Hui-Seon;Kim, Bong-Su;Lee, Han-Gil
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.79-79
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    • 2010
  • The electronic and adsorption structure of O-Phthaladehyde (OPA) on the H-Si(100) surface was investigated by using Near Edge X-ray Fine Structure (NEXAFS) and high resolution photoemission spectroscopy (HRPES). We confirmed that the OPA grown on the H-Si(100) surface showed good dependency with about 60 degree tilting angle using NEXAFS and a single O 1s peak by using HRPES. Hydrogen atom passivated on the Si(100) surface was found to be a seed for making one dimensional organic line that uses a chain reaction as the H-Si(100) surface was compared with the hydrogen free Si(100) surface. Through the spectral analysis, we will demonstrate 1-D directional formation of OPA on H-Si(100) surface using NEXAFS and HRPES.

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A study on the properties in phase change of Y-Ba-Cu-O system superconductor (Y-Ba-Cu-O계 초전도체의 상변화에 따른 특성연구)

  • 조보연;채기병;강기성;소대화
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.90-96
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    • 1994
  • In this paper, an experiment about the fabrication method of superconductor was made in order to obtain crystal structure by making High T$\sub$C/, superconductor Y$_1$Ba$_2$Cu$_3$O$\sub$x/ to Y$_2$Ba$_1$Cu$_1$O$\sub$x/ of nonsuperconductor phase was added. 211 phase, which can approach crystal structure and growth-orientatoun, was used as seed in the 123 phase which shows the properties of superconductor. Therefore crystal growth effect was able to be attained. And the effect is expected to eleminate thin crack in the growth-process and to improve electrical properties by adding Ag to High T$\sub$c/ superconductor Y$_1$Ba$_2$Cu$_3$O$\sub$x/ combined with Y$_2$Ba$_1$Cu$_1$O$\sub$x/ .

Screening for bioactive compounds from natural products by ELISA assay

  • Iwanami, Naoko
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1998.11a
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    • pp.34-37
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    • 1998
  • Combinatorial chemistry is one of the most interested topics in the area of drug discovery. One of the most important points is how to find a lead compound that gives the seed structure for designing of a combinatorial library. Natural products is suitable for searching a new bioactive compound with new structure. We have carried out systematic screening works to find natural products possessing the effects on inter-and intra-cellular signaling. Two hundreds extracts of medical plants and two thousands microbial culture broth samples have been tested for the induction and inhibition of IL-2 or IL-6 production (Fig. 1). ELISA is an efficient method for screenings from such a large number of samples. Now, we apply this method to search prion- binding agents.

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Structure-Preserving Mesh Simplification

  • Chen, Zhuo;Zheng, Xiaobin;Guan, Tao
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.14 no.11
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    • pp.4463-4482
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    • 2020
  • Mesh model generated from 3D reconstruction usually comes with lots of noise, which challenges the performance and robustness of mesh simplification approaches. To overcome this problem, we present a novel method for mesh simplification which could preserve structure and improve the accuracy. Our algorithm considers both the planar structures and linear features. In the preprocessing step, it automatically detects a set of planar structures through an iterative diffusion approach based on Region Seed Growing algorithm; then robust linear features of the mesh model are extracted by exploiting image information and planar structures jointly; finally we simplify the mesh model with plane constraint QEM and linear feature preserving strategies. The proposed method can overcome the known problem that current simplification methods usually degrade the structural characteristics, especially when the decimation is extreme. Our experimental results demonstrate that the proposed method, compared to other simplification algorithms, can effectively improve the quality of mesh and yield an increased robustness on noisy input mesh.