Extracellular Polymeric Substances (EPS) in the water environment assemble fine, colloidal particles, such as clays, microorganisms and biomass, in large flocs, which are eventually subject to sedimentation and deposition and determine water/sediment quality and quantity. This study hence aimed to investigate the way that water and colloidal chemistry affects EPS-mediated flocculation of colloidal particles, using a jar-test experiment. Especially, ionic strength, divalent cation and humic substances concentrations were selected as experimental variables in the jar-test experiments, to elucidate their effects on EPS-mediated flocculation. A higher ionic strength increased flocculation capability, reducing electrostatic repulsion between EPS-attached colloidal particles and enhancing particle aggregation. 0.1 M NaCl ionic strength had higher flocculation capability, with 3 times larger floc size and 2.5 times lower suspended solid concentration, than 0.001 M NaCl. Divalent cations, such as $Ca^{2+}$, built divalent cationic bridges between colloidal particles and EPS (i.e., $colloid-Ca^{2+}-EPS$ or $EPS-Ca^{2+}-EPS$) and hence made colloidal particles to build into large, settelable flocs. A small $Ca^{2+}$ concentration enhanced flocculation capability, reducing suspended solid concentration 20 times lower than the initial dosed concentration. However, humic substances, adsorbed on colloidal particles, reduced flocculation, because they blocked EPS adsorption on colloidal particles and increased negative charges and electrostatic repulsion of colloidal particles. Suspended solid concentration in the tests with humic substances remained as high as the initial dosed concentration, indicating stabilization rather than flocculation. Findings about EPS-mediated flocculation in this research will be used for better understanding the fate and transport of colloidal particles in the water environment and for developing the best management practices for water/sediment quality.
This study was carried out to assess the seasonal variation of water quality and the effect of pollutant loading from watershed in a shallow eutrophic reservoir (Shingu reservoir) from November 2002 to February 2004, Stable thermocline which was greater than $1^{\circ}C$ per meter of the water depth formed in May, and low DO concentration (< 2 mg $O_2\;L^{-1}$) was observed in the hypolimnion from May to September, 2003. The ratio of euphotic depth to mixing depth ($Z_{eu}/Z_{m}$) ranged 0.2 ${\sim}$ 1.1, and the depth of the mixed layer exceeded that of the photic layer during study period, except for May when $Z_{eu}$ and $Z_{m}$ were 4 and 4.3 m, respectively. Most of total nitrogen, ranged 1.1 ${\sim}$ 4.5 ${\mu}g\;N\;L^{-1}$, accounted for inorganic nitrogen (Avg, 58.7%), and sharp increase of $NH_3$-N Hand $NO_3$-N was evident during the spring season. TP concentration in the water column ranged 43.9 ${\sim}$ 126.5 ${\mu}g\;P\;L^{-1}$, and the most of TP in the water column accounted for POP (Avg. 80%). During the study period, DIP concentration in the water column was &;lt 10 ${\mu}g\;P\;L^{-1}$ except for July and August when DIP concentration in the hypolimnion was 22.3 and 56.7 ${\mu}g\;P\;L^{-1}$, respectively. Increase of Chl. a concentration observed in July (99 ${\mu}g\;L^{-1}$) and November 2003 (109 ${\mu}g\;L^{-1}$) when P loading through two inflows was high, and showed close relationship with TP concentration (r = 0.55, P< 0.008, n = 22). Mean Chl. a concentration ranged from 13.5 to 84.5 mg $L^{-1}$ in the water column, and the lowest and highest concentration was observed in February 2004 (13.5 ${\pm}$ 1.0 ${\mu}g\;L^{-1}$) and November 2003 (84.5 ${\pm}$29.0 ${\mu}g\;L^{-1}$), respectively. TP concentration in inflow water increased with discharge (r = 0.69, P< 0.001), 40.5% of annual total P loading introduced in 25 July when there was heavy rainfall. Annual total P loading from watershed was 159.0 kg P $yr^{-1}$, and that of DIP loading was 126.3 kg P $yr^{-1}$ (77.7% of TP loading. The loading of TN (5.0ton yr-1) was 30 times higher than that of TP loading (159.0 kg P yr-1), and the 78% of TN was in the form of non-organic nitrogen, 3.9 ton $yr^{-1}$ in mass. P loading in Shingu reservoir was 1.6 g ${\cdot}$$m^{-2}$${\cdot}$$yr^{-1}$, which passed the excessive critical loading of Vollenweider-OECD critical loading model. The results of this study indicated that P loading from watershed was the major factor to cause eutrophication and temporal variation of water quality in Shingu reservoir Decrease by 71% in TP loading (159 kg $yr^{-1}$) is necessary for the improvement of mesotrophic level. The management of sediment where tine anaerobic condition was evident in summer, thus, the possibility of P release that can be utilized by existing algae, may also be considered.
This study proposes an efficient management plan for improving the water quality of agricultural reservoirs. Hongdong reservoir is located in an area that includes farmland, forest, residential housing, and livestock farms. The levels of pollutants in Hongdong reservoir were investigated with the aim of improving the water quality in the reservoir. The potential concentrations of total nitrogen (T-N) and total phosphorus (T-P) in Hongdong reservoir were 1.06-3.67 and 0.52-1.12 $g/m^2-d$, respectively. An analysis of leaching characteristics was performed under anaerobic conditions for 72 hours at $20^{\circ}C$. The concentrations of T-P and $PO_4$-P were measured by general leaching for a set period. In the case of T-P, the leaching was measured by irregular leaching due to denitrification of nitrite nitrogen ($NO_2$-N) and nitrate nitrogen ($NO_3$-N). A very small amount of $NH_3$-N on nitrogen ($N_2$) was measured due to the low pH in the column, as a consequence of the anaerobic conditions.
Heavy metal concentrations and benthic foraminiferal distributions were investigated in three short sediment cores in order to understand the pollution history in Masan Bay. Sedimentation rates were 0.33 cm/yr, 0.20 cm/yr and 0.33 cm/yr in the inner bay, the out fall of Dugdong sewage disposal plant, and bay mouth, respectively. The rapid increases of copper, zinc and lead concentrations at the core depth of 10 cm the upper part indicated that Masan Bay has been polluted with industrial wastes since the 1940s. Benthic foraminifera in core sediments show that the variations in their distribution were followed by industrial pollution in the bay. The number of individuals and species diversity decreased, whereas agglutinated tests increased upward in the cores with increased heavy metal pollution. These shifts effectd the abundance of few tolerant forms and consequently decreased the species diversity. The opportunistic species Eggerella advena and Trochammina pacifica increased in polluted sediments. These species can be used as an indicator for assessments of environmental quality in Masan Bay.
Highland fields are concentrated in the Jaun area of Hongcheong-gun, a large amount of sediments are discharged from the highland fields. The sediment runoff affect the turbidity and water quality of the Soyang Lake, furthermore adversely affect water supply source of the capital region. There are several kinds of BMPs(Best management practices) to decrease the sedimentrunoff from the highland fields. Although construction cost of multistage sedimentation basins is very high, there is no actual survey data for the removal efficiency of suspended sediments and water quality in our country. In this study, stormwaterinflow and outflow of the multistage sedimentation basins were surveyed, and the removal efficiency of nonpoint source pollutants were analyzed. The stormwater survey results fortwo rainfall events show thatremoval efficiencies of SS, BOD and TP loads in the multistage sedimentation basins are 35%~62%, 24%~55%, 35%~58%, respectively. Although the measured efficiencies of the basins were lower than the theoretical efficiency, the proper operation and management can improve the removal rate of the basins. Turbid water problem in the upper parts of the Soyang River can be managed effectively through the additional installation of multistage sedimentation basins.
Khakimov, Elyorbek;Chung, Sang Yong;Senapathi, Venkatramanan;Elzain, Hussam Eldin;Son, JooHyeong
Journal of Soil and Groundwater Environment
/
v.22
no.3
/
pp.27-41
/
2017
This study dealt with the characteristics and the interrelations of hydrogeological parameters such as hydraulic conductivity, dispersivity and effective porosity of unconsolidated sediments for providing the basic data necessary for the planning of the management and preservation of groundwater quality in the Nakdong River Delta of Busan City, Korea. Groundwater quality in this area has been deteriorated due to seawater intrusion, agricultural fertilizer and pesticide, industrial wastewater, and contaminated river water. The physical properties (grain size distribution, sediment type, sorting) and aquifer parameters (hydraulic conductivity, effective porosity, longitudinal dispersivity) were determined from grain size analysis, laboratory permeability test and column tracer test. Among 36 samples, there were 18 Sand (S), 7 Gravelly Sand (gS), 5 Silty Sand (zS), 5 Muddy Sand (mS), and 1 Sandy Silt (sZ). Hydraulic conductivity was determined through a falling head test, and ranged from $9.2{\times}10^{-5}$ to $2.9{\times}10^{-2}cm/sec$ (0.08 to 25.6 m/day). From breakthrough curves, dispersivity was calculated to be 0.35~3.92 cm. Also, effective porosity and average linear velocity were obtained through the column tracer test, and their values were 0.04~0.46 and 1.06E-04~6.49E-02 cm/sec, respectively. Statistical methods were used to understand the interrelations among aquifer parameters of hydraulic conductivity, effective porosity and dispersivity. The relation between dispersivity and hydraulic conductivity or effective porosity considered the sample length, because dispersivity was affected by experimental scale. The relations between dispersivity and hydraulic conductivity or effective porosity were all in inverse proportion for all long and short samples. The reason was because dispersivity was in inverse proportion to the groundwater velocity in case of steady hydrodynamic dispersion coefficient, and groundwater velocity was in proportion to the hydraulic conductivity or effective porosity. This study also elucidated that longitudinal dispersivity was dependent on the scale of column tracer test, and all hydrogeological parameters were low to high values due to the sand quantity of sediments. It is expected that the hydrogeological parameter data of sediments will be very useful for the planning of groundwater management and preservation in the Nakdong River Delta of Busan City, Korea.
Journal of Korean Society of Environmental Engineers
/
v.32
no.1
/
pp.1-8
/
2010
To investigate the effects of sediments on the water quality of an estuary reservoir, Asan reservoir, we analyzed physical and chemical characteristics of the sediments and estimated nutrients release rate from the sediments. The sediments characterized as sandy loam are mainly composed of Nonapatite-P(64.7%) which has strong influence on the eutrophication of the reservoir by releasing from the sediments under the condition of increasing pH and anaerobic environment. High nutrient release rates was observed in April. Negative release rates in June show that there is no significant nutrient release from the sediments. The nutrient release was active at the Site B around the confluence of tributary compared to the Site A near the embankment. Based on the information of nutrient release rates and sediments surface area, daily average nutrient release rates of Asan reservoir are estimated; TN 6,609 kg/d, TP 3,877 kg/d. Since the amount of N and P released from the sediments corresponds to the 7.06% of N and 22.04% of P incoming from the watershed, it can be concluded that there is little influence of sediments on the water quality of Asan reservoir.
Kim, Young-Sug;Koo, Jun-Ho;Kwon, Jung-No;Lee, Won-Chan
Journal of the Korean Society of Marine Environment & Safety
/
v.24
no.6
/
pp.735-749
/
2018
In this study, one studied the principal factors and water-quality components that determine the concentration of chemical oxygen demand (COD) in seawater in estuaries, such as the Han, Geum, Youngsan, Seomjin, and Nakdong rivers in Korea. The principal factors determining the concentration of COD in seawater indicated by the principal component analysis were salinity, exogenous origin and autochthonous resources based on chlorophyll-a. Moreover, organic matter in the submarine sediment layer also had a secondary effect. Regression slope assessed the contribution of water-quality components to determine the concentration of COD in the estuary. One found that the effect of salinity on the overall survey was significant. Moreover, the effect of chlorophyll-a was also appeared in April and August. In each estuary, the most significant contribution factor was chlorophyll-a in the Nakdong River and salinity in the Han and Yongsan rivers. The contribution of salinity and chlorophyll-a were found to be the largest in the Geum River. The salinity and chlorophyll-a in the Seomjin River showed a low contribution.
Side scan sonar and SBP (sub-bottom profiler) play a very important role in the survey for seafloor imaging and sub-bottom profiling. In this study, we have acquired side scan sonar and SBP data from the artificial reef area. We applied digital image processing techniques to side scan sonar data in order to improve an image quality. For the enhancement of data quality and image resolution, we applied the typical seismic data processing sequence including gain recovery, muting, spectrum analysis, predictive deconvolution, migration to SBP data. We could easily estimate if artificial reef structures were settled properly and their distribution on the seafloor from the integrated interpretation of side scan sonar and SBP data. From the sampling analysis of seabed sediments, texture filtering of side scan sonar data and SBP data interpretation, we could evaluate the sediment type, distribution and thickness of seafloor sediments in detail.
Lots of pollutants typically originating from urban transportation are accumulating on the paved surfaces during dry periods and are washed-off directly to the river during a storm. Also, paved surfaces are contributing to increase in peak flows and volume of stormwater flows. These are the main reasons why the water quality of rivers and lakes remain polluted and still below standards. Currently, several management practices are being applied in developed countries but the design standards are still lacking. This research was conducted to develop a treatment technology that can be useful to address the problems concerning runoff quality and quantity. A lab scale infiltration device consisting of a pretreatment tank and media zone was designed and tested for various flow regimes characterizing the low, average and high intensity rainfall. Based on the experiments, the high intensity flow resulted to increase in outflow event mean concentration (EMC) of pollutants, about twice as much as the average outflow EMC. However, 78 to 88% of the total suspended solids were captured and retained in the pretreatment tank because of sedimentation. The removal of heavy metals such as zinc and lead was greatly affected by the vertical placement of woodchip layer prior to the media zone. It was observed that the high carbon content (almost 50%) in the woodchip provided opportunity for enhancing its uptake of metal by adsorption. The findings implied that the reduction of pollutants can be greatly achieved by means of proper pretreatment to allow for settling of particles with a combination of using high carbon source media like woodchip and a geotextile mat to reduce the flow before filtering into the media zone and finally discharging to the drainage system.
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