• Analytical Science and Technology
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• v.18 no.2
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• pp.147-153
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• 2005

Benzophenone (BP) which is one of endocrine disrupting chemicals is suspected to contaminate waters (river, lake and industrial drainage) and soils (ground soil and sediment). Analytical method for determination of BP in soil and water was developed by gas chromatography/mass spectrometry. Water sample (100 mL) was extracted with n-hexane, and soil (10 g) was extracted with methanol and n-hexane. Recovery for BP was >71.4% in water and 86.5-94.7% in soil with coefficient variation of less than 19.8%. Calibration curves showed a good linearity ($r^2$ >0.998). In water, soil and sediment collected at nation-wide sites, BP was detected at 5 sites among 43 water sites at the concentration range of 30-200 ng/L. No BP was found in the soil and sediment samples. It is suggested that this method will be useful to the determination of BP in the environmental matrices such as waters, soils and sediments in minute quantities.

• The Korean Journal of Community Living Science
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• v.23 no.4
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• pp.411-418
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• 2012

Phthalates and di-2-ethylhexyladipate are both widely used as industrial chemicals and exposure high levels over long periods of time can cause toxicity, estrogenic responses and endocrine disruption properties in both humans and animals. So far, their global monitoring in environmental matrices has been performed continuously. A developed method, including modified SPEED'98 (Japan Environment Agency) and USEPA was established for simple and rapid determination of phthalates and di-2-ethylhexyladipate in various matrices. This method was applied to explore the distribution levels in domestic environmental media such as water, soil and sediment. Eight phthalates (DEP(di-ethyl), DEHP(di-[2-ethyl-hexyl]), DprP (di-propyl), DBP(di-n-butyl), DPP(di-n-pentyl), DHP(di-n-hexyl), DCHP(di-cyclohexyl), BBP(butyl benzyl) and Adipate (di-2-ethylhexyl adipate) were investigated by seasonal sampling(spring, autumn) at 24 domestic sites. Phthalates and adipate were not detected in water samples and DEP, DBP, and DEHP were mainly detected in soil and sediment samples. The concentrations of DEP and DBP excluding DEHP in spring were higher in soil than those of sediment. Total concentrations of phthalates were significantly decreased in autumn for both soil and sediment.

• 한국생물공학회:학술대회논문집
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• 2000.04a
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• pp.89-91
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• 2000

Polynuclear aromatic hydrocarbon (PAH) compounds are highly carcinogenic chemicals and common groundwater contaminants that are observed to persist in soils. The adherence and slow release of PAHs in soil is an obstacle to remediation and complicates the assessment of cleanup standards and risks. Biological degradation of PAHs in soil has been an area of active research because biological treatment may be less costly than conventional pumping technologies or excavation and thermal treatment. Biological degradation also offers the advantage to transform PAHs into non-toxic products such as biomass and carbon dioxide. Ample evidence exists for aerobic biodegradation of PAHs and many bacteria capable of degrading PAHs have been isolated and characterized. However, the microbial degradation of PAHs in sediments is impaired due to the anaerobic conditions that result from the typically high oxygen demand of the organic material present in the soil, the low solubility of oxygen in water, and the slow mass transfer of oxygen from overlying water to the soil environment. For these reasons, anaerobic microbial degradation technologies could help alleviate sediment PAH contamination and offer significant advantages for cost-efficient in-situ treatment. But very little is known about the potential for anaerobic degradation of PAHs in field soils. The objectives of this research were to assess: (1) the potential for biodegradation of PAH in field aged soils under denitrification conditions, (2) to assess the potential for biodegradation of naphthalene in soil microcosms under denitrifying conditions, and (3) to assess for the existence of microorganisms in field sediments capable of degrading naphthalene via denitrification. Two kinds of soils were used in this research: Harbor Point sediment (HPS-2) and Milwaukee Harbor sediment (MHS). Results presented in this seminar indicate possible degradation of PAHs in soil under denitrifying conditions. During the two months of anaerobic degradation, total PAH removal was modest probably due to both the low availability of the PAHs and competition with other more easily degradable sources of carbon in the sediments. For both Harbor Point sediment (HPS-2) and Milwaukee Harbor sediment (MHS), PAH reduction was confined to 3- and 4-ring PAHs. Comparing PAH reductions during two months of aerobic and anaerobic biotreatment of MHS, it was found that extent of PAHreduction for anaerobic treatment was compatible with that for aerobic treatment. Interestingly, removal of PAHs from sediment particle classes (by size and density) followed similar trends for aerobic and anaerobic treatment of MHS. The majority of the PAHs removed during biotreatment came from the clay/silt fraction. In an earlier study it was shown that PAHs associated with the clay/silt fraction in MHS were more available than PAHs associated with coal-derived fraction. Therefore, although total PAH reductions were small, the removal of PAHs from the more easily available sediment fraction (clay/silt) may result in a significant environmental benefit owing to a reduction in total PAH bioavailability. By using naphthalene as a model PAH compound, biodegradation of naphthalene under denitrifying condition was assessed in microcosms containing MHS. Naphthalene spiked into MHS was degraded below detection limit within 20 days with the accompanying reduction of nitrate. With repeated addition of naphthalene and nitrate, naphthalene degradation under nitrate reducing conditions was stable over one month. Nitrite, one of the intermediates of denitrification was detected during the incubation. Also the denitrification activity of the enrichment culture from MHS slurries was verified by monitoring the production of nitrogen gas in solid fluorescence denitrification medium. Microorganisms capable of degrading naphthalene via denitrification were isolated from this enrichment culture.

• Journal of Soil and Groundwater Environment
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• v.12 no.3
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• pp.1-9
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• 2007

As Total Maximum Daily Load program is being implemented, needs for the management and treatment of contaminated sediment are rising to attain cleaner water resources. In this paper, impacts and management methods of contaminated sediment were reviewed. Remediation technologies for contaminated sediment including dredging, natural attenuation, in situ solidification/stabilization, in situ biological remediation, in situ chemical remediation and capping were reviewed. Integrated remediation scheme was presented as well.

• Journal of agriculture & life science
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• v.43 no.4
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• pp.1-8
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• 2009

The physically based model KINEROS2 was applied to forest road segments for simulating hydrology and sediment production. Data on rainfall amounts, runoff volume, and sediment yields were collected at two small plots in the Yangpyong experimental watershed. The KlNEROS2 model can be parameterized to match the volume of surface flow and sediment yields during seven storm events. Model predictions of hydrology were in good agreement with the observed data at two plots in the year 1997 and 1998. A comparison between the observed and predicted sediment yields indicated that the model provided reasonable estimates, although the model tended to under-estimate for some storm events. The overall result shows that the KINEROS2 model properly represents the hydrology and sediment transport processes in the forest road segments.

• Journal of the Korean Association of Geographic Information Studies
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• v.6 no.3
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• pp.1-10
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• 2003

RUSLE(revised universal soil loss equation) has been widely used for estimating soil loss. It is very difficult to validate the model estimation since the calculated soil loss should be compared with the survey data for quantification. The input variables for RUSLE model were estimated to grid cell for raster analysis in Bosung basin. Both reconnaissance(1:250,000) and detailed(1:25,000) soil maps were used to derive the input variables for soil erodibility factor. Soil loss calculated using RUSLE were compared to the unit sediment deposit surveyed by KICT(Korea Institute of Construction Technology, 1992) in Bosung basin for assessment. Unit sediment deposit from the cell size of 120m and 150m were the closest to the survey data in 1:250,000 and 1:25,000 map scale, respectively.

• Journal of Soil and Groundwater Environment
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• v.22 no.6
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• pp.66-73
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• 2017

Empirical erosion models like Universal Soil Loss Equation (USLE) models have been widely used to make spatially distributed soil erosion vulnerability maps. Even if the models detect vulnerable sites relatively well utilizing big data related to climate, geography, geology, land use, etc within study domains, they do not adequately describe the physical process of soil erosion on the ground surface caused by rainfall or overland flow. In other words, such models are still powerful tools to distinguish the erosion-prone areas at large scale, but physics-based models are necessary to better analyze soil erosion and deposition as well as the eroded particle transport. In this study a physics-based soil erosion modeling system was developed to produce both runoff and sediment yield time series at watershed scale and reflect them in the erosion and deposition maps. The developed modeling system consists of 3 sub-systems: rainfall pre-processor, geography pre-processor, and main modeling processor. For modeling system validation, we applied the system for various erosion cases, in particular, rainfall-runoff-sediment yield simulation and estimation of probable maximum sediment (PMS) correlated with probable maximum rainfall (PMP). The system provided acceptable performances of both applications.

• Korean Journal of Agricultural Science
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• v.47 no.4
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• pp.803-814
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• 2020

Managing erosion control dams requires the annual average sediment yield to determine their storage capacity and time to full sediment-fill and dredging. The GeoWEPP (Geo-spatial interface for Water Erosion Prediction Project) model can predict the annual average sediment yield from various land uses and vegetation covers at a watershed scale. This study assessed the GeoWEPP to determine the annual average sediment yield for managing erosion control dams by applying it to five erosion control dams and comparing the results with field observations using ground-based LiDAR (light detection and ranging). The modeling results showed some differences with the observed sediment yields. Therefore, GeoWEPP is not recommended to determine the annual average sediment yield for erosion control dams. Moreover, when using the GeoWEPP, the following is recommended :1) use the US WEPP climate files with similar latitude, elevation and precipitation modified with monthly average climate data in Korea and 2) use soil files based on forest soil maps in Korea. These methods resulted in GeoWEPP predictions and field observations of 0 and 63.3 Mg·yr-1 for the Gangneung, 142.3 and 331.2 Mg·yr-1 for the Bonghwa landslide, 102.0 and 107.8 Mg·yr-1 for the Bonghwa control, 294.7 and 115.0 Mg·yr-1 for the Chilgok forest fire, and 0 and 15.0 Mg·yr-1 for the Chilgok control watersheds. Application of the GeoWEPP in Korea requires 1) building a climate database fit for the WEPP using the meteorological data from Korea and 2) performing further studies on soil and streamside erosion to determine accurate parameter values for Korea.

• Membrane and Water Treatment
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• v.14 no.4
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• pp.147-153
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• 2023

Urbanization has been causing such new pollutants as micro-plastic, thus the environmental impact of new pollutants on ecosystem is rapidly increasing. When it comes to micro-plastic, a representative artificial trace pollutant, its risk has been increased at a much faster rate, however the depth study associated with stormwater sediment and wetland was relatively rare. In this research, soil samples from storm water sediment were analyzed for distribution characteristics of micro-plastics in the J wetland (registered as Ramsar wetland, May 2021 and a representative environmental site in South Korea). Analyzed soil samples found approximately 201 ± 93 particle/kg (based on unit weight, Total micro plastic particles / Total Sample weight) micro-plastics in the samples. When considering the total quantitative numbers in stormwater sediment in the entire area of the J wetland, over 15,000 micro-plastics were estimated to be contaminating such area. In addition, in terms of qualitative numbers, micro-plastics were contaminating the J wetland with 94.7 % ratio of styrofoam type (43.9%) and polyethylene type (50.8%). These research results can be used as base data sets for controlling micro-plastics in the J wetland.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.8 no.2
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• pp.385-394
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• 2007

To study long-term characteristics of the heavy metal contamination, soil and sediment samples were collected at 14 sites in highway roadside during 6 years. The total concentrations of metals including Zn, Ni, Cu. Pb, Cr, Cd, and As in those samples were investigated. The results indicate that concentrations of Zn, Ni, and Cu in highway roadside soils are much higher than the metal concentrations in background soils and appear to be increased gradually. Strong linear relationships between the cumulative traffic and the contents of the metals in highway roadside soils were obtained. Therefore, they might be used to predict the heavy metal concentrations in the future highway roadside soils for establishing the countermeasure of soil and sediment contamination.