• Title/Summary/Keyword: Sediment Clay

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Sorption/Desorption Characteristics of Halogenated Aliphatic Compounds from Activated Sludge, Sediment, and Clay (지방족 할로겐화합물의 활성슬러지와 해안저질 및 점토에서의 흡탈착 특성)

  • 김종오;박종석;최연돈
    • Journal of Environmental Science International
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    • v.11 no.9
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    • pp.961-969
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    • 2002
  • This study was performed : 1) to establish the experimental analysis conditions for the sorption and desorption of toxic organic contaminants to/from the activated sludge, sediment, and clay, and 2) to determine the sorption and desorption equilibrium coefficients of some representative halogenated aliphatic compounds. Through the preliminary sorption test using Azo dye, a setting of quantitative experimental conditions to determine the sorption and desorption characteristics was decided as follows; equilibration time of 180 minutes, centrifuge for 15 minutes at 5000$\times$g, and 500mg/$\ell$ of TOC concentration. The sorption and desorption characteristics of halogenated aliphatic compounds onto activated sludge, sediment and clay could be described very well using the Freundlich isotherm. The preference of the average sorption capacity of the overall compounds showed in the sequence sediment 0.26mg/g, clay 0.23mg/g, and activated sludge 0.11 mg/g. The desorption rate of the sorbed compounds onto activated sludge, sediment and clay was approximately 89.8%, 35.3%, and 66.4%, respectively.

Distribution of heterotrophic bacteria and physico-chemical characteristics of sediments in Kum river estuary (금강 하구 퇴적토의 이화학적 성질과 종속영양세균의 분포에 관하여)

  • 이건형;아영칠;홍순우
    • Korean Journal of Microbiology
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    • v.24 no.3
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    • pp.308-316
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    • 1986
  • Vertical distribution of heterotrophic bacteria and physico-chemical characteristics were measuted in Kum River estuarine sediments. And interrelationship between heterotrophic bacterka and environmental factors was also studied. The type of sediment of Site 1 was silty clay, and sand at Site 2. Annual pH ranges were between 7.1 and 7.7 in the clay type sediment (Site 1) and 6.9-7.2 in the sand type sediment (Site 2). It was shown that organic matter contents were higher in the clay type sediment than those of sand type sediment. Redox potential values of sediments were decreased rapidly with depth at Site 1, but those of Sete 2 showed vertical fluctuation. Nitrogens(ammonia+amino acid-N, nitrate-N, nitrite-N) and phosphate in the clay type sediment showed higher values than those of sand type sediment. Annual distribution of heterotrophic bacteria were ranged $6.71{\times}10^4$ cells/g dry wt. $-2.50{\times}10^6$ cells/g dry wt. In the clay type sediment and $2.67{\times}10^3$ cells/g dry wt. $-1.94{\times}10^6$ cells/g dry wt. in the sand type sediment. Distribution of proteolytic, lipolytic, and amylolytic bacteria were decreased with the depth and the highest density was found in April and the lowest in January. Bacterial populations in sediments were closely correlated with such environmental factors as pH, redox potential, moisture content, organic matter contents, and inorganic nutrients such as nitrite-N and phosphate-P.

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Physicochemical factors affecting the adsorption of E. coli in estuarine sediments (하구퇴적토 환경에서 E.coli의 부착에 영향을 주는 물리화학적 요인)

  • 이건형
    • Korean Journal of Microbiology
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    • v.26 no.3
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    • pp.237-246
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    • 1988
  • The higher bacterial numbers on clay than on sand were caused by different environmental factors. Such factors affecting the adsorption of E. coli ATCC 11775 in the sediment as follows; optimal pH range for the adsorption of E. coli ATCC 11775 was pH 7.5-pH 9.5. E. coli ATCC 11775 were shown maxima in the salinity of 18.$75%_{o}$ on sand type sediment and $12.5%_{o}$ on clay type sediment. Bacteria attached better to clay typed sediment than to sand typed sediment when organic substance was eliminated. Beef extract of 0.5%-1% concentration was found to promote the attachment of E. coli ATCC 11775 effectively. Peptone of 0.5% was enganced the attachment on the clay, and peptone of 1.3%-5%, on the sand. E. coli ATCC 11775 was found to adsorb onto benthonite with the highest efficiency and on celite with the lowest efficiency. Efficiency of adsorption by inorganic ions was shown due to higher values of ion. Adsorption was achieved in the order of $Al^{3+}, Ca^{2+}, Na^{+}$.

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Estimation of the thickness of floating silty clay sediment using dual frequency single beam echo sound system (이중 주파수 에코 사운드 시스템을 이용한 부니층 두께 조사)

  • Ha, Hee-Sang
    • Journal of the Korean Geophysical Society
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    • v.5 no.3
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    • pp.219-231
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    • 2002
  • Single beam echo sounding was used to delineate bathymetry sea bottom in the area of hydrography and marine navigation. This research was aimed at measuring the thickness of floating silty clay sediment with dual frequencies echo sounding system. There occur discrepancies in penetrating depth through sea beds between high frequency(200 KHz) and low(33 KHz) frequency. RI density logging was employed to characterize the floating silty clay sediment of Guangyang bay, which was chosen to investigate the proposed site for reclamation field. The volume of floating silty clay sediment was used to design by estimating size of reclamation site. The estimation strategies developed in this study will be readily applicable to measure the Pattern of sedimentation via regular hydrographic survey in the future.

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Distribution Characteristics of Organic Matter and Heavy Metal of Sediment in Daecheon Port (대천항 퇴적물의 유기물 및 중금속 분포 특성)

  • Shin, Woo-Seok;Lim, Ji-Yoon;Yoon, Young-Gwan
    • Journal of Korean Society of Water Science and Technology
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    • v.26 no.6
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    • pp.43-51
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    • 2018
  • In order to systematically and scientifically manage the organic and heavy metals against sediment at Daecheon Port, this study conducted particle composition, organic materials and heavy metals irradiation studies of sediments. Analysis of the grain size composition of sediments in the target study area showed the distribution characteristics of the mix of sand, silt and clay. That is, Station C (Stn. C) showed superior by fine-grained sediment, Station A and B (Stn. A and B) showed superior by coarse-grained sediment. The organic matter(COD, TOC, and IL) of Stn. C was appeared to be heavily polluted more than Stn. A and B. These data for the spatial properties in sediment showed that organic matter was related positively to the sediment silt-clay content. Also, in the case of heavy metals contamination in surface sediments, Stn. C was higher than Stn. A and B. Particularly, at the Stn. C, high organic matter concentration and C/N ratio value( >10) indicated that the sediment was composed highly of land-derived organic matter. From these results, it considered that the correlation analysis among to silt-clay, organic matter and heavy metal was found to have a good interrelationship.

The distribution characteristics of Sb and As in the surface sediment from the Yellow Sea and the coastal areas of Korea (황해와 한국연안해역 표층퇴적물중 Sb과 As의 농도분포특성)

  • ;Jingyun Han
    • Journal of Environmental Science International
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    • v.12 no.10
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    • pp.1121-1129
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    • 2003
  • We report the distributions of Sb and As in the surface sediment of the Yellow Sea and the coastal areas of Korea. The mean concentrations of Sb and As range from 0.68 ppm to 1.01 ppm and from 7.4 ppm to 15.8 ppm, respectively, and show relatively the high concentrations at the coast of Weolseong in the East Sea for Sb and at the coast of Gadeok Island in the South Sea far As. This may be due to the anthropogenic input of these elements via river and atmosphere from industry complex and agriculture regions around the study areas. Because of the difference of clay to silt proportion, the correlation between silt plus clay contents and Sb, As in the coastal surface sediment of Korea is not shown, the concentrations of Sb and As vary widely for the sample in which the silt plus clay contents are the same. Therefore, we suggest that the distribution patterns of Sb and As in surface sediment of the Yellow Sea and the coastal areas of Korea are mainly controlled by the anthropogenic inputs and the sediment characteristics. On the other hand, the Sb concentrations are lower than those of the lowest effect level which is the standard of judgment for contamination, while the As concentrations are higher than those of the lowest effect level. This implies that the surface sediments of the Yellow Sea and the coastal areas of Korea are considerably contaminated for As.

Distribution of Clay Minerals in Surface Sediments of Kunsan Basin, Yellow Sea and their Transport Pathway (황해 군산분지 표층 퇴적물의 점토광물 함량 분포 및 이동경향 연구)

  • RHO, KYOUNG-CHAN
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.20 no.4
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    • pp.169-179
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    • 2015
  • To understand the transport pathways of muddy sediment of the Kunsan basin in Yellow Sea, grain sizes and clay mineral of 32 surface sediments and a sediment core were analyzed. In the study area, illite is predominant (63.4~71.9%), followed by chlorite (15.1~20.2%), kaolinite (10.3~17.2%) and smectite (2~6.9%), According to the spatial distribution of the clay minerals, illite, kaolinite+chlorite and smectite show relatively higher contents in the center of the north, northeast, and the south of the study area, respectively. Considering the spatial distribution of clay mineral contents the sand ridge alignments and tidal current pathways, the smectite particles were probably derived from the south of the study area, but kaolinite and/or chlorite particles were mainly transported from the Korean coastal zone. Meanwhile, down-core variation in the contents of clay minerals of the core revealed a distinct change in fine-grained muddy sediment provenance: muddy sediment input from the Korean coastal areas has increased while the input from China has decreased since the last 5,000 year ago, by showing the amount decrease of smectite and the increase of kaolinite+chlorite at the top layer of the late Holocene muddy sediment unit of the core.

The vertical environmental characteristics in the tidal flat sediments (갯벌의 수직적 환경 특성)

  • 김종구;유선재
    • Journal of Environmental Science International
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    • v.9 no.2
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    • pp.125-129
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    • 2000
  • As one of the fundamental survey to evaluate purification capacity of pollutants at the tidal flat sediments, we studied vertical environmental characteristics in three tidal flat sediments, Chunjangdae, Eueunri and Gyewhado. These are dissmilar to external feature in each other. The results of this study may be summarized as followed; As the results of particle analysis, Eueunri tidal flat fediment located in Keum river estuary consists of 98.98% as silt & clay, Chunjangdae tidal flat sediment located in SeocheonGun consists of 97.99% as sand. And Gyewhado tidal flat sediment located in Saemankeum in Saemankeum area consists area consists of 32.81% as silt & clay and 67.19% as sand. The concentration of organic pollutants(I.L., COD, POC, PON) in Eueunri tidal flat sediment which highly content of silt & clay were 3~4 times higher than others. The concentration of organic pollutants at each layer were slightly increase goes with deepen layer. The linear correlation between I.L. and COD, POC, PON were obtained. Correlation coefficients were in range of 0.821~0.940. Also the correlation between pH and COD, POC, PON were high(>r=0.9). Filteration rate in Chunjangdae tidal flat sediment was 0.01584cm/s as mean value, but the other were almost nothing filtered off.

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Effect of Particle Size of Sediment on Adsorption of Fluoride (하천 퇴적물의 입자크기에 따른 불소의 흡착 특성)

  • Kim, Chae-Lim;Oh, Jong-Min
    • Korean Journal of Ecology and Environment
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    • v.49 no.4
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    • pp.289-295
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    • 2016
  • The purpose of this study is to find out the effect of particle size of sediment on adsorption of fluoride. Particle size is classified as sand, silt and clay. Adsorption equilibrium time, adsorption isotherms and the effect of pH were investigated through batch tests. The $pH_{pzc}$ of sand, silt, clay was respectively 6, 8, 4.5 and AEC (anion exchange capacity) was highest in silt, respectively 0.0095, 0.0224, $0.014meq\;g^{-1}$. Adsorption of fluoride on the sediment was in equilibrium within 300 minutes from all particle size. The experimental data of isotherms at various pH were well explained by Freundlich equation. As the experimental results of the effect of pH, the adsorption efficiency of sand and silt were reduced after the $pH_{pzc}$. However, the adsorption efficiency of clay was maintained after the $pH_{pzc}$, and decreased rapidly higher than pH 12.

A Study on the Relationships between White Wares and Raw Materials Excavated at Goseong-ri Kiln Site in Chuncheon, Yeongseo Province, Gangwon-do (강원 영서지역 춘천 고성리 가마터 출토 백자 및 태토 원료의 상관관계 연구)

  • Lee, Byeong Hoon
    • Journal of Conservation Science
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    • v.36 no.3
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    • pp.152-161
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    • 2020
  • The purpose of this study was to compare the chemical properties of white soil and refined clay sediment, which are produced early in the refining process. The characteristics of the white wares made at the kiln site in Goseong-ri, Chuncheon were also examined. Three groups of materials were examined: white wares excavated from the white wares kiln, raw material from white soil collected from the surface, and a refined clay sediment group. There were also three analysis methods, which were a main components analysis, a trace components analysis, and a mineral analysis. The main components analysis found that the white wares clay was in the RO24.04~4.28 and the RO + R2O 0.30~0.31 mole areas, which were similar to the results for the refined clay sediment. However, the refining process used to produce better quality white wares meant that the large differences in the early white soil raw material appeared in the refined sediment. The mineral phase analysis showed that the crystals detected in the early white soil raw materials and refined clay sediment were almost identical. However, quartz and mullite mineral phases, which can occur above a certain temperature, were detected in the excavated white wares clay. Rare earth elements that were not affected by the pottery making process and the weathering of clay materials were found to have the same origin in all three groups.