• Title/Summary/Keyword: Secondary particles

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Electrochemical Properties and Structural Analysis of Carbon-Coated Silicon Anode for Lithium Secondary Batteries

  • Kim, Hyung-Sun;Chung, Kyung-Yoon;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.11 no.1
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    • pp.37-41
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    • 2008
  • The effects of carbon-coated silicon anode on the electrochemical properties and structural change were investigated. The carbon-coated silicon powders have been prepared by thermal decomposition under argon/10wt% propylene mixed gas flow at $700^{\circ}C$. The surface and crystal structure of the synthesized materials were examined by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Raman spectroscopy. Lithium cells with electrodes made from the uncoated and the carbon coated silicon anode were assembled and tested. The carbon-coated silicon particles merged together well after the insertion/extraction of lithium ions, and showed a relatively low irreversible capacity compared with the uncoated silicon particle.

An Artificial Neural Network for Efficiently Learning and Representation the Advection and Remove of Fire-Flake Particles (불똥 입자의 이류과 삭제를 효율적으로 학습 표현하는 인공신경망)

  • Kim, Donghui;Kim, Jong-Hyun
    • Proceedings of the Korean Society of Computer Information Conference
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    • 2022.01a
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    • pp.345-348
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    • 2022
  • 본 논문에서는 유체 시뮬레이션(Fluid simulation)중 화염에서 표현되는 불똥 입자(Fire-flake particle)의 생성, 움직임과 삭제를 효율적으로 학습하고 표현할 수 있는 인공지능 기법에 대해 소개한다. 유체 시뮬레이션을 계산하기 위해서는 일반적으로 수치해석학과 같은 학문의 이해가 필요하며 불똥이나 거품과 같은 유체의 2차 효과(Secondary effect)는 기반유체(Underlying fluids)를 통해 추출되기 때문에 복잡하고 계산양이 많아진다. 이러한 문제를 완화하고자 본 논문에서는 인공신경망을 이용한 분류 모델 학습을 통해 격자 내에서 표현되어야 하는 불똥 입자의 생성을 학습하고, 다항 회귀 모델 학습을 통해 불똥 입자의 움직임을 예측한다. 또한, 불똥 입자가 삭제되어야하는 상태를 네트워크 학습을 통해 얻어내며, 수명(Lifespan) 임계값 조절하여 다양한 장면에서 불똥을 제어할 수 있다. 결과적으로 화염의 움직임을 기반으로 불똥의 움직임을 복잡한 수학식이나 디자이너에게 의존하지 않고 인공지능 학습을 통해 쉽게 제어하고 예측하는 결과를 보여준다.

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Secondary Air Injection Effect on Cold Flow in a Laboratory-scale Circulating Fluidized Bed Combustor (실험실 규모 순환유동층 연소로에서 2차공기 주입이 냉간유동에 미치는 영향)

  • Jang, S.D.;La, S.H.;Hwang, J.H.;Kang, K.T.
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.217-228
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    • 2000
  • Circulating Fluidized Bed Combustor(CFBC) has been used for the incineration of waste sewage sludge and for the power generation. In this study hydrodynamic characteristics of two phase flow have been studied in a riser section of CFBC. A lab-scale riser is designed and SiC (Geldart type B) is used for solid particles. Experiments are performed by controlling the fluidization parameters including superficial velocity and secondary air to primary air ratio for determination of solid holdup profiles in the riser. Superficial velocities of each fluidization regime are well agreed with results predicted by a theoretical model. The results show that the axial solid holdup distributions calculated by measuring differential static pressures in the riser are found to show a basic profile described by a simple exponential function. Our flow regime during experiments mainly belongs to fast fluidization regime for particle size of 300${\mu}m$. As the SA/PA ratio increases, solid holdup in the lower dense region of the riser increases.

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Numerical Analysis on the Flow Characteristics Considering the Inspiratory Flow Rate in a Human Airway (수치해석 기법을 이용한 호흡 유량에 따른 사람의 기도 내 유동 특성 연구)

  • Sung, Kun Hyuk;Ryou, Hong Sun
    • Journal of Biomedical Engineering Research
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    • v.33 no.4
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    • pp.177-183
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    • 2012
  • The inspiratory flow rate of a human is changed with the amount of the workload. The flow characteristic is affected by the inspiratory flow rate. In the flow field of airway, the both of turbulence intensity and secondary flow affect the deposition pattern of particles which is important for the drug-aerosol targeting. Thus the analysis of the flow characteristic in a human airway is important. The purpose of this study is to investigate the effects of the inspiratory flow rate on the flow characteristics in a human airway. The tubular airway is consistent with the oral cavity, pharynx, larynx and trachea. The relatively inspiratory flow rate is used at each case of human states regarding the workload. By the effect of geometric airway changes, transition to turbulent airflow after the larynx can occur with relaminarization further downstream. The low Reynolds number k-${\omega}$ turbulence model is used for analysis with flow regime. As the inspiratory flow rate is larger, the turbulence kinetic energy and secondary flow intensity increase in airway. On the other hand, the area of recirculation zone is smaller.

Effect of Heating Rate on the Behavior of the Flame Front in the Pulverized-Coal Flame (미분탄화염에서 가열률이 화염선단의 거동에 미치는 영향)

  • Cho, Han Chang;Park, Jung Kyu;Shin, Hyun Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.5
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    • pp.687-694
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    • 1999
  • An experimental study was carried out in two laboratory-scale reactors to investigate the effect of heating rate on the behavior of flame front in a pulverized coal flame. Each. reactors had different heating mechanisms. For reactor A losing large heat through transparent quartz wall. pulverized coal particles were ignited by secondary air of 1050K. Flame front could be visualized through the transparent wall. Reactor B was insulated with castable refractory to minimize the heat loss through the reactor wall and accompanied with secondary air of 573K. Flame front was estimated from the gas temperature and species concentration measured using R-type thermocouple(Pt-Pt/Rh 13%) and gas chromatograph at various coal-air ratios and swirl intensities. The flame front position was closely related with the magnitude of heating rate. The heating rate for lifted flame was of the order of $10^4$ to $10^5K/s$ and for coal Ignition at least over $10^4K/s$. The heating mechanism had little impact on the extinction limits. The weak swirl number of 0.68 forced the flame front to move toward the upstream by the rapid mixing of coal and air. The primary/secondary momentum ratio was an inappropriate variable to distinct the liftoff of flame.

Fabrication of Ag doped Hydroxyapatite and its Antimicrobial Effects with the Particle Size

  • Oh, Kyung-Sik;Kim, Kyung-Ja;Jeong, Young-Keun
    • Journal of Powder Materials
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    • v.8 no.3
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    • pp.192-196
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    • 2001
  • Ag doped Hydroxyapatite powder in nano-scale was successfully synthesized either by co-precipitation or by ion exchange route. The fabricated powder was successfully dispersed through freeze drying due to the prevention of secondary particles. The antimicrobial effects of nano-HAp against E.coli was superior to micron ones not only in its strength but also in duration.

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Mineralogy of Low-Grade Uranium Ores in the Black Slate of the Ogcheon Group, Korea (옥천계(沃川系) 흑색(黑色)슬레이트내(內) 부존(賦存)하는 저품질(低品質) 우라늄광석(鑛石)에 대(對)한 광물학적(鑛物學的) 연구(硏究))

  • Lee, Dong-Jin
    • Economic and Environmental Geology
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    • v.19 no.2
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    • pp.133-146
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    • 1986
  • Primary uraninite and secondary uranium minerals such as torbernite, metatorbernite, tyuyamunite, metatyuyamunite, autunite and metaautunite have been identified from various types of uranium ores. Uranium minerals occur as accessory minerals in both the primary and secondary ores. Low·grade uranium ores consist of various kinds of primary and secondary minerals. Major constituent minerals of primary uranium ores are graphite. quartz. Ba-feldspar and sericite/muscovite, and accessories are calcite, chlorite, fluorapatite, barite, diopside, sphene, rutile, biotite, laumontite, heulandite, pyrite, sphalerite and chalcopyrite, and secondary minerals consist of kaolinite, gypsum and goethite. Uraninite grains occur as microscopic very fine-grained anhedral to euhedral disseminated particles in the graphitic matrix, showing well·stratified or zonal distribution of uranium on auto-radiographs of low-grade uranium ores. Some uraninite grains are closely associated with very fine-grained pyrite aggregates, showing an elliptical form parallel to the schistosity. Some uraninite grains include extremely fine-grained pyrite particle. Sphalerite and pyrite are often associated with uraninite in graphite-fluorapatite nodule. The size of uraninite is $2{\mu}m$ to $20{\mu}m$ in diameter. Low-grade uranium ores are classified into 5 types on the basis of geometrical pattern of mineralization. They are massive, banded, nodular, quartz or sulfide veinlet-rich and cavity filling types. Well-developed alternation of uranium-rich and uranium-poor layers, concentric distribution of uranium in graphite-fluorapatite nodule and geopetal fabrics due to the load cast of the nodule suggest that the uranium was originally deposited syngenetically. Uraninite crystals might have been formed from organo-uranium complex during diagenesis and recrystallized by metamorphism. Secondary uranium minerals such as torbernite, tyuyamunite and autunite have been formed by supergene leaching of primary ores and subsequent crystallization in cavities.

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The Flow of the Interstellar Plasmas surrounding the Heliopause estimated via IBEX-Lo Observations

  • Park, Jeewoo;Kucharek, Harald;Isenberg, Philip A.;Paschalidis, Nikolaos
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.1
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    • pp.51.3-52
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    • 2018
  • Since Voyager 1 passed the Heliopause in 2012, it has provided the observations of the charged particles in the local interstellar medium. However, Voyager 1 only provides the information along with its trajectory. In order to understand the global view of the interstellar plasma flow surrounding the Heliopause, we need another tool. When the interstellar plasmas approach the Heliopause, the ions are deflected around the Heliopause due to the draping of the interstellar magnetic field. The draping of the interstellar magnetic field is strongly connected with the shape of the Heliopause. A fraction of the diverted ions exchanges their charges with the undisturbed primary interstellar neutral atoms, and then the ions become neutral atoms called the secondary interstellar neutral atoms. The newly created neutral atoms carry information on the diverted flow of the interstellar ions, and a fraction of them can travel to the Sun. Therefore, the secondary component of the interstellar neutrals is an excellent diagnostic tool to provide important information to constrain the shape of the Heliopause. The secondary interstellar neutrals are observed by Interstellar Boundary Explorer (IBEX) at Earth's orbit. Since 2009, two energetic neutral atom cameras on IBEX have measured neutral atoms and it has provided sky maps of neutral atoms. In this presentation, we will discuss the directional distribution of the secondary interstellar neutrals at Earth's orbit. In the sky maps, the primary interstellar neutral gas is seen between $200^{\circ}$ and $260^{\circ}$ in ecliptic longitude and the secondary components are seen in the longitude range of $160^{\circ}-200^{\circ}$. We also present a simplified model of the outer heliosheath to help interpret the observations of interstellar neutrals by the IBEX-Lo instruments. We extract information on the large-scale shape of the Heliopause by comparing the neutral flux measured at IBEX along four different look directions with simple models of deflected plasma flow around hypothetical obstacles of different aspect ratios to the flow. Our comparisons between the model results and the observations indicate that the Heliopause is very blunt in the vicinity of the Heliospheric nose, especially compared to a Rankine half-body or cometary shape.

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Improvement in the Dispersion Stability of Iron Oxide (Magnetite, Fe3O4) Particles with Polymer Dispersant Inject (고분자 분산제 주입을 통한 철산화물(Magnetite, Fe3O4) 입자의 분산 안정성 향상)

  • Song, Geun Dong;Kim, Mun Hwan;Lee, Yong Taek;Maeng, Wan Young
    • Applied Chemistry for Engineering
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    • v.24 no.6
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    • pp.656-662
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    • 2013
  • The iron oxide ($Fe_3O_4$) particles in the coolant of the secondary system of a nuclear power plant reduce the heat transfer performance or induce corrosion on the surface of the heat transfer tube. To prevent these problems, we conducted a study to improve the dispersion stability of iron oxide using polymeric dispersant injection in simulated secondary system water. The three kinds of anionic polymers containing carboxyl groups were selected. The dispersion characteristics of the iron oxide particles with the polymeric dispersants were evaluated by performing a settling test and measuring the transmission, the zeta potential, and the hydrodynamic particle size of the colloid solutions. Polymeric dispersants had a significant impact on the iron oxide dispersion stability in an aqueous solution. While the dispersant injection tended to improve the dispersion stability, the dispersion stability of iron oxide did not increase linearly with an increase in the dispersant concentration. This non-linearity is due to the agglomerations between the iron oxide particles above a critical dispersant concentration. The effect of the dispersant on the dispersion stability improvement was significant when the dispersant concentration ratio (ppm, dispersant/magnetite) was in the range of 0.1 to 0.01. This suggests that the optimization of dispersant concentration is required to maximize the iron oxide removal effect with the dispersant injection considering the applied environments, the iron oxide concentration and the concentration ratio of dispersant to iron oxide.