• Title/Summary/Keyword: Secondary formation

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Preparation of zirconia coated graphite powders

  • Kim, J.H.;Lee, K.G.;Lee, S.K.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.45-48
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    • 1997
  • ZrO$_2$ coated flake graphite powders were prepared by the controlled hydrolysis of zirconium oxichloride. The stirring process plays an important role in the coating process. There are two types of coated ZrO$_2$ particles: (a)primary particles with few nm size were obtained by the direct formation of the shell by precipitation of the surface of the graphite and (b) Secondary particles of ZrO$_2$ with ∼0.1$\mu\textrm{m}$ size were obtained by the independent formation of primary particles ZrO$_2$ and subsequent heterocoagulation at the graphites surface.

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A Study the THMs Formation by Chloramination Disinfection (클로라민 소독에 의한 THMs 생성에 관한 연구)

  • 김평청;우달식;남상호
    • Journal of environmental and Sanitary engineering
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    • v.14 no.1
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    • pp.11-16
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    • 1999
  • This study was performed to investigate THMs formation by chloramination as a secondary disinfection in drinking water distribution system. As the $Cl_2/NH_3-N$ ratio increased from 1:1 to 4:1, the THMs concentration had actually no change in the breakpoint curve of pH 6, 7. At pH 8, THMs level was not augmented at between 1:1 and 5:1. In the $Cl_2/NH_3-N$ ratio of more than 5:1 and 6:1 respectively, THMs level was raised. Only the chloroform of THMs was insignificantly detected by both preformed chloramine and preammoniation applications, which was probably attributed to the stoichiometrically unstable equilibrium in the preparation of chloramine, whereas $CHCl_3$, $CHCl_2Br$ and $CHClBr_2$ of THMs were found in the application of free chlorine. However it turned out that the THMs levels by chloramine was incomparably inferior to that of free chlorine.

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A Study of Abnormal Expansion to be Synthesized Barium Titanate in Solid-solid Reaction (Barium Titanate를 고상반응으로 합성할때 일어나는 이상팽창에 관한 연구)

  • 이은상;임대영
    • Journal of the Korean Ceramic Society
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    • v.22 no.6
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    • pp.9-14
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    • 1985
  • When the barium titanate is Synthesized in Solid-solid reaction the abnormal expansion occurs at about 110$0^{\circ}C$. The mixture was made of corresponding to the theoretical composition of barium titanate. The mixture was fired at various temperature from 90$0^{\circ}C$ to 130$0^{\circ}C$, After that the specimen was tested closely with XDR dilatometer and SEM. The results indicate that 1, The activation energy of barium titanate formation was 42 Kcal/mole. 2, Thermal expansion up to to 90$0^{\circ}C$ was mainly caused by $CO_2$ whereas it was mainly caused by the formation of the secondary phase above 100$0^{\circ}C$. 3. Thermal expansion was not influenced by the forming pressure up to 1000kg/$cm^2$ but it was largely influenced bythe forming pressure above 200kg/$cm^2$.

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Formation Mechanism of Surface Crack and Its Control on Continuously Cast Slabs of Nb-containing Austenitic Stainless Steel (Nb 첨가 오스테나이트계 스테인레스강의 연속주조시 표면크랙 형성기구 및 제어)

  • Shim, Sang-Dae;Kim, Sun-Koo
    • Journal of Korea Foundry Society
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    • v.21 no.5
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    • pp.280-285
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    • 2001
  • Nb-containing austenitic stainless steel is widely used as exhaust frame and diffuser assembly in power plant. However, this steel is known to be difficult to produce by the continuous casting process due to the surface cracks. Therefore, the continuous casting technology was developed for the prevention of the surface cracks on CC slabs. Precipitates and the analysis of heat trasfer in a slab were investigated in order to find out the formation mechanism of surface cracks on cc slabs It was found that surface cracks are occurred due to the NbC precipitates, which are formed along the grain boundaries around $800^{\circ}C$. The secondary cooling pattern has been developed to produce the defect free CC slabs of Nb-containing austenitic stainless steel.

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An analytical Machining models based on Flow Stress Properties for Non-Heat Treated and Heat Treated AISI 4140 Steel (열처리 및 비 열처리 AISI4140강의 유동응력 물성치를 기초로 하는 해석적 가공 모델 연구)

  • Lee, Tae-Hong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.4
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    • pp.419-426
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    • 2011
  • In this study, an experimental and theoretical program were carried out to determine the cutting forces and chip formation at different cutting speeds using a 0.4mm nose radius ceramic insert and -7 rake angle for non heat-treated AISI 4140 (27HRc) and heat-treated AISI 4140 (45 HRc) steel. The results obtained were compared to show the hardness differences between the materials. The secondary deformation zone thicknesses when comparing the two materials show different physical structure but similar size. These results were also discussed in light of the heat treatment and the effects it had on the machining characteristics of the material. In addition, the Oxley Machining Theory was used to predict the cutting forces for these materials and a comparison made. The predicted cutting performances were verified experimentally and showed good agreement with experimental data.

Osteoma of the Frontal Sinus with Secondary Subdural Empyema Formation

  • Cho, Sung-Yun;Kim, Jeong-Whun;Kim, Chae-Yong
    • Journal of Korean Neurosurgical Society
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    • v.40 no.3
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    • pp.202-205
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    • 2006
  • Osteomas of the paranasal sinuses rarely lead to intracranial manifestations. The authors report an unusual case of a frontal sinus osteoma leading to subdural emyema formation. A 19-year-old man presented with headache and fever one month after minor facial trauma. Neuroradiological studies revealed subdural empyema in left frontal lobe with moderate cerebral edema and a osteoma in the left frontal sinus with sinusitis of maxillary sinus. The patient was surgically treated in one stage operation of decompressive craniectomy, removal of subdural empyema with frontal sinus osteoma, and endoscopic sinus surgery via cranial and nasal route. The patient recovered very well after surgery and postoperative antibiotic therapy. The etiology of intracranial infection and the treatment strategy are to be discussed.

A new type of helix in protein structure.

  • Son, Hyeon-S.
    • Proceedings of the Korean Society for Bioinformatics Conference
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    • 2000.11a
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    • pp.86-87
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    • 2000
  • Protein folding is a fundamental problem in structural bioinformatics and so numerous studies have been devoted to the subject. As the most common regular secondary conformation in proteins, helix has been an important ingredient of the protein folding problem. In particular, alanine based polypeptides are widely studied to identify the helix folding process in that the aianine amino acid is known to have one of the highest helix propensities. In principle, intrinsic helix propensities can be obtained from gas-phase measurements where solvent effect is absent. Hudgins et al. studied alanine-based peptides in vacuo using high-resolution ion mobility measurement technique. It was reported that introduction of a single Iysine at the C terminus resulted in the formation of very stable, monomeric polyalanine helices. We also have investigated helix formation in vacuo with different terminal charge conditions; we have found a new type of helix motif, To the best of our knowledge, this type of helix conformation has not been characterized before and we name it as I-helix.

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A Study on the Mixture Formation in a Fuel Injection System (연료분사장치의 혼합기 형성에 관한 연구)

  • ;;;Lee, K. H.;Seo, Y. H.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.10
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    • pp.2690-2698
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    • 1995
  • Fuel atomization and mixture formation in an gasoline engine has influence on the engine performance and pollutant emission. The throttle valve installed in an intake system plays a greater role in control of mixture quantity in accordance with engine drive condition. In this study, the characteristics of secondary atomization developed at the downstream of the valves were observed using an image processing method. Two major kinds of valves, solid and perforated ones, are chosen in order to compare the valve performance with the experimental parameters of air flow rate, valve opening angle, and valve shapes. For the perforated valve, we can obtain the relatively small sized droplets, and nearly uniformed and dense distributed sprays with low loss coefficient than for the solid valve.

Re-formation plan of open dumping landfill for coastal management (연안환경관리를 위한 연안불량매립지 교정방법 비교고찰)

  • Yoon, Sung-Yoon
    • Journal of Wetlands Research
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    • v.2 no.2
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    • pp.109-116
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    • 2000
  • The equipment of a landfill need whole cut off facilities so that leachate generated from the landfill primarily do not leak to the ocean. Also, the whole collected leachate need a consecutive clarification treatment to discharge. A method is considered the best among the three alternatives. The merits of this method are as follows; have no secondary pollution. can cut down the expense of treatment, have good effects on preventing external leakage, don't need a leachate well, reliable quality control and easy post management. The weaknesses of this method are as follows; need a thorough survey about underground water and quality of the soil, need a special process to use as the land.

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Synthesis of zeolite MFI films on alumina and silicon supports using seed crystals (알루미나와 실리콘 지지체에 종자결정에 의한 제올라이트 MFI 필름의 합성)

  • Ko, Tae-Seog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.1
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    • pp.38-44
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    • 2008
  • Contiuous c-oriented zeolite MFI films $(<35{\mu}m)$ were prepared by hydrothermal secondary growth of silicalite-1 seed crystal in the surface of alumina porous substrate and silicon substrate. The supported films were characterized with scanning electron microscopy and X-ray diffraction. Effect of substrate surface roughness were investigated and a mechanism for c-oriented film formation and characteristic dom-like defects formation which is observed after seeding growth was discussed. The roughness of substrate plays an important role.