• Title/Summary/Keyword: Secondary air

Search Result 901, Processing Time 0.034 seconds

Effect of Air Stagnation Conditions on Mass Size Distributions of Water-soluble Aerosol Particles (대기 정체와 수용성 에어로졸 입자의 질량크기분포의 관계)

  • Park, Seungshik;Yu, Geun-Hye
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.34 no.3
    • /
    • pp.418-429
    • /
    • 2018
  • Measurements of 24-hr size-segregated ambient particles were made at an urban site of Gwangju under high pressure conditions occurred in the Korean Peninsula late in March 2018. The aim of this study was to understand the effect of air stagnation on mass size distributions and formation pathways of water-soluble organic and inorganic components. During the study period, the $NO_3{^-}$, $SO_4{^{2-}}$, $NH_4{^+}$, water-soluble organic carbon (WSOC), and humic-like substances(HULIS) exhibited mostly bi-modal size distributions peaking at 1.0 and $6.2{\mu}m$, with predominant droplet modes. In particular, outstanding droplet mode size distributions were observed on March 25 when a severe haze occurred due to stable air conditions and long range transport of aerosol particles from northeastern regions of China. Air stagnation conditions and high relative humidity during the study period resulted in accumulation of primary aerosol particles from local emission sources and enhanced formation of secondary ionic and organic aerosols through aqueous-phase oxidations of $SO_2$, $NO_2$, $NH_3$, and volatile organic compounds, leading to their dominant droplet mode size distributions at particle size of $1.0{\mu}m$. From the size distribution of $K^+$ in accumulation mode, it can be inferred that in addition to the secondary organic aerosol formations, accumulation mode WSOC and HULIS could be partly attributed to biomass burning emissions.

Synthesis and Characterizations of Mn1+XCo2-XO4 Solid Solution Catalysts for Highly Efficient Li/Air Secondary Battery (고효율의 리튬/공기 이차전지 공기전극용 Mn1+XCo2-XO4 고용체 촉매 합성 및 분석)

  • Park, Inyeong;Jang, Jaeyong;Lim, Dongwook;Kim, Taewoo;Shim, Sang Eun;Park, Seok Hoon;Baeck, Sung-Hyeon
    • Journal of the Korean Electrochemical Society
    • /
    • v.18 no.4
    • /
    • pp.137-142
    • /
    • 2015
  • $Mn_{1+X}Co_{2-X}O_4$ solid solutions with various Mn/Co ratios were synthesized by a combustion method, and used as cathode catalysts for lithium/air secondary battery. Their electrochemical and physicochemical properties were investigated. The morphology was examined by transmission electron microscopy (TEM), and the crystallinity was confirmed by X-ray diffraction (XRD) analyses. For the measurement of electrochemical properties, charge and discharge measurements were carried out at a constant current density of $0.2mA/cm^2$, monitoring the voltage change. Electrochemical impedance spectroscopy (EIS) analyses were also employed to examine the change in charge transfer resistance during charge-discharge process. $Mn_{1+X}Co_{2-X}O_4$ solid solutions showed enhanced cycleability as a cathode of Li/air secondary battery, and the performance was found to be strongly dependent on Mn/Co ratio. Among synthesized catalysts, $Mn_{1.5}Co_{1.5}O_4$ exhibited the best performance and cycleability, due to high charge transfer rate.

Consideration of Ozone Removal and Control in Built Environment by Building Materials (건축자재에 의한 실내 오존제거 및 제어에 대한 고찰)

  • Chung, Ok-Young;Jeong, Su-Gwang;Kim, Jun-Hyun;Kim, Su-Min
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.24 no.6
    • /
    • pp.467-475
    • /
    • 2012
  • Recently, residents have been spending almost 90% of their time indoors, which presents a higher risk from inhalation of pollutants than when spending time outdoors. Therefore, controlling indoor air quality became important. It is reported that the lung diseases and mortality for occupants are increased when there is high density of ozone which is one of the pollutants among the indoor air. In addition, the reactions between ozone and building materials produce VOCs and formaldehyde. The studies to eliminate the ozone by building materials have been actively investigated. However, ozone removal and secondary pollutants from ozone reactions with building materials have not been reported in Korea. For this reason, the aim of this study is to introduce ozone removal by HVAC filters, various building materials, and eco-friendly building materials including the quantity of secondary pollutant emissions.

Investigation on Characteristics of High PM2.5 Pollution Occurred during October 2015 in Gwangju (광주 지역에서 2015년 10월에 발생한 PM2.5 고농도 사례 특성 분석)

  • Yu, Geun-Hye;Park, Seung-Shik;Jung, Sun A;Jo, Mi Ra;Lim, Yong Jae;Shin, Hye Jung;Lee, Sang Bo;Ghim, Young Sung
    • Journal of Korean Society for Atmospheric Environment
    • /
    • v.34 no.4
    • /
    • pp.567-587
    • /
    • 2018
  • A severe haze event occurred in October 2015 in Gwangju, Korea. In this study, the driving chemical species and the formation mechanisms of $PM_{2.5}$ pollution were investigated to better understand the haze event. Hourly concentrations of $PM_{2.5}$, organic and elemental carbon, water-soluble ions, and elemental constituents were measured at the air quality intensive monitoring station in Gwangju. The haze event occurred was attributed to a significant contribution (72.3%) of secondary inorganic species concentration to the $PM_{2.5}$, along with the contribution of organic aerosols that were strongly attributed to traffic emissions over the study site. MODIS images, weather charts, and air mass backward trajectories supported the significant impact of long-range transportation (LTP) of aerosol particles from northeastern China on haze formation over Gwangju in October 2015. The driving factor for the haze formation was stagnant atmospheric flows around the Korean peninsula, and high relative humidity (RH) promoted the haze formation at the site. Under the high RH conditions, $SO{_4}^{2-}$ and $NO_3{^-}$ were mainly produced through the heterogenous aqueous-phase reactions of $SO_2$ and $NO_2$, respectively. Moreover, hourly $O_3$ concentration during the study period was highly elevated, with hourly peaks ranging from 79 to 95ppb, suggesting that photochemical reaction was a possible formation process of secondary aerosols. Over the $PM_{2.5}$ pollution, behavior and formation of secondary ionic species varied with the difference in the impact of LTP. Prior to October 19 when the influence of LTP was low, increasing rate in $NO_3{^-}$ was greater than that in $NO_2$, but both $SO_2$ and $SO{_4}^{2-}$ had similar increasing rates. While, after October 20 when the impact of haze by LTP was significant, $SO{_4}^{2-}$ and $NO_3{^-}$ concentrations increased significantly more than their gaseous precursors, but with greater increasing rate of $NO_3{^-}$. These results suggest the enhanced secondary transformation of $SO_2$ and $NO_2$ during the haze event. Overall, the result from the study suggests that control of anthropogenic combustion sources including vehicle emissions is needed to reduce the high levels of nitrogen oxide and $NO_3{^-}$ and the high $PM_{2.5}$ pollution occurred over fall season in Gwangju.

An Improved High Efficiency Resonant Converter for the Contactless Power Supply with a Low Coupling Transformer (낮은 커플링 변압기를 갖는 비접촉 전원의 개선된 고효율 공진 컨버터)

  • Kong Young-Su;Kim Eun-Soo;Lee Hyun-Kwan
    • The Transactions of the Korean Institute of Electrical Engineers B
    • /
    • v.54 no.1
    • /
    • pp.33-39
    • /
    • 2005
  • Comparing with the conventional transformer without the air gap, a contactless transformer with the large air gap between the long primary winding and the secondary winding has increased leakage inductance and reduced magnetizing inductance. For transferring the primary power to the secondary one, the high frequency series resonant converter has been widely used for the contactless power supply system with the large air gap and the increased leakage inductance of the contactless transformer However, the high frequency series resonant converter has the disadvantages of the low efficiency and high voltage gain characteristics in the overall load range due to the large air gap and the circulating magnetizing current. In this paper, the characteristics of the high efficiency and unit voltage gain are revealed in the proposed three-level series-parallel resonant converter. The results are verified on the simulation based on the theoretical analysis and the 5kW experimental prototype.

Advanced Secondary Wastewater Treatment Using the DOF (Dissolved Ozone Flotation) System (DOF(Dissolved Ozone Flotation) 시스템을 이용한 하수처리장 방류수의 고도처리에 대한 연구)

  • Lee, Byoung Ho;Kim, Sang Hee
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.19 no.6
    • /
    • pp.767-774
    • /
    • 2005
  • The DOF (Dissolved Ozone Flotation) system was used to treat the effluent of the secondary wastewater treatment plant. The DOF system uses ozone instead of air, while DAF (Dissolved Air Flotation) uses air. Moreover, since the solubility of ozone is higher than air, the DOF system produces larger volume of micro-bubbles than the DAF system does. Thus, the DOF system performs better than the DAF system in floating ability. The DOF system could remove 70% of turbidity to an average of 0.59NTU in effluent from 2.31NTU in influent. The removal efficiency of absorbance measured with UV-254 in the effluent of the DOF system was 63%, while only 19% was removed by the DAF system. the DOF system removed 84% of the color from 25~26CU to 4CU, while DAF system removed 42% of the color to 15 CU. The CODMn removal efficiency of the DOF system was 34%, 6.8mg/l of effluent $COD_{Mn}$ concentratin, while it was 20%, 8.3mg/L of effluent $COD_{Mn}$ concentratin, to use the DAF system. Microbial bacteria such as coliform bacteria, and heterotrophic bacteria were removed over 99% by the DOF system, and 42~45% by the DAF system. That is, Microbial bacteria were almost completely destroyed by the DOF system. To sum up with, the DOF system was found to be very effective to treat effluent of the wastewater treatment plant.

Characteristics of long-range transported PM2.5 at a coastal city using the single particle aerosol mass spectrometry

  • Cai, Qiuliang;Tong, Lei;Zhang, Jingjing;Zheng, Jie;He, Mengmeng;Lin, Jiamei;Chen, Xiaoqiu;Xiao, Hang
    • Environmental Engineering Research
    • /
    • v.24 no.4
    • /
    • pp.690-698
    • /
    • 2019
  • Air pollution has attracted ever-increasing attention because of its substantial influence on air quality and human health. To better understand the characteristics of long-range transported pollution, the single particle chemical composition and size were investigated by the single particle aerosol mass spectrometry in Fuzhou, China from 17th to 22nd January, 2016. The results showed that the haze was mainly caused by the transport of cold air mass under higher wind speed (10 m·s-1) from the Yangtze River Delta region to Fuzhou. The number concentration elevated from 1,000 to 4,500 #·h-1, and the composition of mobile source and secondary aerosol increased from 24.3% to 30.9% and from 16.0% to 22.5%, respectively. Then, the haze was eliminated by the clean air mass from the sea as indicated by a sharp decrease of particle number concentration from 4,500 to 1,000 #·h-1. The composition of secondary aerosol and mobile sources decreased from 29.3% to 23.5% and from 30.9% to 23.1%, respectively. The particles with the size ranging from 0.5 to 1.5 ㎛ were mainly in the accumulation mode. The stationary source, mobile source, and secondary aerosol contributed to over 70% of the potential sources. These results will help to understand the physical and chemical characteristics of long- range transported pollutants.