• Title/Summary/Keyword: Secondary Pollution

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Investigation on the operational state of the public food waste treatment facilities and suggestions on their efficient operational management (음식물류폐기물 공공 자원화시설의 운영실태 조사를 통한 처리공정별 효율적인 운영방안 검토)

  • Jang, Yun-Hyeok;Park, Joon-Seok;Kim, Joung-Dae;Phae, Chae-Gun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.1
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    • pp.47-56
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    • 2010
  • At present, 265 national food waste recycling facilities have been operated by public facilities 95 and private facilities 160. it has continuously installed a food waste treatment facility from 1997. The government set up and implemented guidelines and inspection standards for the installation and operation of the facilities. However, unclear detailed examination items, designs and process standards for the installation procedures of the facilities are causing problems due to the unskilled operation management system, decrease in efficiency and defects of a facility. This study conducted mail and site surveys on 95 public food waste recycling facilities that it suggest the ways to operate facilities which minimize problems. At the result of investigation, a pre-treatment facility was not installed 2 systems(2 inputting facilities) and hopper covers and food was overloaded. also the transportation amount was excessive. In case of a main treatment facility, the secondary environmental pollution was caused by inexperienced operation and the efficiency of the facility was reduced due to excessive input of food. also the operation management standards of the facilities were inappropriate. The odor and food waste leachate treatment facility is investigated as problems that are unskilled operation, lack of regular inspection and inappropriate capacity of the treatment facility. Based on the problems found through the investigation, it suggested some ways of efficient operation. this study might contribute to minimize mistakes and defects and improve the efficiency of install and operation course of food waste recycling facilities through finding.

Geochemistry, Secondary Contamination and Heavy Metal Behavior of Soils and Sediments in the Tohyun Mine Creek, Korea (토현광산 수계에 분포하는 토양과 퇴적물의 지구화학적 특성, 이차적 오염 및 중금속의 거동)

  • 이찬희;이현구;윤경무
    • Economic and Environmental Geology
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    • v.34 no.1
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    • pp.39-53
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    • 2001
  • Environmental pollution of the Tohyun mine creek area was investigated on the basis of geology, mineralogy and geochemistry. In soils and sediments of the mine area, ${Al_2}{O_3}/{Na_2O}$ and ${K_2}O/{Na_2}O$ ratios are partly negative correlation against ${SiO_2}/{Al_2}{O_3}$, respectively. Geochemical characteristics of some trace and rare earth elements such as V/Ni, Ni/Co, La/Ce, Th/Yb, Th/U, La/Th, ${La_N}/{Yb_N}$, La/Sc and Sc/Th are revealed a narrow range and homogeneous compositions may be explained by simple source lithology. These results suggest that sediments source of the host shale around the mine area could be originated by basic to intermediate igneous rocks. Mineral compositions of soil and sediment near the mine area were partly variable mineralogy, which are composed of quartz, mica, feldspar, chlorite, clay minerals and some pyrite. Soils and sediments with highly concentrated heavy minerals, gravity separated mineralogy, are composed of some pyrite, arsenopyrite, chalcopyrite, sphalerite, galena, goethite and various kinds of hydroxide minerals on the polished sections. As normalized by bed rock composition, average enrichment indices of major elements in sediments, precipitates, farmland soils and paddy soils are 1.0, 1.7, 0.9 and 0.8, respectively. Maximum concentration of environmental toxic elements in the mine creek are detected with Ag = 186 ppm, As = 17,100 ppm, Bi = ]27 ppm, Cd = 77 ppm, Cu = 12,299 ppm, Pb = 8,897 ppm, Sb = 1,350 ppm, W = 599 ppm and Zn = 12,250 ppm, which are increasing with total FeO increasing, and extremely high concentrations of surface sediments and precipitates near the waste rock dump. These toxic elements (As, Bi, Cd, Cu, Pb, Sb, W and Zn) of the samples, normalizing by host rock concentration, revealed that average enrichment index is 106.0 for sediments, 279.6 for precipitates, 3.5 for farmland soils and 1.6 for paddy soils. However, on the basis of EPA values, enrichment indices of all the samples are 40.7, 121.4, 1.3 and 0.6, respectively.

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The Effects of Carbonate Minerals in Gully-pot Sediment on the Leaching Behavior of Heavy Metals Under Acidified Environment (우수관퇴적물에 함유된 탄산염광물이 산성환경에서의 중금속 용출거동에 미치는 영향 평가)

  • 이평구;유연희
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.257-271
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    • 2002
  • One of the main interests in relation to heavily contaminated gully-pot sediment in urban area is the short term mobility of heavy metals, which depends on the pH of acidic rainwater and on the buffering effects of carbonate minerals. The buffering effects of carbonates are determined by titration (acid addition). Leaching experiments are carried out in solutions with variable initial HN03 contents for 24h. The gully-pot sediment appears to be predominantly buffered by calcite and dolomite. In case of sediment samples, which highly contain carbonates, pH decreases more slowly with increasing acidity. On the other hand, for the sediment samples, which less contain carbonate minerals, pH rapidly drops until it reaches about 2 then it decreases slowly. The leaching reactions are delayed until more acid is added to compensate for the buffering effects of carbonates. The Zn, Cu, Pb and Mn concentrations of leachate rapidly increase with decreased pH, while Cd, Co, Ni, Cr and Fe dissolutions are very slow and limited. The solubility of heavy metals depends not only on thc pH values of leachatc but also on the speciation in which metals are associated with sediment particles. In slightly to moderately acid conditions, Zn, Cd, Co, Ni and Cu dissolutions become increasingly important. As deduced from leaching runs, the relative mobility of heavy metals at pH of 5 is found to be: Zn > Cd > Co > Ni > Cu » Pb > Cr, suggesting that moderately acid rainwater leach Zn, Cd, Co, Ni and Cu from thc contaminated gully-pot sediment, while Pb and Cr would remain fixed. The buffering effects of Ca- and Mg-carbonates play an important role in delaying as well as limiting the leaching reactions of heavy metals from highly contaminated gully-pot sediment. The extent of such a secondary environmental pollution will thus depends on how well the metals in sediment can be leached by somewhat acidic rain water. Changes in the physicochemical environments may result in the severe environmental pollution of heavy metals. These results are to be taken into account in the management of contaminated sediments during rainstorms.

Biological Water Quality Evaluation using the Benthic Macroinvertebrates in Miryang River (저서성 대형 무척추동물에 의한 밀양강의 생물학적 수질평가)

  • 박연규;박현철
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.7-18
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    • 1999
  • Fauna and biological water quality using benthic macroinvertebrates were analysed and estimated macroinvertebrates. Samples were collected 5 times from the 7 sites in the river between April and December 1997, and the results are summarized as follows. The taxa of benthic macroinvertebrates was totally composed 81 species, 45 genus, 37 families, 15 orders, 8 classes in 3 phyla. Among them, aquatic insects were mostly abundant as 65 species, and also, there were a species of oligochaetes, 2 species of hirundinida, 6 species of gastropods, 5 species of polecypoda, and 2 species of crustaceans. Average individual numbers in the whole sampling sites was 815 per square meter, and insects were abundant (Approx. 80%). Among the insects, the major taxa were respectively ephemeroptera (Approx. 70%) and trichoptera (Approx. 18%). According to the average individual numbers in each site, Chung-do stream (site 1) showed the highest appearance rate as 262 individual/ $m^3$ (32.2%), and the lowest value was at the end of Miryang River (site 7) as 38 individual / $m^3$(4.7%). The dominant species among the whole samples was Ecdyomurus levis Navas, and dominance indices was 0.3. In each site, Ecdyomurus levis Navas was dominant species from site 1 to site 5, and dominant species at site 6 and 7 was respectively Hirudinidae sp. 1. Species diversity index in total average of samples was 2.66. Average of species diversity index according to each study site was the highest value at site 4 (H'=3.47), and site 2, 1, 3, 5, 6, and 7 in that order. According to the water quality as biotic indices, GPI value was 1.49 in total average of Miryang river, and the pollution indices evaluated secondary water quality criteria as $\beta$-mesosaprobics. In each site, the best water quality was at site 3, and it revealed the first water quality criteria as Oligosaprobic. It was then site 1, 2, 4 and 5 in the order of water quality, and was evaluated secondary water quality criteria as $\beta$-mesosaprobics, respectively. Site 6 was also revealed the third water quality criteria as $\beta$-mesosaprobics. The worst water quality was at site 7, which revealed the third water quality criteria as a-mesosaprobics.

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Difference in Chemical Composition of PM2.5 and Investigation of its Causing Factors between 2013 and 2015 in Air Pollution Intensive Monitoring Stations (대기오염집중측정소별 2013~2015년 사이의 PM2.5 화학적 특성 차이 및 유발인자 조사)

  • Yu, Geun Hye;Park, Seung Shik;Ghim, Young Sung;Shin, Hye Jung;Lim, Cheol Soo;Ban, Soo Jin;Yu, Jeong Ah;Kang, Hyun Jung;Seo, Young Kyo;Kang, Kyeong Sik;Jo, Mi Ra;Jung, Sun A;Lee, Min Hee;Hwang, Tae Kyung;Kang, Byung Chul;Kim, Hyo Sun
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.1
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    • pp.16-37
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    • 2018
  • In this study, difference in chemical composition of $PM_{2.5}$ observed between the year 2013 and 2015 at six air quality intensive monitoring stations (Bangryenogdo (BR), Seoul (SL), Daejeon (DJ), Gwangju (GJ), Ulsan (US), and Jeju (JJ)) was investigated and the possible factors causing their difference were also discussed. $PM_{2.5}$, organic and elemental carbon (OC and EC), and water-soluble ionic species concentrations were observed on a hourly basis in the six stations. The difference in chemical composition by regions was examined based on emissions of gaseous criteria pollutants (CO, $SO_2$, and $NO_2$), meteorological parameters (wind speed, temperature, and relative humidity), and origins and transport pathways of air masses. For the years 2013 and 2014, annual average $PM_{2.5}$ was in the order of SL ($${\sim_=}DJ$$)>GJ>BR>US>JJ, but the highest concentration in 2015 was found at DJ, following by GJ ($${\sim_=}SJ$$)>BR>US>JJ. Similar patterns were found in $SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$. Lower $PM_{2.5}$ at SL than at DJ and GJ was resulted from low concentrations of secondary ionic species. Annual average concentrations of OC and EC by regions had no big difference among the years, but their patterns were distinct from the $PM_{2.5}$, $SO{_4}^{2-}$, $NO_3{^-}$, and $NH_4{^+}$ concentrations by regions. 4-day air mass backward trajectory calculations indicated that in the event of daily average $PM_{2.5}$ exceeding the monthly average values, >70% of the air masses reaching the all stations were coming from northeastern Chinese polluted regions, indicating the long-range transportation (LTP) was an important contributor to $PM_{2.5}$ and its chemical composition at the stations. Lower concentrations of secondary ionic species and $PM_{2.5}$ at SL in 2015 than those at DJ and GJ sites were due to the decrease in impact by LTP from polluted Chinese regions, rather than the difference in local emissions of criteria gas pollutants ($SO_2$, $NO_2$, and $NH_3$) among the SL, DJ, and GJ sites. The difference in annual average $SO{_4}^{2-}$ by regions was resulted from combination of the difference in local $SO_2$ emissions and chemical conversion of $SO_2$ to $SO{_4}^{2-}$, and LTP from China. However, the $SO{_4}^{2-}$ at the sites were more influenced by LTP than the formation by chemical transformation of locally emitted $SO_2$. The $NO_3{^-}$ increase was closely associated with the increase in local emissions of nitrogen oxides at four urban sites except for the BR and JJ, as well as the LTP with a small contribution. Among the meterological parameters (wind speed, temperature, and relative humidity), the ambient temperature was most important factor to control the variation of $PM_{2.5}$ and its major chemical components concentrations. In other words, as the average temperature increases, the $PM_{2.5}$, OC, EC, and $NO_3{^-}$ concentrations showed a decreasing tendency, especially with a prominent feature in $NO_3{^-}$. Results from a case study that examined the $PM_{2.5}$ and its major chemical data observed between February 19 and March 2, 2014 at the all stations suggest that ambient $SO{_4}^{2-}$ and $NO_3{^-}$ concentrations are not necessarily proportional to the concentrations of their precursor emissions because the rates at which they form and their gas/particle partitioning may be controlled by factors (e.g., long range transportation) other than the concentration of the precursor gases.

Composition comparison of PM10 and PM2.5 fine particulate matter for Asian dust and haze events of 2010-2011 at Gosan site in Jeju Island (황사와 연무 시 PM10 및 PM2.5 미세먼지 조성 비교: 2010-2011년 고산지역 측정)

  • Kim, Ki-Ju;Lee, Seung-Hoon;Hyeon, Dong-Rim;Ko, Hee-Jung;Kim, Won-Hyung;Kang, Chang-Hee
    • Analytical Science and Technology
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    • v.27 no.1
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    • pp.1-10
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    • 2014
  • The $PM_{10}$ and $PM_{2.5}$ samples were collected at Gosan Site of Jeju Island, and analyzed, in order to investigate the size distribution and pollution characteristics of their components. $NH{_4}{^+}$, nss-$SO{_4}^{2-}$, $K^+$, and $CH_3COO^-$ were mostly existed in fine particles. Meanwhile, $NO{_3}{^-}$ was distributed in both fine and coarse particles, and $Na^+$, $Cl^-$, $Mg^{2+}$, nss-$Ca^{2+}$ were rich in coarse particle mode. The concentrations of nss-$Ca^{2+}$ and $NO{_3}{^-}$ were increased 36.7 and 3.2 times in coarse particles, and 15.0 and 3.1 times in fine particles during the Asian Dust periods. Especially, the concentrations of crustal elemental species such as Al, Fe, Ca, K, Mg, Ti, Mn, Sr, Ba were highly increased for those periods. In the haze events, the concentrations of secondary air pollutants were increased 1.3~2.6 and 1.5~4.2 times in coarse and fine particles, respectively. Moreover, the remarkable increase of $NO{_3}{^-}$ concentration was also observed in fine particle mode. The factor analysis showed that the composition of coarse particles was influenced mainly by marine sources, followed by soil and anthropogenic sources. On the other hand, the fine particles were influenced by anthropogenic sources, followed by marine and soil sources.

A Study on the Stability and Sludge Energy Efficiency Evaluation of Torrefied Wood Flour Natural Material Based Coagulant (반탄화목분 천연재료 혼합응집제의 안정성 및 슬러지 에너지화 가능성 평가에 관한 연구)

  • PARK, Hae Keum;KANG, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.48 no.3
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    • pp.271-282
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    • 2020
  • Sewage treatment plants are social infrastructure of cities. The sewage distribution rate in Korea is reaching 94% based on the sewage statistics based in the year of 2017. In Korean sewage treatment plants, use of PAC (Poly Aluminum Chloride) accounts for 58%. It contains a large amount of impurities (heavy metal) according to the quality standards, however, there have been insufficient efforts to reinforce the standards or technically improve the quality, which resulted in secondary pollution problems from injecting excessive coagulant. Also, the increase in the use of chemicals is leading to the increases in the annual amount of sewage sludge generated in 2017 and the need to reuse sludge. As such, this study aims to verify the possibility of reusing sludge by evaluating the stability of heavy metals based on the injection of coagulant mixture during water treatment which uses the torrefield wood powder and natural materials, and evaluating the sedimentation and heating value of sewage sludge. As a result of analyzing heavy metals (Cr, Fe, Zn, Cu, Cd, As, Pb, and Ni) from the coagulant mixture and PAC (10%), Cr, Cd, Pb, Ni, and Hg were not detected. As for Zn, while its concentration notified in the quality standards for drinking water is 3 mg/L, only a small amount of 0.007 mg/L was detected in the coagulant mixture. Maximum amounts of over double amounts of Fe, Cu, and As were found with PAC (10%) compared to the coagulant mixture. Also, an analysis of sludge sedimentation found that the coagulant mixture showed a better performance of up to double the speed of the conventional coagulant, PAC (10%). The dry-basis lower heating value of sewage sludge produced by injecting the coagulant mixture was 3,378 kcal/kg, while that of sewage sludge generated due to PAC (10%) was 3,171 kcal/kg; although both coagulants met the requirements to be used as auxiliary fuel at thermal power plants, the coagulant mixture developed in this study could secure heating values 200 kal/kg higher than the counterpart. Therefore, utilization of the coagulant mixture for water treatment rather than PAC (10%) is expected to be more environmentally stable and effective, as it helps generating sludge with better stability against heavy metals, having a faster sludge sedimentation, and higher heating value.

Teachers' Understanding of Environment around Schools and Actual Survey in Prejudical Business in Taegu City (대구지역(大邱地域) 학교주변(學校周邊) 환경(環境)에 대한 교사(敎師)의 인식(認識)과 유해업소(有害業所) 실지조사(實地調査))

  • Yang, Myung Sook;Kim, Sang Soon
    • Journal of the Korean Society of School Health
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    • v.7 no.1
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    • pp.45-55
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    • 1994
  • The purpose of this study is to contribute to improvement of educational environment by analysing all problems related to environment around the school. To accomplish this purpose, this study was carried out by examining the problems in controlling the areas required for cleanup with 220 teachers in charging the cleanup duties of the primary and secondary schools in Taegu between June 1 and July 15, 1993 and by actually surveying the prejudical business stores around 72 primary schools between August 10 and September 20, 1993. Although most teachers answered to the questionnaires that it is necessary to cleanup the bad environment around the school, the duties of its cleanup tend not to be considered as an important matter. The teachers considered that the most prejudical business store around the school is totally the game room, and in such order as comic books' store, liquor selling shop and causing noise and pollution. 57.3% of total respondents answered that the present cleanup movements have resulted in failure mostly because of both supervising authorities' careless promotion and store owners' excessive commercial transactions. The result of actual survey in environmental and sanitary cleanup area around 72 primary schools showed that the greatest number of 1,258 prejudical stores was the video tapes shop, and then in such order as lodgings, and game rooms, while the number of prejudical store by the schools was 17.5 stores per school on the average which showed a various distribution from zero to 77 places. In general, these prejudical stores were mainly located around the schools in Jung-gu and Seo-gu areas. In addition, it was shown that the more the number of students, the more the number of the prejudical stores. In order to improve the environment around the school, it is necessary to strictly carry out the zoning system relating to the usage of land, to strongly restrict the stores without permit and abnormal stores and to establish the basis asking the city development authorities to go through the environmental evaluation. Moreover, it is absolutely required to make efforts to establish the national right sense of education, and to closely cooperate with the related authorities.

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Screening of the Optimum Filter Media in the Constructed Wetland Systems through Phosphorus Adsorption Capacities (인의 흡착능 평가를 통한 인공습지 하수처리 시스템의 여재 선발)

  • Lee, Hong-Jae;Seo, Dong-Cheol;Cho, Ju-Sik;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.22 no.2
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    • pp.148-152
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    • 2003
  • The phosphorus(P) adsorption capacities of various filter media were investigated in relation to the size and types of fitter media to screen the optimum condition. The objective of this study was to evaluate the constructed wetland longevity by improving P adsorption capacity. The maximum P adsorption capacities of filter media A($4{\sim}10\;mm$), B($2{\sim}4\;mm$) and C($0.1{\sim}2\;mm$) were 8, 10 and 22 mg/kg, respectively, showing those increased as the filter media size decreased. Among the experimental media, the optimum filter media size was $0.1{\sim}2\;mm$. When the filter Medium was supplemented with organic materials which were piled up and decayed in the constructed wetland, the P adsorption capacity was significantly enhanced Under the conditions of optimum fitter media size, the respective Maximum P adsorption capacities of filter media C when supplemented with Ca, Mg, Al and Fe were higher than that of filter media C. However the addition of Ca, Mg, Al and Fe to constructed wetland were not recommended because of the possibility of their secondary pollution. The maximum P adsorption capacity of filter media C was 22 mg/kg, but this was increased to 36 mg/kg when filter media C was supplemented with 2% oyster shell.

Studies on the Strength of Briquette Ash Hardened by Cement (연탄재를 시멘트로서 경화(硬化)시켰을 때의 강도(强度)에 관(關)한 연구(硏究))

  • Kim, Seong-Wan
    • Korean Journal of Agricultural Science
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    • v.6 no.1
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    • pp.45-55
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    • 1979
  • This study made to find the variation of strengths of briquette ash which were hardened into cement. The briquette ash were mixed with the cement, ((cement (90%)+slaked lime (10%)) and ((cement (80%)+fly ash (20%)) in the ratio of 1:2, 1:3, 1:4, 1:5, 1:7 and 1:9, respectively, and these were compared with the one made of cement plus standard sand in the strengths of compression, tension and bending at the ages of 7 days and 28 days. The results from the study conducted preliminary without studying the economical aspects or duration of the products are summarized as follows: 1. The compressive strengths of mortar made of 1 to 2 ratios of cement to briquette ash, (cement+slaked lime) to briquette ash and (cement+fly ash) to briquette ash were 84%, 90% and 75% at the age of 7 days and 84.9%, 73.5% and 69.8%, respectively of those of Korean Standard values. 2. The compressive strength s of mortar made of 1 to 2 ratios of cement to briquette ash, (cement+slaked lime) to briquette ash and (cement+fly ash) to briquette ash were 69.3%, 75.1% and 41.3% at the age of 7 days and 56.4%, 49%, and 46.5% at the age of 28 days, respectively of the mortar made of standard sand. 3. The tension strengths of mortar made of 1 to 2 ratios of cement to briquette ash, (cement+slaked lime) to briquette ash, and (cement+fly ash) to briquette ash were 64.4%, 47.1% and 35.4% at the age of 7days and 69.6%, 64.8%, and 57.3%, respectively of that of the mort ar produced with standard sand. 4. The bending strengths of mortar made of 1 to 2 ratios of cement to briquette ash, (cement+slaked lime) to briquette ash, and (cement+fly ash) to briquette ash were 46.3%, 65.9% and 39.1% at the age of 7 days and 89.9%, 96.7%, and 85.1%, respectively of that of mortar produced with standard sand. 5. The bending strength of the mortar was lower than that of cement mortar, when the briquette ash were harqened into cement. However, the mortar produced by such method seemed to be used as the secondary products of cement or concrete. The additional usefullness of the hardened biquette ash can be found in contributing toward the solving the various pollution problems, the saving the labor costs needed to clean-up waste materials, and the saving the construction materials.

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