• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1879-1884
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• 2012

The kinetic studies on the reactions of dipropyl chlorophosphate (3O) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) have been carried out in acetonitrile at $55.0^{\circ}C$. The obtained deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are primary normal ($k_H/k_D$ = 1.09-1.01) with the strongly basic anilines while secondary inverse ($k_H/k_D$ = 0.74-0.82) with the weakly basic anilines. The steric effects of the two ligands on the rates are extensively discussed for the anilinolyses of the ($R_1O$)($R_2O$)P(=O or S)Cl-type chlorophosphates and chlorothiophosphates. A concerted mechanism is proposed with a frontside nucleophilic attack involving a hydrogen-bonded four-center-type transition state for the strongly basic anilines and with a backside attack transition state for the weakly basic anilines on the basis of the DKIEs, primary normal and secondary inverse with the strongly and weakly basic anilines, respectively.

• Bulletin of the Korean Chemical Society
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• v.34 no.5
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• pp.1435-1440
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• 2013

To investigate the influence of the carbon matrix on the electrochemical performance of Si/C composites, four types of Si/C composites were prepared using graphite, petroleum coke, pitch and sucrose as carbon precursors. A ball mill was used to prepare Si/C blends from graphite and petroleum coke, whereas a dispersion technique was used to fabricate Si/C composites where Si was embedded in disordered carbon matrix derived from pitch or sucrose. The Si/pitch-based carbon composite showed superior Si utilization (96% in the first cycle) and excellent cycle retention (70% after 40 cycles), which was attributed to the effective encapsulation of Si and the buffering effect of the surrounding carbon matrix on the silicon particles.

• Corrosion Science and Technology
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• v.10 no.5
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• pp.175-179
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• 2011

The transportation and deposition of iron corrosion products are important elements that affect both the steam generator (SG) integrity and secondary system in pressurized water reactor (PWR) nuclear power plants. Most of iron corrosion products are generated on carbon steel materials due to flow accelerated corrosion (FAC). The several parameters like water chemistry, temperature, hydrodynamic, and steel composition affect FAC. It is well established that the at-temperature pH of the deaerated water system has a first order effect on the FAC rate of carbon steels through nuclear industry researches. In order to reduce transportation and deposition of iron corrosion products, increasing pH(t) tests were applied on secondary system of A, B units. Increasing pH(t) successfully reduced flow accelerated corrosion. The effect of increasing pH(t) to inhibit FAC was identified through the experiment and pH(t) evaluation in this paper.

• The Journal of Korean Academy of Prosthodontics
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• v.27 no.1
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• pp.193-211
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• 1989

The purpose of this study was to investigate the effect of secondary heat treatment on dimensional changes of acrylic resin partial denture base. For this study, 6 specimens were made: 2 groups of 2 specimens, each was treated with $125^{\circ}C$ dry heat and glycerine heat for 3 minutes, and the others were prepared for control group. The change of the internal diameter of specimens were measured after 3 hrs, 1 day, 1 week, 2 weeks, 4 weeks by three-dimensional space analyzer. The results were as follows : 1. All of the acrylic resin denture bases showed tissue ward thermal contraction. 2. Thermal contraction of the mesial area reinforced with metal framework was lesser than that of the distal area without metal framework. 3. Thermal contraction of the lingual flange reinforced with metal framework occured more slowly than that of the buccal flange without the metal framework. 4. The thermal contraction of dry heat treated acrylic resin base, compared to glycerine heat group, was moderately greater and occurred acutely.

• The KSFM Journal of Fluid Machinery
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• v.7 no.5 s.26
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• pp.36-42
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• 2004

The effect of tip clearance height on the three-dimensional flow and aerodynamic loss in the wake region of a high-turning turbine rotor cascade has been investigated with a miniature cone-type five-hole probe. Distributions of velocity magnitude, secondary velocity vectors, and total-pressure loss coefficient are presented for three tip gap-to-span ratios of h/s = 0.0, 0.5 and 1.0 percent. The result shows that with the increment of h/s, tip leakage vortex tends to be intensified and aerodynamic loss due to the leakage vortex is increased as well. In the case of h/s = 1.0 percent, aerodynamic loss in the tip-leakage flow region is found dominant in comparison with that in the passage vortex region. With increasing h/s, mass-averaged secondary loss coefficient has a greater portion in the mass-averaged total-pressure loss coefficient.

• Carbon letters
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• v.5 no.3
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• pp.108-112
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• 2004

Effect of silicon infiltration on the bend and tensile strength of 2D cross-ply carbon-carbon composites are studied. It is observed that bend strength higher than tensile strength in both types of composite is due to the different mode of fracture and loading direction. After silicon infiltrations bend and tensile strength suddenly decreases of carbon-carbon composites. This is due to the fact that, after silicon infiltration, silicon in the immediate vicinity of carbon forms the strong bond between carbon and silicon by formation silicon carbide and un-reacted silicon as free silicon. Therefore, these composites consist of three components carbon, silicon carbide and silicon. Due to mismatch between these three components secondary cracks developed and these cracks propagate from $90^{\circ}$ oriented plies to $0^{\circ}$ oriented plies by damaging the fibers (i.e., in-situ fiber damages). Hence, secondary cracks and in-situ fiber damages are responsible for degradation of mechanical properties of carbon-carbon composites after silicon infiltration which is revealed by microstructure investigation study by scanning electron microscope.

• Journal of the Korean Vacuum Society
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• v.9 no.1
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• pp.36-41
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• 2000

$SnO-2$ thin films for thin film secondary battery anode were deposited n glass substrate with stain-less steel collector and charge/discharge experiments were conducted to investigate feasibility of $SnO-2$ thin film as a new anode material. The as-deposited films were pure $SnO-2$ phase which is not related to deposition condition. The grain size on the surface of as-deposited films increased with increase of oxygen partial pressure. However, the grain size did not show any change above oxygen partial pressure of 80:20. The surface roughness of the as-deposited films increased after decreasing because of resputtering effect of oxygen negative ion in plasma. All films showed typical $SnO-2$ anode characteristics which has a side effect at the first cycle, which is not related to the deposition condition. The charge/discharge experiments of 200cycles indicated that capacity of $SnO-2$ films depended on oxygen contents and surface roughness. The cycle characteristics was determined by initial charge/discharge reaction. The $SnO-2$ film with low initial capacity showed more stable cycle characteristics than film with high initial capacity.

• Korean Journal of Materials Research
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• v.12 no.7
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• pp.580-586
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• 2002

The effect of processing and designing variables such as pouring temperature(1400 or $1500^{\circ}C$), inoculation and risering design(T and H type) on the formation of defects such as external depression, primary and secondary shrinkage cavities in GC150 gray cast iron was investigated. In T type risering design, external depression or primary shrinkage cavity due to liquid contraction was formed in all of the eight cases. Regardless of its modulus value, the riser could not function properly in T type risering design because directional solidification was not promoted toward the riser. On the other hand, the four cases of H type risering design in which thermal sleeves were set onto the risers produced defect-free castings. In both types of the risering designs, secondary shrinkage cavity caused by solidification contraction was not observed in the casting because of the expansion pressure due to graphite precipitation and the application of rigid pep-set mold. The degree of external depression or primary shrinkage cavity was reduced with lowered pouring temperature. The effect of inoculation was diminished because of the high carbon equivalent of GC 150 gray cast iron.

• Journal of the Korean Society for Precision Engineering
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• v.21 no.11
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• pp.91-98
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• 2004

TFLIM(Transverse Flux Linear Induction Motor), making its closed magnetic path with the direction of the traveling field orthogonal, had been developed to decrease an edge effect of the general induction motor. To control the levitation force and the thrust force on the secondary part of TFLIM independently, the various methodologies have been presented. When we try to achieve the independent control using only the multi-phase inputs assigned in the stator coils as an approach, in which condition we can minimize the coupling effect between two forces\ulcorner In this paper, we show the qualitative influence of a slip frequency, an ac magnitude, a dc offset superposed in the ac power, and a major parameter of TFLIM on the couple through the computer simulation. And to realize the independent motions between levitation and thrust motion without any auxiliary means fur isolation of the secondary part of TFLIM, the decouple compensator is suggested, including the experimental results.

• Metals and materials international
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• v.24 no.6
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• pp.1221-1231
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• 2018

The effect of strain aging on tensile behavior and properties of API X60, X70, and X80 pipeline steels was investigated in this study. The API X60, X70, and X80 pipeline steels were fabricated by varying alloying elements and thermomechanical processing conditions. Although all the steels exhibited complex microstructure consisting of polygonal ferrite (PF), acicular ferrite, granular bainite (GB), bainitic ferrite (BF), and secondary phases, they had different fractions of microstructures depending on the alloying elements and thermomechanical processing conditions. The tensile test results revealed that yielding behavior steadily changed from continuous-type to discontinuous-type as aging temperature increases after 1% pre-strain. After pre-strain and thermal aging treatment in all the steels, the yield and tensile strengths, and yield ratio were increased, while the uniform elongation and work hardening exponent were decreased. In the case of the X80 steel, particularly, the decrease in uniform elongation was relatively small due to many mobile dislocations in PF, and the increase in yield ratio was the lowest because a large amount of harder microstructures such as GB, BF, and coarse secondary phases effectively enhanced work hardening.