• Journal of the Korean Society of Industry Convergence
• /
• v.25 no.3
• /
• pp.451-459
• /
• 2022

Recently, in accordance with the demand for a large capacity of a secondary battery according to an increase in the demand for energy storage devices, a modular series battery configuration is essential. Accordingly, various cell balancing techniques have been proposed to prevent high efficiency and performance degradation of the battery. In this paper, propose a battery voltage balancing topology consisting of a flyback DC/DC converter type of a SIMO (Single-Input-Multiple Output) two-switch configuration for a series battery configuration. The proposed topology shows a structure in which a DC/DC converter connected to each module and a battery cell share one transformer. The topology cell balancing operation is a principle in which the voltage balancing converter of the battery converges to the same value through a transformer that shares a magnetic flux with the cells constituting the module through a single high-frequency transformer. In this paper, the dynamic characteristics analysis of the proposed circuit using PSIM was based and it was verified through experiments on one module.

• Membrane Journal
• /
• v.26 no.4
• /
• pp.310-317
• /
• 2016

Lithium ion secondary battery (LISB) is an energy conversion system operated via charging-discharging cycle based on Lithium ion migration. LISB has a lot of advantages such as high energy density, low self-discharge rate, and a relatively high lifetime. Recently, increasing demands of electric vehicles have been encouraging the development of LISB with high capacity. Unfortunately, it causes some critical safety issues. It includes dendrite formation on negative electrode, resulting in electric shortage problems and battery explosion. Also, the elevated temperatures occurred during the LISB operation induces thermal shrinkage of polyolefin (e.g., polyethylene and polypropylene) separators. Consequently, the low thermal stability leads to decay of LISB performances and the reduction of lifetime. In this study, sulfonated poly (arylene ether sulfone) (SPAES) random copolymers were used as key materials to prepare polyolefin pore-filling separator. The resulting separators were evaluated in the term of metal ion chelation capability associated with dendrite formation, $Li^+$ ion conductivity and thermal durability.

• Journal of the Korean Electrochemical Society
• /
• v.18 no.4
• /
• pp.137-142
• /
• 2015

$Mn_{1+X}Co_{2-X}O_4$ solid solutions with various Mn/Co ratios were synthesized by a combustion method, and used as cathode catalysts for lithium/air secondary battery. Their electrochemical and physicochemical properties were investigated. The morphology was examined by transmission electron microscopy (TEM), and the crystallinity was confirmed by X-ray diffraction (XRD) analyses. For the measurement of electrochemical properties, charge and discharge measurements were carried out at a constant current density of $0.2mA/cm^2$, monitoring the voltage change. Electrochemical impedance spectroscopy (EIS) analyses were also employed to examine the change in charge transfer resistance during charge-discharge process. $Mn_{1+X}Co_{2-X}O_4$ solid solutions showed enhanced cycleability as a cathode of Li/air secondary battery, and the performance was found to be strongly dependent on Mn/Co ratio. Among synthesized catalysts, $Mn_{1.5}Co_{1.5}O_4$ exhibited the best performance and cycleability, due to high charge transfer rate.

• Korean Journal of Materials Research
• /
• v.33 no.6
• /
• pp.257-264
• /
• 2023

To develop a high capacity lithium secondary battery, a new approach to anode material synthesis is required, capable of producing an anode that exceeds the energy density limit of a carbon-based anode. This research synthesized carbon nano silicon composites as an anode material for a secondary battery using the RF thermal plasma method, which is an ecofriendly dry synthesis method. Prior to material synthesis, a silicon raw material was mixed at 10, 20, 30, 40, and 50 wt% based on the carbon raw material in a powder form, and the temperature change inside the reaction field depending on the applied plasma power was calculated. Information about the materials in the synthesized carbon nano silicon composites were confirmed through XRD analysis, showing carbon (86.7~52.6 %), silicon (7.2~36.2 %), and silicon carbide (6.1~11.2 %). Through FE-SEM analysis, it was confirmed that the silicon bonded to carbon was distributed at sizes of 100 nm or less. The bonding shape of the silicon nano particles bonded to carbon was observed through TEM analysis. The initial electrochemical charging/discharging test for the 40 wt% silicon mixture showed excellent electrical characteristics of 1,517 mAh/g (91.9 %) and an irreversible capacity of 133 mAh/g (8.1 %).

• 한국전기화학회:학술대회논문집
• /
• 1998.10a
• /
• pp.83-83
• /
• 1998

• Journal of Energy Engineering
• /
• v.3 no.2
• /
• pp.159-166
• /
• 1994

• 한국전기화학회:학술대회논문집
• /
• 2005.04a
• /
• pp.25-25
• /
• 2005

• 한국전기화학회:학술대회논문집
• /
• 2002.04a
• /
• pp.16-17
• /
• 2002

• 한국전기화학회:학술대회논문집
• /
• 2003.10a
• /
• pp.17-17
• /
• 2003

• Ingenium
• /
• v.11 no.3
• /
• pp.66-75
• /
• 2004