• Title/Summary/Keyword: Scraps

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Recovery of Copper Powder form MoO3 Leaching Solution Using Cementation Reaction System (MoO3 침출공정 폐액으로부터 치환반응 시스템을 이용한 구리 분말 회수에 대한 연구)

  • Kim, Geon-Hong;Hong, Hyun-Seon;Jung, Hang-Chul
    • Journal of Powder Materials
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    • v.19 no.6
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    • pp.405-411
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    • 2012
  • Recovery of copper powder from copper chloride solution used in $MoO_3$ leaching process was carried out using a cementation method. Cementation is a simple and economical process, necessitating less energy compared with other recovery methods. Cementation utilizes significant difference in standard reduction potential between copper and iron under standard condition. In the present research, Cementation process variables of temperature, time, and added amount of iron scraps were optimized by using design of experiment method and individual effects on yield and efficiency of copper powder recovery were investigated using bench-scale cementation reaction system. Copper powders thus obtained from cementation process were further characterized using various analytical tools such as XRF, SEM-EDS and laser diffraction and scattering methods. Cementation process necessitated further purification of recovered copper powders and centrifugal separation method was employed, which successfully yielded copper powders of more than 99.65% purity and average $1{\mu}m$ in size.

Feasibility of Indium Tin Oxide (ITO) Swarf Particles to Transparent Conductive Oxide (TCO)

  • Hong, Sung-Jei;Yang, DuckJoo;Cha, Seung Jae;Lee, Jae-Yong;Han, Jeong-In
    • Current Photovoltaic Research
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    • v.3 no.2
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    • pp.50-53
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    • 2015
  • Indium (In) is widely used for transparent electrodes of photovoltaics as a form of indium tin oxide (ITO) due to its superior characteristics of environmental stability, relatively low electrical resistivity and high transparency to visible light. However, In has been worn off in proportion to growth the In related market, and it leads to raise of price. Although In is obtained from ITO target scarps, much harmful elements are used for the recycling process. To decrease of harmful elements, ITO swarf particles obtained from target scraps was characterized whether it is feasible to transparent conductive oxide (TCO). The ITO swarf was crushed with milling process, and it was mixed with new ITO nanoparticles. The mixed particles were well dispersed into ink solvent to make-up an ink, and it was well coated onto glass substrate. After heat-treatment at $400^{\circ}C$ under $N_2$ rich environments, optical transmittance at 550 nm and sheet resistance of the ITO ink coated layer was 71.6% and $524.67{\Omega}/{\square}$, respectively. Therefore, it was concluded that the ITO swarf was feasible to TCO of touch screen panel.

Preparation of Cathode Materials for Lithium Rechargeable Batteries using Transition Metals Recycled from Li(Ni1-x-yCoxMny)O2 Secondary Battery Scraps (Li(Ni1-x-yCoxMny)O2계 이차전지 공정 스크랩으로부터 회수한 전이금속을 활용한 리튬이차전지 양극재 제조)

  • Lee, Jae-Won;Kim, Dae Weon;Jang, Seong Tae
    • Journal of Powder Materials
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    • v.21 no.2
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    • pp.131-136
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    • 2014
  • Cathode materials and their precursors are prepared with transition metal solutions recycled from the the waste lithium-ion batteries containing NCM (nickel-cobalt-manganese) cathodes by a $H_2$ and C-reduction process. The recycled transition metal sulfate solutions are used in a co-precipitation process in a CSTR reactor to obtain the transition metal hydroxide. The NCM cathode materials (Ni:Mn:Co=5:3:2) are prepared from the transition metal hydroxide by calcining with lithium carbonate. X-ray diffraction and scanning electron microscopy analyses show that the cathode material has a layered structure and particle size of about 10 ${\mu}m$. The cathode materials also exhibited a capacity of about 160 mAh/g with a retention rate of 93~96% after 100 cycles.

Feasibility of Copper Powder Fabrication by Ball Milling of Copper Chip Scrap Occurred During Cutting Process of Copper Pipe (구리 관(管)의 절단(切斷) 공정(工程)중 발생한 구리칩 스크랩의 볼밀링에 의한 구리 분말(粉末) 제조(製造) 가능성(可能性))

  • Hong, Seong-Hyeon
    • Resources Recycling
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    • v.20 no.6
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    • pp.37-42
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    • 2011
  • Copper chip scrape has been occurred by cutting of copper pipe. The feasibility of copper chip scrape into the copper powder by milling was studied. Two milling type such as rod milling and horizontal balling milling were applied in this research. Copper chip can not fragmented into powder by using rod milling. In contrast to rod milling, copper chip can be changed into powder by horizontal ball milling for above 36 hours. It was found that recycling of copper chip scraps into copper powder by horizontal ball milling is possible and powder fraction percent ($75{\sim}150{\mu}m$) of milled copper chip for 48 hours is 25.3%.

Urban Mine Resources and Metal Recycling in Korea (한국(韓國)의 도시광산(都市鑛山)(사용후제품) 자원(資源)과 금속재자원화(金屬再資源化))

  • Oh, Jae-Hyun;Kim, Joon-Soo;Moon, Suk-Min;Min, Ji-Won
    • Resources Recycling
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    • v.20 no.6
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    • pp.3-18
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    • 2011
  • In order to review the recycling status of urban mine resources in Korea, metal consumption, metal stock reserves and metal scraps and wastes such as iron scrap, end of life vehicles(ELV), E-waste were surveyed. In making up the list of the metal consumption, the statistical data from the Korea Non-Ferrous Association, the Korea Iron and Steel Association, the HS code of Korea Custom Service, the symposium and the related companies were collected. Finally, "Principle uses and recycling potential of metals in the periodic table" by T.E.Graedel was introduced. This paper suggested the key point for development of urban mine resources.

Selective Removal of Cu in Ferrous Scrap by Chlorine gas (염소가스에 의한 철 스크랩 중 Cu의 선택적 제거)

  • Lee, So-Yeong;Sohn, Ho-Sang
    • Resources Recycling
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    • v.27 no.5
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    • pp.54-60
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    • 2018
  • The quality of steel produced from scrap can be adversely affected because of the buildup of tramp elements in recycled scrap. The tramp element of greatest concern is copper because of its effect on steel quality, even in small percentage quantities. In this study, possibility of removal of copper from ferrous scrap by using $Cl_2$ gas is experimentally examined in a small size experimental apparatus. Synthetic ferrous scraps containing copper were reacted with $Cl_2$ gas in various atmosphere. The copper was chloridized and evaporated, whereas iron was oxidized and was not reacted with Cl2 and oxygen mixture gas.

Study on Recycling of Scraps from Process of Silicon-single-crystal for Semiconductor

  • Lee, Sang-Hoon;Lee, Kwan-Hee;Hiroshi Okamoto
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.705-710
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    • 2001
  • So for the quartz-glassy crucible wastes which was used for pulling up silicon-single-crystal ingot have simply reused for refractory raw-materials, or exhausted. This study is concerned on the advanced recycling-technology that is obtained by the proper micro-particle preparation process in order to fabricate fine amorphous silica filler for EMC (Epoxy Molding Compound). Therefore, this paper will deal with the physical, chemical and thermal pre-treatment process for efficient impurity removal and with the proper micro-particle process for producing the amorphous silicafiller. In view of the results, if the chemical, physical and thermal pre-treatment process for efficient elimination of impurity was passed, the purity of wasted fused glassy crucible is almost equal to the its of first anhydrous quartz glass. Thus, it was understood that this wasted fused glassy crucible was sufficient value of recycling, though it was damaged. When the ingot was fabricated, Phase transformation of crystallization by heat treatment (heat hysteresis phenomenon) was not changed. So, it was understood that as fused silica in the amorphous state, as It is, recycling possibility was very high

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The External Deconstruction Trend Expressed in the Works of Jean Paul Gaultier (Jean Paul Gaultier 작품에 나타난 외적 해체경향)

  • Choi, Young-Ok
    • Fashion & Textile Research Journal
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    • v.4 no.4
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    • pp.327-338
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    • 2002
  • The analysis and examination of this study are focussed on the external deconstruction trend expressed in the works of Jean Paul Gaultier. The external deconstruction is a way of expression faithful to the literal meaning of 'deconstruction' and is the applied case of exposure, destruction, poverty, and decomposition as they are. The method and scope of this study are from 1980's to present, and the followings are the results of this examination focussed on the various literature of philosophy, aesthetics and literary criticism, and the domestic and foreign fashion journals. The exposure phenomena through the deconstruction expressed repeatedly in the works of Gaultier deconstructed the fixed idea of 'the inner wear should be worn inside the outer wear' and at the same time denied the dichotomical interpretation of the exposure and suppression, the traditional beauty and decadent beauty, the chastity and unchastity, the asceticism and sexuality, and obscured the notion of the inner wear and outer wear. The destructive deconstruction expressed in the works of Jean Paul Gaultier introduced the elements such as hippy, punk, and kitsch, slashed before making dresses, crumpled unseemly like wastepaper, or made dresses with textures like paper scraps, and through destroying textures, yielded shock effects and tension. Poverty, through borrowing from the outwardly poor-looking elements of design, i.e. the patch work, decolor, dye, fading, fringing, incompletion, and handmadeness, liberated dresses and their ornaments from the outside. The traditional dresses were dresses having certain forms with formative beauty, but Gaultier disassembled dresses and raised questions about the logic of dresses themselves.

Reduction Kinetics of Zinc Oxide in EAF Dust (전기로 분진중 아금산화물의 환원속도)

  • Moon Seok Min;Kim Tae Wook;Min Dong Joon
    • Resources Recycling
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    • v.11 no.4
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    • pp.37-43
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    • 2002
  • As the consumption of galvanized steels in cans and automobiles and the quantity of scraps increase, the recycling problems of EAF dust become a important problem. Valuable metals such as Fe, Zn, Pb are of continued interest to metallurgists. To recover the valuable metal and to remove the toxicity of EAF dust, high temperature smelting process is or researching as a pilot scale. The Reduction kinetics of Zn in EAF dust is so important in a view of the economic consideration of the process. In this study, the kinetics behavior of Zn in EAF dust were measured as a point of application in high temperature smelting process. The rate control step in ZnO and franklinite is revealed to be chemical reaction on the reaction surface.

Preparation and Characteristics of Anionic Surfactant Using Waste Fleshing Scrap (피혁 제조 공정 중 발생하는 폐돈지를 이용한 음이온성 계면활성제 제조 및 특성)

  • Shin, Soo-Beom;Min, Byung-Wook;Yang, Seung-Hun;Park, Min-Seok;Won, Gi-Chun;Paek, Doo-Hyeon
    • Textile Coloration and Finishing
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    • v.18 no.6 s.91
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    • pp.31-36
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    • 2006
  • Study has been made for producing anionic surfactant using waste fleshing scraps from the leather making process through refining, esterification, sulfonation and blending processes. As a most optimum lard oil refining method, refining was carried out for 4 hours under temperature of $120^{\circ}C$ and approximately 200 mbar vacuum, which gave a recovery of more than 80% lard oil. Refined lard oil obtained thus was undergone methlyl-esterification, then sulfonated to make a degreasing agent. By methyl-esterification using lard oil, more than 85% of fatty acid and $12{\sim}13%$ of glycerine were extracted from the oil. Sulfonation of the extracted fatty acid ester lard oil has shown most optimum at $15{\sim}20%$ chlorosulfonic acid content, and the content of bonding sulfate at this time was higher than 3.5%. Finally the followed anionic surfactant having degreasing force of 80% and higher could be made by blending process.