• Title/Summary/Keyword: Saturated Boiling

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Extraction of Dimethyl-$\beta$-propiothetin from Enteromorpha intestinalis (창자파래(Enteromorpha intestinalis)로부터 Dimethyl-$\beta$-propiothetin 추출)

  • 배태진;강동수;최옥수
    • The Korean Journal of Food And Nutrition
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    • v.13 no.4
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    • pp.334-341
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    • 2000
  • The DMPT produced by marine algae is the main biogenic precursor of oceanic DMS. Also, DMPT is an efficient stimulant for growth, feeding, and body movement of fish and striped prawn, and appears to play a physiologic role as an osmoprotectant in algae. This study was focused on the extraction of dimethyl-$\beta$-propiothetin as bioactive substance from green seaweed. Identification and quantification of dimethyl-$\beta$-propiothetin were measured by headspace gas chromatography after conversion to dimethyl sulfide by treatment with saturated NaOH solution. Dimethyl-$\beta$-propiothetin was extracted through various processes(solvent extraction, ultrasonication, boiling and autoclaving) from Enteromorpha intesinalis. The content of dimethyl-$\beta$-propiothetin extracted by autoclaving treatment showed higher than those of various extraction methods. Dimethyl-$\beta$-propiothetin content in extract of Enteromorpha Enteromorpha was 311,200ng/g after autoclaving at 121$^{\circ}C$ for 60min. Dimethyl-$\beta$-propiothetin in extract of Enteromorpha intestinalis was comparatively stable under low temperature. The retentions of dimethyl-$\beta$-propiothetin content in extract of Enteromorpha intestinalis were 75.8 ~99.8% by incubation at 10~6$0^{\circ}C$ for 2 hours. Chemical decomposition of dimethyl-$\beta$-propiothetin was observed under laboratory conditions at pH values higher than 9.5.

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Analysis of Long-term Stability of Direct Methanol Fuel Cell and Investigation of the Methods to Improve its Performance (직접메탄올 연료전지의 장기운전 특성 분석 및 성능향상 연구)

  • Lee, Hyun-Sook;Bae, Byung-Chan;Lee, Jae-Young;Im, Tae-Hun;Ha, Heung-Yong;Hong, Seong-Ahn
    • Journal of Hydrogen and New Energy
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    • v.16 no.1
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    • pp.31-39
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    • 2005
  • Direct methanol fuel cell (DMFC) is considered as a candidate for portable power sources, that could overcome the disadvantages of lithium battery. But in order to attain commercial viability the long term stability of the DMFC should be achieved. Understanding the long-term behavior of membrane-electrode assembly (MEA) is a prerequisite to this purpose and the optimization of the MEA is also needed. In this study we have investigated the changes in performance and electrochemical properties of the MEA during extended operation and the effects of heat treatment of MEA on the long-term performance. The MEAs have been treated in an autoclave with saturated water vapor at 120$^{\circ}C$, vacuum oven at 140$^{\circ}C$ and boiling in organic solvents. The autoclaved MEA was found to be have the best long term performance. The on-off operation mode also increased the performance probably due to effective removal of products from the electrodes. Physical and electrochemical analyses using a scanning electron microscope, impedance analyser and half-cell technique have been done to characterize the MEAs.

Gallnut dyeing of Crabyon Fiber Contained Cotton Towels (크라비욘 원사가 함유된 면타올의 오배자 염색)

  • Woo, Ji-Hae;Lee, Shin-Hee
    • Fashion & Textile Research Journal
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    • v.17 no.6
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    • pp.1030-1038
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    • 2015
  • The purpose of this study is to investigate the dyeability of crabyon fiber contained cotton towels after dyeing with gallut. In this study, the colorants of gallnut were extracted with boiling water at 60℃ and 60min. Crabyon, composite fiber of Chitin/Chitosan and cellulose, is manufactured by uniformly blending Chitin/Chitosan and cellulose viscose and extruding the blended viscose into spin-bath. Cotton towels with crabyon fiber dyed with extracted solution from gallnut according to concentration, temperature and time. Crabyon fiber contained cotton towels dyed using gallnut were pre of post-mordanted using Al, Cu, and Fe. The dyeability(K/S) and color characteristics(L*, a*, b*, C, and h(color angle)) of dyed crabyon fiber contained cotton towels were measured by computer color matching machine and photographs. The crabyon fiber composition of cotton towels was conformed by amide peak(-CONH-) of chitin or chitosan of FT-IR spectroscopy. The results obtained were as follows; The amide peak of crabyon fiber contained cotton towels appeared at about 1652 cm−1. The dyeability of crabyon fiber contained cotton towel was increased gradually with increasing concentration of gallnut dyeing solution and saturated at about 150%(o.w.f). The optimum dyeing temperature and dyeing time were 90~100℃ and 80minutes expectively. The crabyon fiber contained cotton towels were dyed reddish yellow by non, Al, and Cu mordanting, reddish blue by Fe mordanting, respectively. The fastness to washing according to concentration of gallnut in and mordanting method indicated good grade result as more than 3~4 degree in all conditions.

A Study on Design and Performance of a Heat pipe for the Application to Solar Collector (태양열 집열기용 열파이프의 구조와 작동 특성에 관한 연구)

  • 임광빈;김철주
    • Journal of Energy Engineering
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    • v.2 no.2
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    • pp.179-186
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    • 1993
  • Heat pipes. applied to a flat plate solar collector, have a long and slender configuration with relatively low heat flux in the evaporator section. Such a heat pipe has a tendency to build-up a liquid pool at the lower part of the evaporator section. and at this pool occurs such complicated phenomena of evaporation and fluid dynamics as superheat, sudden generation of bubble, its likely explosive growth process and flooding, etc. In the present study. we tried to solve these problems by means of adjusting two principal design parameters, the liquid inventory and the installation region of the wick, using 4 heat pipes and 3 thermospheres. The corresponding results can be summarized as follows$\^$1)/. The effective thermal conductances of the heat pipe was greatly improved by eliminating the wick in the adiabatic and condenser sections$\^$2)/. The liquid inventory should be increased by about 40% larger than what is saturated the wick$\^$3)/. In the evaporator section the wick has a favorable effect to reduce both unstable operation by intermittent occurrence of nucleate boiling and response time at the initial start-up process.

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Development of a Computer Program for Thermal Sizing of a Copper Bonded Steam Generator (구리밀봉 증기발생기의 열적크기 계산을 위한 프로그램 개발)

  • 김의광;김연식;어재혁;김성오;백병준
    • Journal of Energy Engineering
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    • v.12 no.2
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    • pp.84-92
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    • 2003
  • A one-dimensional thermal-hydraulic analysis computer program is developed for thermal sizing of a copper bonded steam generator. It is assumed that the conduction heat transfer of copper region between the hot side and the cold side tube is one-dimensional and its thermal resistance is derived as a function of a tube pitch. The flow regions of the water/steam side are divided into four regions: subcooled, saturated, film boiling, and super-heated. The number of tube selected ranges from 250 to 3500 and the pitch to tube diameter (P/D) ratios are 1.4, 1.6 and 1.8 for the parametric study calculation. The calculation results showed that when the number of tube was 2500, the length of the heating tube was about 12 m and the outside diameter of the steam generator was about 3 m. If the P/D ratio increases, the thermal resistance of copper component also increases, however the length of the heating tube is not so much increased.

A Study on the Chemical Pre-Treatments Suitable for the Layer Differentiation of FRP Waste (폐FRP의 층간분리를 위한 전처리방법에 관한 연구)

  • Lee, Seung-Hee;Lee, Jung-Ki;Kim, Yong-Ju
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.1
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    • pp.47-53
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    • 2012
  • As one of the methods for recycling the FRP from the waste ships, separation of roving layer from the mat has some merits in a sense of the eco-friendly and economical recycling process. Similar characteristics, however, between the roving and the mat even with different ratio of the resin and the glass and the thickness of the roving, much thinner than the mat, make the mechanically automatic differentiation difficult. In this study spectrochemical differentiation between the two layers has been made using boiling concentrated sulfuric acid, methanol and isopropanol solution saturated with KOH, or hydrogen fluoride (HF) solution. Furthermore efficiently coloring water-soluble dye following the HF treatment makes the roving layer more distinguishable photophysically. The layer differentiation and the automatic layer distraction move up the date of simple and automatic separation process for the waste FRP.

A Study on the Chemical Treatments Suitable for the Simple Mechanical Manipulation During the Recycling Process of FRP Waste from Ships (폐 선박의 FRP를 재활용 과정에서 용이한 기계적 조작을 위한 화학적 처리 방법에 관한 연구)

  • Lee, Seung-Hee;Kim, Yong-Seop;Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.1
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    • pp.55-59
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    • 2009
  • As one of the methods for recycling the FRP from the small and medium waste ships, separation of roving layer from the mat has some merits in a sense of the recycling energy and the environmental effects. Similar characteristics, however, between the roving and the mat even with different ratio of the resin and the glass and the thickness of the roving, much thinner than the mat, make the mechanically automatic differentiation difficult. In this study spectrochemical differentiation between the two layers has been made using (1) boiling concentrated sulfuric acid which can dissolve the resin in the FRP layer, (2) methanol and isopropanol solution saturated with KOH which can dissolve the glass, or (3) hydrogen fluoride(HF) solution which can reacts with $SiO_2$ fragments of the glass. Furthermore coloring water-soluble dye following the HF treatment makes the roving layer more distinguishable photo-physically.

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Comparison of the Perception of Frozen Processed Food, Food Labeling and Nutrition Labeling between Employees and Non-employees in the Frozen Food Industry (냉동 가공 식품, 식품 표시 및 영양 표시에 대한 냉동 식품 산업 종사자와 비종사자의 인식 차이 조사 연구)

  • Lee, Min-Jin;Yoon, Ki-Sun
    • Journal of the East Asian Society of Dietary Life
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    • v.19 no.4
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    • pp.533-543
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    • 2009
  • The objective of this study was to compare the differences of opinion, purchasing behavior, and recognition of food labeling and nutrition labeling of frozen processed food between employees and non-employees in the frozen food industry. The results of this survey study showed that the group working in the frozen food industry had a positive opinion of frozen processed food compared to the non-employee group who was not working in the food industry. The main reason for the positive opinion of frozen processed food was because it was convenient and easy to prepare while the main concern with consuming frozen processed food was that it was bad for one's health. The most popular menu was western style. Sixty one percent of employees in the frozen food industry preferred the microwave-cooking method, while only 37.9% of non-employees preferred the microwave-cooking method followed by cooking in boiling water (27.6%). There was a significant (p<0.001) difference in the preference of cooking method between these two groups. Most of the respondents considered 'taste' as the most important factor and 32.9% of the respondents selected 'sanitation/health' as the most serious concern for the consumption of frozen processed food. Both groups checked the food & nutrition label to verify the expiration date and the presence of food additives. The non-employee group recognized the need for nutritional information on total calorie, carbohydrate, protein, fat, saturated fat, cholesterol, minerals, vitamins, sodium, and fiber on the nutrition label of frozen processed food.

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Production of Lard Based Biodiesel Using Ultrasound Assisted Trans-Esterification (초음파가 도입된 전이에스테르화 반응을 이용한 돈지원료 바이오디젤의 제조)

  • Cho, Hae-Jin;Lee, Seung-Bum;Lee, Jae-Dong
    • Applied Chemistry for Engineering
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    • v.22 no.2
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    • pp.155-160
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    • 2011
  • An animal fat is an attractive biodiesel energy source for its high stability against oxidation and low incomplete combustion ratio due to the high heating value and cetane value. However, it requires a refinery process because of the high content of saturated acid and impurity which increas the boiling point. In this study, the optimum biodiesel synthetic process of lard is suggested. Indeed, we demonstrate new biodiesel production processes to alter conventional process of heating and mixing by applying ultrasonic energy. While the optimum reaction temperature and mole ratio of methanol and lard, when using conventional mixing and heating process, were $55^{\circ}C$ and 12, respectively, the reaction time were reduced to 30 minutes by applying ultrasonic irradiation power of 500 W. The new process applying ultrasonic irradiation yielded synthetic biodiesel properties as followings: 3.34 cP of the viscosity, 37.0 MJ/kg of the caloric value and below 0.25 mgKOH/g of the acidic value, which satisfy biodiesel quality criteria.

Changes in Physicochemical Characteristics of Squid upon Acid and Heat Treatment (산 및 열처리에 따른 오징어의 이화학적 특성변화)

  • Lee, Hye-Young;Kim, Seong-Ho;Kim, Duk-Jin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.4
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    • pp.539-549
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    • 2012
  • In order to acquire basic data on the development of squid processing food, we investigated changes in the composition of boiled squid upon heat treatment ($100^{\circ}C$), acid treatment (acetic acid, 0~5%), and pre-boiling ($55^{\circ}C$, $80^{\circ}C$). The proximate composition of squid was 73~78% moisture and 19~24% crude protein, treatment with acid solution had a significant effect on the proximate composition of boiled squid (p<0.05). The major free sugars were ribose and glucose in all treatment samples. The $55^{\circ}C$ pre-boiled sample had lower levels of glucose than the other samples. The total free sugar content of the non-peeled sample was the highest, followed by the $80^{\circ}C$ pre-boiled sample, whereas the sugar content in the $55^{\circ}C$ pre-boiled sample was very low. With regards to amino acid content, proline was the highest in all samples, followed by taurine and histidine. Treatment with acid solution had a significant effect on the total free amino content of boiled squid (p<0.05). The total free amino acid content of the $55^{\circ}C$ pre-boiled sample was the highest, followed by the $80^{\circ}C$ pre-boiled sample and non-peeled sample. Inosine and related compounds were not detected in any of the samples, and the adenosine triphosphate (ATP) content was low. The hypoxanthine contents of the $55^{\circ}C$ and $80^{\circ}C$ pre-boiled samples were the highest, the adenosine monophosphate (AMP) and inosine monophosphate (IMP) contents were similar, and the IMP content of the non-peeled sample was higher than those of the peeled samples. The palmitic acid content was very high and constituted 40% of total saturated fatty acids. eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA) contents were also high and constituted 60% of total unsaturated fatty acids. Of these, DHA content was the highest, followed by palmitic acid and EPA, which accounted for about 85% of total fatty acids. No difference in fatty acid content was observed between acid treatment and pre-boiling. The mineral P content was the highest on average in all boiled squid samples, followed by K, Na, Mg, and Ca contents. In addition, the pre-boiling temperature and acid solution concentration had significant effects on the mineral content. Further, heavy metal, Cd, Pb, and As contents were detected only at trace amounts, and their levels were lower than standard and permissible amounts for food.