• Nuclear Engineering and Technology
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• v.28 no.4
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• pp.423-430
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• 1996

The improved and advanced Annulus Gas System(AGS) has been developed for Wolsong 2 to satisfy the requirements of the regulatory body. The Atomic Energy Control Board(AECB) required a shorter detection time following a small leak from a pressure tube and/or calandria tube. This paper describes licensing requirements, functional requirements and detail design description for the AGS. The Wolsong unit No. 1 AGS was designed to operate as a stagnant system normally requiring only pressure regulation and having provisions for purging. no improved AGS involves the adoption of gas recirculation in AGS, duplication of dew point indicators with additional instrumentation and sampling provisions to prompt operator action. The improved system operates in the recirculation mode with continuous dew point measurement for leak detection. An AGS with improved detection instrumentation is provided.

• Bulletin of the Korean Chemical Society
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• v.34 no.6
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• pp.1703-1707
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• 2013

A fast and simple sampling and sample preparation device, (NTD) has been developed and applied to sample and analyze volatile components from ground coffee beans. Coffee fragrances and other volatile organic compounds (VOCs) were sampled by the NTD and then analyzed by gas chromatograph-mass spectrometry (GC/MS). Divinylbenzene (DVB) particles (80/100 mesh size) were the sorbent bed of the NTD. More than 150 volatile components were first identified based on the database of the mass library and then finally 30 fragrances including caffeine were further confirmed by comparing experimental retention indices (i.e. Kovat index) with literature retention indices. Total sampling time was 10 minutes and no extra solvent extraction and/or reconstitution step need. Straight n-alkanes (C6-C20) were used as retention index probes for the calculation of experimental retention indices. In addition, this report suggests that an empty needle can be an alternative platform for analyzing polymers by pyrolysis-GC/MS.

• International Journal of Safety
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• v.3 no.1
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• pp.27-31
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• 2004

Some of the petroleum products contain benzene which is well known as a confirmed human carcinogen. For example, gasoline products contain benzene ranging up to several percents by weight. High exposures to the benzene and other organic solvents would be likely to occur during intermittent tasks and or processes rather than continuous jobs such as sampling, repair, inspection, and loading/unloading jobs. The work time for these jobs is various. However, most of work time is very short and the representative time interval is 15 minutes. Thus, it is preferable to do exposure assessment for 15 minute time weighted average which is known as a short time exposure level(STEL) by ACGIH rather than for 8-hours TWA. It is particularly significant to the exposure monitoring for benzene since it has been known that the exposure rate plays an important role to provoke the leukemia. Due to the large variations, a number of processes/tasks, the traditional sampling technique for organic solvents with the use of the charcoal and sampling pumps is not appropriate. Limited number of samples can be obtained due to the shortage of sampling pumps. Passive samplers can eliminate these limitations. However, low sampling rates resulted in collection of small amount of the target analysts in the passive samplers. This is originated the nature of passive samplers. Field applications were made with use of passive samplers to compare with the charcoal tube methods for 15 minutes. Gasoline loading processes to the tank lorry trucks at the loading stations in the petroleum products storage area. Good agreements between the results of passive samplers and those of the charcoal tubes were achieved. However, it was found that special cautions were necessary during the analysis at very low concentration levels.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2007.10a
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• pp.374-375
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• 2007

• Journal of Korean Society for Atmospheric Environment
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• v.30 no.6
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• pp.586-599
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• 2014

During the last two decades, indoor air quality and volatile organic compounds (VOCs) have been of concern in Korean society due to their nature of potential health impacts. In order to investigate the pollution levels of VOCss in indoor environments, establishment of a solid test method for monitoring the airborne VOCss is essential. In Korea, a method based on adsorbent sampling and GC analysis coupled with thermal desorption was proclaimed as the Korea Standard Method for Indoor Air Quality Test. This study was carried out to examine some inherent problems of the VOCs measurement method. The VOCs method does not describe in detail preparing the standard samples. The standard samples may be prepared by impregnation of either liquid standard solutions or a mixture of standard gases. In this study, we investigated the optimal temperature condition for transferring the liquid standards onto a standard adsorbent tube. As a result, keeping the impregnation temperature at $250^{\circ}C$ will be recommended in regard of the boiling points of multiple target analytes and the thermal stability of the adsorbent. We also demonstrated some problems associated with handling of a syringe used for transferring the standard solutions onto the adsorbent tubes, and a best way to get rid of the syringe problems was suggested. Finally, a number of field works were conducted to evaluate the performance of adsorbent sampling methods. Comparison of different adsorbent tubes, i.e. tube packed with single sorbent (Tenax) and double sorbents (Tenax with Carbotrap), revealed that 30 to 40% differences between the two groups, implying that sampling efficiency is depending on the volatility and the strength of adsorbents. However, duplicate precisions for VOCs sampling with a same type of adsorbent and at same flow rates appeared to be satisfactory to be all within 20%, which is a quality control guideline. Distributed volume precisions were also found to be within a guideline value, 25%, although the precision was in general inferior to the duplicate precision. The Korea indoor VOCs test method should be more refined and improved in many aspects, particularly procedure and instrumentation for preparing the standard samples and specification of quality control assessment.

• Analytical Science and Technology
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• v.25 no.2
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• pp.91-101
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• 2012

A list of volatile fatty acids (VFA) including propionic acid, butyric acid, isovaleric acid, valeric acid, etc. is well known for offensive odorants. The analysis of odorant VFA is a highly delicate task due to high reactivity and unstable recovery rate. At present, analytical methods of VFA are recommended to include alkali impregnation filter method and alkali absorption method by the malodor prevention law of the Korea Ministry of Environment (KMOE). In this review, a survey has been made to explore various approaches available for the analysis of VFA to include both official methods of the KMOE and others. In light of the unreliability of those established analytical methods, it is highly desirable to develop some substituting methods for VFA. Among such options, one may consider such option as sorbent tube (ST) sampling and cryogenic trapping-thermal desorption technique. Moreover, procedures used for standard preparation, sampling steps, and instrumental detection stage are also evaluated. Application of container sampling (like Tedlar bag) is however not recommendable due to significant (sorptive) loss in sampling and in storage stage. In the detection stage, the use of GC/MS is recommendable to replace GC/FID due to the presence of diverse interfering substances. Thus, it is essential to properly establish the basic quality assurance (QA) for VFA analysis in air.

• Journal of the Korean GEO-environmental Society
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• v.9 no.3
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• pp.29-34
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• 2008

A large diameter sampler was developed to take undisturbed samples from not only soft ground but also sandy and weathered ground. The large diameter sampler which was developed in Korea Institute of Construction Technology(KICT-type large diameter sampler) was manufactured based on the principle of triple core barrel sampling. A specially designed cutting device was used to cut and contain various kinds of samples in the sampler during a sampling and retrieval procedure. By adjusting the stiffness of the spring located at the top of the sampler, the distance between the cutting shoe and auger can be controlled in accordance with the ground condition. In order to investigate the applicability of the developed sampler and compare the quality of the samples taken by the sampler with that by the traditional thin-walled tube sampler, samples were taken at various sites according to the ground condition. And a series of laboratory tests such as the unconfined compress ion test, triaxial compression test, oedometer test, large diameter Rowe cell consolidation test (D: 150 mm) were performed. The test results showed that the samples by the KICT-type large diameter sampler show higher quality than the samples by the thin-walled tube sampler. And the validity and applicability of the developed KICT-type large diameter sampler was confirmed accordingly.

• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1338-1348
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• 2019

The Geomunoreum Lava Tube System, declared as a UNESCO World Heritage Site, has a unique natural ecosystem. The information available about this ecosystem, which contains lava caves with secondary carbonate speleothems, is sparse. Hence, extensive research is warranted for establishing a conservation standard. We commenced microbial research on the system and have been studying the microorganisms coating the lava tube wall to acquire fundamental information for understanding the lava cave ecology of Jeju Island. Samples were collected from yellow-colored walls in six caves that are part of the system-the Bengdwi, Utsanjeon, Bukoreum, Manjang, Gimnyeong, and Yongcheon caves. This study focused on yellow walls as it is the most easily distinguished color. According to previous studies, the color of cave walls is attributed to microorganisms or their components. To determine whether the yellow mats from the Jeju lava tube walls are caused by microorganisms, we examined samples at the microscopic scale, by staining mats and analyzing bacterial isolates from glitter particles. As a result, we found that the yellow walls of lava tubes are comprised of microbial mats.

• Journal of the Korean Society for Nondestructive Testing
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• v.30 no.4
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• pp.302-310
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• 2010

In this paper, we studied Bagging neural network for predicting defect size of steam generator(SG) tube in nuclear power plant. Bagging is a method for creating an ensemble of estimator based on bootstrap sampling. For predicting defect size of SG tube, we first generated eddy current testing signals for 4 defect patterns of SG tube with various widths and depths. Then, we constructed single neural network(SNN) and Bagging neural network(BNN) to estimate width and depth of each defect. The estimation performance of SNN and BNN were measured by means of peak error. According to our experiment result, average peak error of SNN and BNN for estimating defect depth were 0.117 and 0.089mm, respectively. Also, in the case of estimating defect width, average peak error of SNN and BNN were 0.494 and 0.306mm, respectively. This shows that the estimation performance of BNN is superior to that of SNN.

• Particle and aerosol research
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• v.15 no.3
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• pp.105-113
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• 2019

The exhaust emissions from coal-fired power plants have received much attention because coal-fired power plants are the one of the largest sources of particulate matter (PM) emissions in South Korea. To measure the PM10 and PM2.5, we developed the novel diluter which is comprised of ejector and porous tube in series. The dilution ratio must be defined to calculate particle concentrations of the sampled air as well as to probe match for the isokinetic sampling. For this reason, we verified the dilution ratio of the developed diluter by the flow rate, numerical solution, gas concentration and particle concentration. The ejector-supplied flow rates were 10-50 L/min and the porous tube-supplied flow rates were 30, 50 L/min in this study. All methods above showed similar dilution ratios to each other within 10 % error rate. The dilution ratio was confirmed by comparing mass concentrations before and after the dilution process.