• Korean Journal of Optics and Photonics
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• v.15 no.1
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• pp.63-67
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• 2004

We have obtained optical constants for cholesteric liquid crystal (CLC) films by fitting theoretical spectra of transmittance and reflectance with measured ones. Berreman's 4${\times}$4 matrix approach was used for the calculation of theoretical spectra. The fitting method was applied to three samples with different reflection bands and fitted results of refractive indices for CLC samples were compared with measured ones for a parallel-aligned LC sample. It was found that the two results were in fairly good agreement within the error of the fitted results for the three CLC samples.

• Journal of the Korean Society of Tobacco Science
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• v.36 no.1
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• pp.12-19
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• 2014

A matrix solid-phase dispersion (MSPD) method was developed for extracting and cleaning-up the selected agrochemicals in tobacco using gas chromatography-mass spectrometry with selected ion monitoring (GC/MS-SIM). Different parameters of the method were investigated and optimized, such as the type of solid-phase (alumina, $C_{18}$ and Florisil) and eluent (acetone, acetonitrile, ethylacetate and n-hexane). The best results were obtained using 0.5 g of tobacco sample, 1.0 g of $C_{18}$ as dispersant sorbent, 1.0 g of Florisil as clean-up sorbent and acetonitile saturated with n-hexane as eluting solvent. The method was validated using tobacco samples fortified with agrochemicals at their different concentration levels. This method gave good linearity for the selected agrochemicals of ranging from $0.01{\mu}g/mL$ to $0.1{\mu}g/mL$. Recoveries of the selected agrochemicals in tobacco were more than 80 % and reproducibilities were found to be better than 10 % RSD. Those results suggested that the analytical procedure including MSPD method in combining with GC/MS could be applicable to the rapid determination often the selected agrochemicals in tobacco.

• Proceedings of the KIEE Conference
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• 1989.07a
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• pp.202-206
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• 1989

A new algorithm is suggested to solve the optimal reactive power control(optimal VAR control) problem. An efficient computer program based on the latest achievements in the sparse matrix/vector techniques has been developed for this purpose. The model minimizes the real power losses in the system. The constraints include the reactive power limits of the generators, limits on the bus voltages and the operating limits of control variables- the transformer tap positions, generator terminal voltages and switchable reactive power sources. The method developed herein employs linearized sensitivity relationships of power systems to establish both the objective function for minimizing the system losses and the system performance sensitivities relating dependent and control variables. The algorithm consists of two modules, i.e. the Q-V module for reactive power-voltage control, Load flow module for computational error adjustments. In particular, the acceleration factor technique is introduced to enhance the convergence property in Q-module, The combined use of the afore-mentioned two modules ensures more effective and efficient solutions for optimal reactive power dispatch problems. Results of the application of the method to the sample system and other worst-case system demonstrated that the algorithm suggested herein is compared favourably with conventional ones in terms of computation accuracy and convergence characteristics.

• The Korean Journal of Ceramics
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• v.5 no.3
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• pp.278-283
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• 1999

Formaldehyde has widely been used for the cross-linking of polyvinyl alcohol polyvinyl alcohol polymer. The effects of formaldehyde on the water resistance of MDF cement composites were investigated as a function of types of catalyst, base or acid, and the amount of formaldehyde. The acetalization, reaction of OH group of PVA with aldehyde, was ended incompletely under base atmosphere. However, by addition of citric acid, the cross-linking of PVA polymer could be acheved through acetalization of PVA and formaldehyde. The effects of these different patterne according to the types of catalyst on the water resistance of MDF cement were studied by the preparation of PVA films and MDF composites. Thanks to the cross-linking reaction of PVA polymer chains by formaldehyde, the modified PVA films and MDF composites showed a good water-resistant propety. The modified MDF cement composite to which 3 wt% formaldehyde and 1 wt% cirtic acid were added showed 80% of initial flexural strength and good interfacial state between cement grain and polymer matrix. However, 4 wt% formaldehyde deteriorted the processing conditions, microstructures and eventually the flexural strength, causing sharp increase in the viscosity of sample dough during the mixing process. To study the relatins of flexural strength and interface of cement grain and polymer matrix, SEM and MIP measurement were performed.

• Journal of the Korean Ceramic Society
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• v.33 no.5
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• pp.536-546
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• 1996

The TiC-Ni/Al reaction-bonding composites were prepared by the infiltration of Ni/Al melt into the TiC preforms. The microstructure the reaction composition crystalline phase and the mechanical properties of the composites were investigated. During the reaction-bonding Ni/Al mixture had a good wettability and per-meability with TiC preform and pore-free and fully dense sintered bodies were produced. In the case of the Ni/Al atomic ratio of 0.3 and 0.5 TiC raw particle shape was changed to irregular particles because of the decomposition in the liquid matrix and its phenomena was more distinguished in the Al-rich liquid matrix. With increasing more than 1 of the Ni/Al atomic ratio the sample of TiC grain shape was changed from spherical to palatelet particles. Also with increasing the atomic ratio of Ni/Al bending strength and fracture spherical to palatelet particles. Also with increasing the atomic ratio of Ni/Al bending strength and fracture toughness were increased and its maximum value was 1073 MPa and 11 MPa.m1/2 respectively.

• ETRI Journal
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• v.31 no.4
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• pp.438-447
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• 2009

In this paper, a novel image projection technique for face recognition application is proposed which is based on linear discriminant analysis (LDA) combined with the relevance-weighted (RW) method. The projection is performed through 2-directional and 2-dimensional LDA, or $(2D)^2$LDA, which simultaneously works in row and column directions to solve the small sample size problem. Moreover, a weighted discriminant hyperplane is used in the between-class scatter matrix, and an RW method is used in the within-class scatter matrix to weigh the information to resolve confusable data in these classes. This technique is called the relevance-weighted $(2D)^2$LDA, or RW$(2D)^2$LDA, which is used for a more accurate discriminant decision than that produced by the conventional LDA or 2DLDA. The proposed technique has been successfully tested on four face databases. Experimental results indicate that the proposed RW$(2D)^2$LDA algorithm is more computationally efficient than the conventional algorithms because it has fewer features and faster times. It can also improve performance and has a maximum recognition rate of over 97%.

• Bulletin of the Korean Chemical Society
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• v.32 no.2
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• pp.477-482
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• 2011

The structural analysis of polytrimethylene terephthalate (PTT) and characterization of the hydrolytic degradation products after acid hydrolysis were performed using MALDI-TOF mass spectrometry. Mass spectra of the PTT samples were analyzed using a self-calibration method as well as an internal calibration method with standard materials of known masses. PTT structures constituting the samples were determined from the analyses of the spectra, and their relative compositions were estimated. The MALDI-TOF mass spectra of the acid-hydrolyzed PTT sample showed three main series of oligomer products with different end groups in accordance with the hydrolysis schemes. From the spectra of both $Na^+$ and $K^+$ adducts, it was concluded that the PTT samples have higher affinity for $Na^+$ compared with $K^+$ and therefore show higher ionization efficiency with sodium ions when dithranol is used as a matrix. Two different wavelength laser beams ($\lambda$ = 337 nm and 355 nm) were tested and it was observed that the 355 nm beam was more efficient in obtaining the MALDI spectra of PTT using dithranol as a matrix under our experimental conditions.

• 한국초전도학회:학술대회논문집
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• v.10
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• pp.230-235
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• 2000

The extrusion process for long-length multi-filaments of BSCCO 2223 superconductor tape has been investigated with aids of Finite Element Method and experimental inspection. Since the arrangement of filaments in matrix material has characteristic of rotational symmetry, a 2-dimensional commercial FEM package, DEFORM-2D, was adopted to simulate extrusion process with different variables such as hardness of sheath material, lengths of each filament and arrangement. From the FEM analysis, since the inner filaments move faster than the outer one, distribution of filaments is needed to be optimized. In the case of pure Ag matrix, undesirable non-uniform distribution of filament was obtained due to low hardness of sheath material. Dummy sample(brass (sheath) and talc powder(filament)), however, which has relatively high hardness of sheath material, had been produced with desirable results. Therefore, it is necessary to optimize hardness of sheath material, extrusion temperature and billet design.

• Journal of Korea Foundry Society
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• v.16 no.2
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• pp.141-148
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• 1996

In high chromium cast iron, the control of matrix microstructure as well as carbide structure is important to the performance as a wear resistant material. In this study, 3.0% C-24.0% Cr white cast irons with various molybdenum contents(residual, 1.0%, 3.0% and 5.0%) were solidified conventionally and unidirectionally for studying their effects on the microstructure and hardness. In the conventional casting, two sets of castings were poured from each melt. One set of the castings consisted of cylindrical bars of 10 and 20mm by 155mm long. The second set of the castings was a cylindrical bar of 30mm by 200mm long. On the other hand, a pep-set mold set on the Cu plate was employed to make the solidification unidirectionally. X-ray diffraction method was used to observe retained austenite and carbides in the high chromium cast iron. The morphology of eutectic $M_7C_3$ carbides changed from needle-like type to nodular type with the increase of Mo content. And, the presence of $M_2C$ carbides was identified in the sample where Mo was added over 3.0 %. Primary and eutectic carbides appeared as rod type and corngrain type, respectively in the unidirectionally solidified samples which were cut to parallel to the solidification direction. In the EDX analysis, Cr concentration was higher in the primary and eutectic $M_7C_3$ carbides, Mo in the $M_2C$ carbides, and Fe in the matrix.

• Mass Spectrometry Letters
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• v.2 no.2
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• pp.53-56
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• 2011

[ $C_8$ ]functionalized magnetic nanoparticles were synthesized by coating magnetic $Fe_3O_4$ nanoparticles with silicaamine groups using 3-aminopropyltriethoxysilane and by subsequently modifying the amine groups with chloro(dimethyl)octylsilane to produce octyl groups on the surface of the MNPs. The $C_8$-functionalized MNPs were used to enrich peptides from tryptic protein digests of myoglobin and ${\alpha}$-casein. The enriched peptides were analyzed by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF-MS). MALDI-MS was also used to investigate desalting of the $C_8$-functionalized MNPs. Sample solutions were prepared in 1.0 M NaCl, and the successful removal of salt was observed. Enrichment with $C_8$-functionalized MNPs was very effective for separating and concentrating tryptic peptides.