• Bulletin of the Korean Chemical Society
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• v.9 no.3
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• pp.157-160
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• 1988

The rates of hydrolysis of N-(benzenesulfonyl) benzimidoyl chlorides (p-H, $p-CH_3,\;p-CH_3,\;p-NO_2\;and m-NO_2$) have been measured by UV spectrometry in 60% methanol-water at $25^{\circ}C$ and a rate equation which can be applied over wide pH range was obtained. Below pH 7.00, the substituent effect on the hydrolysis rate of N-(benzenesulfonyl) benzimidoyl chloride was found to conform to the Hammett ${\sigma}$ constant with ${\rho}$ = -0.91, whereas above pH 9.00, with ${\rho}$ = 0.94. On the basis of the rate equation obtained and the effect of solvent, substituents and salt, the following reaction mechanism were proposed; below pH 7.00, the hydrolysis of N-(benzenesulfonyl) benzimidoyl chloride proceeds by $S_N1$ mechanism, however, above pH 9.00, the hydrolysis is initiated by the attack of the hydroxide ion and in the range of pH 7.00-9.00, these two reactions occur competitively.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.115-116
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• 2022

Large concrete mass members are commonly used as matte bases for skyscrapers. In general, Integral casting is preferred to secure construction convenience and durability quality rather than separate casting. However, there is a possibility that cracks may occur in the early stages due to the generation of a lot of hydration heat, and thus durability will decrease, so it is necessary to determine an appropriate mixture and verify it through experiments. The purpose of the study was to conduct a review on the durability of the optimal high-performance low-heating concrete combination derived through the experiment and to conduct a review analysis on the performance satisfaction and performance expression mechanism.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.199-200
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• 2023

Eco-friendly concrete contains only 5% of cement yet achieves equal or greater strength compared to conventional concrete, reducing salt-attack impact and hydration heat by more than 30% and ensuring higher construction quality for underground structures. Furthermore, eco-friendly concrete can reduce up to 90% of carbon dioxide emissions compared to traditional concrete, enabling a reduction of approximately 6,000 tons of carbon emissions for 1,000 of apartment units construction. This is equivalent to planting around 42,000 trees

• Journal of the Korea Concrete Institute
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• v.15 no.3
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• pp.400-408
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• 2003

Chloride ion inside concrete destroys the so-called passive film surrounding reinforcing bars inside concrete so that the so-called salt attack accelerates corrosion which is the most critical factor for durability as well as structural safety of reinforced concrete structures. Recently, as a solution of the salt attack, the ground granulated blast-furnace slag(GGBFS) have been used as binder or blended cement more extensively. In this paper, characteristics of chloride ion diffusion for the GGBFS concrete, which is known to possess better resistance to damage due to the chloride ion penetration than ordinary portland cement(OPC) concrete possesses, are analyzed and a chloride ion diffusion model for the GGBFS concrete is proposed by modifying an existing diffusion model for the OPC concrete. The proposed model is verified by comparing diffusion analysis results using the model accelerated chloride penetration test results for concrete specimens as well as field test results for an RC bridge pier. Then, an optimal resistance condition to chloride penetration for the GGBFS concrete is obtained according to degrees of fineness and replacement ratios of the GGBFS concrete. The result shows that the GGBFS concrete has better resistance to chloride ion penetration than OPC concrete has and the resistance is more affected by the replacement ratio than the degree of fineness of the GGBFS.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.43 no.5
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• pp.611-619
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• 2023

The first survey of the airborne chlorides along the nationwide coast of South Korea was conducted 18 years ago, and the area index of coastal airborne chlorides and salt attack environmental rating are being utilized in the design, construction, and maintenance of domestic structures. However, due to environmental changessuch as climate change and coastal topography changes, changes of airborne chlorides along the coast are expected to occurregionally and by sea area. Therefore, the second survey has been conducted since 2021. Inthis paper, we analyzed the seasonal variations of airborne chlorides along the coast by region and sea area for one year of the second survey. Additionally, we compared the results withthe survey results of Japan's coastal airborne chlorides, which islocated close to South Korea and has a similar climate, to increase the objectivityofthe analysis. The averageairborne chloridesin the second surveywas highest on the west coast, and the seasonal variation was also the largest on the west coast. Looking at the seasonal variations by sea area, the East Sea had highairborne chloridesinthe summer and autumn,theWestSea inthe autumnandwinter, and the SouthSea in the summer. In addition, compared to the firstsurvey, allsea areasshowed short periods ofsignificantly higher coastalsalinity and clearerseasonal variations.

• Advances in aircraft and spacecraft science
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• v.4 no.1
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• pp.37-52
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• 2017

Gas turbines operating in dusty or sandy environment polluted with micron-sized solid particles are highly prone to blade surface erosion damage in compressor stages and molten sand attack in the hot-sections of turbine stages. Commercial/Military fixed-wing aircraft engines and helicopter engines often have to operate over sandy terrains in the middle eastern countries or in volcanic zones; on the other hand gas turbines in marine applications are subjected to salt spray, while the coal-burning industrial power generation turbines are subjected to fly-ash. The presence of solid particles in the working fluid medium has an adverse effect on the durability of these engines as well as performance. Typical turbine blade damages include blade coating wear, sand glazing, Calcia-Magnesia-Alumina-Silicate (CMAS) attack, oxidation, plugged cooling holes, all of which can cause rapid performance deterioration including loss of aircraft. The focus of this research work is to simulate particle-surface kinetic interaction on typical turbomachinery material targets using non-linear dynamic impact analysis. The objective of this research is to understand the interfacial kinetic behaviors that can provide insights into the physics of particle interactions and to enable leap ahead technologies in material choices and to develop sand-phobic thermal barrier coatings for turbine blades. This paper outlines the research efforts at the U.S Army Research Laboratory to come up with novel turbine blade multifunctional protective coatings that are sand-phobic, sand impact wear resistant, as well as have very low thermal conductivity for improved performance of future gas turbine engines. The research scope includes development of protective coatings for both nickel-based super alloys and ceramic matrix composites.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2008.11a
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• pp.227-233
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• 2008

Porous concrete has large continuous voids of 20-30 % by volume, and this concrete is attractive as environmental material in Japan i.e. permeable road pavement, river bank protection with vegetation and green roof system which influence thermal environment. It is necessary to confirm the frost resistance when constructing porous concrete structure in cold region. However applicable test method and evaluation criterion of porous concrete has not defined yet. Therefore, the object of this study is to investigate the frost resistance of porous concrete and this investigation attempts to address this concern by comparing 4 kinds of specified freezing and thawing tests methods (JIS A1148 procedure A/B and RILEM CIF/CDF test) in consideration of actual environment. RILEM freeze-thaw tests are different from JIS A1148 freeze-thaw tests, which are widely adopted for evaluating the frost resistance of conventional concrete in Japan, in water absorption, cooling rate, length of freezing and thawing period, and number of freezing and thawing cycles. RILEM CIF test measures internal damage and is primarily applicable for pure frost attack. CDF test is appropriate for freeze-thaw and de-icing salt attack. JIS A1148 procedure A/B showed extremely low frost resistance of porous concrete if the large continuous voids were filled with water and the ice expansion in the large continuous voids set in during cooling. Frost resistance of porous concrete was improved by mixing coarse aggregate (G7) which particle size is smaller and fine aggregate in JIS freezing and thawing tests. RILEM CIF/CDF test showed that freeze-thaw and de-icing resistance of porous concrete was seems to be superior in that of conventional concrete.

• Journal of the Korea Concrete Institute
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• v.14 no.3
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• pp.409-419
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• 2002

Nowadays, antiwashout underwater concrete is widely used for constructing underwater concrete structures but they, especially placed in marine environment, can be easily attacked by chemical ions such as SO$\^$2-/$\_$4/ Cl$\^$-/ and Mg$\^$2＋/, so the quality and capability of concrete structures go down. In this paper, to solve and improve those matters, flyash and GGBFS(ground granulated blast furnace slag) were used as partial replacements for ordinary portland cement. As results of experiments for fundamental properties of antiwashout underwater concrete containing 10, 20, 30％ of flyash and 40, 50, 60 ％ of GGBFS respectively, setting time, air contents, suspended solids and pH value were satisfied with the "Standard Specification of Antiwashout Admixtures for Concrete" prescribed by KSCE, and also slump flow, efflux time and elevation of head were more improved than that of control concrete. From the compressive strength test, it was revealed that the antiwashout underwater concrete containing mineral admixtures(flyash and GGBFS) is more effective for long term compressive strength than control concrete. An attempt to know how durable when they are under chemical attack has also been done by immersing in chemical solutions that were x2 artificial seawater, 5 ％ sulphuric acid solution, 10％, sodium sulfate solution and 10％ calcium chloride solution. After immersion test for 91days, XRD analysis was carried out to investigate the reactants between cement hydrates and chemical ions and some crystalline such as gypsum ettringite and Fridel′s salt were confirmed.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.5
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• pp.3587-3595
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• 2015

Low-carbon eco-friendly precast concrete (PC) box structure has been recently was developed as an low-cost infrastructure of near-surface transit system. The concrete of PC box was manufactured by industrial byproducts such as ground granulated blast furnace (GGBF) slag, flyash and rapid-cooling electric arc furnace (EAF) oxidizing slag, its mechanical property and durability were estimated in this study. Based on the mechanical and durability tests, it is found that low-carbon eco-friendly concrete shows high initial compressive strength, more than 90% of design strength (35MPa), and high resistance to salt-attack, chemical- attack and freeze-thaw. Therefore, low-carbon eco-friendly PC box concrete technology is expected to contribute to the railway with low environmental impact.

• Journal of Ocean Engineering and Technology
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• v.25 no.1
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• pp.32-38
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• 2011

Galvanized steel has gone through a chemical process to keep it from corroding. The steel gets coated in layers of zinc because rust will not attack this protective metal. For countless outdoor, marine, or industrial applications, galvanized steel is an essential fabrication component. The reduction of the corrosion rate of zinc is an important topic. In the past, a very popular way to reduce the corrosion rate of zinc was to use chemical conversion layers based on $Cr^{+6}$. However, a significant problem that has arisen is that the use of chromium salts is now restricted because of environmental protection legislation. Therefore, it is very important to develop new zinc surface treatments that are environmentally friendly to improve the corrosion resistance of zinc and adhesion with a final organic protective layer. In this study, a Urethane solution (only Urethane 20 wt.%; S-700) and an organic/inorganic solution with Si (Si polysilicate 10 wt.% + Urethane 10 wt.%; LRO-317) are used. Based on the salt spray test of 72 h, S-700 and LRO-317 had a superior effect for the corrosion resistance on EGI and HDGI, respectively.